粉末涂料的MSDS

粉末涂料（塑粉）的MSDS1 产品热固性粉末涂料产品名称静电喷涂应用成分构成2./信息化学品（危险品知识与包装）规章的范围内体现健康危害的1997在: 物质）R-含量范围名称代表符号术语（* <5.0% T R46 R23/25 R48/22 异氰尿酸三缩水0.1至(TGIC) R41 R43 甘油酯）详见（*16小节3．危害识别可能会有损害遗传基因的风险。

该产品因含有被定为具有毒性。

TGIC 可能引起皮肤接触性过敏。

吸入和误食均有伤害。

．急救措施4 一般：若有任何疑问或有症状持续出现，请寻医助。

保证失去意识的患者口中无任何东西。

吸入：移到通风处，保持患者体温和静止。

如果患者呼吸不规律或停止，进行人工呼吸急救。

保证口中无异物。

如果失去意识，安置在恰当位置并寻医助。

眼睛接触：保证眼皮张开并取下隐形眼睛。

用大量干净的清水冲洗至少十分钟，寻医助。

皮肤接触：脱下被污染的衣物。

用肥皂和水或者是合适的皮肤清洁剂彻底清洗。

切忌使用溶剂或稀释剂。

吞服：如不慎吞食，立即寻求医助。

保持患者静躺，切勿导吐。

5．消防措施灭火媒介：建议：水，泡末，干粉，CO2，水喷淋或水雾禁止使用：高压惰性气体（如CO2），水枪喷射建议：10火灾现场浓厚的黑烟包含很多由于燃烧产生的有害物质（参看第小节）。

暴露于这种分解的物质中对健康有害。

需要自带呼吸器的器切勿把灭火器的流出械。

用水喷的方式冷却暴露在火中的密闭容器。

物直接排到下水道或河道中。

6．应急意外泄露排除火源，保证场地通风。

无关人员远离现场。

避免吸入灰尘。

涉及小节。

打扫溢出粉末应使用防静电的真空清、87到的保护措施列在小节）收集在密13洁器或湿的清洁刷，并根据废物处理规则（参看闭容器中待处理。

切勿使用扫把，以免形成灰尘层和静电积累。

请勿直接排放到下水道或河道中。

如果污染应立即联系当地自来水公司；如果产品进入下水道或河道，了河流、小溪或湖泊，应求助当地环保部门。

．处置和存储7 处置采取措施以预防灰尘积聚到高于爆炸或偶然爆炸极限。

电气和照明设备应根据相宜标准进行保护，切勿让灰尘接触热表面、火星或其它点火火源。

保证容器密封。

排除热源、火星和明火。

避免吸入灰尘。

在储存和使用区域严禁抽烟、进食和饮水。

操作人员应佩带防静电鞋，地面保持导电。

8涉及到个人防护参看小节。

本产品包装物应交有资质的部门处理。

储存℃之下、通风良好、干燥的室内，阅读储存措施标识。

一般贮存在35不经授权不得进入。

避免阳光直射。

禁止抽烟。

不得靠近火源、暖气，打开的包装一定要重新密封，并摆放适当位置防止泄露。

8．暴露控制/个人防护暴露极限职业暴露极限物质）（15）（8小时TWA1 分钟STEL2mg/m3 (3) mg/m3 (3)TGIC 0.1MEL注释：—8小时时间的加权平均值）（1 长期暴露极限分钟参考周期15 （2）短期暴露极限—，“OES”3）是指Occupational Exposure Standard(职业暴露标准)（是取)是指Maximum Exposure Limit(最大暴露极限，“OELS”“MEL”自于EH40的当前版本。

的暴对）方法来测量。

TGIC（对TGIC的暴露可以用MDHS85HSE）然后TIP露还可以通过另外一种方法来测量，即测出总吸入微粒（TGIC的含量是多少。

再计算出这种物质中2 mg/m3 的暴露低于范围的产品，含量在对于TGIC0.1%—5.0%TIP 0.1 mg/m3 MEL 就意味着TGIC的暴露低于。

具有呼吸道疾病和过敏反应病史的人员必须要在适当的医疗监督下才能暴露于此产品中或处理此类产品。

技术措施如果这使用现场的排气通风和抽风装置来减少粉尘。

避免吸入粉尘。

就需要佩带合适些措施仍不能将粉尘浓度控制在职业暴露极限之下，章节）的呼吸保护装备。

（参考下面的“个人防护”个人防护RPEPPE（个人防护装备）包括用来控制对有害物质的暴露所有的（呼吸保护装备）都必须达标。

呼吸保护：如果喷涂人员或附近其他人员对于产品的暴露不能控制在职业暴露本产品喷涂时则必须极限之下，或是技术控制措施没有合理的改进，佩带合适的呼吸保护装置。

手的保护：皮肤暴露可能发生的区域，建议从手套供应商处选择合适的型号。

眼睛的保护：当有可能暴露于产品中时，应佩带相应的防护镜免于灰尘的暴露。

皮肤的保护：通常棉或合成棉的用品比较合适。

应确保避免脖子和手腕处皮肤与粉末接选择防护布料时一定要注意，触，以免其受刺激发炎。

．物理和化学性质9 物理状态细粉状1.9 1.2比重—在水中的溶解性不溶于水400℃最低点燃温度—20mJ 5最低点燃能量：70g/m3 —最低爆炸浓度：20 10．稳定性和反应活性小节）下产品保持稳定。

在燃烧中，7在建议的贮存和处理条件（见产品会分解有害物如烟、CO、CO2，也可能产生其它氮氧化合物。

．11 毒性信息关于产品本身没有可获得的数据。

粉末可能会引起局部皮肤褶皱处或衣物紧裹处刺激。

12．生态信息关于产品本身没有可获得的数据。

，因此可能会对水生环境造成长期该产品含有对水生物有害的TGIC 的不利影响。

或是在可能影响土壤或地表水的地方本产品不准排入河流或下水道，沉积。

当应用本产品时应遵循在《环境保护法》中制定的《空气污染控制》规章要求。

13．处理考虑因素不允许排入河道或下水道或是在可能影响土壤或地表水的地方沉积。

废弃物包括空的容器，应根据在《污染控制法》和《环境保护法》中制定的规章处理。

咨询你的废弃物处理商以获得更详尽的信息。

14．运输信息确保运输人员在发生泄露等事件时完整，运输时确保包装物的密封、知道如何处理。

在国际章程项下该产品并未被划分为危险运输品。

15．管理信息《化学品规章》（有害信息和包装）的要求该产品的安全1997根据术语如下：该产品含有TGIC被定为有毒级别。

R46 可能损害遗传基因R43 可能引起皮肤接触性过敏对眼睛有刺激性R36R20/22 若吸入或吞服均有损害S24/25 避免与皮肤和眼睛接触意外事件或是你感觉不佳，立即需求医助（可能的话向医生出S45 示标签）S38 若通风不足应佩带合适的呼吸器具使用前熟悉特殊指导说明—S53 避免暴露并不此安全数据页里所包含的信息，根据其它健康和安全法律要求，使用本产品时为了工作的健康能构成用户本身工作场地风险的评估。

和安全，应该遵循物质对健康危害的控制章程。

．其他信息16《化学品规章》（有害信此安全数据页里所包含的信息是根据1997 息和包装）的要求提供。

术语全文是：在第二小节包含的R 若吸入或吞服均有毒性R23/25R41 对眼睛严重损伤的风险R43 可能引起皮肤接触性过敏R46 可能损害遗传基因R48/22 有害：长期暴露和误食对健康的严重损害危险在没有向粉末供应商联系并获得书面的作业指导前，本产品不得用作除第一部分所列的其他用途。

若本产品是在供应商控制之外其他特殊条件下使用，用户应确保遵从相关的法律要求。

此安全数据页里所包含的信息是基于现有的知识形态和当前的国家法律。

它对本产品健康、安全和环境方面提供指导，但做特殊用途时并不能提供技术性能或稳定性的保证。

更详尽的信息和建议可从下列获得： 437）物质有害健康控制章程》（SL1999：《1999 01372 360 660）《英国涂料联盟粉末涂料静电喷涂（安全惯例代码）应用》（）SL 1992：2793《1992操作处理规章手册》（71 ） HS（G 《化学品的入库贮存》：密封危险品的贮存）：28391992《环境保护章程》（SL 1992 ）：3247《1997化学品（危险品信息和包装）章程》（SL 1997**** Powder CoatingSAFETY DATA SHEET NO 29COATING POWDERALL PRODUCT PROVIDED THE SDS 29 MATERIAL Product and reference：***. **st, 2009 Date of Issue：1 IDENTIFICATION OF THE PREPARATION AND COMPANYProduct name and/or code: Thermosetting Coating PowderIntended use: ***Name and full address: *********Emergency phone number: ***2. COMPOSITION/INFORMATION ON INGREDIENTSSubstances presenting a health hazard within the meaning of the Chemicals (Hazard Informationand Packaging) Regulations 1997:）（*Name Conc. Range Symbol Letter R-phrasesTriglycidyl(TGIC) 0.1 to <5.0% T R46, R23/25, R48/22,R41,R43 IsocyanurateFor full text see section 16 *）（3.HAZARDS IDENTIFICATIONdamage. genetic heritable toxic. as Possible risk of classified and contains This product TGIC is inhalation andeyes. be irritating cause sensitisation by skin May contact and may to Harmful byif swallowed.4. FIRST AID MEASURESGeneral:In all cases of doubt, or when symptoms persist, seek medical attention.Never give anything by mouth to an unconscious person.Inhalation：Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recoveryposition and seek medical advice.Eye contact：Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10minutes, holding the eyelids apart, and seek medical advice.Skin Contact:skin proprietary or use a thoroughly with soap and water Wash Remove contaminated clothing. skin cleaner. Do NOT use solvents or thinners.Ingestion:If accidentally swallowed, obtain medical attention. Keep at rest. Do NOT induce vomiting.5. FIRE FIGHTING MEASURESExtinguishing media:Recommended: water, extinguisher of foam, Powder and Carbon dioxide, water spray/mist.water jets. ），（e.g. CO2Not to be used: high pressure inert gasRecommendations:10). (see Section products of combustion black Fire will produce dense smoke containing hazardous breathing self-contained health. Appropriate a products may be hazard to decomposition Exposure toallow fire with water spray. Do not required. Cool closed containers exposed to may be apparatusrun-off from fire fighting to enter drains or watercourses.6. ACCIDENTAL RELEASE MEASURESExclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoidspillage and Contain collect 7&8. in measures to dust. breathing Refer protective listed Sectionswith an anti- electrostatic vacuum cleaner or by wet brushing and place in a closed containerfor disposal in accordance with the waste regulations (see Section 13). Do not use a dry brushor static electricity can be created. Do not allow to enter drains or watercourses.immediately; be contacted local water company should If the product enters drains or sewers, thein case of contamination of streams, rivers or lakes, the relevant environment agency.7. HANDLING AND STORAGEHandling:Precautions should be taken to prevent the formation of dusts in concentrations above explosiveor occupational exposure limits.Electrical equipment and lighting should be protected to appropriate standards and to preventdust coming into contact with hot surfaces, sparks or other ignition sources.Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Avoid theinhalation of dusts. Smoking, eating and drinking should be prohibited in areas of storage anduse.Operators should wear anti-static footwear and floors should be electrically conductive.For personnel protection see Section 8.The containers of this product should be handled in qualified department.Storage:sources from place away a ℃ in dry, well ventilated the Observe label precaution. Store below 35which access. Containers Prevent sunlight. No smoking. unauthorized of heat, ignition and directare opened should be properly released and upright to prevent leakage.8. EXPOSURE CONTROLS/ PERSONAL PROTECTIONExposure Limits:Substance Occupational Exposure Limits） 15min STEL）（28hr TWA（1mg/m3 (3) mg/m3 (3)TGIC 0.1 MELNotes:8 hour time weighted average —） Long term exposure limit（115 minutes reference periodShort term exposure limit—2（）“OES”indicates an Occupational Exposure Standard. ‘MEL' indicates a Maximum Exposure ）（3Limit. OELS are taken from the current version of EH40.exposure of estimate (HSE). MDHS described the measured can to Exposure TGIC be by method in 85 An to TGIC can also be carried out by measuring exposure to total inhalation particulate(TIP), and then calculating how much of this material is TGIC.For products with TGIC content in the range 0.1 to <5.0% exposure to TIP below 2 mg/m3 will mean exposure to TGIC will be below the MEL of 0.1 mg/m3.Persons with a history respiratory problems or allergic responses should only be exposed to, or handle, this product under appropriate medical supervision.Engineering Measures:Avoid the inhalation of dusts. Where reasonably practicable this should be achieved by the use maintain to not sufficient are good general extraction. If there exhaust of local ventilation and concentrations of dust below the relevant Occupational Exposure Limits, suitable respiratoryipment should be worn (see ‘personal protection' below). protective equPersonal Protection:meet selected to hazardous substances must be to All PPE, including RPE, used control exposure to the relevant requirements.Respiratory Protection:Suitable respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and the engineering controls and methods cannot reasonably be improved.Hand Protection:types. appropriate suppliers on should be sought from glove advice skin Where exposure may occur,Eye protection:Eye protection designed to protect against exposure to dusts should be worn when there is a likelihood of exposure.Skin Protection:Cotton or cotton/ synthetic overalls or overalls are normally suitable.Care should be taken in the selection of protective clothing to ensure that inflammation and irritation of the skin at the neck and wrists through contact with the powder is avoided.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state: Fine powder1.9 —Specific Gravity: 1.2Solubility in water: insolubleMinimum ignition temp: 400℃20mJ—Minimum ignition energy: 570g/m3 Minimum explosive concentration: 20—10. STABILITY AND REACTIVITYhazardous fire, In a handling conditions (See Section 7). storage Stable under the recommended and may of nitrogen carbon dioxide and oxides carbon decomposition products such as smoke, monoxide, be produced.11. TOXICOLOGICAL INFORMATIONThere is no data available on the product itself. Coating powders can cause localized skin irritation in folds of the skin or in contact with tight clothing.12. ECOLOGICAL INFORMATIONThere is no data available on the product itself.This product contains Triglycidyl Isocyanurate (TGIC) which is classified as harmful to aquatic organisms, and may cause long-term adverse effects in the aquatic environment.The product should not be allowed to enter drains or watercourses or be deposited where it can affect ground or surface waters.The Air Pollution Control requirements of regulations made under the Environmental ProtectionAct may apply to the use of this product.13. DISPOSAL CONSIDERATIONSDo not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed ofin accordance with regulations made under the Control of Pollution Act.14. TRANSPORT INFORMATIONpersons that and secure. Ensure are in Always transport closed containers that uprighttransporting the product know what to do in the event of accident or spillage.The product is not classified as dangerous for carriage under International regulations.15. REGULATORY INFORMATIONThe safety phrases of this product is identified in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations (1997) as follows.This product contains Triglycidyl Isocyanurate (TGIC) and is classified as toxic.R46 May cause heritable genetic damageR43 May cause sensitisation by skin contact.R36 Irritating to eyes.R20/22 Harmful by inhalation and if swallowedS24/25 Avoid contact with skin and eyes.S45 In case of accident or if you feel unwell, seek medical advice immediately (showthe label where possible).S38 In case of insufficient ventilation wear suitable respiratory equipment.obtain special instructions before use. –S53 Avoid exposureassessment the user's own safety data sheet does not constitute in The information contained thisHealth provisions of the health and safety legislation. The as of workplace risks required by otherand Safety at Work etc Act and the Control of Substances Hazardous to Health Regulations applyto the use of this product at work.16. OTHER INFORMATIONthe the requirements of The information in this safety data sheet is provided in accordance with Chemicals (Hazard Information and Packaging) Regulations 1997.The full text of the R phrase contained in Section 2 is:-R23/25 Toxic by inhalation and if swallowed.R41 Risk of serious damage to eyes.R43 May cause sensitisation by skin contact.R46 May cause heritable genetic damage.R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.referring first 1 shown in Section without product should not used for purposes other than those Theto the powder supplier and obtaining written handling instructions. As the specific conditionsre outside the supplier's control, the user is responsible for ensuring of use of the product athat the requirements of relevant legislation are complied with.current and state of knowledge is this data sheet based on the present The information contained in national legislation. It provides guidance on health, safety and environmental aspects of thefor performance or suitability construed be as any guarantee of technical product and should not particular application.Further information and relevant advice can be found in:.437）：The Control of Substances Hazardous to Health Regulations 1999（SL1999British Practice) from Spraying (Code of Safe Coatings The Application of Powder by Electrostatic.）Coatings Federation（01372 360 660. ）SL 1992：2793（The Manual Handling Operations Regulations 199271 GChemical Warehousing: Storage of Packaged Dangerous Substances HS（）. ：2839）The Environmental Protection (Duty of Care) Regulations 1992（SL 1992）.The Chemicals (Hazard Information and Packaging) Regulations 1997（SL 1997：324703-8 00:27 jjw920 -试用期一级回答者：我来评论>>其他回答共 2 条希望下面内容对你有用：，是一份关于粉末涂料燃、爆、毒性和生态危害以及安全使用、MSDS粉末涂料安全技术说明书，英文简称泄露应急处理、主要理化参数、法律法规等方面信息的综合性文件，作为对客户的一种服务，特别是生产企业和进出口企业，粉末涂料供应商应随粉末涂料产品一起向客户提供粉末涂料安全技术说明书，使客户明了粉末涂料的有关危害，施工使用时能自主进行防护，起到减少职业危害和预防化学事故的作用。