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Metal-Matrix Composites: Challenges and
Opportunities
Scope and Definitions
A metal-matrix composite (MMC) combines into a si ngle material a metallic base with a reinforcing constituent, which is usually non-metallic and is commonly a ceramic. By definition, MMCs are produced by means of processes other than conventional metal alloying. Like their polymer -matrix constituents (e.g. a metal and a ceramic fibre). Pro cesses commonly used include powder metallurgy, diffusion bonding, liquid phase sintering, squeeze infiltration and sti r-casting. Alternatively, the typically high reactivity of meta ls at processing temperatures can be exploited to form the reinforcement and/or the matrix in situ, i.e by chemical rea ction within a precursor of the composite.
There are several reasons why MMCs have generated considerable interest within the materials community for nearly 30 years.
(1)The “composite” approach to metallurgical processing is the
only pathway for the production of entire classes of metallic materials. Only in this way can aluminium, copper, or magnesium be combined with significant volume fractions of
carbide, oxide or nitride phases because, unlike iron, the solubility of carbon, nitrogen in the molten metal is (with the exception of O in Cu) far too low.
(2)The approach facilitates significant alterations in the physical
properties of metallic materials. Composites offer scope for exceeding the specific elastic modulus value of about 26 J/kg, which is exhibited by all the main engineering metals.
Composites also offer the only path-way for producing materials with tailored physical combinations:an example is that of low thermal expansivity combined with high thermal conductivity, a combination of importance for electronic packaging.
(3)MMCs offer significant improvements over their polymer
matrix counterparts with regard to several properties, including tolerance of high temperature, transverse strength, chemical inertness hardness and wear resistance, while significantly outperforming ceramic matrix composites in terms of toughness and ductility.
(4)Exceptional properties can be obtained in some cases. An
example is that of 3M’s Nextel-reinforced aluminium composites, which exhibit along the fibre direction a tensile strength of 1.5 Gpa, a compressive strenght of 3 Gpa and a
transverse strength above 200 Mpa, in a material of density only slightly above 3 g/cm-3.
MMCs come in several distinct classes, generally defined with reference to the shape of their reinforcement. Particle-reinforced metals (PRMs) contain approximately equiaxed reinforcements, with an aspect less than about 5. There are generally ceramic (SiC, Al2O3, etc.). PRMs commonly contain below 25 vol.% ceramic reinforcement when used for structural applications, but can have as much as 80 vol.% ceramic when used for electronic packaging. In general, PRMs are at least approximately isotropic. They are produced using both solid state (powder metallurgy) and liquid metal techniques (stir casting, infiltration). Their mechanical properties, while often inferior to those of fibre-reinforced metals, are more or less isotropic and often represent, at moderate cost, significant improvements over those of corresponding unreinforced metais.
Short fibre and whisker-reinforced metals. These contain reinforcements with an aspect ratio of greater than 5, but are not continuous. These composites are commonly produced by squeeze infiltration. They often form part of a locally reinforced component, generally produced to