南京大学物理化学
- 1、下载文档前请自行甄别文档内容的完整性，平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益，请联系客服反馈,我们会尽快为您处理(人工客服工作时间：9:00-18:30)。
Electrochemistry Reference books
南京大学《物理化学》，北京大学《物理化学》
Atkins' Physical Chemistry, 7th Ed., Peter Atkins, Julio de Paula, Oxford University Press.
课件下载网址/
下载密码: jg4103
学习物理化学（电化学）的特点和要点
1.通过自学接受知识
2.学习严谨推理和归纳本领
3.掌握电化学的定位和特点
4.学习分析问题的方法
Physical Chemistry
Thermochemistry，Electrochemistry, Photochemistry，…
Colloid Chemistry，Catalysis，
Computational Chemistry，…
Electrochemistry Physical
Chemistry Solution electrochemistry
(electrolyte solution)
Equilibrium state
electrochemistry
Thermodynamics
Solid electrochemistry Photoelectrochemistry Bioelectrochemistry
Quantum Chemistry Statistical Thermodynamics
Three Characteristics of Electrochemistry
1. Long history 1. Long history
2. Wide application
2. Wide application
3. Electrochemical phenomena
exist everywhere
3. Electrochemical phenomena exist everywhere
Electrochemistry is over 200 Years Old! Luigi Galvani–Physician/Anatomist –“Animal Electricity”(1791)
1799
Volta Pile by A.Volta The most important gift
to 19th century!
Electrochemistry Science
Volta Pile
1. Long history
Alesandro Volta –“Metallic Electricity”(1800)
The Characteristics of Electrochemistry
1. Long history
1799Volta Pile
1834Faraday’s Law
1887Journal of Physical Chemistry
2. Wide Applications in Scientific Areas 2. Wide Applications in Scientific Areas Energy （battery, fuel cell, …)
Materials（electrolysis, electrodeposition, corrosion…）Life（heart-electroencephalogram, electrophoresis, …) Environment (sensor, waste treatment, …）Information（surface process, chip fabrication …）
3. Electrochemical Phenomena Exist Everywhere 3. Electrochemical Phenomena Exist Everywhere
water exists universally in our natural world
→electrolyte solution →charged ions(i)
μiα≠μiβi -charged particle
→spontaneous charge transfer
between two phases
μiα≠μiβi -charged particle →spontaneous transfer between phases, forming potential difference
(b)
μi α≠μ
i βi -charged particle →charge transfer between two phases (c)excess charge at the interface →potential difference
(a)→Electrolyte solution →charged ions i
water exists universally in our natural world
The Characteristics of Electrochemistry 1. Long history
2. Wide application
3. Existing everywhere
1. Long history
2. Wide application
3. Existing everywhere Charged particles
Multiphase systems