最新en14362-1-翻译汇总

最新en14362-1-翻译汇总
最新en14362-1-翻译汇总

E N14362-1-2012翻

1 范围

这个欧洲标准描述一个用于检测可能不只用于制造或处理某些日用品的某些特定偶氮染料程序,这些纺织纤维使用或不使用萃取的方法可以达到还原裂解。不使用萃取的方法就可以达到还原裂解的偶氮染料用于:

-------有纤维质的纤维(举例来说棉,纤维胶)

-------蛋白质纤维(举例来说羊毛,丝绸)

-------人造的纤维(举例来说聚酰胺,丙烯酸)

使用萃取的方法可以达到还原裂解的偶氮染料用于使用分散染料的人造纤维。下列的人造纤维可以被分散染料染色:聚酯纤维,醋酸纤维,三醋酸基纤维,丙烯酸和含氯纤维。

对于一定的用纤维素和(或)蛋白质并混合人造纤维制造的日用品必须要先萃取染料。

本方法适用于所有的染色纺织品,例如染料,印刷和涂层纺织品。

2 相关标准

下面相关文档对于这份欧洲标准的应用是不可缺少的。对于有限期的相关标准,仅适用于所引用的版本。对于无限期的相关标准,适用于相关文档(包括任何修订)的最新版本。

EN ISO 3696:1995,分析实验用水—规格和测试方法(ISO 3696:1987)

3 概要

某些偶氮染料可以豁免,偶氮组分被还原裂解成一种或多种下列芳香胺,这些芳香胺在欧洲议会的法规和建立一个化学品管理的化学品的登记、评估、批准、限制委员会(REACH)2006年12月18日的相关法规No 1907/2006下是被禁止的.

表1----REACH法规1907/2006/附件17下描述的芳香胺

4 原理

从纺织品中选出有色测试样品,测试样品依据分散染料萃取的方法和(或)其他种类染料直接还原的方法测试。

根据测试样品的纤维的种类(纯净的纤维或混合的纤维)和颜色的处理(染色或印刷的过程)使用2种方法中的1种或结合2种方法。相应地,如果测试样品在依据2种方法中的1种应用时不褪色,则另一种方法被采用。

当分散染料萃取着色剂方法被使用时,着色剂在使用氯苯回流下先从顶部位置的纤维里萃取出来。萃取液经浓缩后用甲醇转移到反应器中,后面在70℃柠檬酸盐缓冲溶液(PH=6)中使用连二亚硫酸钠还原.如果纺织样品在使用氯苯萃取后没有完全褪色,把样品和分散染料中的甲醇溶液加入反应器中一起还原。

当使用其他种类染料的处理方法时,测试样品在密闭容器中70℃柠檬酸盐缓冲溶液(PH=6)里使用连二亚硫酸钠还原处理。

还原后,过程中释放的任何胺通过使用硅藻土柱进行液液萃取转移到叔丁基甲基醚中。叔丁基甲基醚萃取液被浓缩,残渣经适当的溶解后用色谱仪检测(见附录A)。

附录E描述了一个不使用硅藻土柱进行液液萃取的方法。

如果任何一种胺被检测出来,需要使用1种或多种选择性的方法进行确认。

5 安全预防

5.1 警告—条款3中所列的物质(胺)类属于已知或者被怀疑为可致癌性物质。这类物质的操作和处理必须严格遵循国家健康与安全条例。

5.2使用者有责任使用安全适当的技术用于处理该测试方法中的材料。参考产品明确的细节例如材料安全资料表和其他的建议。

5.3需遵守良好的实验室规程。在所有的实验区带安全眼镜并且在处理染料粉末时使用单独的呼吸器。

5.4使用者需要遵从所有的国家和地方安全规章。

6 试剂

除非另外的指定,应该使用化学分析等级。

6.1 氯苯

6.2 乙腈

6.3 甲醇

6.4 叔丁基甲基醚

6.5 正戊烷

6.6 柠檬酸/氢氧化钠缓冲溶液,ph=6,c=0.06mol/l

6.7 连二亚硫酸钠水溶液,ρ=200mg./ml 新鲜的(当天)准备

6.8 硅藻土

6.9 胺类物质—胺1至4,7至21(表1中指定的),苯胺和1,4-苯二胺—所有最高的可以达到的定义纯净标准品。

6.10 标准溶液

6.10.1 胺的储备溶液,配制均匀的溶液,每一种胺浓度300ug/ml

备注:对于储备溶液,乙腈是一种适当的溶剂,对胺的结果又很好的稳定性。

6.10.2 胺每天使用的校正曲线溶液

从6.10.1的储备溶液中稀释成每一种胺浓度15.0ug/ml的适当的溶液

6.10.3 胺的量化的校正溶液,每一种胺浓度范围2-50ug/ml的适当的溶液

备注:每个实验室有责任选择合适浓度的校正曲线。

6.10.4 内标溶液(IS),用适当的内标溶液ρ=1.0mg of IS/ml

假设用GC-MS分析,使用下列内标之一:

-----IS1:联苯胺-d8,CAS No:92892-63-6;

-----IS2:萘-d8,CAS No:1146-65-2;

-----IS3:2,4,5-氯苯胺,CAS No:636-30-6;

-----IS4:蒽-d10,CAS No:1719-06-8;

备注:如果用DAD或TLC做联苯胺的确认分析,使用IS1:联苯胺-d8,CAS No:92892-63-6 是不可行的,因为它的峰和不加氘到联苯胺不能区分开。

6.11 氢氧化钠缓冲溶液,质量分数为10%

6.12三级水,参照 EN ISO 3696:1995.

7 仪器

7.1 萃取装置,依据图片1,由下列组成:

------缠绕管冷凝器口径29/32

------一个吊钩,用惰性材料制作,使样品处于指定的位置,保证浓缩溶液水滴滴在上面

------100ml圆底烧瓶口径29/32

------加热源

备注:如果要获得同样的结果,要使用相似的设备。

7.2 超声浴,可控制加热

7.3 反应器(20ml至50ml)带密封可加热的玻璃制品

7.4 加热源,可产生(70±2)℃

7.5 玻璃或聚丙烯柱,内径25mm至30mm,长度130mm至150mm,装20g硅藻土,出口带有玻璃纤维过滤器。

可以买预先装好的硅藻土柱,也可以按照给定的尺度将20g硅藻土装入到一个玻璃的或者聚丙烯的柱子中。

7.6带有真空控制和水浴的真空旋转蒸发仪

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猎头公司head-hunter 假日经济holiday economy 人力资本human capital 航空和航天工业aerospace industry 飞机制造工业aircraft industry 电子工业electronic industry 汽车制造工业car industry 娱乐业entertainment industry 信息产业information industry 知识密集型产业knowledge-intensive industry 国有大中型企业large and medium-sized state-owned enterprises 轻工业light industry 博彩业lottery industry 制造业manufacturing industry 垄断行业monopoly industries 市场多元化market diversification 市场经济market economy 市场监管market supervision 购买力purchasing power 熊市bear market 牛市bull market

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