环境水化学绪论
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phosphorus in urban and agricultural systems (4) small-scale nutrient cycling processes in soil-sediment-
water systems.
12
其他相关课本
François M. M. Morel Janet G. Hering
25
本课程主要内容
➢ 酸-碱平衡 ➢ 沉淀-溶解 ➢ 配位化学 ➢ 氧化还原反应 ➢ 表面化学与吸附 ➢ 水体颗粒物 ➢ 水体光解反应 ➢ 水体有机污染物
26
专题讨论
➢VMINEQL软件 ➢金属离子形态与生物有效性 ➢天然有机质（NOM） ➢沉积物质量 ➢营养元素（N、P）循环
27
环境水化学的学科地位
➢ Stumm W, Morgan J J. Aquatic Chemistry: Chemical Equilibria and Rates in Natural Water (3ed). John Wiley & Sons,
New York, 1996. 斯塔姆等，汤鸿霄等译。《水化学》。科学出版社，北京，1987。 ➢ 汤鸿霄。《环境水化学纲要》。 环境科学丛刊，1988。 ➢ 陈静生。《水环境化学》。高等教育出版社，北京，1988。 ➢ 期刊论文等。
Chemistry’ ➢ 1967，Stumm ‘Equilibrium Concepts in Natural
Waters’ ➢ 1970，Aquatic chemistry: An introduction
emphasizing chemical equilibria in natural waters
➢1966，Environmental Science and Technology 首任主编
10
Patrick L. Brezonik
➢ Education: B.S., 1963, Chemistry, Marquette University M.S., 1965, Water Chemistry, University of Wisconsin-Madison Ph.D., 1968, Water Chemistry, University of Wisconsin-Madison ➢ Experience: Assistant, Associate, and Full Professor, Department of Environmental Engineering
4
参考书目
➢ Brezonik P L, Arnold W A. Water Chemistry：An Introduction
to the Chemistry of Natural and Engineered Aquatic Systems.
Oxford University Press, New York, 2011. （教材）
Sciences, University of Florida, 1966-81 Guest Professor, EAWAG-Swiss Federal Institute of Technology (ETH), Zurich,
Switzerland, 1971-72 and summer, 1980 Professor, Department of Civil Engineering, University of Minnesota, 1981-2010. Program Director for Environmental Engineering, National Science Foundation,
19
20
名字由来
➢ 1925，Water, Sewage, and Sanitation Chemistry ➢ 1958，Water, Air, and Waste Chemistry ➢ 1973，Environmental Chemistry ➢ 1962，Lee 科研项目‘water chemistry’ ➢ 1965，会议‘Principles and Applications of Water
Resources Centre （EAWAG）
6
7
➢ Albert Einstein World Award of Science (1985) ➢ Tyler Prize for Environmental Achievement (1986)--
-国际环境科学最高奖 ➢ Stockholm Water Prize (1999) ➢ V.M. Goldschmidt Medal (1999)--美国地球化学学
➢ advances in scientific approaches and Technology ➢ advances within the field that led to new areas or
会最高奖
8
9
James J. Morgan
Marvin L. Goldberger Professor of Environmental Engineering Science, Emeritus
California Institute of Technology ，美国工程院院士
b. 1932 B.C.E. 1954, Manhattan College M.S.E. 1956, University of Michigan M.A. 1962 and Ph.D. 1964, Harvard University D.Sc.H.C. 1989, Manhattan College
EnvirLeabharlann Baidunmental Aquatic Chemistry
绪论（Introduction）
2
课程目标
➢化学原理——认识水环境 what、why 组成、形态、转化、效应
➢定量——平衡与动力学过程求解 how ➢应用——水处理与水环境修复
3
成绩评定
➢平时成绩30%：作业、参与课程、出勤 ➢小论文30% ➢期末40%
Mark Benjamin （ James O. Leckie--Stumm）13
Leckie Benjamin
Stumm
Morgan Morel
Lee Brezonik
Hering
14
15
环境水化学研究圣地
瑞士联邦水质科学技术研究所EAWAG
16
EAWAG主要研究领域
Firmly anchored in its home country of Switzerland, but with a global network, Eawag is concerned with concepts and technologies for dealing sustainably with water bodies and with water as a resource. In collaboration with universities, other research institutions, public bodies, industry and non-governmental organisations, Eawag works to harmonise ecological, economic and social interests in respect of water usage. The Institute thus serves as a bridge between the scientific world and the ‘real world’.
Arlington, VA, 2004-2007
11
➢ Research Interests (1) mercury biogeochemistry (2) applications of remote sensing (mainly satellite imagery)
to evaluate lake quality (3) coupled biogeochemical cycles of carbon, nitrogen and
23
概念讨论
Water Chemistry & Aquatic Chemistry 水环境化学与环境水化学 环境水质学
24
Aquatic Environmental Chemistry Environmental Aquatic Chemistry Aqueous Environmental Chemistry Environmental Aqueous Geochemistry Environmental Water Chemistry Water Environmental Chemistry
Environ. Sci. Technol. 2012, 46, 5650−5657
28
HOW HAS WATER CHEMISTRY CHANGED OVER THE PAST 50 YEARS
➢ environmental quality and pollution issues that had a chemical focus
21
Stumm设想
Aquatic Chemistry的两条研究路线： • 欧美院系开展water treatment chemistry • Scandinavia院系和USGS开展hydrochemistry
22
what he wanted to do, and what we discussed, was to try to blend—give a sense of the unity of applications of chemistry to environmental problems, whether it was a lake, groundwater, an estuary, a river, or a treatment plant. And the argument we made was that aquatic systems, whether they’re engineered or natural, are going to be guided by very much the same core body of principles: acid/base chemistry, solubility, precipitation, electron transfer, complex formation. And the choice of “aquatic chemistry” [as a title] was not a frivolous（轻率的） choice; it was an attempt to say, “This is what we’re going to embrace. We’re going to embrace the chemistry of the aquatic environment whether it’s contained in a treatment plant or whether it’s out there.” ------Morgan JJ口述（ P73）
5
Werner Stumm
(1924-1999) ➢Ph. D, 1952, inorganic chemistry, University
of Zürich ➢1953-1969, Harvard University ➢1970-1992, Head of the Swiss Federal Water
17
污水厂升级改造 河岸过滤与供水
18
环境水化学发展历程
➢ 萌芽期（1960年以前）：从属地位 ➢ 转折与发展（1961-1970年）。Sillén The Physical
Chemistry of Seawater，学科自身学术价值 平衡观点、Geotitration、speciation Stumm （哈佛）和Lee （威斯康辛）热力学与动力学 ➢ 学科建立。1970, Stumm & Morgan, Aquatic Chemistry
water systems.
12
其他相关课本
François M. M. Morel Janet G. Hering
25
本课程主要内容
➢ 酸-碱平衡 ➢ 沉淀-溶解 ➢ 配位化学 ➢ 氧化还原反应 ➢ 表面化学与吸附 ➢ 水体颗粒物 ➢ 水体光解反应 ➢ 水体有机污染物
26
专题讨论
➢VMINEQL软件 ➢金属离子形态与生物有效性 ➢天然有机质（NOM） ➢沉积物质量 ➢营养元素（N、P）循环
27
环境水化学的学科地位
➢ Stumm W, Morgan J J. Aquatic Chemistry: Chemical Equilibria and Rates in Natural Water (3ed). John Wiley & Sons,
New York, 1996. 斯塔姆等，汤鸿霄等译。《水化学》。科学出版社，北京，1987。 ➢ 汤鸿霄。《环境水化学纲要》。 环境科学丛刊，1988。 ➢ 陈静生。《水环境化学》。高等教育出版社，北京，1988。 ➢ 期刊论文等。
Chemistry’ ➢ 1967，Stumm ‘Equilibrium Concepts in Natural
Waters’ ➢ 1970，Aquatic chemistry: An introduction
emphasizing chemical equilibria in natural waters
➢1966，Environmental Science and Technology 首任主编
10
Patrick L. Brezonik
➢ Education: B.S., 1963, Chemistry, Marquette University M.S., 1965, Water Chemistry, University of Wisconsin-Madison Ph.D., 1968, Water Chemistry, University of Wisconsin-Madison ➢ Experience: Assistant, Associate, and Full Professor, Department of Environmental Engineering
4
参考书目
➢ Brezonik P L, Arnold W A. Water Chemistry：An Introduction
to the Chemistry of Natural and Engineered Aquatic Systems.
Oxford University Press, New York, 2011. （教材）
Sciences, University of Florida, 1966-81 Guest Professor, EAWAG-Swiss Federal Institute of Technology (ETH), Zurich,
Switzerland, 1971-72 and summer, 1980 Professor, Department of Civil Engineering, University of Minnesota, 1981-2010. Program Director for Environmental Engineering, National Science Foundation,
19
20
名字由来
➢ 1925，Water, Sewage, and Sanitation Chemistry ➢ 1958，Water, Air, and Waste Chemistry ➢ 1973，Environmental Chemistry ➢ 1962，Lee 科研项目‘water chemistry’ ➢ 1965，会议‘Principles and Applications of Water
Resources Centre （EAWAG）
6
7
➢ Albert Einstein World Award of Science (1985) ➢ Tyler Prize for Environmental Achievement (1986)--
-国际环境科学最高奖 ➢ Stockholm Water Prize (1999) ➢ V.M. Goldschmidt Medal (1999)--美国地球化学学
➢ advances in scientific approaches and Technology ➢ advances within the field that led to new areas or
会最高奖
8
9
James J. Morgan
Marvin L. Goldberger Professor of Environmental Engineering Science, Emeritus
California Institute of Technology ，美国工程院院士
b. 1932 B.C.E. 1954, Manhattan College M.S.E. 1956, University of Michigan M.A. 1962 and Ph.D. 1964, Harvard University D.Sc.H.C. 1989, Manhattan College
EnvirLeabharlann Baidunmental Aquatic Chemistry
绪论（Introduction）
2
课程目标
➢化学原理——认识水环境 what、why 组成、形态、转化、效应
➢定量——平衡与动力学过程求解 how ➢应用——水处理与水环境修复
3
成绩评定
➢平时成绩30%：作业、参与课程、出勤 ➢小论文30% ➢期末40%
Mark Benjamin （ James O. Leckie--Stumm）13
Leckie Benjamin
Stumm
Morgan Morel
Lee Brezonik
Hering
14
15
环境水化学研究圣地
瑞士联邦水质科学技术研究所EAWAG
16
EAWAG主要研究领域
Firmly anchored in its home country of Switzerland, but with a global network, Eawag is concerned with concepts and technologies for dealing sustainably with water bodies and with water as a resource. In collaboration with universities, other research institutions, public bodies, industry and non-governmental organisations, Eawag works to harmonise ecological, economic and social interests in respect of water usage. The Institute thus serves as a bridge between the scientific world and the ‘real world’.
Arlington, VA, 2004-2007
11
➢ Research Interests (1) mercury biogeochemistry (2) applications of remote sensing (mainly satellite imagery)
to evaluate lake quality (3) coupled biogeochemical cycles of carbon, nitrogen and
23
概念讨论
Water Chemistry & Aquatic Chemistry 水环境化学与环境水化学 环境水质学
24
Aquatic Environmental Chemistry Environmental Aquatic Chemistry Aqueous Environmental Chemistry Environmental Aqueous Geochemistry Environmental Water Chemistry Water Environmental Chemistry
Environ. Sci. Technol. 2012, 46, 5650−5657
28
HOW HAS WATER CHEMISTRY CHANGED OVER THE PAST 50 YEARS
➢ environmental quality and pollution issues that had a chemical focus
21
Stumm设想
Aquatic Chemistry的两条研究路线： • 欧美院系开展water treatment chemistry • Scandinavia院系和USGS开展hydrochemistry
22
what he wanted to do, and what we discussed, was to try to blend—give a sense of the unity of applications of chemistry to environmental problems, whether it was a lake, groundwater, an estuary, a river, or a treatment plant. And the argument we made was that aquatic systems, whether they’re engineered or natural, are going to be guided by very much the same core body of principles: acid/base chemistry, solubility, precipitation, electron transfer, complex formation. And the choice of “aquatic chemistry” [as a title] was not a frivolous（轻率的） choice; it was an attempt to say, “This is what we’re going to embrace. We’re going to embrace the chemistry of the aquatic environment whether it’s contained in a treatment plant or whether it’s out there.” ------Morgan JJ口述（ P73）
5
Werner Stumm
(1924-1999) ➢Ph. D, 1952, inorganic chemistry, University
of Zürich ➢1953-1969, Harvard University ➢1970-1992, Head of the Swiss Federal Water
17
污水厂升级改造 河岸过滤与供水
18
环境水化学发展历程
➢ 萌芽期（1960年以前）：从属地位 ➢ 转折与发展（1961-1970年）。Sillén The Physical
Chemistry of Seawater，学科自身学术价值 平衡观点、Geotitration、speciation Stumm （哈佛）和Lee （威斯康辛）热力学与动力学 ➢ 学科建立。1970, Stumm & Morgan, Aquatic Chemistry