科莱恩阻燃剂介绍

- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
n
Others
Polyamides
Printed Wiring Boards
FR Polyamides with Phosphinates
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 5
– ELINCS inventory (Europe) – TSCA (USA) – IECSC (China) – ENCS (Japan) – DSL (Canada) – ECL (Korea) – HNSO (New Zealand) – AICS (Australia)
Phosphinates as Flame Retardants
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
_ O R 1 P O M n+ R2
n
Toxicologic Findings for the Phosphinate
Sensitization
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
– Lead free soldering Polyamide 6 and 66
– Glow wire test – Electrical properties – Recycling Study Polyester (PBT) Epoxy resins Conclusion
Clariant‘s New Phosphinate Plant
Toxicity – Daphnia – Fish – Bacteria – Algae
non-sensitizing (Guniea pig)
not mutagenic no experimental indications
EC50 > 100 mg/l (48 h, daphnia magna) LC50 > 100 mg/l (96 h, zebra fish) EC50 = 1968 mg/l (3 h, activated sludge) NOEC > 180 mg/l (scendenemus subspicatus)
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 7
Mutagenity – Ames-Test – Genotoxicity in vivo
Coloribility CTI 600 V good mechanical properties low density of compounds good flow properties high temperature stability Laser marking and laser welding possible
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 6
Thermally stable up to 350°C Mineral-like characteristics of metal phosphinate FR system decomposes to solid phosphates no migration and blooming virtually no emissions
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 10
Mechanical Properties in PA-HT
Lifecycle considerations – Reprocessing of production waste – Recycling of used materials – End of life – environmental properties – Total costs
Phosphinate Flame Retardants
Registration is completed in compliance with
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
Polyesters
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 8
_ O R 1 P O M n+ R2
Phosphinate Based Flame Retardants – A growing number of applications
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
Phosphinates, the Flame
Public
Dr. S. Hörold Development Flame Retardants ATPG 24.11.2006
Retardants for Polymers in
Electronics
FR Polymers in the E&E Industry – Demanding requirements
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2百度文库06
Slide 2
Material properties (selection) – small parts, thin wall, low density – Surface Mount Technology – lead free soldering – laser markability / weldability – glow wire test
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 3
Properties of Phosphinates High temperature Polyamides
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 4
Phosphinates, a new class of FR Systems
Compounding on Leistritz ZSE 27 HP – 44D PA 6T/66 30% Glass fibres Without flame retardants With Br-PS/ATO/PTFE UL 94 V-0 With Exolit OP 1230 UL 94 V-0
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
- Properties of Phosphinates - HT Polyamides Lead free soldering - Polyamide 6 and 66 Glow wire test Electrical properties Recycling Study - Polyester (PBT) - Epoxy resins - Conclusion
Phosphinates, the Flame
Retardants for Polymers in
Electronics
Public Dr. S. Hörold Development Flame Retardants ATPG
24.11.2006
Slide 9
PA-HT Recipes for Comparison
Tensile (dry as moulded)