Ch18 - Magnetic Materials

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材料类 期刊 IF

材料类 期刊 IF

IEEE JOURNAL OF QUANTUM IEEE量子电子学杂志 ELECTRONICS Mechanics of Materials Journal of Solid State Chemistry Journal of nanoparticle research CORROSION SCIENCE APPLIED PHYSICS EXPRESS 材料力学 固体化学 纳米颗粒研究 腐蚀科学
CHEMISTRY OF MATERIALS INTERNATIONAL MATERIALS REVIEWS Advances in Catalysis JOURNAL OF MATERIALS CHEMISTRY CARBON
材料化学 国际材料评论 先进催化 材料化学杂志 碳
0897-4756 0950-6608 0360-0564 0959-9428 0008-6223
1520-6106 0022-5096 0957-44Y
opt express Microscopy and Microanalysis CURR OPIN SOLID CURRENT OPINION IN SOLID 固态和材料科学的动 STATE & MATERIALS 态 ST M SCIENCE SCRIPTA MATER SCRIPTA MATERIALIA 材料快报 J PHYS CHEM A BIOMETALS ULTRAMICROSCOP Y MICROPOR MESOPOR MAT J EUR CERAM SOC COMPOS SCI TECHNOL CURR NANOSCI Journal of Physical Chemistry A BIOMETALS ULTRAMICROSCOPY Microporous and Mesoporous Materials JOURNAL OF THE EUROPEAN CERAMIC SOCIETY COMPOSITES SCIENCE AND TECHNOLOGY Current Nanoscience 物理化学杂志,A辑 生物金属 超显微术 多孔和类孔材料 欧洲陶瓷学会杂志 复合材料科学与技术 当代纳米科学 电化学界 固体离子 1431-9276 1359-0286 1359-6462 1089-5639 0966-0844 0304-3991 1387-1811 0955-2219 0266-3538 1573-4137 0013-4651 0167-2738 0018-9197 0167-6636 0022-4596 1388-0764 0010-938X

磁性生物炭材料的研究进展

磁性生物炭材料的研究进展

磁性生物炭材料的研究进展*周银1 张平1,2* 李四坤1 康莉会1 柯霆1 蔡君瀚1 高源伶1 张宏1,2(1.西北民族大学 化工学院 甘肃 7301242.甘肃省高校环境友好复合材料及生物质利用重点实验室 甘肃 730124)摘要:生物炭以其良好的理化性质,作为吸附剂被广泛应用于水污染处理。

将磁性物质负载到生物炭上制备磁性生物炭,赋予生物炭磁响应特性,能有效解决吸附剂回收难、损失大等问题。

磁性生物炭具有含碳量高、比表面积大、可磁分离等优良特性,已成为近年来的研究热点。

对磁性生物炭的制备方法、应用性能等方面进行了综述,并提出磁性生物炭的未来研究方向,以期为磁性生物炭材料的深化研究和应用提供参考。

关键词:生物炭;磁性;性能;复合材料;吸附中图分类号:T 文献标识码:AResearch Progress of Magnetic Biochar MaterialsZhou Yin 1, Zhang Ping 1, 2, Li Sikun 1, Kang Lihui 1, Ke Ting 1, Cai Junhan 1, Gao Yuanling 1, Zhang Hong 1, 2(1. College of Chemical Engineering, Northwest Minzu University, Gansu, 7301242. Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu Province,Gansu, 730124)Abstract :As an adsorbent, biochar has been widely used in water pollution treatment because of its good physical and chemical properties.The magnetic biochar was prepared by combining biochar with magnetic material, and biochar was endowed with the characteristics of magnetic response, which could effectively solve the problems of difficult recovery and easy loss of adsorbent. Magnetic biochar with high carbon content, large specific surface area, magnetic separation and other excellent properties, has become a hot research topic in recent years. The preparation methods and application properties of magnetic biochar were reviewed. The future research directions of magnetic biochar were put forward in order to provide reference for further research and application of magnetic biochar materials.Key words :biochar ;magnetic ;performance ;composite material ;adsorbent生物炭(biochar)也称生物质炭,一般是指农林废弃物等生物质原料在缺氧或无氧的条件下,经高温热裂解(<700℃)生成稳定的多孔富碳固态物质。

iec60404-5-amd1 FDIS331 2007e

iec60404-5-amd1 FDIS331 2007e

FINAL DRAFT INTERNATIONAL STANDARDINTERNATIONAL ELECTROTECHNICAL COMMISSION COMMISSION ÉLECTROTECHNIQUE INTERNATIONALE THIS DOCUMENT IS A DRAFT DISTRIBUTED FOR APPROVAL. IT MAY NOT BE REFERRED TO AS AN INTERNATIONAL STANDARD UNTIL PUBLISHED AS SUCH.IN ADDITION TO THEIR EVALUATION AS BEING ACCEPTABLE FOR INDUSTRIAL, TECHNOLOGICAL, COMMERCIAL AND USER PURPOSES, FINAL DRAFT INTERNATIONAL STANDARDS MAY ON OCCASION HAVE TO BE CONSIDERED IN THE LIGHT OF THEIR POTENTIAL TO BECOME STANDARDS TO WHICH REFERENCE MAY BE MADE IN NATIONAL REGULATIONS.CE DOCUMENT EST UN PROJET DIFFUSÉ POUR APPROBATION. IL NE PEUT ÊTRE CITÉ COMME NORME INTERNATIONALE AVANT SA PUBLICATION EN TANT QUE TELLE.OUTRE LE FAIT D'ÊTRE EXAMINÉS POUR ÉTABLIR S'ILS SONT ACCEPTABLES À DES FINS INDUSTRIELLES, TECHNOLOGIQUES ET COMMERCIALES, AINSI QUE DU POINT DE VUE DES UTILISATEURS, LES PROJETS FINAUX DE NORMES INTERNATIONALES DOIVENT PARFOIS ÊTRE EXAMINÉS EN VUE DE LEUR POSSIBILITÉ DE DEVENIR DES NORMES POUVANT SERVIR DE RÉFÉRENCE DANS LES RÈGLEMENTATIONS NATIONALES.TitleAmendment 1 to IEC 60404-5 Ed. 2.0: Magnetic materials - Part 5: Permanent magnet (magnetically hard) materials - Methods of measurement of magnetic propertiesTitreAmendement 1 à la CEI 60404-5 Ed. 2.0: Matériaux magnétiques - Partie 5: Aimants permanents (magnétiques durs) - Méthodes de mesure des propriétés magnétiquesCopyright © 2006 International Electrotechnical Commission, IEC. All rights reserved. It is permitted to download this electronic file, to make a copy and to print out the content for the sole purpose of preparing National Committee positions. You may not copy or "mirror" the file or printed version of the document, or any part of it, for any other purpose without permission in writing from IEC.FORM FDIS (IEC)/FORMULAIRE FDIS (CEI) 2002-08-08FOREWORDThis amendment has been prepared by IEC technical committee 68: Magnetic alloys and steels. The text of this amendment is based on the following documents:FDIS Report on voting68/XX/FDIS 68/XX/RVDFull information on the voting for the approval of this amendment can be found in the report on voting indicated in the above table.The committee has decided that the contents of this amendment and the base publication will remain unchanged until the maintenance result date1) indicated on the IEC web site under "http://webstore.iec.ch" in the data related to the specific publication. At this date, the publication will be• reconfirmed,• withdrawn,• replaced by a revised edition, or• amended._____________Page 3CONTENTSAdd the following line at the end:Annex B (informative) Influence of the ambient temperature on measurement resultsPage 91.2 Normative referencesThe following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.Delete the dates to the 4 dated references.___________1)The National Committees are requested to note that for this publication the maintenance result date is 2012.Page 198 Determination of the demagnetization curveInsert at the end of the first sentence of the 3rd paragraph:“(see Annex B)”and after the 3rd paragraph the following note:“NOTE For the methods of (non-normative) measurements at elevated temperatures, see IEC 61807”.8.1 Principle of determination of the demagnetization curve, test specimen magnetizedin the electromagnetAdd at the end of the first paragraph:“(see Figure 2)”Page 218.2 Principle of determination of the demagnetization curve, test specimen magnetizedin a superconducting coil or pulse magnetizerAdd the following sentence at the end of the first paragraph:“The magnetic field strength required for saturation depends on the type of the magnetic material of the test specimen and on its coercivity.”Insert the following note after the 4th paragraph:“NOTE The magnetic field strength obtainable using an electromagnet may not be sufficient to measure very high values of the coercivity related to the magnetic polarization, H cJ. In such a case, the measurement can be carried out using other methods such as a superconducting coil or the pulse field method (see IEC 62331). These methods are, however, not normative.”9.2 (BH)max productOn page 23, at the end of a), replace “(see figure 2)” with:“(see Figure 3)”9.4 Determination of the recoil line and the recoil permeabilityIn the first sentence, replace “(Figure 3)” with:“(Figure 4)”Pages 26 and 27Insert the following new Figure 2 after Figure 1.Renumber the existing Figures 2 and 3 as Figures 3 and 4.H probeKeyH H measuring equipment E power supply to magnetize the specimen B B measuring equipment S switchingequipment(J J measuring equipment)equipmentR X-YrecordingFigure 2 – Measuring circuitPage 29Annex AAdd the following last line to the “table” above Figure A.1:(Material d / l)0,005”“REFeB340/130Add the following new Annex B:Annex B(informative)Influence of the ambient temperatureon measurement resultsTable B.1 shows the temperature coefficients of B r and H cJ of various kinds of permanent magnet materials.Table B.1 – Temperature coefficients of B r and H cJ of permanent magnet materials Material α(B r) %/℃α(H cJ) %/℃AlNiCo CrFeCo FeCoVCr RECo REFeB Hard ferrites –0,02–0,05 to –0,03–0,01–0,04 to –0,03–0,12 to –0,09–0,2–0,07 to +0,03–0,04–0–0,3 to –0,25–0,6 to –0,450,20 to 0,50The ambient temperature recommended in this standard is (23 ± 5) °C. This temperature range is considered to be adequate in the case of AlNiCo, CrFeCo and FeCoVCr permanent magnet materials because the absolute value of temperature coefficient of H cJ of these materials is smaller than 0,1 %/°C.However, in the case of temperature sensitive magnet materials such as REFeB and hard ferrites, the temperature variation within the range of ±5 °C may change measurement results considerably. For example, in the case of REFeB 240/200, the difference of measured H cJ values between 18 °C (the lowest temperature in the range) and 28 °C (the highest temperature in the range) measurements is estimated to be 100 kA/m supposing that its H cJ is 2000 kA/m and the temperature coefficient of H cJ is –0,50 %/°C.When measuring magnet materials which are sensitive to temperature, it is recommended that the ambient temperature is controlled within ±1 °C.Add the following new Bibliography:BibliographyIEC 61807, Magnetic properties of magnetically hard materials at elevated temperatures – Methods of measurementIEC 62331, Pulsed field magnetometry___________ISBN 2-8318-XXXX-XTypeset and printed by the IEC Central OfficeGENEVA, SWITZERLAND。

TAT肽—阿霉素磁性脂质体的制备及初步实验研究

TAT肽—阿霉素磁性脂质体的制备及初步实验研究

2013届硕士研究生学位论文TAT肽-阿霉素磁性脂质体的制备及初步实验研究PREPARATION AND INITIAL INVESTIGATION OFTAT-DOXORUBICIN MAGNETIC LIPOSOMES学科专业 药 剂 学研究方向 纳 米 药 物导 师 徐维平 教授研 究 生 黄向华论文完成单位安徽中医药大学2013年5月•合肥目录中文摘要 (1)Abstract (2)英文缩略词表 (4)前言 (6)第一章阿霉素脂质体体外分析方法的建立 (11)1.仪器与试药 (11)1.1仪器 (11)1.2试药 (11)2.方法与结果 (12)2.1含量测定方法学的建立 (12)2.1.1测定波长的确定 (12)2.1.2标准曲线的绘制 (12)2.1.3精密度试验 (13)2.1.4稳定性试验 (14)2.1.5回收率试验 (14)2.2包封率检测方法的建立 (15)2.2.1阿霉素脂质体制备预实验 (16)2.2.2总药量测定方法 (16)2.2.3游离药物测定方法 (16)3. 讨论与小结 (18)3.1讨论 (18)3.2小结 (18)第二章磁性阿霉素脂质体制备方法筛选及制备工艺的研究 (19)1.仪器与试药 (19)1.1仪器 (19)1.2试药 (19)2 实验方法与结果 (20)2.1 阿霉素脂质体制备处方和制备工艺筛选 (20)2.1.1脂质体制备方法的选择 (20)2.1.2 空白脂质体制备条件的优化 (21)2.1.3单因素考察脂质体的处方和工艺 (23)2.1.4 正交设计优化脂质体处方和工艺 (24)2.2磁性阿霉素脂质体的研制 (27)2.2.1 Fe3O4的制备 (27)2.2.2 TAT肽修饰磷脂 (28)2.2.3 TAT-阿霉素脂质体和TAT-Fe3O4阿霉素脂质体的制备 (28)3 讨论与小结 (29)3.1 讨论 (29)3.2小结 (31)第三章脂质体的理化性质和体外实验 (32)1 仪器与材料 (32)1.1仪器 (32)1.2试药 (33)1.3细胞株 (33)2 方法与结果 (34)2.1 脂质体理化性质的研究 (34)2.1.1形态观察 (34)2.1.2 粒径分布与zeta电位的测定 (34)2.1.3 包封率和含量的测定 (35)2.1.4 脂质体的稳定性 (37)2.2脂质体体外释放实验 (37)2.2.1阿霉素在PBS溶液中分析方法的建立 (37)2.2.2 样品释放度测定 (40)2.3脂质体体外细胞实验 (41)2.3.1细胞培养 (42)2.3.2 MTT实验方法 (43)2.3.3 细胞摄取实验 (43)2.3.4 细胞毒性实验 (44)2.3.5体外细胞抑制率实验 (45)3 讨论与小结 (47)3.1讨论 (47)3.2 小结 (48)第四章阿霉素脂质体在小鼠体内穿透血脑屏障研究 (49)1.材料与仪器 (49)1.1实验动物与材料 (49)1.2仪器设备 (49)2.实验方法与结果 (50)2.1实验动物分组 (50)2.2动物实验方法 (50)2.2.1游离阿霉素注射液的配制 (50)2.2.2阿霉素脂质体注射液的配制 (50)2.2.3 尾静脉注射剂量的确定 (50)2.2.4给药 (51)2.2.5组织样本收集 (51)2.3高效液相检测方法的建立 (51)2.3.1色谱条件 (51)2.3.2生物组织样品处理 (51)2.3.3方法专属性 (52)2.3.4脑组织标准曲线的建立 (52)2.3.5回收率的测定 (53)2.3.6精密度试验 (54)2.3.7稳定性试验 (55)2.4高效液相法测定组织中阿霉素含量 (55)2.5脑组织中铁含量的测定 (57)2.5.1组织样品处理 (57)2.5.2含量测定 (57)3讨论与小结 (57)3.1讨论 (57)3.2小结 (59)全文总结 (60)参考文献 (61)综述:脑靶向脂质体的研究进展 (66)作者简介 (75)攻读学位期间发表的学术论文目录 (76)致谢 (77)中文摘要目的:血脑屏障的存在使得大部分药物无法进入大脑,从而加大了中枢系统疾病的治疗难度。

二环己基-18-冠-6对锶的萃取

二环己基-18-冠-6对锶的萃取

YANG n — ig,W AN n s e g,M A n,PAN a — ig,TANG u h a Yo g qn J ~h n u Ya Xio bn Xi— u n,XI AO n Ya
No t r hwe tI tt eofN u l a c olgy,Xi a 00 s nsiut c e rTe hn o ’ n 71 24, Chna i
关 键 词 :二 环 己基 -8冠- ; ; 取 1- 6 锶 萃
中图 分 类 号 :0 1 . 2 6 4 6 文 献 标 识 码 :A
Ex r c i n o t o i m ih Diy l h x l 1 ・ o t a to fS r ntu W t c c o e y ・ ・ ・ 8 Cr wn。 - 6
l to s s u e u i n wa t did.The i fue e oft on e r to f DCH 8 n l nc he c c nt a i n o 1 C6,d fe e t a i ,d fe e t if r n cds if r n d l e t ,a d t o e r to t i cd wa x m i e . The r s t ho t tSr c n be iu n s n he c nc nt a i n ofnirca i se a n d e uls s w ha 。 a
文 章 编 号 : 2 39 5 ( o 7 O 一 2 4O O 5 — 9 O 2 o ) 4O O 一 6
二环 己基一8冠一 锶 的萃 取 1 一 6对
杨永青, 万俊生, 燕, 马 潘孝兵, 唐秀欢, 艳 肖
西 北 核技 术 研 究 所 , 西 西 安 陕 70 2 10 4

聚苯乙烯-丙烯酸磁性高分子微球的制备及性能

聚苯乙烯-丙烯酸磁性高分子微球的制备及性能

第25卷第7期高分子材料科学与工程Vol.25,No.7 2009年7月POL YM ER MA TERIAL S SCIENCE AND EN GIN EERIN GJ ul.2009聚(苯乙烯2丙烯酸)磁性高分子微球的制备及性能杨瑞成1,2,郧 栋1,穆元春1(1.兰州理工大学甘肃省有色金属新材料省部共建国家重点实验室;2.兰州理工大学有色金属合金省部共建教育部重点实验室,甘肃兰州730050)摘要:以苯乙烯为单体、丙烯酸为功能基单体、N ,N ′2亚甲基双丙烯酰胺为交联剂,加入自制的纳米Fe 3O 4磁流体,采用分散聚合的方法制备出聚(苯乙烯2丙烯酸)磁性高分子微球。

采用XRD 、FT 2IR 、SEM 、752N 型分光光度计和化学滴定法,对所制得的磁性高分子微球进行了表征及性能分析,研究了交联剂N ,N ′2亚甲基双丙烯酰胺的加入对其性能的影响。

结果表明,所制磁性微球粒径在017μm ~2m 之间,单分散性好;交联剂对微球性能有着明显的影响,随着交联剂的增加,微球粒径变小、粒径分布变宽、表面羧基含量增加、耐酸碱性增强,最佳含量应为单体用量的4%。

关键词:Fe 3O 4纳米微粒;磁性高分子微球;分散聚合;交联剂中图分类号:TB383 文献标识码:A 文章编号:100027555(2009)0720114204收稿日期:2008206204基金项目:甘肃省有色金属新材料省部共建国家重点实验室基金(SK L05011)通讯联系人:杨瑞成,主要从事材料微观结构与性能研究, E 2mail :yangruic @ 磁性高分子微球是指通过用适当的方法将纳米无机磁性粒子与高分子结合起来形成的具有一定磁性和特殊结构的复合材料[1,2]。

由于其既具有磁性又具有不同的功能性基团(-OH 、-COH 、-COOH 、-N H 2、-OH 等),因此在生物工程、有机与生化合成、分析化学、标准计量等方面都有着广泛的应用前景[3,4]。

材料期刊IF

材料期刊IF

先进功能材料 物理评论快报 表面科学进展
18 19 20 21 22
SMALL BIOMATERIALS ADV POLYM SCI MRS BULL CHEM COMMUN
small BIOMATERIALS ADVANCES IN POLYMER SCIENCE MRS BULLETIN Chemical Communications
合成金属 化学和工程资料杂志
80
J MAGN MAGN MATER
磁学与磁性材料杂志
81
SOLID STATE SCI
Solid State Sciences
固体科学
82
THIN SOLID FILMS
THIN SOLID FILMS
固体薄膜
83
SURF COAT TECH
SURFACE & COATINGS TECHNOLOGY
复合材料 A应用科学与制备
86
J BIOMATER APPL
JOURNAL OF BIOMATERIALS APPLICATIONS
生物材料应用杂志
87
J NUCL MATER
JOURNAL OF NUCLEAR MATERIALS
核材料杂志
88
MATER LETT
Materials Letters
材料快报
89
J INTEL MAT SYST STR
Journal of Intelligent Material Systems and Structures
智能材料系统与结构
90
J MATER SCI-MATER M
JOURNAL OF MATERIALS SCIENCEMATERIALS IN MEDICINE

“天问一号”成功发射背后的那些新材料

“天问一号”成功发射背后的那些新材料

料可展开梁和上海空间电源研究所研制的柔性太阳能薄膜电池。该系统基 于 复 合 材 料 力 学 理 论 、结构精
细化设计和形状记忆聚合物复合材料结构,可 以 实 现 柔 性 太阳能电池的锁紧、释 放 和 展 开 ,以及展开后高
刚度可承载等功能。 摘自《中国工业报社》2021-05-17
(编辑部)
[ 10 ] Lukin A A, Il"Yashenko E I, Skjeltorp A T, et al. Improvement of Thermal Stability of Nd-Tb-Fe-Co-B Sintered Magnets by Additions of Pr, Ho, Al, and Cu[J]. Physics Research Interna­ tional, 2012, 2012:70.
在火星上首次留下中国印迹,迈出了我国星际探测征程的重要一步。火 星 的 环 境 是 出 了 名 的 恶 劣 ,那 么 ,
在“天 问 一 号 ”探 测 器 成 功 发 射 的 背 后 ,有 哪 些 新 材 料 扮 演 了 重 要 角 色 ?
1. 超轻质蜂窝增强烧蚀防热材料密度更低防热效率更高
蜂 窝 增 强 轻 质 烧 蚀 防热材料是空间飞行器防热的一员“老 将 ”。“神舟 ”号 载 人 飞 船 、月地高速再入返
2. 连续纤维增强中密度防热材料兼顾耐烧蚀和承载能力
由于火星距离地球较远,为 使 运 载 火 箭 推 送 得 更 远 天 问 一 号 ”不 能 过 重 ,需要尽可能“压 榨 ”防热结
构及材料质量。除了超轻质峰窝增强低密度烧蚀防热材料,团队还研制了连续纤维增强中密度防热结构
一体化材料,既 能 满足结构要求,又具备轻质特点。

磁性纳米复合界面固定材料的致突变试验

磁性纳米复合界面固定材料的致突变试验

磁性纳米复合界面固定材料的致突变试验摘要】目的:从遗传毒理学方面了解并评价磁性纳米多孔复合(Nano-HA/PLLA/Fe2O3)材料的生物相容性,从而为其在移植肌腱固定的临床运用提供依据。

方法:用Nano-HA/PLLA/Fe2O3磁性纳米复合界面固定材料制备混悬液,进行Ames致突变试验,以检测其对鼠伤寒沙门菌的致突变比值(实验组回变菌落数/阴性对照组回变菌落数)。

结果:此人工骨材料的各浓度组混悬液对鼠伤寒沙门菌的致突变比值均小于2。

结论:Nano-HA/PLLA/Fe2O3磁性纳米复合界面固定材料不引起鼠伤寒沙门菌的回复突变数增加,说明此材料无致基因突变性。

【关键词】羟基磷灰石纳米界面固定材料致突变试验【中图分类号】R319 【文献标识码】A 【文章编号】1672-5085(2014)11-0061-02Mutagenicity test of magnetic composites material for interface fixationHuang jianghong, Zhu weimin, Wang daping, et al. Department of rheumatism,Shenzhen Second People’s Hospital, Shenzhen, 518035【Abstract】Objective To evaluate the bio-compatibility and safety of the magnetic composite(Nano-HA/PLLA/Fe2O3) from the aspects of inherited toxicology of it for the clinical use of interface fixation.Methods Produce Nano-HA/PLLA/Fe2O3 magnetic composites material and it’s diffusion and test the diffusion through Ames test。

C18-磁性纳米颗粒萃取虾肉中氯霉素残留

C18-磁性纳米颗粒萃取虾肉中氯霉素残留

C18-磁性纳米颗粒萃取虾肉中氯霉素残留王西丽;陈巧燕;李金峰;李颖;薛峰;蒋原;朱海【摘要】A method of C18 - functionalized magnetic silica nanoparticles solid phase extraction of chloramphenicol residues from shrimp was developed. The reversed -phase extraction dual particles were synthetized by bonding C18 groups on the surface of the superparamagnetic Fe3O4 nanoparticles and were used to extract veterinary drug residues by SPE. The process conditions, such as temperature, uniting time and additive amount of C18 -functionalized magnetic silica nanoparticles were optimized. The detection method showed good linear relationship within the range of 0.1 - 10 μg/kg(R2 = 0. 9941 ) and the detection limit was 0.1 μg/kg. The recovery range was between 73. 3% and 112. 3%. The method was reliable, accurate and had a good reproducibility, which can meet the demands of the detection of chloramphenicol residues in shrimp.%建立了一种用C18键合磁珠固相萃取虾肉中氯霉素残留的方法。

用废旧锂离子电池制备Cu2+掺杂钻铁氧体

用废旧锂离子电池制备Cu2+掺杂钻铁氧体

用废旧锂离子电池制备Cu2+掺杂钻铁氧体席国喜;席晓丽;王霖;蔺松波【期刊名称】《电子元件与材料》【年(卷),期】2011(30)1【摘要】以废旧锂离子电池为原料,柠稼酸为凝胶剂,采用sol-gel法制备出一系列Cu2+掺杂钴铁氧体Co1-xCuxFe2O4,研究了Cu2+的掺杂量对钴铁氧体微观结构和晶态的影响.结果表明:用废旧锂离子电池可以制备出磁性能优良的Cu2+掺杂钴铁氧体;最适宜的Cu2+掺杂量x=0.15,制得的样品的饱和磁化强度Ms为65.41A·m2·kg-1,剩余磁化强度A为34.37A·m2·kg-1,娇顽力Hc为190.80 kA·m-1掺杂适量的Cu2+有利于样品的晶化和烧结的致密化.%Using spent lithium-ion battery as raw material and citric acid as gelata, a series ofCu2+ doped cobalt ferrites (Co1-xCuxFe2O4) were synthesized by sol-gel method. Influences of the amount of copper doping on the microstructure and crystalline state of cobalt ferrites were studied. The results show the magnetic performance of Cu2+ doped cobalt ferrites is fine, the best doped amount of Cu2+ is x = 0.15. The saturation magnetization (Ms), remnant magnetization (Mr), and coercivity (Hc) of Cu2+ doped cobalt ferrites are 65.41 A · m2 · kg-1, 34.37 A · m2 · kg-1 and 190.80 kA · m-1, respectively. A doping certain amount of Cu2+ is conducive to crystallization and sintering densification in process of cobalt ferrites.【总页数】3页(P69-71)【作者】席国喜;席晓丽;王霖;蔺松波【作者单位】河南师范大学,化学与环境科学学院,河南省环境污染控制重点实验室,河南,新乡,453007;河南师范大学,化学与环境科学学院,河南省环境污染控制重点实验室,河南,新乡,453007;河南师范大学,化学与环境科学学院,河南省环境污染控制重点实验室,河南,新乡,453007;河南师范大学,化学与环境科学学院,河南省环境污染控制重点实验室,河南,新乡,453007【正文语种】中文【中图分类】TQ174.75+6【相关文献】1.废旧锂离子电池溶胶-凝胶法制备钴铁氧体的研究 [J], 席国喜;焦玉字;路迈西2.废旧锂离子电池水热法制备钕掺杂钴铁氧体 [J], 席国喜;邢新艳;范仁秀;路迈西3.用废旧锂离子电池制备镍掺杂钴铁氧体 [J], 席国喜;焦玉字;路迈西4.回收废旧锂离子电池制备镧掺杂钴铁氧体 [J], 席国喜;赵婷婷;衡晓莹5.废旧锂离子电池溶胶-凝胶法制备钴铁氧体研究 [J], 席国喜;侯进才;王霖;席晓丽;蔺松波因版权原因,仅展示原文概要,查看原文内容请购买。

石墨包覆纳米镍颗粒的结构及磁性能的表征

石墨包覆纳米镍颗粒的结构及磁性能的表征

石墨包覆纳米镍颗粒的结构及磁性能的表征罗宁;李晓杰;孙贵磊;王海涛【摘要】Aimed at synthesizing the encapsulation of nickel nanocrystal within graphitic carbon, effective experiments were carried out by adjusting the mole ratio of carbon source and metal source in these precursors. The chemical composition, nanostructures and magnetic properties of the composite particles were analyzed by using X-ray diffraction (XRD) , transmission electron microscopy (TEM), energy dispersive X-ray detector (EDX) and vibrating sample magnetometer (VSM). The results showed that the different size and spherical graphite-encapsulated nickel nanoparticles with a perfect core-shell structure had been prepared and that these magnetic composite particles mainly distributed in 10-55 nm. The magnetic measurements demonstrated that the as-prepared CENNPs took on super-paramagnetic or ferromagnetic behaviors at room temperature.%在密闭容器中,用爆轰分解掺杂含有镍离子的混合炸药前驱体合成了核壳结构石墨包覆镍纳米颗粒.调整混合炸药前驱体中碳源材料和金属源材料的有效摩尔比合成了球形、不同尺寸、核壳结构的磁性石墨包覆纳米镍颗粒.采用X射线衍射仪(XRD)、透射电镜(TEM)、能谱分析仪(EDX)和振动样品磁强计(VSM)表征化学构成、结构形貌及磁性能.结果表明:颗粒大小主要分布在10~55 nm之间,复合纳米颗粒主要由面心立方镍纳米晶体和石墨碳构成,常温下这些复合纳米颗粒主要表现出超顺磁性和铁磁性能.【期刊名称】《爆炸与冲击》【年(卷),期】2011(031)004【总页数】6页(P433-438)【关键词】爆炸力学;石墨包覆镍;X射线衍射仪;复合纳米颗粒;磁性能【作者】罗宁;李晓杰;孙贵磊;王海涛【作者单位】大连理工大学工业装备结构分析国家重点实验室,辽宁大连116024;大连理工大学工业装备结构分析国家重点实验室,辽宁大连116024;中国劳动关系学院安全工程系,北京100048;大连理工大学工业装备结构分析国家重点实验室,辽宁大连116024【正文语种】中文【中图分类】O389由于金属纳米颗粒在很多领域具有潜在应用价值,尤其在磁性纳米材料领域,例如高密度磁储介质、磁性油墨、电磁吸波材料、电磁屏蔽材料和磁流体等[1-3]。

酞菁绿G/十八胺电泳液微胶囊制备与表征

酞菁绿G/十八胺电泳液微胶囊制备与表征

Preparation and Characterization of Pigment
Phthalocyanine Green G/Octadecylamine Electrophoretic Ink Microcapsule 1 2 ~TT~T~ r'~.
.1 1
作者: 倪睿阳[1] 张琪瑶[2] 郑志伟[1] 汪进阳[1] 倪卓[2]
作者机构: [1]深圳中学,广东深圳518000 [2]深圳大学化学与化工学院,广东深圳518060出版物刊名: 黑龙江科学
页码: 44-46页
年卷期: 2012年 第5期
主题词: 电泳液 微胶囊 酞箐绿G 电场响应
摘要:试验在采用十八胺(ODA)(C17H35CH2NH2)化学修饰酞菁绿,并制备了稳定性良好的电泳液基础上,以此电泳液为囊芯,通过尿素和甲醛单体进行缩聚反应合成囊壁,制备绿色电子墨水微胶囊。

采用光学显微技术(OM)和电镜技术(SEM)表征该电子墨水微胶囊,微胶囊呈现球形,表面光滑,平均粒径为91μm,包覆率达81%,在电场作用下具有明显的可逆移动。

二叔丁基二环己基-18-冠-6的合成及其对锶的萃取

二叔丁基二环己基-18-冠-6的合成及其对锶的萃取

二叔丁基二环己基-18-冠-6的合成及其对锶的萃取
王婧;曹世权;朱杉;颜玉芳;晏敏皓
【期刊名称】《核化学与放射化学》
【年(卷),期】2024(46)2
【摘要】^(90)Sr(T_(1/2)=28.9 a)是一种具有高释热性和强放射性的高毒性核素,高放废液在进行处置之前必须准确测量放射性废液中^(90)Sr的含量,而将^(90)Sr 从放射性废液中分离出来是其准确测量的关键。

本工作通过改变合成反应路径和优化合成反应参数,解决了二叔丁基二环己基-18-冠-6(DtBuCH18C6)合成反应存在的加氢危险、纯化困难的问题,实现了高纯度产品的合成;而后采用溶剂萃取法,以DtBuCH18C6为萃取剂,分别研究稀释剂种类、萃取剂浓度、硝酸浓度、相比等条件对Sr^(2+)萃取性能的影响,以此来确定Sr^(2+)选择性分离的最佳萃取条件,建立一种有效的快速分离Sr^(2+)的方法,为后续提取^(90)Sr提供了一种可供选择的材料。

【总页数】13页(P158-169)
【作者】王婧;曹世权;朱杉;颜玉芳;晏敏皓
【作者单位】西南科技大学环境友好能源材料国家重点实验室;西南科技大学材料与化学学院;四川长晏科技有限公司;中国科学技术大学核科学技术学院
【正文语种】中文
【中图分类】TL941.1;O615.11
【相关文献】
1.硝酸介质中二环己基18-冠-6对锶的萃取
2.二环己基-18-冠-6对锶的萃取
3.冠醚萃取法从高放废液中去除锶Ⅲ.二环己基18冠6-辛醇-[2]对锶的萃取
4.利用二环己基-18-冠-6和二-(2-乙基己基)磷酸协同萃取硝酸铀酰的研究
5.二环己基-18-冠-6异构体A与铀的萃取配合物的结构研究
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四氯合钯(Ⅱ)酸正十八烷铵的差示扫描量热法和红外光谱法研究

四氯合钯(Ⅱ)酸正十八烷铵的差示扫描量热法和红外光谱法研究

四氯合钯(Ⅱ)酸正十八烷铵的差示扫描量热法和红外光谱法研

徐瑞云;蔡蕍;丁蕙
【期刊名称】《化学世界》
【年(卷),期】2003(44)11
【摘要】合成了四氯合钯( )酸正十八烷铵(n-C18H37NH3)2PdCl4(简称
C18PdCl4),并对其进行了化学分析。

使用差示扫描量热法(DSC)和红外光谱法(IR),测定了C18PdCl4的固-固相变温度和相变焓。

在350~390K温度区间内,该化合物具有82.60kJ/mol的摩尔固-固相变焓,此类相转变是晶格内的长链烷烃从有序排列向无序排列转变的结果。

【总页数】3页(P578-579)
【关键词】四氯合钯(Ⅱ)酸正十八烷铵;DSC;IR;固-固相变
【作者】徐瑞云;蔡蕍;丁蕙
【作者单位】上海应用技术学院化学工程系
【正文语种】中文
【中图分类】O642;TQ013.1
【相关文献】
1.差示扫描量热法与红外光谱法快速鉴别肉苁蓉药材的对比研究 [J], 张丽;郭永辉;侯艳艳;马林;孙素琴;吕扬
2.红外光谱法/差示扫描量热法鉴别氯醚橡胶类型 [J], 姚玉红;许耀东;田友峰;杨登基;何广德;陈晋阳;
3.红外光谱法/差示扫描量热法鉴别氯醚橡胶类型 [J], 姚玉红;许耀东;田友峰;杨登基;何广德;陈晋阳
4.用差示扫描量热法研究酸变性淀粉的糊化特性 [J], 黄立新;周俊侠;杨兆禧
5.差示扫描量热法研究丙烯腈-衣康酸共聚物的热稳定化 [J], 欧阳琴;程璐;王浩静;孙予罕
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葵花籽壳对溶液中铀酰离子的吸附

葵花籽壳对溶液中铀酰离子的吸附

葵花籽壳对溶液中铀酰离子的吸附王长福;刘峙嵘;薛桂荣;赖毅;王云;周利民【摘要】选取农业副产物葵花籽壳作为吸附剂,研究其对溶液中铀酰离子的吸附性能.用元素分析、扫描电镜、红外光谱分析等方法对吸附铀前后的葵花籽壳进行分析和表征,通过静态实验分别研究了时间、温度、pH值、铀酰离子初始浓度、葵花籽壳用量等因素对吸附效果的影响.结果表明:吸附的适宜pH为5.0~6.0,35℃下,当铀溶液初始质量浓度为50 mg/L,溶液pH=5.0,葵花籽壳质量浓度为1.00 g/L时,饱和吸附量可达29.2 mg/g.【期刊名称】《核化学与放射化学》【年(卷),期】2016(038)002【总页数】9页(P107-115)【关键词】葵花籽壳;铀;吸附【作者】王长福;刘峙嵘;薛桂荣;赖毅;王云;周利民【作者单位】东华理工大学化学生物与材料科学学院,江西南昌330013;东华理工大学化学生物与材料科学学院,江西南昌330013;东华理工大学化学生物与材料科学学院,江西南昌330013;东华理工大学化学生物与材料科学学院,江西南昌330013;东华理工大学化学生物与材料科学学院,江西南昌330013;东华理工大学化学生物与材料科学学院,江西南昌330013【正文语种】中文【中图分类】TL941.19农林作物的收获和加工过程中所产生的废弃物资和垃圾称为农林废弃物,如玉米、花生、高梁、棉花、豆类等的秸秆,植物的枝叶和藤蔓,木材加工的废料,以及食品加工过程中产生的残渣,如饼粕、酒糟、蔗渣、甜菜渣、食品工业下脚料等[1]。

近年来,农林废弃物等已逐渐开始被用做吸附剂来修复污染水体。

农林废弃物主要由蛋白质以及纤维、半纤维、木质素等成分组成,对重金属离子有良好的吸附效果。

稻草[2-4]、橘子皮[5-7]、香蕉皮[8]、米糠[9]、玉米芯[10-13]、锯屑[14-15]、树皮[16]、树叶[17]、椰壳纤维[18]、甘蔗渣[19]、水生植物[20]等植物材料常被用来做为吸附剂。

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CHAPTER18 Magnetic Materials
Each of these steel billets is being heated uni-
formly in a cost-effective way by two adjacent
coils which utilize an oscillating electrical cur-
rent to produce an oscillating magneticflux and
the resulting heating due to the“hysteresis”of
a ferromagnetic core material.(Courtesy of
CoreFlux Heating Systems.)
Figure18-1A simple illustration of magnetism shows the magneticfield (seen as magneticflux lines)gen-erated around an electrical current
loop.
Figure18-2A magnetic material can generate a magneticfield without an electrical current.This simple
bar magnet is an example.
Figure18-3Attraction of two adja-cent bar magnets.
Figure18-4Comparison of diamagnetism and paramagnetism on a plot of induction(B)versus magneticfield strength(H).Neither of these phe-nomena is of practical engineering importance due to the modest level of
induction that can be generated.
Figure18-5In contrast to Figure18–4,the B-H plot for a ferromagnetic material indicates substantial utility for engineering applications.A large rise in B oc-curs during initial magnetization(shown by the dashed line).The induction reaches a large,“saturation”value(B s)upon application of sufficientfield strength. Much of that induction is retained upon removal of thefield(B r=remanent induction).A coercivefield(H c)is required to reduce the induction to zero.
By cycling thefield strength through the range indicated,the B-H plot continu-
ously follows the path shown as a solid line.This is known as a hysteresis loop.
Element Sc Ti V Cr Mn Fe Co Ni Cu
29
2827262524232221123554320
= electronic spin orientation
Atomic number
Figure 18-6The electronic structure of the 3d orbital for transition metals.Un-paired electrons contribute to the magnetic nature of these metals.
Figure18-7The alignment of magnetic moments for adjacent atoms leads to the large net magnetic moment(and B s on a B-H plot)for the bulk solid. The example here is pure bcc iron at
room temperature.
Figure18-8The domain structure of an unmagnetized iron crystal gives a net B=0even though individual domains have the large magnetic
moment indicated by Figure18–7.
H
Figure18-9The sharp rise in B during initial magnetization is due to do-main growth.
Figure18-10The domain,or Bloch,wall is a narrow region in which atomic moments change orientation by180◦.Domain wall motion (implied in Figures18–8and18–9)simply involves a shift in this
reorientation region.No atomic migration is required.
Figure18-11Summary of domain microstructures during the course of a ferromag-netic hysteresis loop.
H (104
A/m)
B (web/m 2
)
magnets.
B , w e b e r /m e t e r 2
Figure 18-14A comparison of initial magnetization for three ferrous alloys.The silicon addition increases magnetic permeability and,consequently,B s .Preferred orienta-tion,or texturing,increases initial magnetization substantially (see Figure 18–13).(From R.M.Rose,L.A.Shepard,and J.Wulff,The Structure and Properties of Materials ,Vol.4:Electronic Properties ,John Wiley &Sons,Inc.,New York,1966.)
H (BH
Figure18-15Replotting data in the“demagnetization quadrant”of the hys-teresis loop demonstrates a maximum value of the|BH|product,(BH)max. This quantity is a convenient measure of the“power”of permanent mag-
nets.Table18.3gives(BH)max for various hard magnets.
B (web/m 2)
|BH |
10
5
00.30.6
kJ m 3
΂΃
Figure18-16Schematic illustration of magnetic storage and retrieval using a recording medium composed of needlelike particles ofγ-Fe2O3.(From J.
U.Lemke,MRS Bulletin,15,31[1990].)
Figure18-17Schematic illustration of a thinfilm of a metal alloy,Sendust (FeAlSi),on the pole faces of the ferrite recording head in a metal-in-gap or MiG design.(From A.S.Hoagland and J.E.Monson,Digital
Magnetic Recording,2nd ed.,Wiley-Interscience,New York,1991.)
0400
30020010002040
T (K)60C r i t i c a l f i e l d (A -t u r n s /m )80YBa 2Cu 3O 7(La, Sr)2CuO 4
Nb 3Ge
100
Figure 18-18Comparison of the critical magnetic field versus temperature for a metallic superconductor (Nb 3Ge)and two ceramic superconductors.。

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