半导体物理与器件第四版课后习题标准答案

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半导体物理与器件第四版课后习题标准答案4

Chapter 44.1⎪⎪⎭⎫ ⎝⎛-=kTE N N n gc i exp 2υ ⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=kT E T N N g O cO exp 3003υ where cO N and O N υ are the values at 300 K.4.2Plot_______________________________________ 4.3(a) ⎪⎪⎭⎫⎝⎛-=kT E N N n g c i exp 2υ()()()319192113001004.1108.2105⎪⎭⎫⎝⎛⨯⨯=⨯T()()⎥⎦⎤⎢⎣⎡-⨯0259.012.1exp T()3382330010912.2105.2⎪⎭⎫ ⎝⎛⨯=⨯T()()()()⎥⎦⎤⎢⎣⎡-⨯T 0259.030012.1expBy trial and error, 5.367≅T K (b)()252122105.2105⨯=⨯=i n()()()()()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=T T 0259.030012.1exp 30010912.2338By trial and error, 5.417≅T K_______________________________________ 4.4At 200=T K, ()⎪⎭⎫⎝⎛=3002000259.0kT017267.0=eVAt 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV()()()()17222102210025.31040.11070.7200400⨯=⨯⨯=ii nn⎥⎦⎤⎢⎣⎡-⎥⎦⎤⎢⎣⎡-⨯⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=017267.0exp 034533.0exp 30020030040033g g E E⎥⎦⎤⎢⎣⎡-=034533.0017267.0exp 8g g E E()[]9578.289139.57exp 810025.317-=⨯g Eor()1714.38810025.3ln 9561.2817=⎪⎪⎭⎫ ⎝⎛⨯=g E or 318.1=g E eV Now()32103004001070.7⎪⎭⎫⎝⎛=⨯o co N N υ⎪⎭⎫⎝⎛-⨯034533.0318.1exp()()172110658.2370.210929.5-⨯=⨯o co N N υso 371041.9⨯=o co N N υcm 6- _______________________________________ 4.5 ()()⎪⎭⎫ ⎝⎛-=⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛-=kT kT kT A n B n i i 20.0exp 90.0exp 10.1exp For 200=T K, 017267.0=kT eV For 300=T K, 0259.0=kT eVFor 400=T K, 034533.0=kT eV (a) For 200=T K,()()610325.9017267.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i(b) For 300=T K,()()41043.40259.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (c) For 400=T K, ()()31005.3034533.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i_______________________________________ 4.6(a) ()⎥⎦⎤⎢⎣⎡---∝kT E E E E f g F c F c exp ()⎥⎦⎤⎢⎣⎡---∝kT E E E E c c exp()⎥⎦⎤⎢⎣⎡--⨯kT E E F c exp Let x E E c =-Then ⎪⎭⎫⎝⎛-∝kT x x f g F c exp To find the maximum value: ()⎪⎭⎫⎝⎛-∝-kT x x dx f g d F c exp 212/10exp 12/1=⎪⎭⎫ ⎝⎛-⋅-kT x x kTwhich yields 2212/12/1kT x kT x x =⇒= The maximum value occurs at2kTE E c += (b) ()()⎥⎦⎤⎢⎣⎡---∝-kT E E E E f g F F exp 1υυ ()⎥⎦⎤⎢⎣⎡---∝kT E E E E υυexp ()⎥⎦⎤⎢⎣⎡--⨯kT E E F υexp Let x E E =-υ Then ()⎪⎭⎫ ⎝⎛-∝-kT x x f g F exp 1υ To find the maximum value ()[]0exp 1=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛-∝-kT x x dx d dx f g d F υ Same as part (a). Maximum occurs at 2kTx =or 2kT E E -=υ _______________________________________ 4.7 ()()()()⎥⎦⎤⎢⎣⎡---⎥⎦⎤⎢⎣⎡---=kT E E E E kT E E E E E n E n c c c c 221121exp exp where kT E E c 41+= and 22kT E E c += Then()()()⎥⎦⎤⎢⎣⎡--=kT E E kT kTE n E n 2121exp 24()5.3exp 22214exp 22-=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛--=or()()0854.021=E n E n_______________________________________ 4.8Plot_______________________________________ 4.9Plot_______________________________________ 4.10⎪⎪⎭⎫ ⎝⎛=-**ln 43n pmidgap Fi m m kT E ESilicon: o p m m 56.0*=, o n m m 08.1*=0128.0-=-midgap Fi E E eVGermanium: o p m m 37.0*=,o n m m 55.0*=0077.0-=-midgap Fi E E eV Gallium Arsenide: o p m m 48.0*=, o n m m 067.0*=0382.0+=-midgap Fi E E eV_______________________________________ 4.11 ()⎪⎪⎭⎫ ⎝⎛=-c midgap Fi N N kT E E υln 21 ()()kT kT 4952.0108.21004.1ln 211919-=⎪⎪⎫ ⎛⨯⨯= 4.12 (a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n pmidgap Fi m m kT E E ()⎪⎭⎫⎝⎛=21.170.0ln 0259.043 63.10-⇒meV(b) ()⎪⎭⎫⎝⎛=-080.075.0ln 0259.043midgap Fi E E47.43+⇒meV_______________________________________ 4.13Let ()==K E g c constant Then()()dE E fE g n FE co c⎰∞=dE kT E E Kc E F⎰∞⎪⎪⎭⎫⎝⎛-+=exp 11()dE kT E E K cE F ⎰∞⎥⎦⎤⎢⎣⎡--≅exp Let kTE E c-=η so that ηd kT dE ⋅= We can write ()()c F c F E E E E E E -+-=- so that()()()η-⋅⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--exp exp exp kT E E kT E E F c F The integral can then be written as ()()ηηd kT E E kT K n F c o ⎰∞-⎥⎦⎤⎢⎣⎡--⋅⋅=0exp exp which becomes ()⎥⎦⎤⎢⎣⎡--⋅⋅=kT E E kT K n F c o exp _______________________________________ 4.14 Let ()()c c E E C E g -=1 for c E E ≥Then()()dE E f E g n F E c o c⎰∞=()dE kT E E E E C c E F c ⎰∞⎪⎪⎭⎫ ⎝⎛-+-=exp 11()()dE kT E E E E C F E C c⎥⎦⎤⎢⎣⎡---≅⎰∞exp 1LetkTE E c-=η so that ηd kT dE ⋅= We can write()()F c c F E E E E E E -+-=- Then()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1()()dE kT E E E E c E c c⎥⎦⎤⎢⎣⎡---⨯⎰∞exp or()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1 ()()()[]()ηηηd kT kT -⨯⎰∞exp 0We find that()()()11exp exp 0+=---=-∞∞⎰ηηηηηdSo()()⎥⎦⎤⎢⎣⎡--=kT E E kT C n F c o exp 21 _______________________________________ 4.15We have ⎪⎪⎭⎫⎝⎛=∈*1m m a r o r o For germanium, 16=∈r , o m m 55.0*= Then()()()53.02955.01161=⎪⎭⎫⎝⎛=o a roroA r 4.151=The ionization energy can be written as ()6.132*⎪⎪⎭⎫⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E eV ()()029.06.131655.02=⇒=E eV _______________________________________ 4.16We have⎪⎪⎭⎫ ⎝⎛=∈*1m m a r o r o For gallium arsenide, 1.13=∈r ,o m m 067.0*= Then()()oA r 10453.0067.011.131=⎪⎭⎫⎝⎛= The ionization energy is ()()()6.131.13067.06.1322*=⎪⎪⎭⎫ ⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E or0053.0=E eV_______________________________________ 4.17(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1519107108.2ln 0259.02148.0=eV (b) ()F c g F E E E E E --=-υ90518.02148.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp()⎥⎦⎤⎢⎣⎡-⨯=0259.090518.0exp 1004.11931090.6⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1107ln 0259.0338.0=eV_______________________________________ 4.18(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.0162.0=eV(b) ()υE E E E E F g F c --=- 958.0162.012.1=-=eV(c) ()⎪⎭⎫⎝⎛-⨯=0259.0958.0exp 108.219o n31041.2⨯=cm 3-(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1016105.1102ln 0259.0365.0=eV_______________________________________ 4.19(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=519102108.2ln 0259.08436.0=eV ()F c g F E E E E E --=-υ 8436.012.1-= 2764.0=-υE E F eV (b) ()⎪⎭⎫ ⎝⎛-⨯=0259.027637.0exp 1004.119o p 1410414.2⨯=cm 3- (c) p-type_______________________________________ 4.20(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.028.0exp 300375107.42/317o n 141015.1⨯=cm 3-()28.042.1-=--=-F c g F E E E E E υ 14.1=eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.014.1exp 3003751072/318o p 31099.4⨯=cm 3-(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=-14171015.1107.4ln 0259.0F c E E2154.0=eV()2154.042.1-=--=-F c g F E E E E E υ 2046.1=eV()⎥⎦⎤⎢⎣⎡-⨯=0259.02046.1exp 10718o p 21042.4-⨯=cm 3-_______________________________________ 4.21(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.028.0exp 300375108.22/319o n 151086.6⨯= cm 3-()28.012.1-=--=-F c g F E E E E E υ 840.0=eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.0840.0exp 3003751004.12/319o p 71084.7⨯=cm 3-(b) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=151910862.6108.2ln 0259.02153.0=eV9047.02153.012.1=-=-υE E F eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0904668.0exp 1004.119o p31004.7⨯=cm 3-_______________________________________ 4.22(a) p-type(b) 28.0412.14===-g F E E E υeV()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp ()⎥⎦⎤⎢⎣⎡-⨯=0259.028.0exp 1004.119141010.2⨯=cm 3- ()υE E E E E F g F c --=- 84.028.012.1=-=eV()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.084.0exp 108.21951030.2⨯=cm 3-_______________________________________ 4.23(a) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 105.110 131033.7⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 105.11061007.3⨯=cm 3-(b) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp ()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 108.16 91080.8⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 108.1621068.3⨯=cm 3-_______________________________________ 4.24(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=151********.1ln 0259.01979.0=eV (b) ()υE E E E E F g F c --=- 92212.019788.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡-⨯=0259.092212.0exp 108.219o n 31066.9⨯=cm 3-(d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1105ln 0259.03294.0=eV _______________________________________ 4.25()034533.03004000259.0=⎪⎭⎫⎝⎛=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3-()2/319300400108.2⎪⎭⎫⎝⎛⨯=c N19103109.4⨯=cm 3-()()1919210601.1103109.4⨯⨯=i n⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 24106702.5⨯= 1210381.2⨯=⇒i n cm 3- (a) ⎪⎪⎭⎫ ⎝⎛=-oF pN kT E E υυln ()⎪⎪⎭⎫⎝⎛⨯⨯=151910510601.1ln 034533.02787.0=eV(b) 84127.027873.012.1=-=-F c E E eV(c) ()⎥⎦⎤⎢⎣⎡-⨯=034533.084127.0exp 103109.419o n 910134.1⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=121510381.2105ln 034533.02642.0=eV _______________________________________ 4.26(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 10718o p 141050.4⨯=cm 3-17.125.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.017.1exp 107.417o n 21013.1-⨯=cm 3- (b) 034533.0=kT eV ()2/318300400107⎪⎭⎫⎝⎛⨯=υN1910078.1⨯=cm 3- ()2/317300400107.4⎪⎭⎫⎝⎛⨯=c N1710236.7⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191050.410078.1ln 034533.03482.0=eV072.13482.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.007177.1exp 10236.717o n 41040.2⨯=cm 3-_____________________________________ 4.27(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 1004.119o p141068.6⨯=cm 3-870.025.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0870.0exp 108.219o n 41023.7⨯=o n cm 3- (b) 034533.0=kT eV ()2/3193004001004.1⎪⎭⎫ ⎝⎛⨯=υN1910601.1⨯=cm 3- ()2/319300400108.2⎪⎭⎫ ⎝⎛⨯=c N1910311.4⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191068.610601.1ln 034533.03482.0=eV7718.03482.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.077175.0exp 10311.419o n 91049.8⨯=cm 3-_______________________________________ 4.28(a) ()F c o F N n ηπ2/12=For 2kT E E c F +=,5.02==-=kTkT kT E E c F F η Then ()0.12/1≅F F η()()0.1108.2219⨯=πo n191016.3⨯=cm 3-(b) ()F c o F N n ηπ2/12=()()0.1107.4217⨯=π171030.5⨯=cm 3-_______________________________________ 4.29()Fo F N p ηπυ'=2/12()()FF ηπ'⨯=⨯2/119191004.12105So ()26.42/1='FF η We find kTE E FF-=≅'υη0.3()()0777.00259.00.3==-F E E υeV_______________________________________ 4.30(a) 44==-=kTkTkT E E c F F ηThen ()0.62/1≅F F η()F c o F N n ηπ2/12=()()0.6108.2219⨯=π201090.1⨯=cm 3-(b) ()()0.6107.4217⨯=πo n181018.3⨯=cm 3-_______________________________________ 4.31For the electron concentration ()()()E f E g E n F c =The Boltzmann approximation applies, so ()()c nE E h m E n -=32/3*24π()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or()()()⎥⎦⎤⎢⎣⎡--=kT E E h m E n F c nexp 2432/3*π()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTc c exp DefinekTE E x c-=Then ()()()x x K x n E n -=→exp To find maximum ()()x n E n →, set()()x x K dx x dn -⎢⎣⎡==-exp 2102/1 +()()⎥⎦⎤--x x exp 12/1or()⎥⎦⎤⎢⎣⎡--=-x x Kx 21exp 02/1which yieldskT E E kT E E x c c 2121+=⇒-==For the hole concentration ()()()[]E f E g E p F -=1υUsing the Boltzmann approximation ()()E E h m E p p-=υπ32/3*24()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or()()()⎥⎦⎤⎢⎣⎡--=kT E E h m E p F pυπexp 2432/3*()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTυυexp DefinekTEE x -='υThen()()x x K x p '-''='exp To find maximum value of ()()x p E p '→, set()0=''x d x dp Using the results from above,we find the maximum atkT E E 21-=υ_______________________________________ 4.32(a) Silicon: We have()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp We can write()()F d d c F c E E E E E E -+-=- For045.0=-d c E E eV and kT E E F d 3=-eV we can write()⎥⎦⎤⎢⎣⎡--⨯=30259.0045.0exp 108.219o n ()()737.4exp 108.219-⨯=or171045.2⨯=o n cm 3- We also have()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp Again, we can write()()υυE E E E E E a a F F -+-=- ForkT E E a F 3=- and 045.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=0259.0045.03exp 1004.119o p()()737.4exp 1004.119-⨯=or161012.9⨯=o p cm 3-(b) GaAs: assume 0058.0=-d c E E eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00058.0exp 107.417o n()()224.3exp 107.417-⨯= or161087.1⨯=o n cm 3-Assume 0345.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00345.0exp 10718o p()()332.4exp 10718-⨯=or161020.9⨯=o p cm 3-_______________________________________ 4.33Plot_______________________________________ 4.34(a) 151510310154⨯=-⨯=o p cm 3- ()415210105.7103105.1⨯=⨯⨯=on cm 3-(b) 16103⨯==d o N n cm 3- ()316210105.7103105.1⨯=⨯⨯=o p cm 3-(c) 10105.1⨯===i o o n p n cm 3-(d) ()()3191923003751004.1108.2⎪⎭⎫⎝⎛⨯⨯=i n()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030012.1exp1110334.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()8152111034.110410334.7⨯=⨯⨯=o n cm 3-(e) ()()3191923004501004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030012.1exp1310722.1⨯=⇒i n cm 3-()2132141410722.1210210⨯+⎪⎪⎭⎫ ⎝⎛+=o n1410029.1⨯=cm 3-()12142131088.210029.110722.1⨯=⨯⨯=op cm 3-_______________________________________ 4.35(a) 151510104-⨯=-=d a o N N p 15103⨯=cm 3-()3152621008.1103108.1-⨯=⨯⨯==o i o p n n cm 3-(b) 16103⨯==d o N n cm 3- ()416261008.1103108.1-⨯=⨯⨯=op cm 3-(c) 6108.1⨯===i o o n p n cm 3-(d) ()()318172300375100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030042.1exp810580.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()215281044.110410580.7⨯=⨯⨯=on cm 3-(e) ()()318172300450100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030042.1exp1010853.3⨯=⇒i n cm 3- 1410==d o N n cm 3-()7142101048.11010853.3⨯=⨯=o p cm 3-_______________________________________ 4.36(a) Ge: 13104.2⨯=i n cm 3-(i)2222i d d o n N N n +⎪⎪⎭⎫⎝⎛+=()21321515104.221022102⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=or15102⨯=≅d o N n cm 3-()152132102104.2⨯⨯==o i o n n p111088.2⨯= cm 3-(ii)151610710⨯-=-≅d a o N N p 15103⨯=cm 3- ()152132103104.2⨯⨯==o i o p n n111092.1⨯=cm 3- (b) GaAs: 6108.1⨯=i n cm 3- (i)15102⨯=≅d o N n cm()315261062.1102108.1-⨯=⨯⨯=op cm 3-(ii)15103⨯=-≅d a o N N p cm 3-()315261008.1103108.1-⨯=⨯⨯=on cm 3-(c) The result implies that there is only one minority carrier in a volume of 310cm 3. _______________________________________ 4.37(a) For the donor level⎪⎪⎭⎫ ⎝⎛-+=kT E E N n F d d d exp 2111⎪⎭⎫ ⎝⎛+=0259.020.0exp 2111or41085.8-⨯=dd N n(b) We have()⎪⎪⎭⎫ ⎝⎛-+=kTE E E f FF exp 11Now()()F c c F E E E E E E -+-=- or245.0+=-kT E E F Then()⎪⎭⎫⎝⎛++=0259.0245.01exp 11E f For()51087.2-⨯=E f F_______________________________________ 4.38(a) ⇒>d a N N p-type (b) Silicon:1313101105.2⨯-⨯=-=d a o N N p or13105.1⨯=o p cm 3- Then()7132102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- Germanium:2222i da d a o n N N N N p +⎪⎪⎭⎫ ⎝⎛-+-=()21321313104.22105.12105.1⨯+⎪⎪⎭⎫⎝⎛⨯+⎪⎪⎭⎫ ⎝⎛⨯=or131026.3⨯=o p cm 3- Then()131321321076.110264.3104.2⨯=⨯⨯==o i o p n n cm 3-Gallium Arsenide:13105.1⨯=-=d a o N N p cm 3- and()216.0105.1108.113262=⨯⨯==o i o p n n cm 3- _______________________________________ 4.39(a) ⇒>a d N N n-type(b) 1515102.1102⨯-⨯=-≅a d o N N n 14108⨯=cm 3-()51421021081.2108105.1⨯=⨯⨯==o i o n n p cm 3- (c) ()d a ao N N N p -+'≅ 151515102102.1104⨯-⨯+'=⨯aN 15108.4⨯='⇒aN cm 3-()41521010625.5104105.1⨯=⨯⨯=on cm 3-_______________________________________ 4.40()155210210125.1102105.1⨯=⨯⨯==o i o p n n cm 3- ⇒>o o p n n-type_______________________________________ 4.41()()318192300250100.61004.1⎪⎭⎫⎝⎛⨯⨯=in()()⎥⎦⎤⎢⎣⎡-⨯3002500259.066.0exp24108936.1⨯=1210376.1⨯=⇒i n cm 3- 2222414i o o i o i o n n n n p n n =⇒==i o n n 21=⇒ So 111088.6⨯=o n cm 3-,Then 121075.2⨯=o p cm 3-2222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 212210752.2⎪⎪⎭⎫ ⎝⎛-⨯a N 242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=a N()21224210752.2105735.7⎪⎪⎭⎫ ⎝⎛+⨯-⨯aa N N 242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=aN so that 1210064.2⨯=a N cm 3-_______________________________________ 4.42Plot_______________________________________ 4.43Plot_______________________________________ 4.44Plot_______________________________________ 4.452222i ad a d o n N N N N n +⎪⎪⎭⎫ ⎝⎛-+-= 2102.1102101.1141414⨯-⨯=⨯2214142102.1102i n +⎪⎪⎭⎫⎝⎛⨯-⨯+()()221321314104104101.1i n +⨯=⨯-⨯22727106.1109.4i n +⨯=⨯ so 131074.5⨯=i n cm 3-1314272103101.1103.3⨯=⨯⨯==o i o n n p cm 3- _______________________________________ 4.46(a) ⇒>d a N N p-typeMajority carriers are holes1616105.1103⨯-⨯=-=d a o N N p16105.1⨯=cm 3-Minority carriers are electrons()4162102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- (b) Boron atoms must be addedd a ao N N N p -+'=161616105.1103105⨯-⨯+'=⨯aN So 16105.3⨯='aN cm 3-()316210105.4105105.1⨯=⨯⨯=on cm 3-_______________________________________ 4.47(a) ⇒<<i o n p n-type(b) oi o o i o p n n n n p 22=⇒=on ()16421010125.1102105.1⨯=⨯⨯=cm 3-⇒electrons are majority carriers4102⨯=o p cm 3-⇒holes are minority carriers (c) a d o N N n -=151610710125.1⨯-=⨯d N so 1610825.1⨯=d N cm 3-_______________________________________ 4.48⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln1510=N cm 3- 4.49 (a) ⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln ()⎪⎪⎭⎫⎝⎛⨯=d N 19108.2ln 0259.0 For 1410cm 3-, 3249.0=-F c E E eV1510cm 3-, 2652.0=-F c E E eV1610cm 3-, 2056.0=-F c E E eV 1710cm 3-, 1459.0=-F c E E eV (b) ⎪⎪⎭⎫⎝⎛=-i d Fi F n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=10105.1ln 0259.0d N For 1410cm 3-, 2280.0=-Fi F E E eV 1510cm 3-, 2877.0=-Fi F E E eV 1610cm 3-, 3473.0=-Fi F E E eV 1710cm 3-, 4070.0=-Fi F E E eV_______________________________________ 4.50(a) 2222i dd o n N N n +⎪⎪⎭⎫ ⎝⎛+= 151005.105.1⨯==d o N n cm 3- ()21515105.01005.1⨯-⨯()2215105.0i n +⨯=so 2821025.5⨯=i n Now()()3191923001004.1108.2⎪⎭⎫ ⎝⎛⨯⨯=T n i()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382830010912.21025.5⎪⎭⎫ ⎝⎛⨯=⨯T⎥⎦⎤⎢⎣⎡-⨯T 973.12972exp By trial and error, 5.536=T K (b) At 300=T K,⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln ()⎪⎪⎭⎫⎝⎛⨯=-151910108.2ln 0259.0F c E E2652.0=eV At 5.536=T K,()046318.03005.5360259.0=⎪⎭⎫⎝⎛=kT eV()2/3193005.536108.2⎪⎭⎫ ⎝⎛⨯=c N1910696.6⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=-15191005.110696.6ln 046318.0F c E E5124.0=eV then ()2472.0=-∆F c E E eV (c) Closer to the intrinsic energy level._______________________________________ 4.51⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln At 200=T K, 017267.0=kT eV 400=T K, 034533.0=kT eV 600=T K, 0518.0=kT eV At 200=T K,()()3191923002001004.1108.2⎪⎭⎫⎝⎛⨯⨯=i n⎥⎦⎤⎢⎣⎡-⨯017267.012.1exp410638.7⨯=⇒i n cm 3- At 400=T K,()()3191923004001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 1210381.2⨯=⇒i n cm 3-At 600=T K,()()3191923006001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯0518.012.1exp 1410740.9⨯=⇒i n cm 3- At 200=T K and 400=T K, 15103⨯==a o N p cm 3- At 600=T K,2222i a a o n N N p +⎪⎪⎭⎫⎝⎛+=()2142151510740.921032103⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=1510288.3⨯=cm 3-Then, 200=T K, 4212.0=-F Fi E E eV 400=T K, 2465.0=-F Fi E E eV600=T K, 0630.0=-F Fi E E eV_______________________________________ 4.52(a)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-6108.1ln 0259.0ln a i a F Fi N n N kT E E For 1410=a N cm 3-,4619.0=-F Fi E E eV 1510=a N cm 3-,5215.0=-F Fi E E eV1610=a N cm 3-,5811.0=-F Fi E E eV1710=a N cm 3-,6408.0=-F Fi E E eV (b)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-a a F N N N kT E E 18100.7ln 0259.0ln υυ For 1410=a N cm 3-,2889.0=-υE E F eV1510=a N cm 3-,2293.0=-υE E F eV1610=a N cm 3-,1697.0=-υE E F eV 1710=a N cm 3-, 1100.0=-υE E F eV_______________________________________ 4.53 (a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E()()10ln 0259.043= or0447.0+=-midgap Fi E E eV (b) Impurity atoms to be added so 45.0=-F midgap E E eV (i) p-type, so add acceptor atoms (ii)4947.045.00447.0=+=-F Fi E E eV Then⎪⎪⎭⎫⎝⎛-=kT E E n p F Fi i o exp()⎪⎭⎫⎝⎛=0259.04947.0exp 105or131097.1⨯==a o N p cm 3-_______________________________________ 4.54()⎥⎦⎤⎢⎣⎡--=-=kT E E N N N n F c c a d o exp so()⎪⎭⎫⎝⎛-⨯+⨯=0259.0215.0exp 108.21051915d N15151095.6105⨯+⨯= or16102.1⨯=d N cm 3-_______________________________________ 4.55(a) Silicon(i)⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()2188.0106108.2ln 0259.01519=⎪⎪⎭⎫⎝⎛⨯⨯=eV(ii)1929.00259.02188.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡--=kT E E N N F c c d exp()⎥⎦⎤⎢⎣⎡-⨯=0259.01929.0exp 108.2191610631.1⨯=d N cm 3-15106⨯+'=dN 1610031.1⨯='⇒dN cm 3- Additionaldonor atoms (b) GaAs(i)()⎪⎪⎭⎫⎝⎛⨯=-151710107.4ln 0259.0F c E E15936.0=eV(ii)13346.00259.015936.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.013346.0exp 107.417d N1510718.2⨯=cm 3-1510+'=dN 1510718.1⨯='⇒dN cm 3- Additionaldonor atoms_______________________________________ 4.56(a) ⎪⎪⎭⎫⎝⎛=-a F Fi N N kT E E υln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.01620.0=eV(b) ⎪⎪⎭⎫⎝⎛=-d c Fi F N N kT E E ln()1876.0102108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯⨯=eV(c) For part (a);16102⨯=o p cm 3- ()162102102105.1⨯⨯==o i o p n n410125.1⨯=cm 3- For part (b):16102⨯=o n cm 3-()162102102105.1⨯⨯==o i o n n p 410125.1⨯=cm 3-_______________________________________ 4.57⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp()⎥⎦⎤⎢⎣⎡⨯=0259.055.0exp 108.16 15100.3⨯=cm 3- Add additional acceptor impurities a d o N N n -=a N -⨯=⨯151510710315104⨯=⇒a N cm 3-_______________________________________ 4.58(a) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()3161.0105.1103ln 0259.01015=⎪⎪⎭⎫⎝⎛⨯⨯=eV(b) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()3758.0105.1103ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV(c) Fi F E E =(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=111510334.7104ln 3003750259.0 2786.0=eV(e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=131410722.110029.1ln 3004500259.0 06945.0=eV_______________________________________ 4.59(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()2009.0103100.7ln 0259.01518=⎪⎪⎭⎫⎝⎛⨯⨯=eV(b) ()⎪⎪⎭⎫ ⎝⎛⨯⨯=--4181008.1100.7ln 0259.0υE E F 360.1=eV(c) ()⎪⎪⎭⎫⎝⎛⨯⨯=-618108.1100.7ln 0259.0υE E F7508.0=eV(d) ()⎪⎭⎫⎝⎛=-3003750259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯152/318104300375100.7ln 2526.0=eV(e) ()⎪⎭⎫⎝⎛=-3004500259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯72/3181048.1300450100.7ln 068.1=eV_______________________________________ 4.60n-type⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()3504.0105.110125.1ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV ______________________________________ 4.612222i a a o n N N p +⎪⎪⎭⎫⎝⎛+= 21051008.51515⨯=⨯22152105i n +⎪⎪⎭⎫⎝⎛⨯+ ()21515105.21008.5⨯-⨯()2215105.2i n +⨯=230301025.6106564.6i n +⨯=⨯ 29210064.4⨯=⇒i n⎥⎦⎤⎢⎣⎡-=kT E N N n g c i exp 2υ()030217.03003500259.0=⎪⎭⎫⎝⎛=kT eV()1921910633.1300350102.1⨯=⎪⎭⎫ ⎝⎛⨯=c N cm 3-()192191045.2300350108.1⨯=⎪⎭⎫ ⎝⎛⨯=υN cm 3- Now()()1919291045.210633.110064.4⨯⨯=⨯⎥⎦⎤⎢⎣⎡-⨯030217.0exp g ESo()()()⎥⎦⎤⎢⎣⎡⨯⨯⨯=29191910064.41045.210633.1ln 030217.0g E 6257.0=⇒g E eV_______________________________________ 4.62(a) Replace Ga atoms ⇒Silicon acts as adonor()()1415105.310705.0⨯=⨯=d N cm 3-Replace As atoms ⇒Silicon acts as anacceptor()()15151065.610795.0⨯=⨯=a N cm 3-(b) ⇒>d a N N p-type(c) 1415105.31065.6⨯-⨯=-=d a o N N p 15103.6⨯=cm 3-()4152621014.5103.6108.1-⨯=⨯⨯==o i o p n n cm 3- (d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()5692.0108.1103.6ln 0259.0615=⎪⎪⎭⎫⎝⎛⨯⨯=eV_______________________________________。

半导体物理与器件第四版课后习题答案(供参考).doc

Chapter 44.1n i 2E gN c N expkTT 3E gexpN cO N O300kTwhere N cO and N Oare the values at 300 K.(a) SiliconT (K) kT (eV) n i (cm 3) 200 0.01727 7.68 104 400 0.03453 2.38 1210 6000.05189.74 1014(c) GaAs(b) GermaniumT (K)n i (cm 3 ) n i (cm 3 ) 200 2.16 10101.38 4008.60 1014 3.28 109 6003.82 10165.72 1012_______________________________________ 4.2Plot_______________________________________4.3(a) n i 2 N c NexpE gkT31121919T5 2.8 1.04 101010300exp1.120.0259 T 300T 32.5 10 232.912 10 38300exp1.12 3000.0259 TBy trial and error, T 367.5 K(b)n i25 10 1222.5 10 2532.912 10 38T exp 1.12 300300 0.0259 TBy trial and error,T 417.5 K _______________________________________4.4At T200 K, kT0.02592003000. 017267eVAt T400 K, kT0.02594003000. 034533eVn i 2400 7.70 101023.025 10 17n i 2 2001.40 10 2 23400expE g3000.0345333200Egexp300 0.017267E gE g8 exp0.0345330.0172673.025 10178 exp E g 57 .9139 28.9578orE g 28.9561ln 3.025 1017 38.17148 or E g 1.318 eVNow7.70 1010N co N o340023001.318 exp0.03453321N co N o 2.370 175.929 10 2.658 10so N co N o 9.41 10 37 cm 6_______________________________________4.5exp 1.10n i kT 0.20Bexpn i A 0.90 kTexp kTFor T 200 K, kT 0.017267 eVFor T 300 K, kT 0.0259 eVFor T 400 K, kT 0.034533 eV(a) For T 200K,n i B exp 0.20 9.325 10 6n i A 0.017267(b) For T 300K,n i Bexp 0.204.43 10 4n i A 0.0259 (c) For T 400K,n i Bexp 0.203.05 10 3n i A 0.034533_______________________________________ 4.6(a) g c f FE E FE E c expkTThen g c f F x expxkTTo find the maximum value:d g c f F 1 x1 / 2 exp xdx 2 kT1 x1 /2 exp x 0kT kTwhich yields1/ 21 x kT2x1/ 2 x 2kTThe maximum value occurs atEkTE c2(b)g 1 f FE F EE E expkTE EE E expkTexpE F EkTLet E E xThen g 1 f F x expxkTTo find the maximum valued g 1 f F d xdx dxx expkTSame as part (a). Maximum occurs atxkT2E E c exp E E ckTorkTE E2E c EF expkTLet E E c x _______________________________________ 4.7E1 E c exp E1 E cn E1 kTn E2E2 E c exp E2 E c kTwhereE1 E c 4kT and E 2 E c kT 2Thenn E1 4kTexp E1 E2n E2 kT kT22 2 exp 4 12 exp 3.522orn E10.0854n E 2_______________________________________ 4.8Plot_______________________________________4.9Plot_______________________________________ 4.10E Fi E midgap 3kT ln m*pm n* 4Silicon: m*p 0.56 m o , m n* 1.08m oE Fi E midgap 0.0128 eVGermanium: m*p 0. 37m o ,*0.55m om nE Fi E midgap 0 .0077 eVGallium Arsenide: m*p 0.48m o ,m n* 0.067m oE Fi E midgap 0 .0382 eV_______________________________________ 4.11E Fi E midgap 1 kT ln N2 N c1kT ln 1.04 1019 0.4952 kT2 2.8 1019T (K) kT (eV) ( E Fi E midgap )(eV) 200 0.01727 0.0086 400 0.03453 0.0171 600 0.0518 0.0257_______________________________________4.12(a) E Fi E midgapm*p3 kT ln4 m n*3 0.0259 ln0.704 1.2110.63 meV(b) E Fi E midgap 3 0.0259 ln0.754 0.08043.47 meV_______________________________________4.13Let g c E K constantThenn o g c E f F E dEE cK1dEE E FEc 1 expkTK expE E FdEkTE cLetE E cso that dE kT dkTWe can writeE EF E c E F E E cso thatE E Fexp E c E FexpexpkTkTThe integral can then be written asn o K kT exp E c E Fexp d kTwhich becomesn o K kTE c EF expkT_______________________________________4.14Let g c E C1E E c for E E cThenn o g c E f F E dEE cC1 E E cdEE c 1exp E EF kTC1 EE E FdE E C expE ckTLetE E cdE kT dso thatkTWe can writeE EF E E c E c E FThenE c E Fn o C1 expkTE E cE E cdE expE ckT orn oE c EF C1 expkTkT exp kT d 0We find thatexp d exp 1 1So2 E c E Fn o C1 kT expkT_______________________________________4.15r1 m oWe have rm*a oFor germanium, r 16 , m* 0.55m oThenr1 16 1 a o 29 0.530.55oror1 15.4 AThe ionization energy can be written asm*2E o 13.6 eVm o s0.552 13.6 E 0.029 eV16_______________________________________ 4.16We have r1 m orm*a oFor gallium arsenide, r 13.1 , *m0.067 m o1or1 13.1 104 A0.530.067The ionization energy ism*20.067E o 13.6 13.6m o s 13.1 2orE0.0053 eV_______________________________________4.17Nc(a) E c E F kT ln2.8 10190.0259 ln 157 100.2148 eV(b) E F E E g E c E F1.12 0.2148 0.90518eV(c) p o NE F E expkT1.04 19 0.9051810 exp0.02596.90 103cm 3(d) Holesn o(e) E F E Fi kT lnn i710 150.0259 ln1.5 10100.338 eV_______________________________________4.18N(a) E F E kT lnp o190.0259 ln 1.0410210160.162 eV(b) E c E F E g E F E1.12 0.162 0.958 eV(c) n o 2.8 19 0.95810 exp0.02592.41 103cm3p o(d) E Fi E F kT lnn i2 10 160.0259 ln 101.5 100.365eV_______________________________________4.19Nc(a) E c E F kT ln0.0259 ln 2.810192 1050.8436 eVE F E E g E c E F1.12 0.8436E F E 0.2764 eV(b) p o 1.04 1019 exp 0.276370.02592.414 1014cm3(c)p-type_______________________________________4.20(a) kT3750.032375 eV0.02593003 / 2n o 4.7 10 17 375 exp 0.28300 0.0323751.15 1014cm3E F E E g E c E F 1.42 0.281.14 eV375 3 / 2 1.14 p o 7 18 exp10300 0.0323754.99 103cm 3(b) E c E F 0.0259 ln 4.7 10171.15 10 140.2154 eVE F E E g E c E F 1.42 0.21541.2046 eVp o 7 10 18 exp 1.20460.02594.42 10 2cm 3_______________________________________ 4.21(a) kT 0.0259 3750.032375 eV 300375 3 / 2 0.28n o 2.8 19 exp10300 0.0323756.86 1015cm 3E F E E g E c E F 1.12 0.280.840 eV375 3 / 20.840p o 1.04 1019 exp300 0.0323757.84 107cm 3(b) E c E F kT ln N cn o0.0259 ln2.8 10196.862 10 150.2153 eVE F E 1.12 0.2153 0.9047 eVp o 1.04 10 19 exp 0.9046680.02597.04 103 cm 3_______________________________________4.22(a) p-typeE g(b) E F E1.124 0.28 eV4p o N exp E F EkT1.04 10 19 exp 0.280.02592.10 1014cm 3E c EF E g E F E1.12 0.28 0.84 eVn o N c exp E c E FkT2.8 1019exp0.840.02592.30 105cm 3_______________________________________4.23(a) n o n iE F E FiexpkT1.5 1010 exp 0.220.02597.3313cm310p oE Fi E Fn i expkT1.5 1010 exp 0.220.02593.07 106cm 3(b) n o n iE F E FiexpkT1.8 10 6 exp 0.220.02598.80 109cm 3p o n i expE Fi E FkT1.8 106 exp 0.220.02593.68 102cm 3_______________________________________4.24(a) E F ENkT lnp o0.0259 ln1.04 10 195 10 150.1979 eV(b) E c E F E g E F E1.12 0.19788 0.92212 eV(c) n o 2.8 1019 exp 0.922120.02599.66 103cm 3(d) Holesp o(e) E Fi E F kT lnn i510 150.0259 ln1.5 10100.3294 eV _______________________________________4.25kT 0.0259 4000.034533 eV 3003 / 2N 1.04 10 19400300 1.601 1019cm 33 / 2N c 2.8 1019400300 4.3109 1019cm 30.2642 eV _______________________________________4.26(a) p o 7 1018 exp 0.250.02594.50 1014cm 3E c EF 1.42 0.25 1.17 eVn o 4.7 10 17 exp 1.170.02591.13 10 2cm 3(b)kT 0.034533eV3 / 2N 7 10184003001.078 1019cm 33 / 217 400N c 4.7 103007.236 1017cm3expn i 2 4.3109 10 19 1.601 10191.12NE F E kT lnp o19 0.0345335.67022410n i 2.381 1012 cm 3(a) E F ENkT lnp o0.034533 ln 1.601 10195 1015 0.2787 eV(b) E c E F 1.12 0.27873 0.84127 eV(c) n o 4.3109 10 19 exp 0.841270.0345331.134 109cm3(d) Holes(e) E Fi E F kT ln p on i510150.034533 ln2.381 10120.034533 ln1.078104.50 10 140.3482 eVE c EF 1.42 0.3482 1.072 eVn o 7.236 1017 exp 1 .071770. 0345332.40 104cm 3_____________________________________4.27(a) p o 1.04 1019 exp 0.250.02596.68 1014cm 3E c EF 1.12 0.25 0.870 eVn o 2.8 10 19 exp 0.8700.0259n o7.2310 4 cm 3(b)kT0.034533 eV3 / 2N 1.04 10194003001.601 1019cm 33 / 2N c 2.8 1019 4003004.311 1019cm 3NE F E kT lnp o1.60110 190.034533ln6.6810140.3482 eVE c EF 1.12 0.34820.7718 eVn o 4.311 1019 exp 0.771750.0345338.49 109cm 3_______________________________________4.282(a) n o N c F1 / 2 FFor E F E c kT 2 ,E F E c kT 2 FkT 0.5kTThen F1/ 2 F 1.0n o 2 2.8 1019 1.03.16 1019cm 3(b) n o 2 N c F1 / 2 F24.7 1017 1.05.30 1017cm 3_______________________________________ 4.29p o 2 N F1/2 F5 1019 2 1.04 1019 F1/2 FSo F1/ 2 F 4.26We find F 3.0E E FkTE EF 3.0 0.0259 0.0777 eV_______________________________________4.30E F E c 4kT(a) F 4kT kTThen F1 / 2 F 6.02N c F1 / 2n o F2 2.8 1019 6.01.90 10 20 cm 3(b) n o 2 4.7 1017 6.03.18 1018cm 3_______________________________________ 4.31For the electron concentrationn E g c E f F EThe Boltzmann approximation applies, so4 * 3 / 22m nE E cn Eh3E E FexpkTor4 2m n* 3 / 2 E c E Fexpn E h3kTE E c E E ckT expkTkTDefinexEE ckTThenn E n x K x exp xTo find maximumn E n x , setdn x 0 K 1 x 1 / 2 exp xdx 2x 1 / 21 expxorKx 1 / 2 expx1 x2which yieldsx1 E E cE E c12kTkT2For the hole concentrationp Eg E 1f F EUsing the Boltzmann approximation4 2m p * 3 / 2p EEEh 3E F EexpkT or3 / 242m *p E F Ep Eh 3expkTE E E EkTexpkTkTDefinexE EkTThenp xK x exp xTo find maximum value ofp Ep x ,setdp xUsing the results from0 dxabove,we find the maximum at1E E kT2_______________________________________4.32 (a) Silicon:We haven oN c expE cE FkTWe can writeE c E FE c E d E d E FForE c E d 0.045 eV andE dE F3kT eVwe can writen o2.8 1019 exp 0.04530.02592.8 1019exp 4.737or10 17 cm3n o2.45 We also havep oN expE F EkTAgain, we can writeE FEE FE aE aEForE FE a3kTandE aE0.045eVThenp o1.04 1019 exp 3 0.0450.02591.04 1019 exp4.737orp o9.12 10 16 cm 3(b) GaAs: assume E c E d0.0058eVThenn o4.7 1017 exp0.0058 30.025917exp 3.2244.7 10orn o1.87 1016 cm3Assume E a E 0.0345 eVThenp o71018 exp0.0345 30.02597 1018 exp 4.332orp o9.20 1016 cm 3_______________________________________ 4.33Plot_______________________________________4.34 10 151015 cm 3(a)p o415 31.5 10 10 2n o7.5 10 4 cm33 10153(b) n oN d316cm1010 2p o1.5 107.5 10 3cm 33 1016 (c)n op on i 1.5 10 10cm33(d) n i 22.8 10 19 1.041019 375300 exp1.12 3000.0259 375n i7.334 1011 cm3p o N a4 10 15 cm 37.334 10 11 2n o1.34 10 8 cm34 10 153(e) n i 22.8 10 19 1.04 10 19 4503001.12 300exp0.0259 450133n i1.722 10 cm14142n o1.722 10 1310102221.029 1014 cm 31.722 1013 2p o2.88 1012 cm 31.029 1014_______________________________________(a) p oN aN d4 101510153 1015 cm 3n i 2 1.8 10 6 2n o1.08 10 3cm 3p o3 1015(b) n oN d 3 10 16 cm 3p o1.8 10 6 2 1.08 10 4 cm33 10163(c) n o p on i1.8 10 6cm375 3(d) n i 24.7 1017 7.0 10 18300 exp1.42 3000.0259 375n i 7.580 10 8 cm 3p o N a4 1015 cm 38 2n o7.580 10 1.44 10 2 cm 34 10 153 (e) 2 4.7 10 17 7.0 18450 n i 10 300 exp1.42 3000.0259 450n i 3.853 1010 cm3n oN d10 14 cm 33.853 1010 2p o1.48 10 7 cm 310 14_______________________________________4.3610 13 cm 3(a) Ge: n i2.42(i) n oN dN dn i 22 22 10152 210152.4 13 22210or2 1015 cm 3n oN d4.35n i 2 2.4 1013 2p o2 1015n o2.88 1011 cm 3(ii) p o N a N d 10167 10153 1015 cm 32n i22.4 10 13n op o310 151.92 1011cm3(b) GaAs: n i 1.8 10 6cm3(i) n o N d2 1015 cm62p o1.8 10 1.62 10 3cm32 10 15(ii) p oN aN d3 10 15 cm 362n o1.8 101.08 10 3cm 33 1015 (c) The result implies that there is only one 33minority carrier in a volume of 10 cm ._______________________________________4.37(a) For the donor leveln d 1N d1 1exp EdE F2kT11 1 exp 0.2020.0259orn d8.85 10 4N d (b) We havef F E1E E F1expkTNowE E FE E cE c E ForE EF kT 0.245Thenf F E10.2451 exp 1 0.0259orf F E 2.87 10 5_______________________________________4.38N aN d(a) p-type(b) Silicon:10131013p oN aN d 2.5 1 or1013 cm 3p o1.5Thenn i 21.5 10 10 210 7cm 3n o1.5p o 1.5 1013 Germanium:N aN d N a N d 2p o2n i 221.5131.5 10 1322.4 101310222or3.26 10 13 cm 3p oThen2n i 22.4 10 13n o1.76 10 13p o3.264 1013cm 3Gallium Arsenide:p oN a N d1.5 10 13 cm 3and2n i 21.8 10 6n o0.216 cm 3p o1.5 1013_______________________________________4.39 (a) N d N an-type(b) n oN d N a 2 10151.2 10158 1014 cm 3n i 21.5 101022.81 10 5cm 3p o8 14n o10(c)p o N aN a N d4 1015N a 1.2 10 152 1015N a 4.8 10 15 cm31.5 10 102n o5.625 10 4cm 3 4 1015_______________________________________4.40n i21.5 101021. 153n o2 10 5 125 10cmp on o p on-type_______________________________________4.413n i 21.04 10196.0 10 18 250300 exp0.660.0259250 3001.8936 102412n i 1.376cm310 n on i 2 n i 2n o 21n i 2p o4n o 4n o1n i2Son o 6.88 1011 cm 3 ,Then p o2.75 1012cm3N a N a 2p on i 222N a22.752 10122N a21.8936 10 24227.5735 10 242.752 10 12 N aN a2N a 21.8936 10 242so that N a 2.064 1012cm 3_______________________________________4.42Plot_______________________________________4.43Plot_______________________________________4.44Plot_______________________________________ 4.45N d N aN dN a 2n o2n i 2214141.1 1014 2 10 1.2 102 2 10141.2 1014 2n i 221.1 10144 10 1324 10132n i 24.9 10 271.6 10 27n i2so n i5.74 10 13 cm 3p on i 23.3 10 273 133n o 1.1 10 1410 cm_______________________________________4.46(a)N a N d p-typeMajority carriers are holesp o N a N d16163 101.5 101.5 1016 cm 3Minority carriers are electrons210 10 2n on i 1.5 1.5 10 4 cm 3p o 1.5 1016(b) Boron atoms must be addedp o N a N aN d5 1016N a 3 10161.5 1016So N a3.5 10 16 cm 31.5 10 102n o4.5 10 3cm 35 10 16_______________________________________4.47p on i (a)n-type(b) p on i 2 n on i 2n op o1.5 10 1021016 cm3n o4 1.125 2 10electrons are majoritycarriersp o2 10 4cm3holes are minority carriers(c) n oN d N a1.125 101615N d 7 10so N d1.825 1016 cm3_______________________________________4.48E Fi E FkT lnp on iFor GermaniumT (K)kT (eV)n i (cm 3)200 0.01727 2.16 1010400 0.03453 8.60 1410 6000.05183.82 1016N aN a 2p o n i 2and22N a10 15 cm 3T (K)p o (cm3)E Fi EF (eV)200 1.0 1015 0.1855 4001.49 1015 0.01898 6003.87 10160.000674_______________________________________4.49(a) E c E FkT lnN cN d0.0259 ln 2.8 1019N dFor 1014cm 3 , E cE F 0.3249eV15 cm 3 ,E cE F0.2652eV1016cm 3, E c E F 0.2056eV 101017 cm 3 , E c E F0.1459eV(b) E F E FikT lnN dn i0.0259 lnN d1.51010For 1014cm 3 , E FE Fi 0.2280 eV15cm 3, E F E Fi 0.2877 eV10 1016 cm 3 , E F E Fi 0.3473 eV 1017 cm 3 ,E F E Fi0.4070 eV_______________________________________ 4.50N d N d 2(a) n on i 222n o1.05N d1.05 10 15 cm 31.05 10150.5 10 1520.5 10152n i2son i 25.25 10 28Now3n i 22.8 1019 1.04 1019T300exp1.120.0259 T 30035.25 10 28 2.912 10 38 T300exp 12972.973TBy trial and error, T 536.5K(b) At T 300 K,E c EF kT ln N cn oE c EF 0.0259 ln 2.8 1019 1015T 536.5 K, 0.2652 eVAt536.5kT0.02590.046318 eV3003 / 2N c 2.8 1019 536.53006.696 1019cm 3E c E FN c kT lnn oE c E F6.696 10 19 0.046318 ln10151.050.5124 eVthen E c E F 0.2472 eV(c)Closer to the intrinsic energy level._______________________________________4.51p oE Fi EF kT lnn iAt T 200K, kT 0.017267 eVT 400 K, kT 0.034533 eVT 600 K, kT 0.0518 eV At T 200K,22.8 10191019 200n i 1.04300exp1.120.017267n i 7.638 10 4 cm 3At T 400 K,3n i 2 2.8 1019 1.04 10 19 4003001.12exp0.034533n i 2.381 1012 cm 3At T 600 K,322.8 1019 19 600n i 1.04 10300exp 1.120.0518n i 9.740 1014 cm 3At T 200 K and T 400 K,p o N a 3 1015 cm 3At T 600 K,N a N a2p o n i22 23 15 3 10 15 2 9.740 10 1410 22 23.288 1015cm3Then, T 200K, E Fi E F 0.4212eVT 400K,E Fi EF 0.2465 eVT600K,E Fi EF 0.0630 eV_______________________________________4.52(a)N a N aE Fi EF kT ln 0.0259 ln6n i 1.8 10For N a10 14 cm 3 ,E FiE F0.4619 eVN a 10 15 cm 3,E FiE F0.5215 eV163,N a 10 cmE FiE F0.5811 eVN a 10 17cm 3,E FiE F 0.6408 eV(b)E FEN7.0 1018kT ln0.0259 lnN aN aFor N a10 14 cm 3 ,E F E0.2889 eVN a 10 15 cm 3 ,E FE0.2293 eV163,N a 10 cmE F E0.1697 eVN a 10 17 cm3,E F E 0.1100 eV_______________________________________ 4.53(a) E Fi3 m *p E midgapkT ln4m n *3 0.0259 ln 104 orE Fi E midgap 0.0447 eV(b) Impurity atoms to be added soE midgap EF 0.45 eV(i) p-type, so add acceptor atoms(ii)E Fi EF 0.0447 0.45 0.4947 eVThenp oE FiE Fn i expkT10 5exp 0.49470.0259 or10 13 cm3p o N a1.97_______________________________________4.54n oN d N aN c expE c E FkTsoN d 5 10 15 2.8 10 19 exp0.2150.025951015 6.95 1015orcm 3N d 1.2 1016_______________________________________4.55(a) Silicon(i) E cE F N ckT lnN d0.0259 ln 2.8 10 190.2188 eV6 1015(ii) E cE F0.2188 0.0259 0.1929 eVN dN c expE c E FkT2.8 10 19 exp0.19290.0259N d1.631 1016 cm3N d 6 1015N d1.031 10 16 cm 3Additional donor atoms(b) GaAs(i) E c E F0.0259 ln4.7101710150.15936eV(ii) E cE F0.15936 0.0259 0.13346 eVN d4.7 1017 exp0.133460.02592.718 1015 cm 3N d 1015N d1.718 10 15 cm3Additionaldonor atoms_______________________________________ 4.56(a) E Fi E FN kT lnN a0.0259 ln 1.04 10190.1620 eV2 1016(b) E F E Fi kT ln N c N d0.0259 ln 2.8 1019 0.1876 eV2 10 16(c) For part (a);p o 2 1016 cm 3n i2 1.5 1010 2n op o 2 10161.125 104cm3For part (b):3n o 2 1016 cmn i 2 1.5 1010 2p on o 2 10 161.125 104cm3_______________________________________ 4.57n oE F E Fin i expkT1.8 10 6 exp 0.550.02593.0 1015cm 3Add additional acceptor impuritiesn o N d N a3 10 15 7 10 15 N aN a 4 10 15 cm 3_______________________________________(a) E Fi E F kT lnpon i0.02593 10 150.3161 eVln10 101.5(b) E F E Fin okT lnn i0.02593 10160.3758 eVln10 101.5(c) E F E Fi(d) E Fi E Fp okT lnn i0.0259 375 ln 4 1015300 7.334 10 110.2786 eV(e) E F E Fi kT lnnon i140.0259 450 ln 1.029 10300 1.722 10 130.06945eV_______________________________________4.59(a) E F ENkT lnp o0.0259 ln7.0 10180.2009 eV3 1015(b) E F E 0.0259 l n7.0 10 181.08 10 41.360 eV(c) E F E 0.0259 l n 7.0 10181.8 10 60.7508 eV4.58(d) E F E 0.0259 375300ln 7.0 10 18 375 300 3 / 24 10 150.2526 eV(e) E F E 0.0259 450 300ln 7.0 10 18 450 300 3/ 21.48 10 71.068 eV_______________________________________4.60n-typeE F E Fi kT ln n o n i0.02591.125 10 16ln100.3504 eV1.5 10______________________________________ 4.61N a N a 2 p o 22 2 n i5.08 1015 5 101525 10 15 2n i225.08 10 15 2.5 10 15 22.5 1015 2n i26.6564 10 30 6.25 10 30 n i2n i 2 4.064 10 29n i2 N c N expE gkTkT 0.02593500.030217 eV3003502N c 1.2 10 19 1.633 1019 cm 33003502N 1.8 1019 2.45 10 19 cm 3300Now4.064 10 29 1.633 1019 2.45 1019E gexp0.030217SoE g 0.030217 ln 1.633 10 19 2.45 10 194.064 10 29E g 0.6257 eV_______________________________________4.62(a) Replace Ga atoms Silicon acts as adonorN d0.05 7 1015 3.5 10 14 cm 3Replace As atoms Silicon acts asanacceptorN a 0.95 7 1015 6.65 10 15 cm 3(b) N a N d p-type(c) p o N a N d 6.65 1015 3.5 10146.3 1015cm 3n i 2 1. 810 6 2n o 5.14 10 4 cm 3 p o 6 .3 1015(d) E Fi E F kT ln p o n i0.0259 ln 6.3 10 150.5692 eV1.8 10 6_______________________________________。

半导体物理与器件第四版课后习题答案1

______________________________________________________________________________________Chapter 1Problem Solutions1.1 (a)fcc: 8 corner atoms 18/1atom6 face atoms32/1atomsTotal of 4 atoms per unit cell (b)bcc: 8 corner atoms 18/1atom1 enclosed atom=1 atom Total of 2 atoms per unit cell(c)Diamond: 8 corner atoms 18/1atom6 faceatoms 32/1atoms4 enclosedatoms= 4 atomsTotal of 8 atoms per unit cell_______________________________________ 1.2 (a)Simple cubic lattice: r a 2Unit cell vol33382rra1 atom per cell, so atom vol 3413r ThenRatio%4.52%10083433rr(b)Face-centered cubic latticerd aa rd22224Unit cell vol 33321622rr a4 atoms per cell, so atom vol3443r ThenRatio%74%10021634433rr (c)Body-centered cubic latticeraa rd3434Unit cell vol 3334ra2 atoms per cell, so atom vol 3423r ThenRatio%68%1003434233r r (d)Diamond lattice Body diagonal raa rd3838Unit cell vol3338r a8 atoms per cell, so atom vol 3483r ThenRatio%34%1003834833rr _______________________________________1.3(a)oA a43.5; From Problem 1.2d,ra38Then oAa r176.18343.583Center of one silicon atom to center ofnearest neighboroAr 35.22______________________________________________________________________________________ (b)Number density22381051043.58cm 3(c)Mass density23221002.609.28105..AN W t At N 33.2grams/cm3_______________________________________1.4(a)4 Ga atoms per unit cell Number density381065.54Density of Ga atoms 221022.2cm34 As atoms per unit cell Density of As atoms 221022.2cm3(b)8 Ge atoms per unit cell Number density381065.58Density of Ge atoms221044.4cm3_______________________________________ 1.5From Figure 1.15 (a)aa d4330.0232oAd 447.265.54330.0(b)aa d7071.022oAd 995.365.57071.0_______________________________________1.674.5423232222sin a a 5.109_______________________________________ 1.7(a) Simple cubic: oAr a 9.32(b)fcc:oAr a515.524(c) bcc:oA r a 503.434(d) diamond:oAra007.9342_______________________________________ 1.8 (a)Br 2035.122035.12oBAr 4287.0(b)oAa 07.2035.12(c)A-atoms: # of atoms1818Density381007.21231013.1cm3B-atoms: # of atoms3216Density381007.23231038.3cm3_______________________________________ 1.9(a)oAr a 5.42# of atoms1818Number density38105.412210097.1cm3______________________________________________________________________________________Mass density AN W t At N ..23221002.65.12100974.1228.0gm/cm3(b)oAr a196.534# of atoms 21818Number density3810196.5222104257.1cm3Mass density23221002.65.12104257.1296.0gm/cm3_______________________________________ 1.10From Problem 1.2, percent volume of fcc atoms is 74%; Therefore after coffee is ground,Volume = 0.74 cm3_______________________________________1.11(b)oAa 8.20.18.1(c)Na: Density38108.22/1221028.2cm3Cl: Density221028.2cm3(d)Na: At. Wt. = 22.99 Cl: At. Wt. = 35.45 So, mass per unit cell23231085.41002.645.352199.2221Then mass density21.2108.21085.43823grams/cm3_______________________________________ 1.12(a)oAa 88.122.223Then oA a 62.4Density of A:22381001.11062.41cm3Density of B:22381001.11062.41cm3(b)Same as (a) (c)Same material_______________________________________ 1.13oAa619.438.122.22(a) For 1.12(a), A-atomsSurface density28210619.411a1410687.4cm2For 1.12(b), B-atoms: oAa 619.4Surface density14210687.41acm2For 1.12(a) and (b), Same material(b) For 1.12(a), A-atoms;oAa 619.4Surface density212a1410315.3cm2B-atoms;Surface density______________________________________________________________________________________14210315.321a cm 2For 1.12(b), A-atoms;oAa 619.4Surface density212a1410315.3cm2B-atoms;Surface density14210315.321acm2For 1.12(a) and (b), Same material_______________________________________ 1.14 (a)Vol. Density31oaSurface Density212oa(b)Same as (a)_______________________________________ 1.15 (i)(110) plane(see Figure 1.10(b))(ii) (111) plane(see Figure 1.10(c))(iii) (220) plane,1,1,21,21Same as (110) plane and [110]direction(iv) (321) plane6,3,211,21,31Intercepts of plane at6,3,2sq p [321] direction is perpendicular to(321) plane_______________________________________1.16(a)31311,31,11(b)12141,21,41_______________________________________ 1.17Intercepts: 2, 4, 331,41,21(634) plane_______________________________________ 1.18(a)oAa d 28.5(b)oAa d734.322(c)oAa d048.333_______________________________________ 1.19(a) Simple cubic(i) (100) plane:Surface density2821073.411a141047.4cm 2(ii) (110) plane:Surface density212a141016.3cm 2(iii) (111) plane: Area of planebh21where oAa b 689.62Now2222243222a a a hSooAh793.573.426______________________________________________________________________________________Area of plane881079304.51068923.62116103755.19cm 2Surface density16103755.19613141058.2cm2(b) bcc(i) (100) plane:Surface density 1421047.41acm2(ii) (110) plane: Surface density222a141032.6cm 2(iii) (111) plane:Surface density16103755.19613141058.2cm2(c) fcc(i) (100) plane:Surface density 1421094.82acm2(ii) (110) plane: Surface density222a141032.6cm 2(iii) (111) plane:Surface density16103755.19213613151003.1cm2_______________________________________ 1.20 (a)(100) plane: - similar to a fcc:Surface density281043.52141078.6cm 2(b)(110) plane:Surface density281043.524141059.9cm2(c)(111) plane: Surface density281043.5232141083.7cm2_______________________________________1.21oAr a703.6237.2424(a)#/cm338310703.64216818a2210328.1cm3(b)#/cm222124142a210703.62281410148.3cm2(c)oA a d74.422703.622(d)# of atoms2213613Area of plane: (see Problem 1.19)oAa b4786.92oAa h2099.826Area88102099.8104786.92121bh______________________________________________________________________________________15108909.3cm2#/cm215108909.32=141014.5cm2oAa d87.333703.633_______________________________________ 1.22Density of silicon atoms 22105cm3and4 valence electrons per atom, soDensity of valence electrons 23102cm3_______________________________________ 1.23Density of GaAs atoms22381044.41065.58cm3An average of 4 valence electrons peratom,SoDensity of valence electrons231077.1cm3_______________________________________ 1.24 (a)%10%10010510532217(b)%104%10010510262215_______________________________________ 1.25 (a)Fraction by weight7221610542.106.2810582.10102(b)Fraction by weight5221810208.206.2810598.3010_______________________________________ 1.26Volume density 1631021dcm3So610684.3dcmoAd 4.368We haveoo Aa 43.5Then85.6743.54.368oa d _______________________________________ 1.27Volume density 1531041dcm 3So61030.6dcmoAd630We have oo Aa 43.5Then11643.5630oa d _______________________________________。

半导体物理与器件第四版课后习题答案

半导体物理与器件第四版课后习题答案第一章半导体材料基础知识1.1 小题一根据题目描述，当n=5时，半导体材料的载流子浓度为’n=2.5×1015cm(-3)’，求势垒能为多少？解答：根据势垒能公式E_g = E_c - E_v其中E_g为势垒能，E_c为导带底，E_v为价带顶。

根据载流子浓度和温度的关系n = 2 * （2 * pi * m_e * k * T / h^2）^(3/2) * e^(-E_g / (2 * k * T))其中m_e为载流子质量，k为玻尔兹曼常数，T为绝对温度。

可以得到E_g = -2 * k * T * ln(n / (2 * （2 * pi * m_e * k * T / h^2）^(3/2)))代入已知条件，计算得到势垒能为E_g = -2 * 1.38 * 10^(-23) * 300 * ln(2.5 * 10^15 / (2 * （2 * pi * 9.1 * 10^(-31) * 1.38 * 10^ (-23) * 300 / (6.63 * 10^(-34))^2）^(3/2)))1.1 小题二根据题目描述，当势垒能E_g=1.21eV时，求温度为多少时，载流子浓度为’n=5.0×1015cm(-3)’？解答：按照1.1 小题一的公式，可以求出温度TT = E_g / (2 * k * ln(n / (2 * （2 * pi * m_e * k * T / h^2）^(3/2))))将已知数据代入公式，计算得到温度T = 1.21 / (2 * 1.38 * 10^(-23) * ln(5 * 10^15/ (2 * （2 * pi * 9.1 * 10^(-31) * 1.38 * 10^(-2 3) * T / (6.63 * 10^(-34))^2）^(3/2))))第二章半导体材料与器件基本特性2.1 小题一根据题目描述，当Si掺杂浓度[N_b]为5×10^15 cm(-3)和[P_e]为2×1017 cm^(-3)，求Si中的载流子浓度和导电类型。

半导体物理与器件第四版课后习题答案9

______________________________________________________________________________________Chapter 99.1(a) We have⎪⎪⎭⎫⎝⎛=d c t n N N eV e ln φ()206.010108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯=eV(c)01.428.4-=-=χφφm BO or27.0=BO φV and206.027.0-=-=n BO bi V φφ or064.0=bi V V Also2/12⎥⎦⎤⎢⎣⎡∈=d bi s d eN V x()()()()()2/116191410106.1064.01085.87.112⎥⎦⎤⎢⎣⎡⨯⨯=-- or6101.9-⨯=d x cm Thensdd x eN ∈=E max()()()()()14616191085.87.1110`1.910106.1---⨯⨯⨯=or4max 1041.1⨯=E V/cm (d)Using the figure, 55.0=Bn φV So206.055.0-=-=n Bn bi V φφ or344.0=bi V V We then find51011.2-⨯=n x cm and4max 1026.3⨯=E V/cm_______________________________________ 9.2(a)n B bi V φφ-=0 ⎪⎪⎭⎫ ⎝⎛=d ct n NN V ln φ ()⎪⎪⎭⎫⎝⎛⨯⨯=1519105108.2ln 0259.0=0.2235 V4265.02235.065.0=-=bi V V (b) ()⎪⎪⎭⎫⎝⎛⨯=161910108.2ln 0259.0n φ2056.0=V4444.02056.065.0=-=bi V V bi V increases, 0B φremains constant (c) ()⎪⎪⎭⎫⎝⎛⨯=151910108.2ln 0259.0n φ2652.0=V3848.02652.065.0=-=bi V V bi V decreases, 0B φremains constant_______________________________________ 9.3(a)09.101.41.50=-=-=χφφm B V (b)n B bi V φφ-=0 ⎪⎪⎭⎫⎝⎛=d c t n N N V ln φ()2056.010108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯=V8844.02056.009.1=-=bi V V (c) ()2/12⎥⎦⎤⎢⎣⎡+∈=d R bi s n eN V V x(i)()()()()()2/116191410106.118844.01085.87.112⎥⎦⎤⎢⎣⎡⨯+⨯=--n x510939.4-⨯=cm______________________________________________________________________________________or μ4939.0=n x msnd x eN ∈=E max()()()()()14516191085.87.1110939.410106.1---⨯⨯⨯= 41063.7⨯=V/cm(ii)()()()()()2/116191410106.158844.01085.87.112⎥⎦⎤⎢⎣⎡⨯+⨯=--n x 510727.8-⨯=cm or μ8728.0=n x m()()()()()1451619max 1085.87.1110727.810106.1---⨯⨯⨯=E51035.1⨯=V/cm_______________________________________ 9.4(a)03.107.41.50=-=-=χφφm B V (b) ()1177.0105107.4ln 0259.01517=⎪⎪⎭⎫⎝⎛⨯⨯=n φV(c)9123.01177.003.1=-=bi V V (d)(i)()()()()()2/1151914105106.119123.01085.81.132⎥⎦⎤⎢⎣⎡⨯⨯+⨯=--n x 510445.7-⨯=cm or μ7445.0=n x m()()()()()1451519max 1085.81.1310445.7105106.1---⨯⨯⨯⨯=E41014.5⨯=V/cm(ii)()()()()()2/1151914105106.159123.01085.81.132⎥⎦⎤⎢⎣⎡⨯⨯+⨯=--n x 410309.1-⨯=cm or μ309.1=n x m()()()()()1441519max 1085.81.1310309.1105106.1---⨯⨯⨯⨯=E41003.9⨯=V/cm_______________________________________ 9.5(b) 1177.0=n φV(c) 7623.01177.088.0=-=bi V V(d) (i)()()()()()2/1151914105106.117623.01085.81.132⎥⎦⎤⎢⎣⎡⨯⨯+⨯=--n x 510147.7-⨯=cm or μ7147.0=n x m()()()()()1451519max 1085.81.1310147.7105106.1---⨯⨯⨯⨯=E 41093.4⨯=V/cm (ii)()()()()()2/1151914105106.157623.01085.81.132⎥⎦⎤⎢⎣⎡⨯⨯+⨯=--n x 410292.1-⨯=cm or μ292.1=n x m()()()()()1441519max 1085.81.1310292.1105106.1---⨯⨯⨯⨯=E41092.8⨯=V/cm_______________________________________ 9.6(a) ()2/12⎥⎦⎤⎢⎣⎡+∈='R bid s V V Ne CWe have 88.00=B φV()⎪⎪⎭⎫⎝⎛⨯=151910108.2ln 0259.0n φ265.0=V615.0265.088.0=-=bi V V (i)()()()()()()2/115141941615.02101085.87.11106.110⎥⎦⎤⎢⎣⎡+⨯⨯=---C 131016.7-⨯= F or 716.0=C pF (ii)______________________________________________________________________________________()()()()()()2/115141945615.02101085.87.11106.110⎥⎦⎤⎢⎣⎡+⨯⨯=---C 131084.3-⨯= F or 384.0=C pF (b) ()206.010108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯=n φV 674.0206.088.0=-=bi V V (i) ()()()()()()2/116141941674.02101085.87.11106.110⎥⎦⎤⎢⎣⎡+⨯⨯=---C 121022.2-⨯= F or 22.2=C pF (ii) ()()()()()()2/1161419456745.02101085.87.11106.110⎥⎦⎤⎢⎣⎡+⨯⨯=---C 121021.1-⨯= F or 21.1=C pF_______________________________________ 9.7 (a) From the figure, 90.0=bi V V(b) We find()1515210034.190.0201031⨯=---⨯=∆⎪⎭⎫ ⎝⎛'∆R V C and d s N e ∈=⨯210034.115 We can then write ()()()()15141910034.11085.81.13106.12⨯⨯⨯=--d N or 161004.1⨯=d N cm 3-(c)⎪⎪⎭⎫⎝⎛=d c t n N N V ln φ ()⎪⎪⎭⎫⎝⎛⨯⨯=16171004.1107.4ln 0259.0or0986.0=n φV (d)0986.090.0+=+=n bi Bn V φφ or9986.0=Bn φV_______________________________________9.8 From Figure 9.5, 63.0≅BO φV(a) ()224.0105108.2ln 0259.01519=⎪⎪⎭⎫ ⎝⎛⨯⨯=n φV406.0224.063.00=-=-=n B bi V φφV(i)()()()()()2/1151914105106.11406.01085.87.112⎥⎦⎤⎢⎣⎡⨯⨯+⨯=--n x 510033.6-⨯=cmor μ6033.0=n x m ()()()()()1451519max 1085.87.1110033.6105106.1---⨯⨯⨯⨯=E 41066.4⨯=V/cm (ii)()()()()()2/1151914105106.15406.01085.87.112⎥⎦⎤⎢⎣⎡⨯⨯+⨯=--n x 410183.1-⨯=cmor μ183.1=n x m ()()()()()1441519max 1085.87.1110183.1105106.1---⨯⨯⨯⨯=E41014.9⨯=V/cm (b)(i) se ∈E=∆πφ4 ()()()()2/1144191085.87.1141066.4106.1⎥⎦⎤⎢⎣⎡⨯⨯⨯=--π 0239.0=V E ∈=s m e x π16()()()()2/1414191066.41085.87.1116106.1⎥⎦⎤⎢⎣⎡⨯⨯⨯=--πor______________________________________________________________________________________ m x 71057.2-⨯=cm (ii) ()()()()2/1144191085.87.1141014.9106.1⎥⎦⎤⎢⎣⎡⨯⨯⨯=∆--πφ 0335.0=V()()()2/1414191014.91085.87.1116106.1⎥⎦⎤⎢⎣⎡⨯⨯⨯=--πm x 71083.1-⨯=cm_______________________________________ 9.9 We have ()x x ex s E -∈-=-πφ16 or()ex xe x e s E +∈=πφ162 Now ()()e x e dx x e d s E +∈-==22160πφ Solving for x , we find E∈==s m ex x π16Substituting this value of m x x = into the equation for the potential, we find E∈E+E∈∈=∆s s see e πππφ161616which yields se ∈E=∆πφ4 _______________________________________ 9.10From Figure 9.5, 88.0≅BO φV(a) ()0997.010107.4ln 0259.01617=⎪⎪⎭⎫⎝⎛⨯=n φV780.00997.088.00≅-=-=n B bi V φφV()()()()()2/116191410106.1780.01085.81.132⎥⎦⎤⎢⎣⎡⨯⨯=--n x510362.3-⨯=cmor μ3362.0=n x m()()()()()1451619max 1085.81.1310362.310106.1---⨯⨯⨯=E 41064.4⨯=V/cm (b) ()()044.088.005.0==∆φV s e ∈E =π4()()()()141921085.81.134106.1044.0--⨯E ⨯=π ()()()()19142106.11085.81.134044.0--⨯⨯=E π510763.1⨯=V/cmNow ()()()()14161951085.81.1310106.110763.1--⨯⨯=⨯=E n x 410277.1-⨯=⇒n x cmAnd ()24210277.1-⨯=n x()()()()()16191410106.1780.01085.81.132--⨯+⨯=R V5.10=⇒R V V_______________________________________ 9.11Plot_______________________________________ 9.12(a) 07.42.5-=-=χφφm BO or13.1=BO φV(b) We have()Bn O g e e E φφ--()n Bn d s itN e eD φφ-∈=21()[]Bn m it ieD φχφδ+-∈-which becomes()Bn e φ--60.043.1______________________________________________________________________________________ ()()()[1419131085.81.13106.12101--⨯⨯⎪⎪⎭⎫ ⎝⎛=e e()()]2/11610.010-⨯Bn φ()()()[]Bn e e φ+-⨯⎪⎪⎭⎫ ⎝⎛⨯---07.42.51025101085.881314orBn φ-83.0()Bn Bn φφ---=13.1221.010.0038.0 We find858.0=Bn φV (c)If 5.4=m φV, then07.45.4-=-=χφφm BO or43.0=BO φVFrom part (b), we have Bn φ-83.0()[]Bn Bn φφ+---=07.45.4221.010.0038.0 We then find733.0=Bn φVWith interface states, the barrier height is lesssensitive to the metal work function._______________________________________ 9.13We have that()Bn O g e e E φφ--()n Bn d s itN e eD φφ-∈=21()[]Bn m it ieD φχφδ+-∈-Let itit D eD '=(cm 2-eV 1-) Then we can write()60.0230.012.1--e()()()[14191085.87.11106.121--⨯⨯'=itD ()()]2/116164.060.0105-⨯⨯ ()()()[]60.001.475.410201085.8814+-⨯'⨯---itD We then find111097.4⨯='itD cm 2-eV 1- _______________________________________ 9.14(a) ()224.0105108.2ln 0259.01519=⎪⎪⎭⎫⎝⎛⨯⨯=n φV(b)666.0224.089.0=-=-=n Bn bi V φφV (c)⎪⎪⎭⎫⎝⎛-=*kT e T A J Bn sT φexp 2()()⎪⎭⎫ ⎝⎛-=0259.089.0exp 300120281029.1-⨯=sT J A/cm 2 (d)()⎪⎭⎫ ⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-81029.15ln 0259.0ln sT t a J J V V 512.0=a V V_______________________________________ 9.15(a)63.00≅B φV ()()⎪⎭⎫ ⎝⎛-=0259.063.0exp 3001202sT J410948.2-⨯=A/cm 2()()84410948.210948.210---⨯=⨯=sT I A(i) ⎪⎪⎭⎫ ⎝⎛=sT t a IIV V ln ()⎪⎪⎭⎫ ⎝⎛⨯⨯=--8610948.21010ln 0259.0 151.0=V______________________________________________________________________________________(ii) ()⎪⎪⎭⎫⎝⎛⨯⨯=--8610948.210100ln 0259.0a V 211.0=V (iii) ()⎪⎪⎭⎫ ⎝⎛⨯=--8310948.210ln 0259.0a V 270.0=V (b) ()030217.03003500259.0=⎪⎭⎫ ⎝⎛=kT eV ()()()⎪⎭⎫ ⎝⎛-=-030217.063.0exp 3501201024sT I610296.1-⨯= A (i) ⎥⎥⎦⎤⎢⎢⎣⎡-⎪⎪⎭⎫ ⎝⎛=1exp t a sT V V I I ()⎥⎥⎦⎤⎢⎢⎣⎡+⨯⨯=--110296.11010ln 030217.066a V 0654.0=V (ii) ()⎥⎦⎤⎢⎣⎡+⨯⨯=--110296.110100ln 030217.066a V 1317.0=V(iii) ()⎪⎪⎭⎫ ⎝⎛⨯≅--6310296.110ln 030217.0a V 201.0=V _______________________________________9.16(a) 88.0≅Bn φV (b) ()()⎪⎭⎫ ⎝⎛-=0259.088.0exp 30012.12sT J1010768.1-⨯=A/cm 2(c) ()⎪⎭⎫ ⎝⎛⨯=-1010768.110ln 0259.0a V 641.0=V(d) ()()()2ln 0259.02ln ==∆t a V V 0180.0=V_______________________________________9.17Plot _______________________________________9.18From the figure, 68.0=Bn φV ⎪⎪⎭⎫ ⎝⎛∆⋅⎪⎪⎭⎫ ⎝⎛-=t t Bn ST V V T A J φφexp exp 2* ()()⎪⎪⎭⎫ ⎝⎛∆⋅⎪⎭⎫ ⎝⎛-=t V φexp 0259.068.0exp 3001202 or⎪⎪⎭⎫ ⎝⎛∆⨯=-t ST V J φexp 10277.45We have s e ∈E =∆πφ4 Now ⎪⎪⎭⎫⎝⎛=d c t n N N V ln φ()2056.010108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯=Vand 4744.02056.068.0=-=-=n Bn bi V φφV (a) We find for 2=R V V, ()2/12⎥⎦⎤⎢⎣⎡+∈=d R bi s d eN V V x()()()()()2/116191410106.14744.21085.87.112⎥⎦⎤⎢⎣⎡⨯⨯=-- or 410566.0-⨯=d x cm μ566.0=m Then s dd x eN ∈=E max ()()()()()14416191085.87.1110566.010106.1---⨯⨯⨯= or 4max 10745.8⨯=E V/cm Now()()()()2/1144191085.87.11410745.8106.1⎥⎦⎤⎢⎣⎡⨯⨯⨯=∆--πφ______________________________________________________________________________________ or 0328.0=∆φV Then()⎪⎭⎫ ⎝⎛⨯=-0259.00328.0exp 10277.451ST J or 411052.1-⨯=ST J A/cm 2 For 410-=A cm 2, we find 811052.1-⨯=R I A (b) For 4=R V V, then()()()()()2/116191410106.14744.41085.87.112⎥⎦⎤⎢⎣⎡⨯⨯=--d x or410761.0-⨯=d x cm μ761.0=mAlso()()()()()1441619max 1085.87.1110761.010106.1---⨯⨯⨯=Eor5max 10176.1⨯=E V/cm and()()()()2/1145191085.87.11410176.1106.1⎥⎦⎤⎢⎣⎡⨯⨯⨯=∆--πφ or03803.0=∆φV Then()⎪⎭⎫⎝⎛⨯=-0259.003803.0exp 10277.452ST Jor421086.1-⨯=ST J A/cm 2 Finally,821086.1-⨯=R I A_______________________________________ 9.19We have thatdn JcE x m s ⎰∞-→=υThe incremental electron concentration is ()()dE E f E g dn F c = where()()c nc E E hm E g -=32/3*24π and assuming the Boltzmannapproximation ()()⎥⎦⎤⎢⎣⎡--=kT E E E f F F exp Then()c nE E h m dn -=32/3*24π()dE kT E E F ⎥⎦⎤⎢⎣⎡--⨯exp If the energy above c E is kinetic energy, thenc n E E m -=2*21υWe can then write2*nc m E E υ=-andυυυυd m d m dE n n **221=⋅=We can also write()()F c c F E E E E E E -+-=-n n e m φυ+=2*21 so that⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛=kT e h m dn n n φexp 23*υυπυd kT m n 22*42exp ⋅⎪⎪⎭⎫ ⎝⎛-⨯We can write2222z y x υυυυ++=The differential volume element is z y x d d d d υυυυυπ=24The current is due to all x-directed velocitiesthat are greater than Ox υ and for all y- andz- directed velocities. Then______________________________________________________________________________________⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛=-→kT e h m J n n m s φexp 23*xx n x d kT m Oxυυυυ⎪⎪⎭⎫⎝⎛-⨯⎰∞2exp 2*y y n d kT m υυ⎰∞∞-⎪⎪⎭⎫⎝⎛-⨯2exp 2*z z n d kT m υυ⎰∞∞-⎪⎪⎭⎫ ⎝⎛-⨯2exp 2* We can write ()a bi Ox n V V e m -=2*21υMake a change of variables:()kTV V kT m a bi x n -+=2222*αυ or()⎥⎦⎤⎢⎣⎡-+=kT V V e m kT a bi n x 2*22αυ Taking the differential, we findααυυd m kT d n x x ⎪⎪⎭⎫⎝⎛=*2We may note that when Ox x υυ=, 0=α. We may define other change of variables,βυβυ⋅⎪⎪⎭⎫⎝⎛=⇒=2/1*22*22n y yn m kT kT mγυγυ⋅⎪⎪⎭⎫ ⎝⎛=⇒=2/1*22*22n z zn m kT kT m Substituting the new variables, we have⎪⎪⎭⎫ ⎝⎛-⋅⎪⎪⎭⎫ ⎝⎛⋅⎪⎪⎭⎫ ⎝⎛=-→kT e m kT h m J n n n m s φexp 222*3*()()αααd kT V V e a bi ⎰∞-⋅⎥⎦⎤⎢⎣⎡--⨯02exp exp ()()γγββd d ⎰⎰∞∞-∞∞--⋅-⨯22exp exp _______________________________________ 9.20 For the Schottky diode, ()()⎪⎪⎭⎫ ⎝⎛⨯=⨯---t a V V exp 106101080.0843 (a) ()()()()⎥⎦⎤⎢⎣⎡⨯⨯=---843106101080.0ln 0259.0SB V a 4845.0=VThen()7695.0285.04845.0=+=pn V a V(b) ()⎪⎭⎫⎝⎛=⨯--0259.07695.0exp 101080.0113pn A 551010998.0--≅⨯=⇒pn A cm 2 _______________________________________9.21 For the pn junction,()()16134104.6108108---⨯=⨯⨯=s I A(a) ()⎪⎪⎭⎫⎝⎛⨯⨯=--166104.610150ln 0259.0a V678.0=V(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=--166104.610700ln 0259.0a V718.0=V(c) ()⎪⎪⎭⎫⎝⎛⨯⨯=--163104.6102.1ln 0259.0a V732.0=VFor the Schottky junction,()()1294108.4106108---⨯=⨯⨯=sT I A(a) ()⎪⎪⎭⎫ ⎝⎛⨯⨯=--126108.410150ln 0259.0a V 447.0=V______________________________________________________________________________________(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=--126108.410700ln 0259.0a V 487.0=V(c) ()⎪⎪⎭⎫⎝⎛⨯⨯=--123108.4102.1ln 0259.0a V 501.0=V_______________________________________9.22 (a) (i) 80.0=I mA in each diode (ii)()()()()⎥⎦⎤⎢⎣⎡⨯⨯⨯=---943106108108.0ln 0259.0SB V a 490.0=V ()()()()⎥⎦⎤⎢⎣⎡⨯⨯⨯=---1343108108108.0ln 0259.0pn V a 721.0=V (b) Same voltage across each diodepn SB I I I +=⨯=-3108.0()()⎪⎪⎭⎫ ⎝⎛⨯⨯=--t aV V exp 10610894()()⎪⎪⎭⎫ ⎝⎛⨯⨯+--t a V V exp 108108134()⎪⎪⎭⎫ ⎝⎛⨯+⨯=--t a V V exp 104.6108.41612Then ()⎥⎦⎤⎢⎣⎡⨯+⨯⨯=---16123104.6108.4108.0ln 0259.0a V 49032.0=a V V ()⎪⎭⎫ ⎝⎛⨯=-0259.049032.0exp 108.412SB I 7998.0=⇒SB I mA ()⎪⎭⎫ ⎝⎛⨯=-0259.049032.0exp 104.616pn Iμ107.0≅⇒pn I A _______________________________________9.23(a) For 8.0=I mA, we find 143.1107108.043=⨯⨯=--J A/cm 2 We have⎪⎪⎭⎫ ⎝⎛=S t a J J V V lnFor the pn junction diode, ()6907.0103143.1ln 0259.012=⎪⎭⎫ ⎝⎛⨯=-a V V For the Schottky diode,()4447.0104143.1ln 0259.08=⎪⎭⎫⎝⎛⨯=-a V V (b) For the pn junction diode,⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛∝∝kT E T n J g i S exp 30032Then()()3300400300400⎪⎭⎫⎝⎛=SS J J()()⎥⎦⎤⎢⎣⎡+-⨯0259.03004000259.0exp g g E E⎥⎦⎤⎢⎣⎡-=03453.012.10259.012.1exp 37.2 or()()51017.1300400⨯=S SJ J Now ()()()12541031017.1107--⨯⨯⨯=I⎪⎭⎫ ⎝⎛⨯03453.06907.0exp or120=I mA For the Schottky diode,⎪⎪⎭⎫⎝⎛-∝kT e T J BO ST φexp 2Now ()()2300400300400⎪⎭⎫⎝⎛=ST ST J J ()()⎥⎦⎤⎢⎣⎡+-⨯0259.03004000259.0exp BO BO φφ______________________________________________________________________________________ ⎥⎦⎤⎢⎣⎡-=03453.082.00259.082.0exp 778.1or()()310856.4300400⨯=ST ST J J Then ()()()83410410856.4107--⨯⨯⨯=I⎪⎭⎫ ⎝⎛⨯03453.04447.0expor3.53=I mA_______________________________________9.24 Plot _______________________________________9.25 (a) Ω===--1.0101034A R R c(b) Ω===--1101044A R R c (c) Ω===--10101054A R R c _______________________________________9.26(a) Ω=⨯==--51010555A R R c (i) ()()551===IR V mV(ii) ()()5.051.0===IR V mV (b) 501010565=⨯=--R Ω (i) ()()50501===IR V mV (ii) ()()5501.0===IR V mV _______________________________________ 9.27 2exp T A V V R t Bn t c *⎪⎪⎭⎫⎝⎛=φ or ⎥⎥⎦⎤⎢⎢⎣⎡=*t c t Bn V T A R V 2ln φ (a) ()()()()⎥⎥⎦⎤⎢⎢⎣⎡⨯=-0259.0300120105ln 0259.025Bn φ258.0=V(b) ()()()()⎥⎥⎦⎤⎢⎢⎣⎡⨯=-0259.0300120105ln 0259.026Bn φ 198.0=V_______________________________________ 9.28 (b) We need 20.00.42.4=-=-=χφφm n V And ⎪⎪⎭⎫⎝⎛=d c t n N N V ln φ or ()⎪⎪⎭⎫⎝⎛⨯=d N 19108.2ln 0259.020.0 which yields161024.1⨯=d N cm 3- (c)Barrier height = 0.20 V _______________________________________ 9.29 We have that ()x x eN n s d-∈-=E Then 222C x x x eN dx n s d +⎪⎪⎭⎫ ⎝⎛-⋅∈=E -=⎰φ Let 0=φ at 002=⇒=C x , so⎪⎪⎭⎫⎝⎛-⋅∈=22x x x eN n s d φ At n x x =, bi V =φ, so 22n s d bi x eN V ⋅∈==φ or______________________________________________________________________________________dbis n eN V x ∈=2 Also n BO bi V φφ-= where ⎪⎪⎭⎫ ⎝⎛=d c t n N N V ln φ Now for35.0270.02===BO φφV we have()()()()[8141910501085.87.11106.135.0---⨯⨯⨯=nd x N()⎥⎥⎦⎤⨯--2105028 or ()81410251073.735.0--⨯-⨯=n d x N We have ()()()2/11914106.11085.87.112⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯=--d bi n N V x andn bi V φ-=70.0By trial and error, we find 18105.3⨯=d N cm 3-_______________________________________9.30(b) ⎪⎪⎭⎫ ⎝⎛==a t p BO N N V υφφln ()⎪⎪⎭⎫⎝⎛⨯⨯=16191051004.1ln 0259.0 or 138.0=BO φV_______________________________________9.31 Sketches_______________________________________ 9.32Sketches_______________________________________9.33Electron affinity rule ()p n c e E χχ-=∆ For GaAs, 07.4=χ and for AlAs,5.3=χ. If we assume a linear extrapolation between GaAs and AlAs, then for Al 3.0Ga 7.0As 90.3=⇒χThen 17.090.307.4=-=∆c E eV _______________________________________9.34 Consider an n-P heterojunction in thermal equilibrium. Poisson's equation is()dx d x dx d E-=∈-=ρφ22 In the n-region, ()ndn n n eN x dx d ∈=∈=E ρ For uniform doping, we have1C xeN ndn n +∈=E The boundary condition is0=E n at n x x -=, so we obatinnn dn x eN C ∈=1Then ()n n dnn x x eN +∈=E In the P-region,PaP p eNdx d ∈-=E which gives 2C x eN P aP P +∈-=E We have the boundary condition that 0=E P at P x x =, so that______________________________________________________________________________________PPaP x eN C ∈=2 Then()x x eN P P aP P -∈=E Assuming zero surface charge density at0=x , the electric flux density D iscontinuous, so ()()00P P n n E =∈E ∈,whichyieldsP aP n dn x N x N = We can determine the electric potential as ()dx x n n ⎰E -=φ322C x x eN x eN n n dn n dn +⎥⎥⎦⎤⎢⎢⎣⎡∈+∈-=Now()()n n n bin x V --=φφ0⎥⎥⎦⎤⎢⎢⎣⎡∈+∈--=n ndn n n dn x eN x eN C C 22332ornndn bin x eN V ∈=22Similarly on the P-side, we findPPaP biP x eN V ∈=22We have thatPPaP n n dn biP bin bi x eN x eN V V V ∈+∈=+=2222 We can write⎪⎪⎭⎫⎝⎛=aP dn n P N N x x Substituting and collecting terms, we find222n aP P n dn n aP dn P bi x N N e N N e V ⋅⎥⎥⎦⎤⎢⎢⎣⎡∈∈∈+∈=Solving for n x , we have()2/12⎥⎦⎤⎢⎣⎡∈+∈∈∈=dn n aPP dn bi aP P n n N N eN V N x Similarly on the P-side, we have()2/12⎥⎦⎤⎢⎣⎡∈+∈∈∈=dn n aP P aP bidn P n P N N eN V N xThe total space charge width is then P n x x W += Substituting and collecting terms, we obtain ()()2/12⎥⎦⎤⎢⎣⎡∈+∈+∈∈=dn n aPP aP dn dn aP bi P n N N N eN N N V W _______________________________________。

半导体物理与器件第四版课后习题答案(完整教资)

Chapter 1Problem Solutions1.1 (a) fcc: 8 corner atoms 18/1=⨯atom 6 face atoms 32/1=⨯atomsTotal of 4 atoms per unit cell (b) bcc: 8 corner atoms 18/1=⨯atom1 enclosed atom =1 atomTotal of 2 atoms per unit cell (c) Diamond: 8 corner atoms 18/1=⨯atom 6 face atoms 32/1=⨯atoms4 enclosed atoms = 4 atomsTotal of 8 atoms per unit cell_______________________________________ 1.2 (a) Simple cubic lattice: r a 2=Unit cell vol ()33382r r a === 1 atom per cell, so atom vol ()⎪⎪⎭⎫⎝⎛=3413r π ThenRatio %4.52%10083433=⨯⎪⎪⎭⎫ ⎝⎛=rr π (b) Face-centered cubic latticer da a r d ⋅==⇒==22224Unit cell vol ()33321622r r a ⋅=⋅==4 atoms per cell, so atom vol()⎪⎪⎭⎫⎝⎛=3443r π ThenRatio ()%74%10021634433=⨯⋅⎪⎪⎭⎫⎝⎛=r r π (c) Body-centered cubic latticer a a r d ⋅=⇒==3434 Unit cell vol 3334⎪⎪⎭⎫⎝⎛⋅==r a 2 atoms per cell, so atom vol()⎪⎪⎭⎫⎝⎛=3423r πThenRatio ()%68%1003434233=⨯⎪⎪⎭⎫ ⎝⎛⎪⎪⎭⎫⎝⎛=r r π (d) Diamond lattice Body diagonalr a a r d ⋅=⇒===3838Unit cell vol 3338⎪⎪⎭⎫⎝⎛==r a 8 atoms per cell, so atom vol ()⎪⎪⎭⎫⎝⎛=3483r π ThenRatio ()%34%1003834833=⨯⎪⎪⎭⎫ ⎝⎛⎪⎪⎭⎫⎝⎛=r r π _______________________________________ 1.3(a)oA a 43.5=; From Problem 1.2d,r a ⋅=38Then ()o A a r 176.18343.583===Center of one silicon atom to center ofnearest neighbor oA r 35.22== (b) Number density()22381051043.58⨯=⨯=-cm 3-(c)Mass density()()()23221002.609.28105..⨯⨯===A N W t At N ρ 33.2=⇒ρ grams/cm 3_______________________________________ 1.4 (a) 4 Ga atoms per unit cellNumber density ()381065.54-⨯=⇒Density of Ga atoms221022.2⨯=cm 3-4 As atoms per unit cell ⇒Density of As atoms 221022.2⨯=cm 3- (b) 8 Ge atoms per unit cellNumber density ()381065.58-⨯=⇒Density of Ge atoms 221044.4⨯=cm 3-_______________________________________ 1.5From Figure 1.15(a)()a a d 4330.0232=⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛= =()()oA d 447.265.54330.0=⇒ (b)()a a d 7071.022=⎪⎭⎫⎝⎛=()()oA d 995.365.57071.0=⇒= _______________________________________ 1.6︒=⇒==⎪⎭⎫ ⎝⎛74.5423232222sin θθa a︒=⇒5.109θ_______________________________________ 1.7(a) Simple cubic: oA r a 9.32== (b) fcc: oA r a 515.524==(c) bcc: oA ra 503.434==(d) diamond: ()oA r a 007.9342==_______________________________________ 1.8(a)()()B r 2035.122035.12+= oB A r 4287.0= (b) ()oA a 07.2035.12==(c)A-atoms: # of atoms 1818=⨯= Density ()381007.21-⨯=231013.1⨯=cm 3-B-atoms: # of atoms 3216=⨯=Density ()381007.23-⨯=231038.3⨯= cm 3- _______________________________________ 1.9 (a)oA r a 5.42==# of atoms 1818=⨯= Number density ()38105.41-⨯=2210097.1⨯=cm 3-Mass density ()AN W t At N ..==ρ ()()23221002.65.12100974.1⨯⨯==228.0gm/cm 3(b)o A ra 196.534==# of atoms 21818=+⨯Number density ()3810196.52-⨯=22104257.1⨯=cm 3-Mass density ()()23221002.65.12104257.1⨯⨯==ρ296.0=gm/cm 3_______________________________________ 1.10From Problem 1.2, percent volume of fcc atoms is 74%; Therefore after coffee is ground,Volume = 0.74 cm 3_______________________________________ 1.11(b)oA a 8.20.18.1=+= (c)Na: Density ()()38108.22/1-⨯=221028.2⨯=cm 3-Cl: Density 221028.2⨯=cm 3- (d) Na: At. Wt. = 22.99Cl: At. Wt. = 35.45So, mass per unit cell ()()23231085.41002.645.352199.2221-⨯=⨯⎪⎭⎫⎝⎛+⎪⎭⎫ ⎝⎛= Then mass density()21.2108.21085.43823=⨯⨯=--ρ grams/cm 3_______________________________________ 1.12 (a)()()oA a 88.122.223=+=Then oA a 62.4= Density of A:()22381001.11062.41⨯=⨯=-cm 3-Density of B: ()22381001.11062.41⨯=⨯=-cm 3-(b) Same as (a) (c) Same material_______________________________________ 1.13()()o A a 619.438.122.22=+=(a) For 1.12(a), A-atoms Surface density ()28210619.411-⨯==a 1410687.4⨯=cm 2-For 1.12(b), B-atoms: oA a 619.4= Surface density 14210687.41⨯==acm 2- For 1.12(a) and (b), Same material(b) For 1.12(a), A-atoms; o A a 619.4= Surface density212a =1410315.3⨯=cm 2-B-atoms;Surface density14210315.321⨯==a cm 2- For 1.12(b), A-atoms; o A a 619.4= Surface density212a =1410315.3⨯=cm 2-B-atoms;Surface density14210315.321⨯==a cm 2- For 1.12(a) and (b), Same material_______________________________________ 1.14(a) Vol. Density 31oa =Surface Density 212oa=(b) Same as (a)_______________________________________ 1.15 (i) (110) plane(see Figure 1.10(b))(ii) (111) plane(see Figure 1.10(c))(iii) (220) plane ⇒()0,1,1,21,21⇒⎪⎭⎫⎝⎛∞Same as (110) plane and [110] direction(iv) (321) plane ()6,3,211,21,31⇒⎪⎭⎫⎝⎛⇒Intercepts of plane at 6,3,2===s q p[321] direction is perpendicular to (321) plane_______________________________________ 1.16(a)()31311,31,11⇒⎪⎭⎫⎝⎛(b)()12141,21,41⇒⎪⎭⎫⎝⎛_______________________________________ 1.17Intercepts: 2, 4, 3 ⇒⎪⎭⎫⎝⎛⇒31,41,21(634) plane_______________________________________ 1.18(a) oA a d 28.5==(b) o A a d 734.322==(c) o A a d 048.333==_______________________________________ 1.19 (a) Simple cubic(i) (100) plane:Surface density ()2821073.411-⨯==a141047.4⨯=cm 2- (ii) (110) plane:Surface density 212a =141016.3⨯=cm 2- (iii) (111) plane:Area of plane bh 21=where oA a b 689.62== Now ()()2222243222a a a h =⎪⎪⎭⎫⎝⎛-= So ()o A h 793.573.426==Area of plane ()()881079304.51068923.621--⨯⨯= 16103755.19-⨯=cm 2Surface density 16103755.19613-⨯⨯=141058.2⨯=cm 2- (b) bcc(i) (100) plane:Surface density 1421047.41⨯==a cm 2- (ii) (110) plane:Surface density 222a =141032.6⨯=cm 2- (iii) (111) plane:Surface density 16103755.19613-⨯⨯=141058.2⨯=cm 2- (c) fcc(i) (100) plane:Surface density 1421094.82⨯==acm 2-(ii) (110) plane:Surface density 222a =141032.6⨯=cm 2- (iii) (111) plane:Surface density 16103755.19213613-⨯⨯+⨯=151003.1⨯=cm 2-_______________________________________ 1.20 (a) (100) plane: - similar to a fcc:Surface density ()281043.52-⨯=141078.6⨯=cm 2- (b) (110) plane:Surface density ()281043.524-⨯=141059.9⨯=cm 2- (c) (111) plane:Surface density ()()281043.5232-⨯= 141083.7⨯=cm 2-_______________________________________ 1.21()o A r a 703.6237.2424===(a) #/cm 3()38310703.64216818-⨯=⨯+⨯=a 2210328.1⨯=cm 3-(b) #/cm 222124142a ⨯+⨯= ()210703.6228-⨯=1410148.3⨯=cm 2- (c) ()o A a d 74.422703.622===(d)# of atoms 2213613=⨯+⨯=Area of plane: (see Problem 1.19)oA a b 4786.92==o A ah 2099.826==Area ()()88102099.8104786.92121--⨯⨯==bh 15108909.3-⨯=cm 2#/cm 215108909.32-⨯= =141014.5⨯ cm 2-()o A a d 87.333703.633===_______________________________________ 1.22Density of silicon atoms 22105⨯=cm 3- and4 valence electrons per atom, so Density of valence electrons 23102⨯=cm 3-_______________________________________ 1.23Density of GaAs atoms()22381044.41065.58⨯=⨯=-cm 3- An average of 4 valence electrons per atom,SoDensity of valence electrons231077.1⨯=cm 3-_______________________________________ 1.24(a) %10%10010510532217-=⨯⨯⨯ (b) %104%10010510262215-⨯=⨯⨯⨯ _______________________________________ 1.25 (a) Fraction by weight()()()()7221610542.106.2810582.10102-⨯=⨯⨯≅ (b) Fraction by weight()()()()5221810208.206.2810598.3010-⨯=⨯≅ _______________________________________ 1.26Volume density 1631021⨯==dcm 3-So 610684.3-⨯=d cm oA d 4.368=⇒ We have oo A a 43.5=Then85.6743.54.368==o a d _______________________________________ 1.27Volume density 1531041⨯==dcm 3-So 61030.6-⨯=d cm oA d 630=⇒ We have oo A a 43.5= Then11643.5630==o a d _______________________________________。

半导体物理与器件第四版第一章课后答案

o
Number density
5.196 10
2

8 3
1.4257 10 22 cm 3
Mass density
1.4257 10 12.5
22
6.02 10 23
0.296 gm/cm 3 _______________________________________
1.10 From Problem 1.2, percent volume of fcc atoms is 74%; Therefore after coffee is ground, Volume = 0.74 cm 3 _______________________________________ 1.11 (b) a 1.8 1.0 2.8 A (c) Na: Density
o
Semiconductor Physics and Devices: Basic Principles, 4th edition Chapter 1 By D. A. Neamen Problem Solutions ______________________________________________________________________________________ (b) Number density a 8 2 5 10 22 cm 3 3 2 5.43 10 8 sin 2 54.74 3 2 2 a 3 (c) Mass density 2 22 N At.Wt. 5 10 28.09 109.5 NA 6.02 10 23 _______________________________________ 2.33 grams/cm 3 1.7 _______________________________________ o (a) Simple cubic: a 2r 3.9 A

半导体物理与器件第四课后习题答案3.doc

Chapter 33.1If o a were to increase, the bandgap energy would decrease and the material would begin to behave less like a semiconductor and more like a metal. If o a were to decrease, the bandgap energy would increase and thematerial would begin to behave more like an insulator._______________________________________ 3.2Schrodinger's wave equation is:()()()t x x V xt x m ,,2222ψ⋅+∂ψ∂- ()tt x j ∂ψ∂=, Assume the solution is of the form:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=ψt E kx j x u t x exp , Region I: ()0=x V . Substituting theassumed solution into the wave equation, we obtain:()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧∂∂-t E kx j x jku x m exp 22 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u exp ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⋅⎪⎭⎫ ⎝⎛-=t E kx j x u jE j exp which becomes()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧-t E kx j x u jk m exp 222 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u jkexp 2 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u exp 22 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-+=t E kx j x Eu exp This equation may be written as()()()()0222222=+∂∂+∂∂+-x u mE x x u x x u jk x u kSetting ()()x u x u 1= for region I, the equation becomes:()()()()021221212=--+x u k dx x du jk dxx u d α where222mE=αIn Region II, ()O V x V =. Assume the same form of the solution:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=ψt E kx j x u t x exp , Substituting into Schrodinger's wave equation, we find:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧-t E kx j x u jk m exp 222 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u jkexp 2 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u exp 22 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-+t E kx j x u V O exp ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=t E kx j x Eu exp This equation can be written as:()()()2222x x u x x u jk x u k ∂∂+∂∂+- ()()02222=+-x u mEx u mV OSetting ()()x u x u 2= for region II, this equation becomes()()dx x du jk dxx u d 22222+ ()022222=⎪⎪⎭⎫ ⎝⎛+--x u mV k O α where again222mE=α_______________________________________3.3We have()()()()021221212=--+x u k dx x du jk dxx u d α Assume the solution is of the form: ()()[]x k j A x u -=αexp 1()[]x k j B +-+αexp The first derivative is()()()[]x k j A k j dxx du --=ααexp 1 ()()[]x k j B k j +-+-ααexp and the second derivative becomes()()[]()[]x k j A k j dxx u d --=ααexp 2212 ()[]()[]x k j B k j +-++ααexp 2Substituting these equations into the differential equation, we find()()[]x k j A k ---ααexp 2()()[]x k j B k +-+-ααexp 2(){()[]x k j A k j jk --+ααexp 2()()[]}x k j B k j +-+-ααexp ()()[]{x k j A k ---ααexp 22 ()[]}0exp =+-+x k j B α Combining terms, we obtain()()()[]222222αααα----+--k k k k k ()[]x k j A -⨯αexp()()()[]222222αααα--++++-+k k k k k ()[]0exp =+-⨯x k j B α We find that 00=For the differential equation in ()x u 2 and the proposed solution, the procedure is exactly the same as above._______________________________________ 3.4We have the solutions ()()[]x k j A x u -=αexp 1()[]x k j B +-+αexp for a x <<0 and()()[]x k j C x u -=βexp 2()[]x k j D +-+βexp for 0<<-x b .The first boundary condition is ()()0021u u =which yields0=--+D C B AThe second boundary condition is201===x x dx dudx du which yields()()()C k B k A k --+--βαα()0=++D k β The third boundary condition is ()()b u a u -=21 which yields()[]()[]a k j B a k j A +-+-ααexp exp ()()[]b k j C --=βexp()()[]b k j D -+-+βexp and can be written as()[]()[]a k j B a k j A +-+-ααexp exp ()[]b k j C ---βexp()[]0exp =+-b k j D β The fourth boundary condition isbx a x dx dudx du -===21 which yields()()[]a k j A k j --ααexp()()[]a k j B k j +-+-ααexp ()()()[]b k j C k j ---=ββexp()()()[]b k j D k j -+-+-ββexp and can be written as ()()[]a k j A k --ααexp()()[]a k j B k +-+-ααexp()()[]b k j C k ----ββexp()()[]0exp =+++b k j D k ββ_______________________________________ 3.5(b) (i) First point: πα=aSecond point: By trial and error, πα729.1=a (ii) First point: πα2=aSecond point: By trial and error, πα617.2=a_______________________________________3.6(b) (i) First point: πα=aSecond point: By trial and error, πα515.1=a (ii) First point: πα2=aSecond point: By trial and error, πα375.2=a_______________________________________ 3.7ka a aaP cos cos sin =+'αααLet y ka =, x a =α Theny x x xP cos cos sin =+'Consider dy dof this function.()[]{}y x x x P dyd sin cos sin 1-=+⋅'- We find()()()⎭⎬⎫⎩⎨⎧⋅+⋅-'--dy dx x x dy dx x x P cos sin 112y dydxx sin sin -=- Theny x x x x x P dy dx sin sin cos sin 12-=⎭⎬⎫⎩⎨⎧-⎥⎦⎤⎢⎣⎡+-'For πn ka y ==, ...,2,1,0=n 0sin =⇒y So that, in general,()()dk d ka d a d dy dxαα===0 And22 mE=αSodk dEm mE dk d ⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛=-22/122221 α This implies thatdk dE dk d ==0α for an k π= _______________________________________ 3.8(a) πα=a 1π=⋅a E m o 212()()()()2103123422221102.41011.9210054.12---⨯⨯⨯==ππa m E o19104114.3-⨯=J From Problem 3.5 πα729.12=aπ729.1222=⋅a E m o()()()()2103123422102.41011.9210054.1729.1---⨯⨯⨯=πE18100198.1-⨯=J 12E E E -=∆1918104114.3100198.1--⨯-⨯= 19107868.6-⨯=Jor 24.4106.1107868.61919=⨯⨯=∆--E eV(b) πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=J From Problem 3.5, πα617.24=aπ617.2224=⋅a E m o()()()()2103123424102.41011.9210054.1617.2---⨯⨯⨯=πE18103364.2-⨯=J 34E E E -=∆1818103646.1103364.2--⨯-⨯= 1910718.9-⨯=Jor 07.6106.110718.91919=⨯⨯=∆--E eV_______________________________________3.9(a) At π=ka , πα=a 1π=⋅a E m o 212()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JAt 0=ka , By trial and error, πα859.0=a o ()()()()210312342102.41011.9210054.1859.0---⨯⨯⨯=πoE19105172.2-⨯=J o E E E -=∆11919105172.2104114.3--⨯-⨯= 2010942.8-⨯=Jor 559.0106.110942.81920=⨯⨯=∆--E eV (b) At π2=ka , πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JAt π=ka . From Problem 3.5, πα729.12=aπ729.1222=⋅a E m o()()()()2103123422102.41011.9210054.1729.1---⨯⨯⨯=πE18100198.1-⨯=J23E E E -=∆1818100198.1103646.1--⨯-⨯= 19104474.3-⨯=Jor 15.2106.1104474.31919=⨯⨯=∆--E eV_______________________________________3.10(a) πα=a 1π=⋅a E m o 212()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JFrom Problem 3.6, πα515.12=aπ515.1222=⋅a E m o()()()()2103123422102.41011.9210054.1515.1---⨯⨯⨯=πE1910830.7-⨯=J 12E E E -=∆1919104114.310830.7--⨯-⨯= 19104186.4-⨯=Jor 76.2106.1104186.41919=⨯⨯=∆--E eV (b) πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JFrom Problem 3.6, πα375.24=aπ375.2224=⋅a E m o()()()()2103123424102.41011.9210054.1375.2---⨯⨯⨯=πE18109242.1-⨯=J 34E E E -=∆1818103646.1109242.1--⨯-⨯= 1910597.5-⨯=Jor 50.3106.110597.51919=⨯⨯=∆--E eV_____________________________________3.11(a) At π=ka , πα=a 1π=⋅a E m o 212()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JAt 0=ka , By trial and error, πα727.0=a oπ727.022=⋅a E m o o()()()()210312342102.41011.9210054.1727.0---⨯⨯⨯=πo E19108030.1-⨯=Jo E E E -=∆11919108030.1104114.3--⨯-⨯= 19106084.1-⨯=Jor 005.1106.1106084.11919=⨯⨯=∆--E eV (b) At π2=ka , πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JAt π=ka , From Problem 3.6,πα515.12=aπ515.1222=⋅a E m o()()()()2103423422102.41011.9210054.1515.1---⨯⨯⨯=πE1910830.7-⨯=J23E E E -=∆191810830.7103646.1--⨯-⨯= 1910816.5-⨯=Jor 635.3106.110816.51919=⨯⨯=∆--E eV_______________________________________3.12For 100=T K, ()()⇒+⨯-=-1006361001073.4170.124gE164.1=g E eV200=T K, 147.1=g E eV 300=T K, 125.1=g E eV 400=T K, 097.1=g E eV 500=T K, 066.1=g E eV 600=T K, 032.1=g E eV_______________________________________3.13The effective mass is given by1222*1-⎪⎪⎭⎫⎝⎛⋅=dk E d mWe have()()B curve dkE d A curve dk E d 2222> so that ()()B curve m A curve m **<_______________________________________ 3.14The effective mass for a hole is given by1222*1-⎪⎪⎭⎫ ⎝⎛⋅=dk E d m p We have that()()B curve dkEd A curve dk E d 2222> so that ()()B curve m A curve m p p **<_______________________________________ 3.15Points A,B: ⇒<0dk dEvelocity in -x directionPoints C,D: ⇒>0dk dEvelocity in +x directionPoints A,D: ⇒<022dk Ednegative effective massPoints B,C: ⇒>022dkEd positive effective mass _______________________________________3.16For A: 2k C E i =At 101008.0+⨯=k m 1-, 05.0=E eV Or ()()2119108106.105.0--⨯=⨯=E J So ()2101211008.0108⨯=⨯-C3811025.1-⨯=⇒CNow ()()38234121025.1210054.12--*⨯⨯==C m 311044.4-⨯=kgor o m m ⋅⨯⨯=--*31311011.9104437.4o m m 488.0=* For B: 2k C E i =At 101008.0+⨯=k m 1-, 5.0=E eV Or ()()2019108106.15.0--⨯=⨯=E JSo ()2101201008.0108⨯=⨯-C 3711025.1-⨯=⇒CNow ()()37234121025.1210054.12--*⨯⨯==C m 321044.4-⨯=kg or o m m ⋅⨯⨯=--*31321011.9104437.4o m m 0488.0=*_______________________________________ 3.17For A: 22k C E E -=-υ()()()2102191008.0106.1025.0⨯-=⨯--C 3921025.6-⨯=⇒C()()39234221025.6210054.12--*⨯⨯-=-=C m31108873.8-⨯-=kgor o m m ⋅⨯⨯-=--*31311011.9108873.8o m m 976.0--=* For B: 22k C E E -=-υ()()()2102191008.0106.13.0⨯-=⨯--C 382105.7-⨯=⇒C()()3823422105.7210054.12--*⨯⨯-=-=C m3210406.7-⨯-=kgor o m m ⋅⨯⨯-=--*31321011.910406.7o m m 0813.0-=*_______________________________________ 3.18(a) (i) νh E =or ()()341910625.6106.142.1--⨯⨯==h E ν1410429.3⨯=Hz(ii) 141010429.3103⨯⨯===νλc E hc 51075.8-⨯=cm 875=nm(b) (i) ()()341910625.6106.112.1--⨯⨯==h E ν1410705.2⨯=Hz(ii) 141010705.2103⨯⨯==νλc410109.1-⨯=cm 1109=nm_______________________________________ 3.19(c) Curve A: Effective mass is a constantCurve B: Effective mass is positive around 0=k , and is negativearound 2π±=k . _______________________________________ 3.20()[]O O k k E E E --=αcos 1 Then()()()[]O k k E dkdE ---=ααsin 1()[]O k k E -+=ααsin 1 and()[]O k k E dk E d -=ααcos 2122Then221222*11 αE dk Ed m o k k =⋅== or212*αE m =_______________________________________ 3.21(a) ()[]3/123/24lt dn m m m =*()()[]3/123/264.1082.04oom m =o dn m m 56.0=*(b)o o l t cnm m m m m 64.11082.02123+=+=*oo m m 6098.039.24+=o cn m m 12.0=*_______________________________________ 3.22(a) ()()[]3/22/32/3lh hh dp m m m +=*()()[]3/22/32/3082.045.0o om m +=[]o m ⋅+=3/202348.030187.0o dp m m 473.0=*(b) ()()()()2/12/12/32/3lh hh lh hh cpm m m m m ++=*()()()()om ⋅++=2/12/12/32/3082.045.0082.045.0 o cp m m 34.0=*_______________________________________ 3.23For the 3-dimensional infinite potential well, ()0=x V when a x <<0, a y <<0, and a z <<0. In this region, the wave equation is:()()()222222,,,,,,z z y x y z y x x z y x ∂∂+∂∂+∂∂ψψψ()0,,22=+z y x mEψ Use separation of variables technique, so let ()()()()z Z y Y x X z y x =,,ψSubstituting into the wave equation, we have222222zZXY y Y XZ x X YZ ∂∂+∂∂+∂∂ 022=⋅+XYZ mEDividing by XYZ , we obtain021*********=+∂∂⋅+∂∂⋅+∂∂⋅ mEz Z Z y Y Y x X XLet01222222=+∂∂⇒-=∂∂⋅X k x X k x X X xx The solution is of the form: ()x k B x k A x X x x cos sin +=Since ()0,,=z y x ψ at 0=x , then ()00=X so that 0=B .Also, ()0,,=z y x ψ at a x =, so that ()0=a X . Then πx x n a k = where ...,3,2,1=x n Similarly, we have2221y k y Y Y -=∂∂⋅ and 2221z k zZ Z -=∂∂⋅From the boundary conditions, we find πy y n a k = and πz z n a k =where...,3,2,1=y n and ...,3,2,1=z n From the wave equation, we can write022222=+---mE k k k z y xThe energy can be written as()222222⎪⎭⎫⎝⎛++==a n n n m E E z y x n n n z y x π _______________________________________ 3.24The total number of quantum states in the 3-dimensional potential well is given (in k-space) by()332a dk k dk k g T ⋅=ππ where222 mEk =We can then writemEk 2=Taking the differential, we obtaindE Em dE E m dk ⋅⋅=⋅⋅⋅⋅=2112121 Substituting these expressions into the density of states function, we have()dE E mmE a dE E g T ⋅⋅⋅⎪⎭⎫ ⎝⎛=212233 ππ Noting thatπ2h=this density of states function can be simplified and written as()()dE E m h a dE E g T ⋅⋅=2/33324π Dividing by 3a will yield the density of states so that()()E h m E g ⋅=32/324π _______________________________________ 3.25For a one-dimensional infinite potential well,222222k a n E m n ==*π Distance between quantum states()()aa n a n k k n n πππ=⎪⎭⎫ ⎝⎛=⎪⎭⎫ ⎝⎛+=-+11Now()⎪⎭⎫ ⎝⎛⋅=a dkdk k g T π2NowE m k n *⋅=21dE Em dk n⋅⋅⋅=*2211 Then()dE Em a dE E g n T ⋅⋅⋅=*2212 π Divide by the "volume" a , so ()Em E g n *⋅=21πSo()()()()()EE g 31341011.9067.0210054.11--⨯⋅⨯=π ()EE g 1810055.1⨯=m 3-J 1-_______________________________________ 3.26(a) Silicon, o n m m 08.1=*()()c nc E E h m E g -=*32/324π()dE E E h m g kTE E c nc c c⋅-=⎰+*232/324π()()kT E E c nc cE E h m 22/332/33224+*-⋅⋅=π()()2/332/323224kT hm n⋅⋅=*π ()()[]()()2/33342/33123210625.61011.908.124kT ⋅⋅⨯⨯=--π ()()2/355210953.7kT ⨯=(i) At 300=T K, 0259.0=kT eV()()19106.10259.0-⨯= 2110144.4-⨯=J Then ()()[]2/3215510144.4210953.7-⨯⨯=c g25100.6⨯=m 3-or 19100.6⨯=c g cm 3-(ii) At 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV()()19106.1034533.0-⨯= 21105253.5-⨯=J Then()()[]2/32155105253.5210953.7-⨯⨯=c g2510239.9⨯=m 3- or 191024.9⨯=c g cm 3-(b) GaAs, o nm m 067.0=*()()[]()()2/33342/33123210625.61011.9067.024kT g c ⋅⋅⨯⨯=--π ()()2/3542102288.1kT ⨯=(i) At 300=T K, 2110144.4-⨯=kT J ()()[]2/3215410144.42102288.1-⨯⨯=c g2310272.9⨯=m 3- or 171027.9⨯=c g cm 3-(ii) At 400=T K, 21105253.5-⨯=kT J ()()[]2/32154105253.52102288.1-⨯⨯=c g2410427.1⨯=m 3-181043.1⨯=c g cm 3-_______________________________________ 3.27(a) Silicon, o p m m 56.0=* ()()E E h mE g p-=*υυπ32/324()dE E E h mg E kTE p⋅-=⎰-*υυυυπ332/324()()υυυπE kTE pE E hm 32/332/33224-*-⎪⎭⎫ ⎝⎛-=()()[]2/332/333224kT hmp-⎪⎭⎫ ⎝⎛-=*π ()()[]()()2/33342/33133210625.61011.956.024kT ⎪⎭⎫ ⎝⎛⨯⨯=--π ()()2/355310969.2kT ⨯=(i)At 300=T K, 2110144.4-⨯=kT J ()()[]2/3215510144.4310969.2-⨯⨯=υg2510116.4⨯=m3-or 191012.4⨯=υg cm 3- (ii)At 400=T K, 21105253.5-⨯=kT J()()[]2/32155105253.5310969.2-⨯⨯=υg2510337.6⨯=m3-or 191034.6⨯=υg cm 3- (b) GaAs, o p m m 48.0=*()()[]()()2/33342/33133210625.61011.948.024kT g ⎪⎭⎫ ⎝⎛⨯⨯=--πυ ()()2/3553103564.2kT ⨯=(i)At 300=T K, 2110144.4-⨯=kT J()()[]2/3215510144.43103564.2-⨯⨯=υg2510266.3⨯=m 3- or 191027.3⨯=υg cm 3-(ii)At 400=T K, 21105253.5-⨯=kT J()()[]2/32155105253.53103564.2-⨯⨯=υg2510029.5⨯=m 3-or 191003.5⨯=υg cm 3-_______________________________________ 3.28(a) ()()c nc E E h m E g -=*32/324π()()[]()c E E -⨯⨯=--3342/33110625.61011.908.124πc E E -⨯=56101929.1 For c E E =; 0=c g1.0+=c E E eV; 4610509.1⨯=c g m 3-J 1-2.0+=c E E eV; 4610134.2⨯=m 3-J 1-3.0+=c E E eV; 4610614.2⨯=m 3-J 1- 4.0+=c E E eV; 4610018.3⨯=m 3-J 1- (b) ()E E h m g p-=*υυπ32/324()()[]()E E -⨯⨯=--υπ3342/33110625.61011.956.024E E -⨯=υ55104541.4 For υE E =; 0=υg1.0-=υE E eV; 4510634.5⨯=υg m 3-J 1-2.0-=υE E eV; 4510968.7⨯=m 3-J 1-3.0-=υE E eV; 4510758.9⨯=m 3-J 1-4.0-=υE E eV; 4610127.1⨯=m 3-J 1-_______________________________________ 3.29(a) ()()68.256.008.12/32/32/3=⎪⎭⎫ ⎝⎛==**pnc m m g g υ(b) ()()0521.048.0067.02/32/32/3=⎪⎭⎫ ⎝⎛==**pncmm g g υ_______________________________________3.30 Plot_______________________________________ 3.31(a) ()()()!710!7!10!!!-=-=i i i i i N g N g W()()()()()()()()()()()()1201238910!3!7!78910===(b) (i) ()()()()()()()()12!10!101112!1012!10!12=-=i W 66=(ii) ()()()()()()()()()()()()1234!8!89101112!812!8!12=-=i W 495=_______________________________________ 3.32()⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F exp 11(a) kT E E F =-, ()()⇒+=1exp 11E f()269.0=E f (b) kT E E F 5=-, ()()⇒+=5exp 11E f()31069.6-⨯=E f(c) kT E E F 10=-, ()()⇒+=10exp 11E f ()51054.4-⨯=E f_______________________________________ 3.33()⎪⎪⎭⎫ ⎝⎛-+-=-kT E E E f F exp 1111or()⎪⎪⎭⎫ ⎝⎛-+=-kT E E E f F exp 111(a) kT E E F =-, ()269.01=-E f (b) kT E E F 5=-, ()31069.61-⨯=-E f(c) kT E E F 10=-, ()51054.41-⨯=-E f_______________________________________ 3.34(a) ()⎥⎦⎤⎢⎣⎡--≅kT E E f F F exp c E E =; 61032.90259.030.0exp -⨯=⎥⎦⎤⎢⎣⎡-=F f 2kT E c +; ()⎥⎦⎤⎢⎣⎡+-=0259.020259.030.0exp F f 61066.5-⨯=kT E c +; ()⎥⎦⎤⎢⎣⎡+-=0259.00259.030.0exp F f 61043.3-⨯=23kT E c +; ()()⎥⎦⎤⎢⎣⎡+-=0259.020259.0330.0exp F f 61008.2-⨯=kT E c 2+; ()()⎥⎦⎤⎢⎣⎡+-=0259.00259.0230.0exp F f 61026.1-⨯=(b) ⎥⎦⎤⎢⎣⎡-+-=-kT E E f F F exp 1111()⎥⎦⎤⎢⎣⎡--≅kT E E F exp υE E =; ⎥⎦⎤⎢⎣⎡-=-0259.025.0exp 1F f 51043.6-⨯= 2kT E -υ; ()⎥⎦⎤⎢⎣⎡+-=-0259.020259.025.0exp 1F f 51090.3-⨯=kT E -υ; ()⎥⎦⎤⎢⎣⎡+-=-0259.00259.025.0exp 1F f 51036.2-⨯=23kTE -υ; ()()⎥⎦⎤⎢⎣⎡+-=-0259.020259.0325.0exp 1F f 51043.1-⨯= kT E 2-υ;()()⎥⎦⎤⎢⎣⎡+-=-0259.00259.0225.0exp 1F f 61070.8-⨯=_______________________________________3.35()()⎥⎦⎤⎢⎣⎡-+-=⎥⎦⎤⎢⎣⎡--=kT E kT E kT E E f F c F F exp exp and()⎥⎦⎤⎢⎣⎡--=-kT E E f F F exp 1 ()()⎥⎦⎤⎢⎣⎡---=kT kT E E F υexp So ()⎥⎦⎤⎢⎣⎡-+-kT E kT E F c exp ()⎥⎦⎤⎢⎣⎡+--=kT kT E E F υexp Then kT E E E kT E F F c +-=-+υOr midgap c F E E E E =+=2υ_______________________________________ 3.3622222ma n E n π =For 6=n , Filled state()()()()()2103122234610121011.92610054.1---⨯⨯⨯=πE18105044.1-⨯=Jor 40.9106.1105044.119186=⨯⨯=--E eV For 7=n , Empty state ()()()()()2103122234710121011.92710054.1---⨯⨯⨯=πE1810048.2-⨯=Jor 8.12106.110048.219187=⨯⨯=--E eV Therefore 8.1240.9<<F E eV_______________________________________ 3.37(a) For a 3-D infinite potential well()222222⎪⎭⎫ ⎝⎛++=a n n n mE z y x π For 5 electrons, the 5th electron occupies the quantum state 1,2,2===z y x n n n ; so()2222252⎪⎭⎫ ⎝⎛++=a n n n m E z y x π()()()()()21031222223410121011.9212210054.1---⨯⨯++⨯=π1910761.3-⨯=Jor 35.2106.110761.319195=⨯⨯=--E eV For the next quantum state, which is empty, the quantum state is 2,2,1===z y x n n n . This quantum state is at the same energy, so 35.2=F E eV(b) For 13 electrons, the 13th electronoccupies the quantum state 3,2,3===z y x n n n ; so ()()()()()2103122222341310121011.9232310054.1---⨯⨯++⨯=πE 1910194.9-⨯=Jor 746.5106.110194.9191913=⨯⨯=--E eVThe 14th electron would occupy the quantum state 3,3,2===z y x n n n . This state is at the same energy, so 746.5=F E eV_______________________________________ 3.38The probability of a state at E E E F ∆+=1 being occupied is()⎪⎭⎫ ⎝⎛∆+=⎪⎪⎭⎫ ⎝⎛-+=kT E kT E E E f F exp 11exp 11111 The probability of a state at E E E F ∆-=2being empty is()⎪⎪⎭⎫ ⎝⎛-+-=-kT E E E f F 222exp 1111⎪⎭⎫ ⎝⎛∆-+⎪⎭⎫ ⎝⎛∆-=⎪⎭⎫ ⎝⎛∆-+-=kT E kT E kT E exp 1exp exp 111or()⎪⎭⎫ ⎝⎛∆+=-kT E E f exp 11122so ()()22111E f E f -=_______________________________________3.39(a) At energy 1E , we want01.0exp 11exp 11exp 1111=⎪⎪⎭⎫ ⎝⎛-+⎪⎪⎭⎫ ⎝⎛-+-⎪⎪⎭⎫ ⎝⎛-kT E E kT E E kT E E F F FThis expression can be written as01.01exp exp 111=-⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-+kT E E kT E E F F or()⎪⎪⎭⎫⎝⎛-=kT E E F 1exp 01.01Then()100ln 1kT E E F += orkT E E F 6.41+= (b)At kT E E F 6.4+=, ()()6.4exp 11exp 1111+=⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F which yields()01.000990.01≅=E f_______________________________________ 3.40 (a)()()⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--=0259.050.580.5exp exp kT E E f F F 61032.9-⨯=(b) ()060433.03007000259.0=⎪⎭⎫⎝⎛=kT eV31098.6060433.030.0exp -⨯=⎥⎦⎤⎢⎣⎡-=F f (c) ()⎥⎦⎤⎢⎣⎡--≅-kT E E f F F exp 1 ⎥⎦⎤⎢⎣⎡-=kT 25.0exp 02.0or 5002.0125.0exp ==⎥⎦⎤⎢⎣⎡+kT ()50ln 25.0=kTor()()⎪⎭⎫⎝⎛===3000259.0063906.050ln 25.0T kT which yields 740=T K_______________________________________ 3.41 (a)()00304.00259.00.715.7exp 11=⎪⎭⎫ ⎝⎛-+=E for 0.304%(b) At 1000=T K, 08633.0=kT eV Then()1496.008633.00.715.7exp 11=⎪⎭⎫ ⎝⎛-+=E for 14.96%(c) ()997.00259.00.785.6exp 11=⎪⎭⎫ ⎝⎛-+=E for 99.7% (d)At F E E =, ()21=E f for all temperatures_______________________________________ 3.42(a) For 1E E =()()⎥⎦⎤⎢⎣⎡--≅⎪⎪⎭⎫ ⎝⎛-+=kT E E kTE E E fF F11exp exp 11Then()611032.90259.030.0exp -⨯=⎪⎭⎫ ⎝⎛-=E fFor 2E E =, 82.030.012.12=-=-E E F eV Then()⎪⎭⎫ ⎝⎛-+-=-0259.082.0exp 1111E for()⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛---≅-0259.082.0exp 111E f141078.10259.082.0exp -⨯=⎪⎭⎫ ⎝⎛-=(b) For 4.02=-E E F eV,72.01=-F E E eVAt 1E E =,()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.072.0exp exp 1kT E E E f F or()131045.8-⨯=E f At 2E E =,()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1 ⎪⎭⎫ ⎝⎛-=0259.04.0expor()71096.11-⨯=-E f_______________________________________ 3.43(a) At 1E E =()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.030.0exp exp 1kT E E E f F or()61032.9-⨯=E fAt 2E E =, 12.13.042.12=-=-E E F eV So()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1 ⎪⎭⎫ ⎝⎛-=0259.012.1expor()191066.11-⨯=-E f (b) For 4.02=-E E F ,02.11=-F E E eV At 1E E =,()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.002.1exp exp 1kT E E E f F or()181088.7-⨯=E f At 2E E =,()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1 ⎪⎭⎫ ⎝⎛-=0259.04.0expor ()71096.11-⨯=-E f_______________________________________ 3.44()1exp 1-⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+=kTE E E f Fso()()2exp 11-⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+-=kT E E dE E df F⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫⎝⎛⨯kT E E kT F exp 1or()2exp 1exp 1⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫⎝⎛-=kT E E kT E E kT dE E df F F (a) At 0=T K, For()00exp =⇒=∞-⇒<dE dfE E F()0exp =⇒+∞=∞+⇒>dEdfE E FAt -∞=⇒=dEdfE E F(b) At 300=T K, 0259.0=kT eVFor F E E <<, 0=dE dfFor F E E >>, 0=dEdfAt F E E =,()()65.91110259.012-=+⎪⎭⎫ ⎝⎛-=dE df (eV)1-(c) At 500=T K, 04317.0=kT eVFor F E E <<, 0=dE dfFor F E E >>, 0=dEdfAt F E E =,()()79.511104317.012-=+⎪⎭⎫ ⎝⎛-=dE df (eV)1- _______________________________________ 3.45(a) At midgap E E =,()⎪⎪⎭⎫⎝⎛+=⎪⎪⎭⎫ ⎝⎛-+=kT E kTE E E f g F2exp 11exp 11Si: 12.1=g E eV, ()()⎥⎦⎤⎢⎣⎡+=0259.0212.1exp 11E for()101007.4-⨯=E fGe: 66.0=g E eV ()()⎥⎦⎤⎢⎣⎡+=0259.0266.0exp 11E for()61093.2-⨯=E f GaAs: 42.1=g E eV ()()⎥⎦⎤⎢⎣⎡+=0259.0242.1exp 11E for()121024.1-⨯=E f(b) Using the results of Problem 3.38, the answers to part (b) are exactly the same as those given in part (a)._______________________________________3.46(a) ()⎥⎦⎤⎢⎣⎡--=kT E E f F F exp ⎥⎦⎤⎢⎣⎡-=-kT 60.0exp 108or()810ln 60.0+=kT()032572.010ln 60.08==kT eV ()⎪⎭⎫⎝⎛=3000259.0032572.0Tso 377=T K(b) ⎥⎦⎤⎢⎣⎡-=-kT 60.0exp 106()610ln 60.0+=kT()043429.010ln 60.06==kT ()⎪⎭⎫⎝⎛=3000259.0043429.0Tor 503=T K_______________________________________ 3.47(a) At 200=T K,()017267.03002000259.0=⎪⎭⎫⎝⎛=kT eV⎪⎪⎭⎫ ⎝⎛-+==kT E E f F F exp 1105.019105.01exp =-=⎪⎪⎭⎫ ⎝⎛-kT E E F()()()19ln 017267.019ln ==-kT E E F 05084.0=eV By symmetry, for 95.0=F f , 05084.0-=-F E E eVThen ()1017.005084.02==∆E eV (b) 400=T K, 034533.0=kT eV For 05.0=F f , from part (a),()()()19ln 034533.019ln ==-kT E E F 10168.0=eVThen ()2034.010168.02==∆E eV _______________________________________。

半导体物理与器件第四版课后习题集答案解析4

Chapter 44.1⎪⎪⎭⎫ ⎝⎛-=kTE N N n gc i exp 2υ ⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=kT E T N N g O cO exp 3003υwhere cO N and O N υ are the values at 300 K.(a) SiliconT (K) kT (eV)i n (cm 3-) 200 400 600 01727.0 03453.0 0518.041068.7⨯ 121038.2⨯ 141074.9⨯(b) Germanium (c) GaAsT (K) i n (cm 3-) i n (cm 3-)200 400 600101016.2⨯ 141060.8⨯ 161082.3⨯38.1 91028.3⨯ 121072.5⨯_______________________________________ 4.2Plot_______________________________________ 4.3(a) ⎪⎪⎭⎫⎝⎛-=kT E N N n g c i exp 2υ ()()()319192113001004.1108.2105⎪⎭⎫⎝⎛⨯⨯=⨯T()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382330010912.2105.2⎪⎭⎫⎝⎛⨯=⨯T()()()()⎥⎦⎤⎢⎣⎡-⨯T 0259.030012.1expBy trial and error, 5.367≅T K(b)()252122105.2105⨯=⨯=i n()()()()()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=T T 0259.030012.1exp 30010912.2338By trial and error, 5.417≅T K_______________________________________ 4.4At 200=T K, ()⎪⎭⎫⎝⎛=3002000259.0kT017267.0=eVAt 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV()()()()17222102210025.31040.11070.7200400⨯=⨯⨯=ii nn⎥⎦⎤⎢⎣⎡-⎥⎦⎤⎢⎣⎡-⨯⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=017267.0exp 034533.0exp 30020030040033g g E E⎥⎦⎤⎢⎣⎡-=034533.0017267.0exp 8g g E E()[]9578.289139.57exp 810025.317-=⨯g Eor()1714.38810025.3ln 9561.2817=⎪⎪⎭⎫⎝⎛⨯=g E or 318.1=g E eVNow ()32103004001070.7⎪⎭⎫⎝⎛=⨯o co N N υ⎪⎭⎫ ⎝⎛-⨯034533.0318.1exp ()()172110658.2370.210929.5-⨯=⨯o co N N υ so 371041.9⨯=o co N N υcm 6-_______________________________________ 4.5()()⎪⎭⎫ ⎝⎛-=⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛-=kT kT kT A n B n i i 20.0exp 90.0exp 10.1exp For 200=T K, 017267.0=kT eV For 300=T K, 0259.0=kT eV For 400=T K, 034533.0=kT eV (a) For 200=T K, ()()610325.9017267.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (b) For 300=T K, ()()41043.40259.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (c) For 400=T K, ()()31005.3034533.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i _______________________________________ 4.6(a) ()⎥⎦⎤⎢⎣⎡---∝kT E E E E f g F c F c exp()⎥⎦⎤⎢⎣⎡---∝kT E E E E c c exp()⎥⎦⎤⎢⎣⎡--⨯kT E E F c exp Let x E E c =-Then ⎪⎭⎫⎝⎛-∝kT x x f g F c expTo find the maximum value: ()⎪⎭⎫⎝⎛-∝-kT x x dx f g d F c exp 212/10exp 12/1=⎪⎭⎫ ⎝⎛-⋅-kT x x kT which yields2212/12/1kTx kT x x =⇒= The maximum value occurs at2kTE E c +=(b)()()⎥⎦⎤⎢⎣⎡---∝-kT E E E E f g F F exp 1υυ()⎥⎦⎤⎢⎣⎡---∝kT E E E E υυexp()⎥⎦⎤⎢⎣⎡--⨯kT E E F υexp Let x E E =-υThen ()⎪⎭⎫ ⎝⎛-∝-kT x x f g F exp 1υTo find the maximum value()[]0exp 1=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛-∝-kT x x dx d dx f g d F υ Same as part (a). Maximum occurs at2kTx =or2kTE E -=υ_______________________________________ 4.7()()()()⎥⎦⎤⎢⎣⎡---⎥⎦⎤⎢⎣⎡---=kT E E E E kT E E E E E n E n c c c c 221121exp expwherekT E E c 41+= and 22kTE E c += Then()()()⎥⎦⎤⎢⎣⎡--=kT E E kT kTE n E n 2121exp 24()5.3exp 22214exp 22-=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛--=or()()0854.021=E n E n_______________________________________ 4.8Plot_______________________________________ 4.9Plot_______________________________________ 4.10⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E Silicon: o p m m 56.0*=, o n m m 08.1*=0128.0-=-midgap Fi E E eV Germanium: o pm m 37.0*=,o n m m 55.0*=0077.0-=-midgap Fi E E eV Gallium Arsenide: o p m m 48.0*=,o n m m 067.0*= 0382.0+=-midgap Fi E E eV _______________________________________ 4.11 ()⎪⎪⎭⎫⎝⎛=-c midgap Fi N N kT E E υln 21()()kT kT 4952.0108.21004.1ln 211919-=⎪⎪⎭⎫ ⎝⎛⨯⨯=T (K) kT (eV)(midgap Fi E E -)(eV) 200 400 600 01727.0 03453.0 0518.0 0086.0- 0171.0- 0257.0-_______________________________________ 4.12(a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E ()⎪⎭⎫⎝⎛=21.170.0ln 0259.04363.10-⇒meV(b) ()⎪⎭⎫⎝⎛=-080.075.0ln 0259.043midgap Fi E E47.43+⇒meV_______________________________________ 4.13Let ()==K E g c constant Then()()dE E fE g n FE co c⎰∞=dE kT E E Kc E F⎰∞⎪⎪⎭⎫⎝⎛-+=exp 11()dE kT E E K cE F ⎰∞⎥⎦⎤⎢⎣⎡--≅exp Let kT E E c-=η so that ηd kT dE ⋅=We can write ()()c F c F E E E E E E -+-=-so that()()()η-⋅⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--e x p e x p e x p kT E E kT E E F c F The integral can then be written as()()ηηd kT E E kT K n F c o ⎰∞-⎥⎦⎤⎢⎣⎡--⋅⋅=0exp exp which becomes()⎥⎦⎤⎢⎣⎡--⋅⋅=kT E E kT K n F c o exp _______________________________________ 4.14Let ()()c c E E C E g -=1 for c E E ≥ Then()()dE E fE g n FE co c⎰∞=()dE kT E E E E C c E Fc ⎰∞⎪⎪⎭⎫⎝⎛-+-=exp 11()()dE kT E E E E C F E C c⎥⎦⎤⎢⎣⎡---≅⎰∞exp 1LetkTE E c-=η so that ηd kT dE ⋅= We can write()()F c c F E E E E E E -+-=-Then()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1()()dE kT E E E E c E c c⎥⎦⎤⎢⎣⎡---⨯⎰∞exp or()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1 ()()()[]()ηηηd kT kT -⨯⎰∞exp 0We find that()()()11exp exp 0+=---=-∞∞⎰ηηηηηdSo()()⎥⎦⎤⎢⎣⎡--=kT E E kT C n F c o exp 21 _______________________________________ 4.15We have ⎪⎪⎭⎫⎝⎛=∈*1m m a r o r o For germanium, 16=∈r , o m m 55.0*= Then()()()53.02955.01161=⎪⎭⎫⎝⎛=o a roroA r 4.151=The ionization energy can be written as ()6.132*⎪⎪⎭⎫⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E eV ()()029.06.131655.02=⇒=E eV_______________________________________ 4.16We have ⎪⎪⎭⎫⎝⎛=∈*1m m a r o r o For gallium arsenide, 1.13=∈r ,o m m 067.0*= Then()()oA r 10453.0067.011.131=⎪⎭⎫⎝⎛=The ionization energy is()()()6.131.13067.06.1322*=⎪⎪⎭⎫ ⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E or0053.0=E eV_______________________________________ 4.17(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1519107108.2ln 0259.02148.0=eV (b) ()F c g F E E E E E --=-υ90518.02148.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp()⎥⎦⎤⎢⎣⎡-⨯=0259.090518.0exp 1004.119 31090.6⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1107ln 0259.0338.0=eV_______________________________________ 4.18(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.0162.0=eV(b)()υE E E E E F g F c --=- 958.0162.012.1=-=eV(c) ()⎪⎭⎫⎝⎛-⨯=0259.0958.0exp 108.219o n31041.2⨯=cm 3-(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1016105.1102ln 0259.0365.0=eV_______________________________________ 4.19(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=519102108.2ln 0259.08436.0=eV ()F c g F E E E E E --=-υ 8436.012.1-= 2764.0=-υE E F eV (b)()⎪⎭⎫⎝⎛-⨯=0259.027637.0exp 1004.119o p1410414.2⨯=cm 3-(c) p-type_______________________________________ 4.20(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.028.0exp 300375107.42/317o n 141015.1⨯=cm 3-()28.042.1-=--=-F c g F E E E E E υ 14.1=eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.014.1exp 3003751072/318o p 31099.4⨯=cm 3-(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=-14171015.1107.4ln 0259.0F c E E2154.0=eV()2154.042.1-=--=-F c g F E E E E E υ 2046.1=eV()⎥⎦⎤⎢⎣⎡-⨯=0259.02046.1exp 10718o p21042.4-⨯=cm 3-_______________________________________ 4.21(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.028.0exp 300375108.22/319o n 151086.6⨯= cm 3-()28.012.1-=--=-F c g F E E E E E υ 840.0=eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.0840.0exp 3003751004.12/319o p 71084.7⨯=cm 3-(b) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=151910862.6108.2ln 0259.02153.0=eV9047.02153.012.1=-=-υE E F eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0904668.0exp 1004.119o p 31004.7⨯=cm 3-_______________________________________ 4.22 (a) p-type(b) 28.0412.14===-g F E E E υeV()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp ()⎥⎦⎤⎢⎣⎡-⨯=0259.028.0exp 1004.119141010.2⨯=cm 3- ()υE E E E E F g F c --=- 84.028.012.1=-=eV()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.084.0exp 108.219 51030.2⨯=cm 3-_______________________________________ 4.23(a) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp ()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 105.110131033.7⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 105.11061007.3⨯=cm 3-(b) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi F i o exp()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 108.16 91080.8⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 108.16 21068.3⨯=cm 3-_______________________________________ 4.24(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=151********.1ln 0259.01979.0=eV(b)()υE E E E E F g F c --=- 92212.019788.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡-⨯=0259.092212.0exp 108.219o n31066.9⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1105ln 0259.03294.0=eV _______________________________________ 4.25()034533.03004000259.0=⎪⎭⎫⎝⎛=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3-()2/319300400108.2⎪⎭⎫⎝⎛⨯=c N19103109.4⨯=cm 3-()()1919210601.1103109.4⨯⨯=i n⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 24106702.5⨯=1210381.2⨯=⇒i n cm 3- (a)⎪⎪⎭⎫ ⎝⎛=-oF pN kT E E υυln ()⎪⎪⎭⎫⎝⎛⨯⨯=151910510601.1ln 034533.02787.0=eV (b) 84127.027873.012.1=-=-F c E E eV(c)()⎥⎦⎤⎢⎣⎡-⨯=034533.084127.0exp 103109.419o n910134.1⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=121510381.2105ln 034533.02642.0=eV _______________________________________ 4.26(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 10718o p141050.4⨯=cm 3-17.125.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.017.1exp 107.417o n21013.1-⨯=cm 3- (b) 034533.0=kT eV ()2/318300400107⎪⎭⎫ ⎝⎛⨯=υN1910078.1⨯=cm 3- ()2/317300400107.4⎪⎭⎫⎝⎛⨯=c N1710236.7⨯=cm 3- ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191050.410078.1ln 034533.03482.0=eV072.13482.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.007177.1exp 10236.717o n 41040.2⨯=cm 3-_____________________________________ 4.27(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 1004.119o p141068.6⨯=cm 3-870.025.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0870.0exp 108.219o n41023.7⨯=o n cm 3- (b)034533.0=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3- ()2/319300400108.2⎪⎭⎫ ⎝⎛⨯=c N1910311.4⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191068.610601.1ln 034533.03482.0=eV7718.03482.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.077175.0exp 10311.419o n91049.8⨯=cm 3-_______________________________________ 4.28(a) ()F c o F N n ηπ2/12=For 2kT E E c F +=,5.02==-=kTkT kT E E c F F η Then ()0.12/1≅F F η()()0.1108.2219⨯=πo n191016.3⨯=cm 3-(b) ()F c o F N n ηπ2/12=()()0.1107.4217⨯=π171030.5⨯=cm 3-_______________________________________ 4.29()F o F N p ηπυ'=2/12()()FF ηπ'⨯=⨯2/119191004.12105So ()26.42/1='FF η We find kTE E FF-=≅'υη0.3()()0777.00259.00.3==-F E E υeV_______________________________________ 4.30(a) 44==-=kTkTkT E E c F F ηThen ()0.62/1≅F F η ()F c o F N n ηπ2/12=()()0.6108.2219⨯=π201090.1⨯=cm 3-(b) ()()0.6107.4217⨯=πo n181018.3⨯=cm 3-_______________________________________ 4.31For the electron concentration ()()()E f E g E n F c =The Boltzmann approximation applies, so ()()c nE E hm E n -=32/3*24π()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or()()()⎥⎦⎤⎢⎣⎡--=kT E E h m E n F c nexp 2432/3*π()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTc c exp DefinekTE E x c-= Then()()()x x K x n E n -=→exp To find maximum ()()x n E n →, set()()x x K dx x dn -⎢⎣⎡==-exp 2102/1 +()()⎥⎦⎤--x x exp 12/1or()⎥⎦⎤⎢⎣⎡--=-x x Kx 21exp 02/1which yieldskT E E kT E E x c c 2121+=⇒-==For the hole concentration ()()()[]E f E g E p F -=1υUsing the Boltzmann approximation ()()E E h m E p p-=υπ32/3*24()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or()()()⎥⎦⎤⎢⎣⎡--=kT E E h mE pF pυπexp 2432/3*()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTυυexp DefinekTEE x -='υThen()()x x K x p '-''='exp To find maximum value of ()()x p E p '→,set()0=''x d x dp Using the results from above,we find the maximum atkT E E 21-=υ_______________________________________4.32 (a) Silicon: We have()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp We can write()()F d d c F c E E E E E E -+-=- For045.0=-d c E E eV andkT E E F d 3=-eV we can write()⎥⎦⎤⎢⎣⎡--⨯=30259.0045.0exp 108.219o n()()737.4exp 108.219-⨯= or171045.2⨯=o n cm 3- We also have()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp Again, we can write()()υυE E E E E E a a F F -+-=- ForkT E E a F 3=- and045.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=0259.0045.03exp 1004.119o p ()()737.4exp 1004.119-⨯= or161012.9⨯=o p cm 3- (b) GaAs: assume 0058.0=-d c E E eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00058.0exp 107.417o n ()()224.3exp 107.417-⨯= or161087.1⨯=o n cm 3-Assume 0345.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00345.0exp 10718o p ()()332.4exp 10718-⨯=or161020.9⨯=o p cm 3-_______________________________________ 4.33Plot_______________________________________ 4.34(a)151510310154⨯=-⨯=o p cm 3- ()415210105.7103105.1⨯=⨯⨯=o n cm 3-(b)16103⨯==d o N n cm 3-()316210105.7103105.1⨯=⨯⨯=o p cm 3-(c)10105.1⨯===i o o n p n cm 3-(d) ()()3191923003751004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030012.1exp1110334.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()8152111034.110410334.7⨯=⨯⨯=on cm 3-(e) ()()3191923004501004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030012.1exp1310722.1⨯=⇒i n cm 3-()2132141410722.1210210⨯+⎪⎪⎭⎫ ⎝⎛+=o n1410029.1⨯=cm 3-()12142131088.210029.110722.1⨯=⨯⨯=o p cm 3-_______________________________________ 4.35(a)151510104-⨯=-=d a o N N p15103⨯=cm 3-()3152621008.1103108.1-⨯=⨯⨯==o i o p n n cm 3-(b)16103⨯==d o N n cm 3-()416261008.1103108.1-⨯=⨯⨯=o p cm 3-(c)6108.1⨯===i o o n p n cm 3-(d) ()()318172300375100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030042.1exp810580.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()215281044.110410580.7⨯=⨯⨯=on cm 3-(e) ()()318172300450100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030042.1exp1010853.3⨯=⇒i n cm 3- 1410==d o N n cm 3-()7142101048.11010853.3⨯=⨯=op cm 3-_______________________________________ 4.36 (a) Ge: 13104.2⨯=i n cm 3-(i)2222i dd o n N N n +⎪⎪⎭⎫ ⎝⎛+=()21321515104.221022102⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=or15102⨯=≅d o N n cm 3-()152132102104.2⨯⨯==o i o n n p111088.2⨯= cm 3- (ii)151610710⨯-=-≅d a o N N p 15103⨯=cm 3- ()152132103104.2⨯⨯==o i o p n n111092.1⨯=cm 3-(b) GaAs: 6108.1⨯=i n cm 3- (i)15102⨯=≅d o N n cm()315261062.1102108.1-⨯=⨯⨯=op cm 3-(ii)15103⨯=-≅d a o N N p cm 3-()315261008.1103108.1-⨯=⨯⨯=on cm 3-(c) The result implies that there is only one minority carrier in a volume of 310cm 3. _______________________________________ 4.37(a) For the donor level⎪⎪⎭⎫ ⎝⎛-+=kT E E N n F d d d exp 2111⎪⎭⎫ ⎝⎛+=0259.020.0exp 2111or41085.8-⨯=dd N n(b) We have()⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F F exp 11Now()()F c c F E E E E E E -+-=- or245.0+=-kT E E FThen()⎪⎭⎫ ⎝⎛++=0259.0245.01exp 11E f For()51087.2-⨯=E f F_______________________________________ 4.38 (a) ⇒>d a N N p-type (b) Silicon:1313101105.2⨯-⨯=-=d a o N N p or13105.1⨯=o p cm 3- Then()7132102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- Germanium:2222i da d a o n N N N N p +⎪⎪⎭⎫ ⎝⎛-+-=()21321313104.22105.12105.1⨯+⎪⎪⎭⎫⎝⎛⨯+⎪⎪⎭⎫ ⎝⎛⨯=or131026.3⨯=o p cm 3- Then()131321321076.110264.3104.2⨯=⨯⨯==o i o p n n cm 3-Gallium Arsenide:13105.1⨯=-=d a o N N p cm 3- and()216.0105.1108.113262=⨯⨯==o i o p n n cm 3- _______________________________________ 4.39 (a) ⇒>a d N N n-type(b)1515102.1102⨯-⨯=-≅a d o N N n14108⨯=cm 3-()51421021081.2108105.1⨯=⨯⨯==o i o n n p cm 3-(c)()d a ao N N N p -+'≅ 151515102102.1104⨯-⨯+'=⨯aN 15108.4⨯='⇒aN cm 3-()41521010625.5104105.1⨯=⨯⨯=on cm 3-_______________________________________ 4.40()155210210125.1102105.1⨯=⨯⨯==o i o p n n cm 3- ⇒>o o p n n-type_______________________________________ 4.41()()318192300250100.61004.1⎪⎭⎫⎝⎛⨯⨯=i n()()⎥⎦⎤⎢⎣⎡-⨯3002500259.066.0exp24108936.1⨯=1210376.1⨯=⇒i n cm 3- 2222414i o o i o i o n n n n p n n =⇒==i o n n 21=⇒So 111088.6⨯=o n cm 3-,Then 121075.2⨯=o p cm 3-2222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 212210752.2⎪⎪⎭⎫ ⎝⎛-⨯a N242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=a N()21224210752.2105735.7⎪⎪⎭⎫ ⎝⎛+⨯-⨯aa N N242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=aN so that 1210064.2⨯=a N cm 3-_______________________________________ 4.42Plot_______________________________________ 4.43Plot_______________________________________ 4.44Plot_______________________________________ 4.452222i ad a d o n N N N N n +⎪⎪⎭⎫ ⎝⎛-+-= 2102.1102101.1141414⨯-⨯=⨯2214142102.1102i n +⎪⎪⎭⎫⎝⎛⨯-⨯+()()221321314104104101.1i n +⨯=⨯-⨯22727106.1109.4i n +⨯=⨯ so 131074.5⨯=i n cm 3-1314272103101.1103.3⨯=⨯⨯==o i o n n p cm 3- _______________________________________ 4.46 (a) ⇒>d a N N p-typeMajority carriers are holes1616105.1103⨯-⨯=-=d a o N N p16105.1⨯=cm 3-Minority carriers are electrons()4162102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- (b) Boron atoms must be addedd a ao N N N p -+'=161616105.1103105⨯-⨯+'=⨯aN So 16105.3⨯='aN cm 3-()316210105.4105105.1⨯=⨯⨯=on cm 3-_______________________________________ 4.47 (a) ⇒<<i o n p n-type (b) oi o o i o p n n n n p 22=⇒=on ()16421010125.1102105.1⨯=⨯⨯=cm 3-⇒electrons are majority carriers4102⨯=o p cm 3-⇒holes are minority carriers (c) a d o N N n -= 151610710125.1⨯-=⨯d N so 1610825.1⨯=d N cm 3-_______________________________________ 4.48⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln For Germanium T (K) kT (eV)i n (cm 3-) 200400 60001727.0 03453.0 0518.0101016.2⨯ 141060.8⨯ 161082.3⨯2222i a a o n N N p +⎪⎪⎭⎫⎝⎛+=and 1510=a N cm 3- T (K) op (cm 3-)()F Fi E E -(eV)200400 60015100.1⨯151049.1⨯ 161087.3⨯1855.0 01898.0 000674.0_______________________________________ 4.49(a) ⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=d N 19108.2ln 0259.0 For 1410cm 3-, 3249.0=-F c E E eV 1510cm 3-, 2652.0=-F c E E eV 1610cm 3-, 2056.0=-F c E E eV 1710cm 3-, 1459.0=-F c E E eV(b) ⎪⎪⎭⎫⎝⎛=-i d Fi F n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=10105.1ln 0259.0d N For 1410cm 3-, 2280.0=-Fi F E E eV 1510cm 3-, 2877.0=-Fi F E E eV 1610cm 3-, 3473.0=-Fi F E E eV 1710cm 3-, 4070.0=-Fi F E E eV _______________________________________ 4.50 (a)2222i d d o n N N n +⎪⎪⎭⎫⎝⎛+= 151005.105.1⨯==d o N n cm 3- ()21515105.01005.1⨯-⨯()2215105.0i n +⨯=so 2821025.5⨯=i nNow()()3191923001004.1108.2⎪⎭⎫ ⎝⎛⨯⨯=T n i()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382830010912.21025.5⎪⎭⎫ ⎝⎛⨯=⨯T⎥⎦⎤⎢⎣⎡-⨯T 973.12972exp By trial and error, 5.536=T K (b) At 300=T K,⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=-151910108.2ln 0259.0F c E E2652.0=eV At 5.536=T K,()046318.03005.5360259.0=⎪⎭⎫⎝⎛=kT eV()2/3193005.536108.2⎪⎭⎫⎝⎛⨯=c N1910696.6⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=-15191005.110696.6ln 046318.0F c E E5124.0=eV then ()2472.0=-∆F c E E eV (c) Closer to the intrinsic energy level._______________________________________ 4.51⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln At 200=T K, 017267.0=kT eV 400=T K, 034533.0=kT eV 600=T K, 0518.0=kT eVAt 200=T K,()()3191923002001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯017267.012.1exp410638.7⨯=⇒i n cm 3- At 400=T K,()()3191923004001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 1210381.2⨯=⇒i n cm 3- At 600=T K,()()3191923006001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯0518.012.1exp1410740.9⨯=⇒i n cm 3- At 200=T K and 400=T K, 15103⨯==a o N p cm 3- At 600=T K,2222i a a o n N N p +⎪⎪⎭⎫⎝⎛+=()2142151510740.921032103⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=1510288.3⨯=cm 3-Then, 200=T K, 4212.0=-F Fi E E eV 400=T K, 2465.0=-F Fi E E eV600=T K, 0630.0=-F Fi E E eV_______________________________________ 4.52(a)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-6108.1ln 0259.0ln a i a F Fi N n N kT E EFor 1410=a N cm 3-,4619.0=-F Fi E E eV1510=a N cm 3-,5215.0=-F Fi E E eV1610=a N cm 3-,5811.0=-F Fi E E eV1710=a N cm 3-,6408.0=-F Fi E E eV (b)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-a a F N N N kT E E 18100.7ln 0259.0ln υυ For 1410=a N cm 3-,2889.0=-υE E F eV1510=a N cm 3-,2293.0=-υE E F eV1610=a N cm 3-,1697.0=-υE E F eV1710=a N cm 3-,1100.0=-υE E F eV_______________________________________ 4.53(a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E ()()10ln 0259.043= or0447.0+=-midgap Fi E E eV(b) Impurity atoms to be added so 45.0=-F midgap E E eV (i) p-type, so add acceptor atoms (ii)4947.045.00447.0=+=-F Fi E E eV Then⎪⎪⎭⎫⎝⎛-=kT E E n p F Fi i o exp()⎪⎭⎫⎝⎛=0259.04947.0exp 105or131097.1⨯==a o N p cm 3-_______________________________________4.54()⎥⎦⎤⎢⎣⎡--=-=kT E E N N N n F c c a d o exp so()⎪⎭⎫⎝⎛-⨯+⨯=0259.0215.0exp 108.21051915d N15151095.6105⨯+⨯=or16102.1⨯=d N cm 3-_______________________________________ 4.55 (a) Silicon(i)⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()2188.0106108.2ln 0259.01519=⎪⎪⎭⎫⎝⎛⨯⨯=eV(ii)1929.00259.02188.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡--=kT E E N N F c c d exp()⎥⎦⎤⎢⎣⎡-⨯=0259.01929.0exp 108.2191610631.1⨯=d N cm 3-15106⨯+'=dN 1610031.1⨯='⇒dN cm 3- Additionaldonor atoms (b) GaAs(i)()⎪⎪⎭⎫⎝⎛⨯=-151710107.4ln 0259.0F c E E15936.0=eV(ii)13346.00259.015936.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.013346.0exp 107.417d N1510718.2⨯=cm 3-1510+'=dN 1510718.1⨯='⇒dN cm 3- Additionaldonor atoms _______________________________________4.56 (a) ⎪⎪⎭⎫ ⎝⎛=-a F Fi N N kT E E υln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.01620.0=eV(b) ⎪⎪⎭⎫⎝⎛=-d c Fi F N N kT E E ln ()1876.0102108.2ln 0259.01619=⎪⎪⎭⎫ ⎝⎛⨯⨯=eV (c) For part (a); 16102⨯=o p cm 3-()162102102105.1⨯⨯==o i o p n n410125.1⨯=cm 3-For part (b): 16102⨯=o n cm 3-()162102102105.1⨯⨯==o i o n n p410125.1⨯=cm 3-_______________________________________4.57⎥⎦⎤⎢⎣⎡-=kT E E n n Fi F i o exp ()⎥⎦⎤⎢⎣⎡⨯=0259.055.0exp 108.1615100.3⨯=cm 3-Add additional acceptor impuritiesa d o N N n -= a N -⨯=⨯151510710315104⨯=⇒a N cm 3-_______________________________________ 4.58(a) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln ()3161.0105.1103ln 0259.01015=⎪⎪⎭⎫⎝⎛⨯⨯=eV (b) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln ()3758.0105.1103ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV(c) Fi F E E =(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln ()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=111510334.7104ln 3003750259.0 2786.0=eV(e) ⎪⎪⎭⎫ ⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=131410722.110029.1ln 3004500259.0 06945.0=eV _______________________________________ 4.59 (a) ⎪⎪⎭⎫ ⎝⎛=-o F p N kT E E υυln()2009.0103100.7ln 0259.01518=⎪⎪⎭⎫ ⎝⎛⨯⨯=eV(b) ()⎪⎪⎭⎫ ⎝⎛⨯⨯=--4181008.1100.7ln 0259.0υE E F 360.1=eV(c) ()⎪⎪⎭⎫⎝⎛⨯⨯=-618108.1100.7ln 0259.0υE E F7508.0=eV(d) ()⎪⎭⎫⎝⎛=-3003750259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯152/318104300375100.7ln 2526.0=eV(e) ()⎪⎭⎫⎝⎛=-3004500259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯72/3181048.1300450100.7ln 068.1=eV_______________________________________ 4.60n-type⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()3504.0105.110125.1ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV ______________________________________ 4.612222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 21051008.51515⨯=⨯22152105i n +⎪⎪⎭⎫ ⎝⎛⨯+()21515105.21008.5⨯-⨯()2215105.2i n +⨯=230301025.6106564.6i n +⨯=⨯29210064.4⨯=⇒i n⎥⎦⎤⎢⎣⎡-=kT E N N n g c i exp 2υ()030217.03003500259.0=⎪⎭⎫⎝⎛=kT eV()1921910633.1300350102.1⨯=⎪⎭⎫ ⎝⎛⨯=c N cm 3-()192191045.2300350108.1⨯=⎪⎭⎫ ⎝⎛⨯=υN cm 3- Now()()1919291045.210633.110064.4⨯⨯=⨯⎥⎦⎤⎢⎣⎡-⨯030217.0exp g ESo()()()⎥⎦⎤⎢⎣⎡⨯⨯⨯=29191910064.41045.210633.1ln 030217.0g E 6257.0=⇒g E eV_______________________________________ 4.62 (a) Replace Ga atoms ⇒Silicon acts as adonor()()1415105.310705.0⨯=⨯=d N cm 3-Replace As atoms ⇒Silicon acts as anacceptor()()15151065.610795.0⨯=⨯=a N cm 3-(b) ⇒>d a N N p-type(c) 1415105.31065.6⨯-⨯=-=d a o N N p 15103.6⨯=cm 3-()4152621014.5103.6108.1-⨯=⨯⨯==o i o p n n cm 3- (d)⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()5692.0108.1103.6ln 0259.0615=⎪⎪⎭⎫⎝⎛⨯⨯=eV_______________________________________。

半导体物理与器件第四版课后习题问题详解4

Chapter 44.1⎪⎪⎭⎫ ⎝⎛-=kTE N N n gc i exp 2υ ⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=kT E T N N g O cO exp 3003υwhere cO N and O N υ are the values at300 K.(a) SiliconT (K)kT (eV) i n (cm 3-) 200 400 60001727.0 03453.0 0518.041068.7⨯ 121038.2⨯ 141074.9⨯(b) Germanium (c) GaAs T (K)i n (cm 3-) i n (cm 3-) 200 400 600101016.2⨯ 141060.8⨯ 161082.3⨯38.1 91028.3⨯ 121072.5⨯_______________________________________ 4.2Plot_______________________________________ 4.3(a) ⎪⎪⎭⎫⎝⎛-=kT E N N n g c i exp 2υ ()()()319192113001004.1108.2105⎪⎭⎫⎝⎛⨯⨯=⨯T()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382330010912.2105.2⎪⎭⎫ ⎝⎛⨯=⨯T()()()()⎥⎦⎤⎢⎣⎡-⨯T 0259.030012.1expBy trial and error, 5.367≅T K(b)()252122105.2105⨯=⨯=i n()()()()()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=T T 0259.030012.1exp 30010912.2338By trial and error, 5.417≅T K_______________________________________ 4.4At 200=T K, ()⎪⎭⎫⎝⎛=3002000259.0kT017267.0=eVAt 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV ()()()()17222102210025.31040.11070.7200400⨯=⨯⨯=ii nn⎥⎦⎤⎢⎣⎡-⎥⎦⎤⎢⎣⎡-⨯⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=017267.0exp 034533.0exp 30020030040033g g E E⎥⎦⎤⎢⎣⎡-=034533.0017267.0exp 8g g E E()[]9578.289139.57exp 810025.317-=⨯g Eor()1714.38810025.3ln 9561.2817=⎪⎪⎭⎫⎝⎛⨯=g E or 318.1=g E eVNow()32103004001070.7⎪⎭⎫⎝⎛=⨯o co N N υ⎪⎭⎫⎝⎛-⨯034533.0318.1exp()()172110658.2370.210929.5-⨯=⨯o co N N υso 371041.9⨯=o co N N υcm 6- _______________________________________4.5()()⎪⎭⎫ ⎝⎛-=⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛-=kT kT kT A n B n i i 20.0exp 90.0exp 10.1exp For 200=T K, 017267.0=kT eVFor 300=T K, 0259.0=kT eVFor 400=T K, 034533.0=kT eV(a) For 200=T K,()()610325.9017267.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (b) For 300=T K, ()()41043.40259.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (c) For 400=T K, ()()31005.3034533.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i_______________________________________4.6 (a)()⎥⎦⎤⎢⎣⎡---∝kT E E E E f g F c F c exp()⎥⎦⎤⎢⎣⎡---∝kT E E E E c c exp ()⎥⎦⎤⎢⎣⎡--⨯kT E E F c exp Let x E E c =- Then ⎪⎭⎫ ⎝⎛-∝kT x x f g F c exp To find the maximum value: ()⎪⎭⎫ ⎝⎛-∝-kT x x dx f g d F c exp 212/1 0exp 12/1=⎪⎭⎫ ⎝⎛-⋅-kT x x kT which yields 2212/12/1kTx kT x x =⇒= The maximum value occurs at2kTE E c += (b) ()()⎥⎦⎤⎢⎣⎡---∝-kT E E E E f g F F exp 1υυ ()⎥⎦⎤⎢⎣⎡---∝kT E E E E υυexp ()⎥⎦⎤⎢⎣⎡--⨯kT E E F υexp Let x E E =-υ Then ()⎪⎭⎫ ⎝⎛-∝-kT x x f g F exp 1υ To find the maximum value()[]0exp 1=⎥⎦⎤⎢⎣⎡⎪⎭⎫⎝⎛-∝-kT x x dx d dx f g d F υ Same as part (a). Maximum occurs at2kTx =or2kTE E -=υ_______________________________________ 4.7()()()()⎥⎦⎤⎢⎣⎡---⎥⎦⎤⎢⎣⎡---=kT E E E E kT E E E E E n E n c c c c 221121exp exp wherekT E E c 41+= and 22kTE E c += Then()()()⎥⎦⎤⎢⎣⎡--=kT E E kT kTE n E n 2121exp 24()5.3exp 22214exp 22-=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛--=or()()0854.021=E n E n_______________________________________ 4.8Plot_______________________________________ 4.9Plot_______________________________________4.10⎪⎪⎭⎫ ⎝⎛=-**ln 43n pmidgap Fi m m kT E ESilicon: o p m m 56.0*=, o n m m 08.1*=0128.0-=-midgap Fi E E eV Germanium: o p m m 37.0*=,o n m m 55.0*=0077.0-=-midgap Fi E E eV Gallium Arsenide: o p m m 48.0*=,o n m m 067.0*= 0382.0+=-midgap Fi E E eV_______________________________________4.11()⎪⎪⎭⎫ ⎝⎛=-c midgap Fi N N kT E E υln 21()()kT kT 4952.0108.21004.1ln 211919-=⎪⎪⎭⎫ ⎝⎛⨯⨯=T (K) kT (eV)(midgap Fi E E -)(eV )200 400 600 01727.0 03453.0 0518.0 0086.0- 0171.0- 0257.0-_______________________________________4.12(a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n pmidgap Fi m m kT E E()⎪⎭⎫⎝⎛=21.170.0ln 0259.04363.10-⇒meV (b) ()⎪⎭⎫⎝⎛=-080.075.0ln 0259.043midgap Fi E E47.43+⇒meV_______________________________________4.13Let ()==K E g c constant Then()()dE E fE g n FE co c⎰∞=dE kT E E Kc E F⎰∞⎪⎪⎭⎫⎝⎛-+=exp 11()dE kT E E K cE F ⎰∞⎥⎦⎤⎢⎣⎡--≅exp LetkTE E c-=η so that ηd kT dE ⋅= We can write()()c F c F E E E E E E -+-=- so that()()()η-⋅⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--exp exp exp kT E E kT E E F c F The integral can then be written as()()ηηd kT E E kT K n F c o ⎰∞-⎥⎦⎤⎢⎣⎡--⋅⋅=0exp exp which becomes()⎥⎦⎤⎢⎣⎡--⋅⋅=kT E E kT K n F c o exp _______________________________________4.14Let ()()c c E E C E g -=1 for c E E ≥ Then()()dE E fE g n FE co c⎰∞=()dE kT E E E E C c E Fc ⎰∞⎪⎪⎭⎫⎝⎛-+-=exp 11()()dE kT E E E E C F E C c⎥⎦⎤⎢⎣⎡---≅⎰∞exp 1Let kTE E c-=η so that ηd kT dE ⋅= We can write()()F c c F E E E E E E -+-=-Then()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1()()dE kT E E E E c E c c⎥⎦⎤⎢⎣⎡---⨯⎰∞exp or()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1 ()()()[]()ηηηd kT kT -⨯⎰∞exp 0We find that()()()11exp exp 0+=---=-∞∞⎰ηηηηηdSo()()⎥⎦⎤⎢⎣⎡--=kT E E kT C n F c o exp 21 _______________________________________4.15We have ⎪⎪⎭⎫⎝⎛=∈*1m m a r o r o For germanium, 16=∈r , o m m 55.0*= Then()()()53.02955.01161=⎪⎭⎫⎝⎛=o a roroA r 4.151=The ionization energy can be written as()6.132*⎪⎪⎭⎫⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E eV ()()029.06.131655.02=⇒=E eV_______________________________________4.16We have ⎪⎪⎭⎫ ⎝⎛=∈*1m m a r o r o For gallium arsenide, 1.13=∈r , o m m 067.0*= Then ()()oA r 10453.0067.011.131=⎪⎭⎫ ⎝⎛=The ionization energy is()()()6.131.13067.06.1322*=⎪⎪⎭⎫ ⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E or0053.0=E eV_______________________________________4.17(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1519107108.2ln 0259.02148.0=eV (b) ()F c g F E E E E E --=-υ90518.02148.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp()⎥⎦⎤⎢⎣⎡-⨯=0259.090518.0exp 1004.11931090.6⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1107ln 0259.0338.0=eV_______________________________________4.18(a)⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.0162.0=eV (b) ()υE E E E E F g F c --=-958.0162.012.1=-=eV(c)()⎪⎭⎫⎝⎛-⨯=0259.0958.0exp 108.219o n31041.2⨯=cm 3-(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1016105.1102ln 0259.0365.0=eV_______________________________________4.19(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=519102108.2ln 0259.08436.0=eV ()F c g F E E E E E --=-υ 8436.012.1-= 2764.0=-υE E F eV (b)()⎪⎭⎫⎝⎛-⨯=0259.027637.0exp 1004.119o p1410414.2⨯=cm 3- (c) p-type_______________________________________4.20(a)()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.028.0exp 300375107.42/317o n 141015.1⨯=cm 3-()28.042.1-=--=-F c g F E E E E E υ 14.1=eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.014.1exp 3003751072/318o p 31099.4⨯=cm 3- (b) ()⎪⎪⎭⎫⎝⎛⨯⨯=-14171015.1107.4ln 0259.0F c E E2154.0=eV()2154.042.1-=--=-F c g F E E E E E υ 2046.1=eV()⎥⎦⎤⎢⎣⎡-⨯=0259.02046.1exp 10718o p 21042.4-⨯=cm 3-_______________________________________4.21(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.028.0exp 300375108.22/319o n 151086.6⨯= cm 3-()28.012.1-=--=-F c g F E E E E E υ 840.0=eV ()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.0840.0exp 3003751004.12/319o p 71084.7⨯=cm 3-(b) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=151910862.6108.2ln 0259.02153.0=eV9047.02153.012.1=-=-υE E F eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0904668.0exp 1004.119o p 31004.7⨯=cm 3-_______________________________________4.22(a) p-type(b) 28.0412.14===-g F E E E υeV()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp ()⎥⎦⎤⎢⎣⎡-⨯=0259.028.0exp 1004.119141010.2⨯=cm 3- ()υE E E E E F g F c --=- 84.028.012.1=-=eV()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.084.0exp 108.219 51030.2⨯=cm 3-_______________________________________4.23(a) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 105.110 131033.7⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 105.11061007.3⨯=cm 3-(b) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp ()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 108.16 91080.8⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 108.16 21068.3⨯=cm 3-_______________________________________4.24(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=151********.1ln 0259.01979.0=eV (b) ()υE E E E E F g F c --=- 92212.019788.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡-⨯=0259.092212.0exp 108.219o n31066.9⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1105ln 0259.03294.0=eV _______________________________________4.25()034533.03004000259.0=⎪⎭⎫⎝⎛=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3-()2/319300400108.2⎪⎭⎫⎝⎛⨯=c N19103109.4⨯=cm 3-()()1919210601.1103109.4⨯⨯=i n⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp24106702.5⨯= 1210381.2⨯=⇒i n cm 3- (a)⎪⎪⎭⎫ ⎝⎛=-oF pN kT E E υυln ()⎪⎪⎭⎫⎝⎛⨯⨯=151910510601.1ln 034533.02787.0=eV(b) 84127.027873.012.1=-=-F c E E eV(c)()⎥⎦⎤⎢⎣⎡-⨯=034533.084127.0exp 103109.419o n910134.1⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=121510381.2105ln 034533.02642.0=eV _______________________________________4.26(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 10718o p141050.4⨯=cm 3-17.125.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.017.1exp 107.417o n21013.1-⨯=cm 3-(b) 034533.0=kT eV()2/318300400107⎪⎭⎫⎝⎛⨯=υN1910078.1⨯=cm 3- ()2/317300400107.4⎪⎭⎫ ⎝⎛⨯=c N1710236.7⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191050.410078.1ln 034533.03482.0=eV072.13482.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.007177.1exp 10236.717o n 41040.2⨯=cm 3-_____________________________________4.27(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 1004.119o p141068.6⨯=cm 3-870.025.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0870.0exp 108.219o n41023.7⨯=o n cm 3- (b)034533.0=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3- ()2/319300400108.2⎪⎭⎫⎝⎛⨯=c N1910311.4⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191068.610601.1ln 034533.03482.0=eV7718.03482.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.077175.0exp 10311.419o n 91049.8⨯=cm 3-_______________________________________4.28(a) ()F c o F N n ηπ2/12=For 2kT E E c F +=,5.02==-=kTkT kT E E c F F η Then ()0.12/1≅F F η()()0.1108.2219⨯=πo n191016.3⨯=cm 3-(b) ()F c o F N n ηπ2/12=()()0.1107.4217⨯=π171030.5⨯=cm 3-_______________________________________4.29()Fo F N p ηπυ'=2/12()()FF ηπ'⨯=⨯2/119191004.12105So ()26.42/1='FF η We find kTE E FF-=≅'υη0.3 ()()0777.00259.00.3==-F E E υeV _______________________________________4.30(a) 44==-=kTkTkT E E c F F ηThen ()0.62/1≅F F η()F c o F N n ηπ2/12=()()0.6108.2219⨯=π201090.1⨯=cm 3-(b) ()()0.6107.4217⨯=πo n181018.3⨯=cm 3-_______________________________________4.31For the electron concentration ()()()E f E g E n F c = The Boltzmann approximation applies, so ()()c n E E hmE n -=32/3*24π()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or ()()()⎥⎦⎤⎢⎣⎡--=kT E E hm E n F c nexp 2432/3*π ()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTc c exp DefinekTE E x c-=Then ()()()x x K x n E n -=→exp To find maximum ()()x n E n →, set()()x x K dx x dn -⎢⎣⎡==-exp 2102/1+()()⎥⎦⎤--x x exp 12/1or()⎥⎦⎤⎢⎣⎡--=-x x Kx 21exp 02/1which yieldskT E E kT E E x c c 2121+=⇒-==For the hole concentration ()()()[]E f E g E p F -=1υUsing the Boltzmann approximation ()()E E hm E p p-=υπ32/3*24()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or()()()⎥⎦⎤⎢⎣⎡--=kT E E h m E p F pυπexp 2432/3* ()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTυυexp DefinekTEE x -='υThen ()()x x K x p '-''='exp To find maximum value of()()x p E p '→, set()0=''x d x dp Using the resultsfrom above,we find the maximum atkT E E 21-=υ_______________________________________4.32(a) Silicon: We have()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp We can write()()F d d c F c E E E E E E -+-=- For045.0=-d c E E eV andkT E E F d 3=-eVwe can write()⎥⎦⎤⎢⎣⎡--⨯=30259.0045.0exp 108.219o n()()737.4exp 108.219-⨯=or171045.2⨯=o n cm 3- We also have()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp Again, we can write()()υυE E E E E E a a F F -+-=- ForkT E E a F 3=- and045.0=-υE E a eVThen()⎥⎦⎤⎢⎣⎡--⨯=0259.0045.03exp 1004.119o p ()()737.4exp 1004.119-⨯=or161012.9⨯=o p cm 3- (b)GaAs: assume 0058.0=-d c E E eVThen()⎥⎦⎤⎢⎣⎡--⨯=30259.00058.0exp 107.417o n ()()224.3exp 107.417-⨯= or161087.1⨯=o n cm 3- Assume 0345.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00345.0exp 10718o p ()()332.4exp 10718-⨯= or161020.9⨯=o p cm 3-_______________________________________4.33Plot_______________________________________4.34(a)151510310154⨯=-⨯=o p cm 3- ()415210105.7103105.1⨯=⨯⨯=o n cm 3-(b)16103⨯==d o N n cm 3-()316210105.7103105.1⨯=⨯⨯=o p cm 3-(c)10105.1⨯===i o o n p n cm 3-(d) ()()3191923003751004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030012.1exp1110334.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()8152111034.110410334.7⨯=⨯⨯=on cm 3-(e) ()()3191923004501004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030012.1exp1310722.1⨯=⇒i n cm 3-()2132141410722.1210210⨯+⎪⎪⎭⎫ ⎝⎛+=o n1410029.1⨯=cm 3-()12142131088.210029.110722.1⨯=⨯⨯=op cm 3-_______________________________________4.35(a)151510104-⨯=-=d a o N N p 15103⨯=cm 3-()3152621008.1103108.1-⨯=⨯⨯==o i o p n n cm 3-(b)16103⨯==d o N n cm 3-()416261008.1103108.1-⨯=⨯⨯=o p cm 3-(c)6108.1⨯===i o o n p n cm 3-(d) ()()318172300375100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030042.1exp810580.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()215281044.110410580.7⨯=⨯⨯=o n cm 3-(e) ()()318172300450100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030042.1exp1010853.3⨯=⇒i n cm 3- 1410==d o N n cm 3-()7142101048.11010853.3⨯=⨯=op cm 3-_______________________________________4.36(a) Ge: 13104.2⨯=i n cm 3-(i)2222i d d o n N N n +⎪⎪⎭⎫⎝⎛+=()21321515104.221022102⨯+⎪⎪⎭⎫⎝⎛⨯+⨯=or15102⨯=≅d o N n cm 3- ()152132102104.2⨯⨯==o i o n n p111088.2⨯= cm 3-(ii)151610710⨯-=-≅d a o N N p 15103⨯=cm 3-()152132103104.2⨯⨯==o i o p n n111092.1⨯=cm 3-(b) GaAs: 6108.1⨯=i n cm 3- (i)15102⨯=≅d o N n cm()315261062.1102108.1-⨯=⨯⨯=op cm 3-(ii)15103⨯=-≅d a o N N p cm 3-()315261008.1103108.1-⨯=⨯⨯=on cm 3-(c) The result implies that there is only one minority carrier in a volume of 310cm 3._______________________________________4.37(a) For the donor level⎪⎪⎭⎫ ⎝⎛-+=kT E E N n F d d d exp 2111⎪⎭⎫ ⎝⎛+=0259.020.0exp 2111or41085.8-⨯=d d N n(b) We have ()⎪⎪⎭⎫ ⎝⎛-+=kTE E E f FF exp 11Now()()F c c F E E E E E E -+-=- or245.0+=-kT E E FThen ()⎪⎭⎫ ⎝⎛++=0259.0245.01exp 11E f For()51087.2-⨯=E f F_______________________________________4.38(a) ⇒>d a N N p-type(b) Silicon:1313101105.2⨯-⨯=-=d a o N N p or13105.1⨯=o p cm 3- Then()7132102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- Germanium:2222i da d a o n N N N N p +⎪⎪⎭⎫ ⎝⎛-+-=()21321313104.22105.12105.1⨯+⎪⎪⎭⎫⎝⎛⨯+⎪⎪⎭⎫ ⎝⎛⨯=or131026.3⨯=o p cm 3-Then()131321321076.110264.3104.2⨯=⨯⨯==o i o p n n cm 3-Gallium Arsenide:13105.1⨯=-=d a o N N p cm 3- and()216.0105.1108.113262=⨯⨯==o io p n n cm 3- _______________________________________4.39(a) ⇒>a d N N n-type(b)1515102.1102⨯-⨯=-≅a d o N N n14108⨯=cm 3-()51421021081.2108105.1⨯=⨯⨯==o i o n n p cm 3-(c)()d a ao N N N p -+'≅ 151515102102.1104⨯-⨯+'=⨯aN 15108.4⨯='⇒aN cm 3- ()41521010625.5104105.1⨯=⨯⨯=on cm 3-_______________________________________4.40()155210210125.1102105.1⨯=⨯⨯==o i o p n n cm 3- ⇒>o o p n n-type_______________________________________4.41()()318192300250100.61004.1⎪⎭⎫⎝⎛⨯⨯=in()()⎥⎦⎤⎢⎣⎡-⨯3002500259.066.0exp24108936.1⨯= 1210376.1⨯=⇒i n cm 3-2222414i o o i o i o n n n n p n n =⇒==i o n n 21=⇒ So 111088.6⨯=o n cm 3-,Then 121075.2⨯=o p cm 3-2222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 212210752.2⎪⎪⎭⎫ ⎝⎛-⨯a N 242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=a N()21224210752.2105735.7⎪⎪⎭⎫⎝⎛+⨯-⨯a a N N242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=a Nso that 1210064.2⨯=a N cm 3- _______________________________________4.42Plot_______________________________________4.43Plot_______________________________________4.44Plot_______________________________________4.452222i ad a d o n N N N N n +⎪⎪⎭⎫ ⎝⎛-+-= 2102.1102101.1141414⨯-⨯=⨯2214142102.1102i n +⎪⎪⎭⎫⎝⎛⨯-⨯+()()221321314104104101.1i n +⨯=⨯-⨯22727106.1109.4i n +⨯=⨯ so 131074.5⨯=i n cm 3-1314272103101.1103.3⨯=⨯⨯==o i o n n p cm 3- _______________________________________4.46(a) ⇒>d a N N p-typeMajority carriers are holes 1616105.1103⨯-⨯=-=d a o N N p 16105.1⨯=cm 3-Minority carriers are electrons()4162102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- (b) Boron atoms must be addedd a ao N N N p -+'=161616105.1103105⨯-⨯+'=⨯aN So 16105.3⨯='aN cm 3-()316210105.4105105.1⨯=⨯⨯=on cm 3-_______________________________________4.47 (a) ⇒<<i o n p n-type (b)oi o o i o p n n n n p 22=⇒=on ()16421010125.1102105.1⨯=⨯⨯=cm 3-⇒electrons are majority carriers4102⨯=o p cm 3-⇒holes are minority carriers(c) a d o N N n -=151610710125.1⨯-=⨯d N so 1610825.1⨯=d N cm 3-_______________________________________4.48⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln For Germanium T (K)kT (eV) i n (cm 3-) 200 400 60001727.003453.0 0518.0101016.2⨯ 141060.8⨯ 161082.3⨯2222i a a o n N N p +⎪⎪⎭⎫⎝⎛+= and1510=a N cm 3- T (K) o p (cm 3-) ()F Fi E E -(eV) 200 400 60015100.1⨯ 151049.1⨯ 161087.3⨯1855.0 01898.0 000674.0_______________________________________4.49(a) ⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=d N 19108.2ln 0259.0 For 1410cm 3-, 3249.0=-F c E E eV 1510cm 3-, 2652.0=-F c E E eV 1610cm 3-, 2056.0=-F c E E eV 1710cm 3-, 1459.0=-F c E E eV (b)⎪⎪⎭⎫⎝⎛=-i d Fi F n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=10105.1ln 0259.0d N For 1410cm 3-, 2280.0=-Fi F E E eV 1510cm 3-, 2877.0=-Fi F E E eV 1610cm 3-, 3473.0=-Fi F E E eV 1710cm 3-, 4070.0=-Fi F E E eV _______________________________________4.50 (a)2222i d d o n N N n +⎪⎪⎭⎫ ⎝⎛+= 151005.105.1⨯==d o N n cm 3- ()21515105.01005.1⨯-⨯()2215105.0i n +⨯=so 2821025.5⨯=i nNow()()3191923001004.1108.2⎪⎭⎫ ⎝⎛⨯⨯=T n i()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382830010912.21025.5⎪⎭⎫ ⎝⎛⨯=⨯T⎥⎦⎤⎢⎣⎡-⨯T 973.12972exp By trial and error, 5.536=T K(b) At 300=T K,⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=-151910108.2ln 0259.0F c E E2652.0=eV At 5.536=T K,()046318.03005.5360259.0=⎪⎭⎫⎝⎛=kT eV()2/3193005.536108.2⎪⎭⎫ ⎝⎛⨯=c N1910696.6⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=-15191005.110696.6ln 046318.0F c E E5124.0=eV then ()2472.0=-∆F c E E eV(c) Closer to the intrinsic energy level._______________________________________4.51⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln At 200=T K, 017267.0=kT eV 400=T K, 034533.0=kT eV 600=T K, 0518.0=kT eVAt 200=T K,()()3191923002001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯017267.012.1exp 410638.7⨯=⇒i n cm 3- At 400=T K,()()3191923004001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 1210381.2⨯=⇒i n cm 3- At 600=T K,()()3191923006001004.1108.2⎪⎭⎫⎝⎛⨯⨯=i n⎥⎦⎤⎢⎣⎡-⨯0518.012.1exp 1410740.9⨯=⇒in cm 3-At 200=T K and 400=T K, 15103⨯==a o N p cm 3- At 600=T K,2222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+=()2142151510740.921032103⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=1510288.3⨯=cm 3-Then, 200=T K, 4212.0=-F Fi E E eV 400=T K, 2465.0=-F Fi E E eV 600=T K, 0630.0=-F Fi E E eV_______________________________________4.52(a)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-6108.1ln 0259.0ln a i a F Fi N n N kT E E For 1410=a N cm 3-,4619.0=-F Fi E E eV1510=a N cm 3-,5215.0=-F Fi E E eV1610=a N cm 3-,5811.0=-F Fi E E eV1710=a N cm 3-,6408.0=-F Fi E E eV(b) ()⎪⎪⎭⎫ ⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-a aF N NN kT E E 18100.7ln 0259.0ln υυ For 1410=a N cm 3-,2889.0=-υE E F eV1510=a N cm 3-,2293.0=-υE E F eV 1610=a N cm 3-,1697.0=-υE E F eV1710=a N cm 3-, 1100.0=-υE E F eV _______________________________________4.53(a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E ()()10ln 0259.043= or0447.0+=-midgap Fi E E eV (b) Impurity atoms to be added so 45.0=-F midgap E E eV (i) p-type, so add acceptor atoms(ii)4947.045.00447.0=+=-F Fi E E eV Then⎪⎪⎭⎫⎝⎛-=kT E E n p F Fi i o exp()⎪⎭⎫⎝⎛=0259.04947.0exp 105or131097.1⨯==a o N p cm 3-_______________________________________4.54()⎥⎦⎤⎢⎣⎡--=-=kT E E N N N n F c c a d o exp so()⎪⎭⎫⎝⎛-⨯+⨯=0259.0215.0exp 108.21051915d N15151095.6105⨯+⨯=or16102.1⨯=d N cm 3-_______________________________________4.55(a) Silicon(i)⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()2188.0106108.2ln 0259.01519=⎪⎪⎭⎫⎝⎛⨯⨯=eV(ii)1929.00259.02188.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡--=kT E E N N F c c d exp()⎥⎦⎤⎢⎣⎡-⨯=0259.01929.0exp 108.2191610631.1⨯=d N cm 3-15106⨯+'=dN 1610031.1⨯='⇒d N cm 3- Additionaldonor atoms(b) GaAs(i)()⎪⎪⎭⎫⎝⎛⨯=-151710107.4ln 0259.0F c E E15936.0=eV(ii)13346.00259.015936.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.013346.0exp 107.417d N1510718.2⨯=cm 3-1510+'=dN 1510718.1⨯='⇒dN cm 3- Additionaldonor atoms_______________________________________4.56(a) ⎪⎪⎭⎫⎝⎛=-a F Fi N N kT E E υln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.01620.0=eV(b) ⎪⎪⎭⎫⎝⎛=-d c Fi F N N kT E E ln()1876.0102108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯⨯=eV(c) For part (a);16102⨯=o p cm 3- ()162102102105.1⨯⨯==o i o p n n410125.1⨯=cm 3-For part (b):16102⨯=o n cm 3-()162102102105.1⨯⨯==o i o n n p 410125.1⨯=cm 3- _______________________________________4.57⎥⎦⎤⎢⎣⎡-=kTE E n n FiFi o exp ()⎥⎦⎤⎢⎣⎡⨯=0259.055.0exp 108.1615100.3⨯=cm 3-Add additional acceptor impurities a d o N N n -=a N -⨯=⨯1515107103 15104⨯=⇒a N cm 3-_______________________________________4.58(a) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()3161.0105.1103ln 0259.01015=⎪⎪⎭⎫⎝⎛⨯⨯=eV(b)⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()3758.0105.1103ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV(c) Fi F E E =(d)⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=111510334.7104ln 3003750259.0 2786.0=eV(e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=131410722.110029.1ln 3004500259.0 06945.0=eV_______________________________________4.59 (a)⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()2009.0103100.7ln 0259.01518=⎪⎪⎭⎫⎝⎛⨯⨯=eV(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=--4181008.1100.7ln 0259.0υE E F360.1=eV(c) ()⎪⎪⎭⎫⎝⎛⨯⨯=-618108.1100.7ln 0259.0υE E F7508.0=eV(d) ()⎪⎭⎫⎝⎛=-3003750259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯152/318104300375100.7ln 2526.0=eV(e) ()⎪⎭⎫⎝⎛=-3004500259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯72/3181048.1300450100.7ln 068.1=eV_______________________________________4.60n-type⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()3504.0105.110125.1ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV______________________________________4.612222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 21051008.51515⨯=⨯22152105i n +⎪⎪⎭⎫ ⎝⎛⨯+()21515105.21008.5⨯-⨯()2215105.2i n +⨯=230301025.6106564.6i n +⨯=⨯ 29210064.4⨯=⇒in⎥⎦⎤⎢⎣⎡-=kT E N N n g c i exp 2υ()030217.03003500259.0=⎪⎭⎫⎝⎛=kT eV()1921910633.1300350102.1⨯=⎪⎭⎫ ⎝⎛⨯=c N cm 3-()192191045.2300350108.1⨯=⎪⎭⎫ ⎝⎛⨯=υN cm 3-Now()()1919291045.210633.110064.4⨯⨯=⨯⎥⎦⎤⎢⎣⎡-⨯030217.0exp g ESo()()()⎥⎦⎤⎢⎣⎡⨯⨯⨯=29191910064.41045.210633.1ln 030217.0g E 6257.0=⇒g E eV_______________________________________4.62(a) Replace Ga atoms ⇒Silicon acts as adonor()()1415105.310705.0⨯=⨯=d N cm 3- Replace As atoms ⇒Silicon acts as anacceptor()()15151065.610795.0⨯=⨯=a N cm 3-(b) ⇒>d a N N p-type(c) 1415105.31065.6⨯-⨯=-=d a o N N p 15103.6⨯=cm 3-()4152621014.5103.6108.1-⨯=⨯⨯==o i o p n n cm 3- (d)⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()5692.0108.1103.6ln 0259.0615=⎪⎪⎭⎫⎝⎛⨯⨯=eV_______________________________________。

半导体物理与器件第四版课后习题问题详解4

Chapter 44.1⎪⎪⎭⎫ ⎝⎛-=kTE N N n gc iexp 2υ ⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=kT E T N N g O cO exp 3003υwhere cO N and O N υ are the values at 300 K.(a) SiliconT (K) kT (eV)i n (cm 3-) 200 400 600 01727.0 03453.0 0518.041068.7⨯ 121038.2⨯ 141074.9⨯(b) Germanium (c) GaAsT (K) i n (cm 3-) i n (cm 3-)200 400 600101016.2⨯ 141060.8⨯ 161082.3⨯38.1 91028.3⨯ 121072.5⨯_______________________________________ 4.2Plot_______________________________________ 4.3(a) ⎪⎪⎭⎫⎝⎛-=kT E N N n g c i exp 2υ ()()()319192113001004.1108.2105⎪⎭⎫⎝⎛⨯⨯=⨯T()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382330010912.2105.2⎪⎭⎫⎝⎛⨯=⨯T()()()()⎥⎦⎤⎢⎣⎡-⨯T 0259.030012.1expBy trial and error, 5.367≅T K(b)()252122105.2105⨯=⨯=i n()()()()()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=T T 0259.030012.1exp 30010912.2338By trial and error, 5.417≅T K_______________________________________ 4.4At 200=T K, ()⎪⎭⎫⎝⎛=3002000259.0kT017267.0=eVAt 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV()()()()17222102210025.31040.11070.7200400⨯=⨯⨯=ii nn⎥⎦⎤⎢⎣⎡-⎥⎦⎤⎢⎣⎡-⨯⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=017267.0exp 034533.0exp 30020030040033g g E E⎥⎦⎤⎢⎣⎡-=034533.0017267.0exp 8g g E E()[]9578.289139.57exp 810025.317-=⨯g Eor()1714.38810025.3ln 9561.2817=⎪⎪⎭⎫⎝⎛⨯=g E or 318.1=g E eVNow ()32103004001070.7⎪⎭⎫⎝⎛=⨯o co N N υ⎪⎭⎫ ⎝⎛-⨯034533.0318.1exp ()()172110658.2370.210929.5-⨯=⨯o co N N υ so 371041.9⨯=o co N N υcm 6-_______________________________________ 4.5()()⎪⎭⎫ ⎝⎛-=⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛-=kT kT kT A n B n i i 20.0exp 90.0exp 10.1exp For 200=T K, 017267.0=kT eV For 300=T K, 0259.0=kT eV For 400=T K, 034533.0=kT eV (a) For 200=T K, ()()610325.9017267.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (b) For 300=T K, ()()41043.40259.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i (c) For 400=T K, ()()31005.3034533.020.0exp -⨯=⎪⎭⎫ ⎝⎛-=A n B n i i _______________________________________ 4.6(a) ()⎥⎦⎤⎢⎣⎡---∝kT E E E E f g F c F c exp()⎥⎦⎤⎢⎣⎡---∝kT E E E E c c exp()⎥⎦⎤⎢⎣⎡--⨯kT E E F c exp Let x E E c =-Then ⎪⎭⎫⎝⎛-∝kT x x f g F c expTo find the maximum value: ()⎪⎭⎫⎝⎛-∝-kT x x dx f g d F c exp 212/10exp 12/1=⎪⎭⎫ ⎝⎛-⋅-kT x x kT which yields2212/12/1kTx kT x x =⇒= The maximum value occurs at2kTE E c +=(b)()()⎥⎦⎤⎢⎣⎡---∝-kT E E E E f g F F exp 1υυ()⎥⎦⎤⎢⎣⎡---∝kT E E E E υυexp()⎥⎦⎤⎢⎣⎡--⨯kT E E F υexp Let x E E =-υThen ()⎪⎭⎫ ⎝⎛-∝-kT x x f g F exp 1υTo find the maximum value()[]0exp 1=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛-∝-kT x x dx d dx f g d F υ Same as part (a). Maximum occurs at2kTx =or2kTE E -=υ_______________________________________ 4.7()()()()⎥⎦⎤⎢⎣⎡---⎥⎦⎤⎢⎣⎡---=kT E E E E kT E E E E E n E n c c c c 221121exp expwherekT E E c 41+= and 22kTE E c += Then()()()⎥⎦⎤⎢⎣⎡--=kT E E kT kTE n E n 2121exp 24()5.3exp 22214exp 22-=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛--=or()()0854.021=E n E n_______________________________________ 4.8Plot_______________________________________ 4.9Plot_______________________________________ 4.10⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E Silicon: o p m m 56.0*=, o n m m 08.1*=0128.0-=-midgap Fi E E eV Germanium: o pm m 37.0*=,o n m m 55.0*=0077.0-=-midgap Fi E E eV Gallium Arsenide: o p m m 48.0*=,o n m m 067.0*= 0382.0+=-midgap Fi E E eV_______________________________________ 4.11()⎪⎪⎭⎫⎝⎛=-c midgap Fi N N kT E E υln 21()()kT kT 4952.0108.21004.1ln 211919-=⎪⎪⎭⎫ ⎝⎛⨯⨯=T (K) kT (eV)(midgap Fi E E -)(eV) 200 400 600 01727.0 03453.0 0518.0 0086.0- 0171.0- 0257.0-_______________________________________ 4.12(a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n pmidgap Fi m m kT E E()⎪⎭⎫ ⎝⎛=21.170.0ln 0259.043 63.10-⇒meV(b) ()⎪⎭⎫⎝⎛=-080.075.0ln 0259.043midgap Fi E E47.43+⇒meV_______________________________________ 4.13Let ()==K E g c constant Then()()dE E fE g n FE co c⎰∞=dE kT E E Kc E F⎰∞⎪⎪⎭⎫⎝⎛-+=exp 11()dE kT E E K cE F ⎰∞⎥⎦⎤⎢⎣⎡--≅exp LetkTE E c-=η so that ηd kT dE ⋅= We can write()()c F c F E E E E E E -+-=- so that()()()η-⋅⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--exp exp exp kT E E kT E E F c F The integral can then be written as()()ηηd kT E E kT K n F c o ⎰∞-⎥⎦⎤⎢⎣⎡--⋅⋅=0exp exp which becomes()⎥⎦⎤⎢⎣⎡--⋅⋅=kT E E kT K n F c o exp _______________________________________ 4.14Let ()()c c E E C E g -=1 for c E E ≥ Then()()dE E fE g n FE co c⎰∞=()dE kT E E E E C c E Fc ⎰∞⎪⎪⎭⎫⎝⎛-+-=exp 11()()dE kT E E E E C F E C c⎥⎦⎤⎢⎣⎡---≅⎰∞exp 1LetkTE E c-=η so that ηd kT dE ⋅= We can write()()F c c F E E E E E E -+-=-Then()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1()()dE kT E E E E c E c c⎥⎦⎤⎢⎣⎡---⨯⎰∞exp or()⎥⎦⎤⎢⎣⎡--=kT E E C n F c o exp 1 ()()()[]()ηηηd kT kT -⨯⎰∞exp 0We find that()()()11exp exp 0+=---=-∞∞⎰ηηηηηdSo()()⎥⎦⎤⎢⎣⎡--=kT E E kT C n F c o exp 21 _______________________________________ 4.15We have ⎪⎪⎭⎫⎝⎛=∈*1m m a r o r o For germanium, 16=∈r , o m m 55.0*= Then()()()53.02955.01161=⎪⎭⎫⎝⎛=o a roroA r 4.151=The ionization energy can be written as ()6.132*⎪⎪⎭⎫⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E eV ()()029.06.131655.02=⇒=E eV_______________________________________ 4.16We have ⎪⎪⎭⎫⎝⎛=∈*1m m a r o r o For gallium arsenide, 1.13=∈r ,o m m 067.0*= Then()()oA r 10453.0067.011.131=⎪⎭⎫⎝⎛=The ionization energy is()()()6.131.13067.06.1322*=⎪⎪⎭⎫ ⎝⎛∈∈⎪⎪⎭⎫ ⎝⎛=s o o m m E or0053.0=E eV_______________________________________ 4.17(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1519107108.2ln 0259.02148.0=eV (b) ()F c g F E E E E E --=-υ90518.02148.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp()⎥⎦⎤⎢⎣⎡-⨯=0259.090518.0exp 1004.119 31090.6⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1107ln 0259.0338.0=eV_______________________________________ 4.18(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.0162.0=eV(b)()υE E E E E F g F c --=- 958.0162.012.1=-=eV(c) ()⎪⎭⎫⎝⎛-⨯=0259.0958.0exp 108.219o n31041.2⨯=cm 3-(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1016105.1102ln 0259.0365.0=eV_______________________________________ 4.19(a) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=519102108.2ln 0259.08436.0=eV ()F c g F E E E E E --=-υ 8436.012.1-= 2764.0=-υE E F eV (b)()⎪⎭⎫⎝⎛-⨯=0259.027637.0exp 1004.119o p1410414.2⨯=cm 3-(c) p-type_______________________________________ 4.20(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.028.0exp 300375107.42/317o n 141015.1⨯=cm 3-()28.042.1-=--=-F c g F E E E E E υ 14.1=eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.014.1exp 3003751072/318o p 31099.4⨯=cm 3-(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=-14171015.1107.4ln 0259.0F c E E2154.0=eV()2154.042.1-=--=-F c g F E E E E E υ 2046.1=eV()⎥⎦⎤⎢⎣⎡-⨯=0259.02046.1exp 10718o p21042.4-⨯=cm 3-_______________________________________ 4.21(a) ()032375.03003750259.0=⎪⎭⎫⎝⎛=kT eV()⎥⎦⎤⎢⎣⎡-⎪⎭⎫⎝⎛⨯=032375.028.0exp 300375108.22/319o n 151086.6⨯= cm 3-()28.012.1-=--=-F c g F E E E E E υ 840.0=eV ()⎥⎦⎤⎢⎣⎡-⎪⎭⎫ ⎝⎛⨯=032375.0840.0exp 3003751004.12/319o p 71084.7⨯=cm 3-(b) ⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=151910862.6108.2ln 0259.02153.0=eV9047.02153.012.1=-=-υE E F eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0904668.0exp 1004.119o p 31004.7⨯=cm 3-_______________________________________ 4.22 (a) p-type(b) 28.0412.14===-g F E E E υeV()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp ()⎥⎦⎤⎢⎣⎡-⨯=0259.028.0exp 1004.119141010.2⨯=cm 3- ()υE E E E E F g F c --=- 84.028.012.1=-=eV()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.084.0exp 108.219 51030.2⨯=cm 3-_______________________________________ 4.23(a) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp ()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 105.110131033.7⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp ()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 105.110 61007.3⨯=cm 3-(b) ⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp()⎥⎦⎤⎢⎣⎡⨯=0259.022.0exp 108.16 91080.8⨯=cm 3-⎥⎦⎤⎢⎣⎡-=kT E E n p F Fii o exp()⎥⎦⎤⎢⎣⎡-⨯=0259.022.0exp 108.16 21068.3⨯=cm 3-_______________________________________ 4.24(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=151********.1ln 0259.01979.0=eV(b)()υE E E E E F g F c --=- 92212.019788.012.1=-=eV(c) ()⎥⎦⎤⎢⎣⎡-⨯=0259.092212.0exp 108.219o n31066.9⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=1015105.1105ln 0259.03294.0=eV_______________________________________ 4.25()034533.03004000259.0=⎪⎭⎫⎝⎛=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3-()2/319300400108.2⎪⎭⎫⎝⎛⨯=c N19103109.4⨯=cm 3-()()1919210601.1103109.4⨯⨯=i n⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 24106702.5⨯= 1210381.2⨯=⇒i n cm 3- (a)⎪⎪⎭⎫ ⎝⎛=-oF pN kT E E υυln ()⎪⎪⎭⎫⎝⎛⨯⨯=151910510601.1ln 034533.02787.0=eV (b) 84127.027873.012.1=-=-F c E E eV(c)()⎥⎦⎤⎢⎣⎡-⨯=034533.084127.0exp 103109.419o n910134.1⨯=cm 3- (d) Holes(e) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=121510381.2105ln 034533.02642.0=eV _______________________________________ 4.26(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 10718o p141050.4⨯=cm 3-17.125.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.017.1exp 107.417o n21013.1-⨯=cm 3- (b) 034533.0=kT eV ()2/318300400107⎪⎭⎫ ⎝⎛⨯=υN1910078.1⨯=cm 3- ()2/317300400107.4⎪⎭⎫ ⎝⎛⨯=c N1710236.7⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191050.410078.1ln 034533.03482.0=eV072.13482.042.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.007177.1exp 10236.717o n 41040.2⨯=cm 3-_____________________________________ 4.27(a) ()⎥⎦⎤⎢⎣⎡-⨯=0259.025.0exp 1004.119o p141068.6⨯=cm 3-870.025.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.0870.0exp 108.219o n41023.7⨯=o n cm 3- (b)034533.0=kT eV()2/3193004001004.1⎪⎭⎫⎝⎛⨯=υN1910601.1⨯=cm 3- ()2/319300400108.2⎪⎭⎫ ⎝⎛⨯=c N1910311.4⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()⎪⎪⎭⎫⎝⎛⨯⨯=14191068.610601.1ln 034533.03482.0=eV7718.03482.012.1=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=034533.077175.0exp 10311.419o n91049.8⨯=cm 3-_______________________________________ 4.28(a) ()F c o F N n ηπ2/12=For 2kT E E c F +=,5.02==-=kTkT kT E E c F F η Then ()0.12/1≅F F η()()0.1108.2219⨯=πo n191016.3⨯=cm 3-(b) ()F c o F N n ηπ2/12=()()0.1107.4217⨯=π171030.5⨯=cm 3-_______________________________________ 4.29()F o F N p ηπυ'=2/12()()FF ηπ'⨯=⨯2/119191004.12105So ()26.42/1='FF η We find kTE E FF-=≅'υη0.3()()0777.00259.00.3==-F E E υeV_______________________________________ 4.30(a) 44==-=kTkTkT E E c F F ηThen ()0.62/1≅F F η ()F c o F N n ηπ2/12=()()0.6108.2219⨯=π201090.1⨯=cm 3-(b) ()()0.6107.4217⨯=πo n181018.3⨯=cm 3-_______________________________________ 4.31For the electron concentration ()()()E f E g E n F c =The Boltzmann approximation applies, so ()()c nE E hm E n -=32/3*24π()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or ()()()⎥⎦⎤⎢⎣⎡--=kT E E h m E n F c nexp 2432/3*π()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTc c exp DefinekTE E x c-= Then()()()x x K x n E n -=→exp To find maximum ()()x n E n →, set()()x x K dx x dn -⎢⎣⎡==-exp 2102/1 +()()⎥⎦⎤--x x exp 12/1or()⎥⎦⎤⎢⎣⎡--=-x x Kx 21exp 02/1which yieldskT E E kT E E x c c 2121+=⇒-==For the hole concentration ()()()[]E f E g E p F -=1υUsing the Boltzmann approximation ()()E E h m E p p-=υπ32/3*24()⎥⎦⎤⎢⎣⎡--⨯kT E E F exp or()()()⎥⎦⎤⎢⎣⎡--=kT E E h mE pF pυπexp 2432/3*()⎥⎦⎤⎢⎣⎡---⨯kT E E kT E E kTυυexp DefinekTEE x -='υThen()()x x K x p '-''='exp To find maximum value of ()()x p E p '→,set()0=''x d x dp Using the results from above,we find the maximum atkT E E 21-=υ_______________________________________ 4.32 (a) Silicon: We have()⎥⎦⎤⎢⎣⎡--=kT E E N n F c c o exp We can write()()F d d c F c E E E E E E -+-=- For045.0=-d c E E eV andkT E E F d 3=-eVwe can write()⎥⎦⎤⎢⎣⎡--⨯=30259.0045.0exp 108.219o n()()737.4exp 108.219-⨯= or171045.2⨯=o n cm 3- We also have()⎥⎦⎤⎢⎣⎡--=kT E E N p F o υυexp Again, we can write()()υυE E E E E E a a F F -+-=- ForkT E E a F 3=- and045.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=0259.0045.03exp 1004.119o p ()()737.4exp 1004.119-⨯= or161012.9⨯=o p cm 3- (b) GaAs: assume 0058.0=-d c E E eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00058.0exp 107.417o n ()()224.3exp 107.417-⨯= or161087.1⨯=o n cm 3-Assume 0345.0=-υE E a eV Then()⎥⎦⎤⎢⎣⎡--⨯=30259.00345.0exp 10718o p ()()332.4exp 10718-⨯=or161020.9⨯=o p cm 3-_______________________________________ 4.33Plot_______________________________________ 4.34(a)151510310154⨯=-⨯=o p cm 3- ()415210105.7103105.1⨯=⨯⨯=o n cm 3-(b)16103⨯==d o N n cm 3-()316210105.7103105.1⨯=⨯⨯=o p cm 3-(c)10105.1⨯===i o o n p n cm 3-(d) ()()3191923003751004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030012.1exp1110334.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()8152111034.110410334.7⨯=⨯⨯=on cm 3-(e) ()()3191923004501004.1108.2⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030012.1exp1310722.1⨯=⇒i n cm 3-()2132141410722.1210210⨯+⎪⎪⎭⎫ ⎝⎛+=o n1410029.1⨯=cm 3-()12142131088.210029.110722.1⨯=⨯⨯=o p cm 3-_______________________________________ 4.35(a)151510104-⨯=-=d a o N N p15103⨯=cm 3-()3152621008.1103108.1-⨯=⨯⨯==o i o p n n cm 3-(b)16103⨯==d o N n cm 3-()416261008.1103108.1-⨯=⨯⨯=o p cm 3-(c)6108.1⨯===i o o n p n cm 3-(d) ()()318172300375100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯3750259.030042.1exp810580.7⨯=⇒i n cm 3- 15104⨯==a o N p cm 3-()215281044.110410580.7⨯=⨯⨯=on cm 3-(e) ()()318172300450100.7107.4⎪⎭⎫⎝⎛⨯⨯=in()()()()⎥⎦⎤⎢⎣⎡-⨯4500259.030042.1exp1010853.3⨯=⇒i n cm 3- 1410==d o N n cm 3-()7142101048.11010853.3⨯=⨯=op cm 3-_______________________________________ 4.36 (a) Ge: 13104.2⨯=i n cm 3-(i)2222i dd o n N N n +⎪⎪⎭⎫ ⎝⎛+=()21321515104.221022102⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=or15102⨯=≅d o N n cm 3-()152132102104.2⨯⨯==o i o n n p111088.2⨯= cm 3- (ii)151610710⨯-=-≅d a o N N p 15103⨯=cm 3- ()152132103104.2⨯⨯==o i o p n n111092.1⨯=cm 3-(b) GaAs: 6108.1⨯=i n cm 3- (i)15102⨯=≅d o N n cm()315261062.1102108.1-⨯=⨯⨯=op cm 3-(ii)15103⨯=-≅d a o N N p cm 3-()315261008.1103108.1-⨯=⨯⨯=on cm 3-(c) The result implies that there is only one minority carrier in a volume of 310cm 3. _______________________________________ 4.37(a) For the donor level⎪⎪⎭⎫ ⎝⎛-+=kT E E N n F d d d exp 2111⎪⎭⎫ ⎝⎛+=0259.020.0exp 2111or41085.8-⨯=dd N n(b) We have()⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F F exp 11Now()()F c c F E E E E E E -+-=- or245.0+=-kT E E FThen()⎪⎭⎫ ⎝⎛++=0259.0245.01exp 11E f For()51087.2-⨯=E f F_______________________________________ 4.38 (a) ⇒>d a N N p-type (b) Silicon:1313101105.2⨯-⨯=-=d a o N N p or13105.1⨯=o p cm 3- Then()7132102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- Germanium:2222i da d a o n N N N N p +⎪⎪⎭⎫ ⎝⎛-+-=()21321313104.22105.12105.1⨯+⎪⎪⎭⎫⎝⎛⨯+⎪⎪⎭⎫ ⎝⎛⨯=or131026.3⨯=o p cm 3- Then()131321321076.110264.3104.2⨯=⨯⨯==o i o p n n cm 3-Gallium Arsenide:13105.1⨯=-=d a o N N p cm 3- and()216.0105.1108.113262=⨯⨯==o i o p n n cm 3- _______________________________________ 4.39 (a) ⇒>a d N N n-type(b)1515102.1102⨯-⨯=-≅a d o N N n14108⨯=cm 3-()51421021081.2108105.1⨯=⨯⨯==o i o n n p cm 3-(c)()d a ao N N N p -+'≅ 151515102102.1104⨯-⨯+'=⨯aN 15108.4⨯='⇒aN cm 3-()41521010625.5104105.1⨯=⨯⨯=on cm 3-_______________________________________ 4.40()155210210125.1102105.1⨯=⨯⨯==o i o p n n cm 3- ⇒>o o p n n-type_______________________________________ 4.41()()318192300250100.61004.1⎪⎭⎫⎝⎛⨯⨯=i n()()⎥⎦⎤⎢⎣⎡-⨯3002500259.066.0exp24108936.1⨯=1210376.1⨯=⇒i n cm 3-2222414i o o i o i o n n n n p n n =⇒==i o n n 21=⇒So 111088.6⨯=o n cm 3-,Then 121075.2⨯=o p cm 3-2222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 212210752.2⎪⎪⎭⎫ ⎝⎛-⨯a N242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=a N()21224210752.2105735.7⎪⎪⎭⎫ ⎝⎛+⨯-⨯aa N N242108936.12⨯+⎪⎪⎭⎫ ⎝⎛=aN so that 1210064.2⨯=a N cm 3-_______________________________________ 4.42Plot_______________________________________ 4.43Plot_______________________________________ 4.44Plot_______________________________________ 4.452222i ad a d o n N N N N n +⎪⎪⎭⎫ ⎝⎛-+-= 2102.1102101.1141414⨯-⨯=⨯2214142102.1102i n +⎪⎪⎭⎫⎝⎛⨯-⨯+()()221321314104104101.1i n +⨯=⨯-⨯22727106.1109.4i n +⨯=⨯ so 131074.5⨯=i n cm 3-1314272103101.1103.3⨯=⨯⨯==o i o n n p cm 3- _______________________________________ 4.46 (a) ⇒>d a N N p-typeMajority carriers are holes1616105.1103⨯-⨯=-=d a o N N p16105.1⨯=cm 3-Minority carriers are electrons()4162102105.1105.1105.1⨯=⨯⨯==o i o p n n cm 3- (b) Boron atoms must be addedd a ao N N N p -+'=161616105.1103105⨯-⨯+'=⨯aN So 16105.3⨯='aN cm 3-()316210105.4105105.1⨯=⨯⨯=on cm 3-_______________________________________ 4.47 (a) ⇒<<i o n p n-type (b) oi o o i o p n n n n p 22=⇒=on ()16421010125.1102105.1⨯=⨯⨯=cm 3-⇒electrons are majority carriers4102⨯=o p cm 3-⇒holes are minority carriers (c) a d o N N n -= 151610710125.1⨯-=⨯d N so 1610825.1⨯=d N cm 3-_______________________________________ 4.48⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln For Germanium T (K) kT (eV)i n (cm 3-) 200400 60001727.0 03453.0 0518.0101016.2⨯ 141060.8⨯ 161082.3⨯2222i a a o n N N p +⎪⎪⎭⎫⎝⎛+=and 1510=a N cm 3- T (K) op (cm 3-)()F Fi E E -(eV)200400 60015100.1⨯151049.1⨯ 161087.3⨯1855.0 01898.0 000674.0_______________________________________ 4.49(a) ⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=d N 19108.2ln 0259.0 For 1410cm 3-, 3249.0=-F c E E eV 1510cm 3-, 2652.0=-F c E E eV 1610cm 3-, 2056.0=-F c E E eV 1710cm 3-, 1459.0=-F c E E eV(b) ⎪⎪⎭⎫⎝⎛=-i d Fi F n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=10105.1ln 0259.0d N For 1410cm 3-, 2280.0=-Fi F E E eV 1510cm 3-, 2877.0=-Fi F E E eV 1610cm 3-, 3473.0=-Fi F E E eV 1710cm 3-, 4070.0=-Fi F E E eV _______________________________________ 4.50 (a)2222i d d o n N N n +⎪⎪⎭⎫⎝⎛+= 151005.105.1⨯==d o N n cm 3- ()21515105.01005.1⨯-⨯()2215105.0i n +⨯=so 2821025.5⨯=i nNow()()3191923001004.1108.2⎪⎭⎫ ⎝⎛⨯⨯=T n i()()⎥⎦⎤⎢⎣⎡-⨯3000259.012.1exp T()3382830010912.21025.5⎪⎭⎫ ⎝⎛⨯=⨯T⎥⎦⎤⎢⎣⎡-⨯T 973.12972exp By trial and error, 5.536=T K (b) At 300=T K,⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯=-151910108.2ln 0259.0F c E E2652.0=eV At 5.536=T K,()046318.03005.5360259.0=⎪⎭⎫⎝⎛=kT eV()2/3193005.536108.2⎪⎭⎫⎝⎛⨯=c N1910696.6⨯=cm 3-⎪⎪⎭⎫⎝⎛=-o c F c n N kT E E ln()⎪⎪⎭⎫⎝⎛⨯⨯=-15191005.110696.6ln 046318.0F c E E5124.0=eV then ()2472.0=-∆F c E E eV (c) Closer to the intrinsic energy level._______________________________________ 4.51⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln At 200=T K, 017267.0=kT eV 400=T K, 034533.0=kT eV 600=T K, 0518.0=kT eVAt 200=T K,()()3191923002001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯017267.012.1exp410638.7⨯=⇒i n cm 3- At 400=T K,()()3191923004001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯034533.012.1exp 1210381.2⨯=⇒i n cm 3- At 600=T K,()()3191923006001004.1108.2⎪⎭⎫⎝⎛⨯⨯=in⎥⎦⎤⎢⎣⎡-⨯0518.012.1exp1410740.9⨯=⇒i n cm 3- At 200=T K and 400=T K, 15103⨯==a o N p cm 3- At 600=T K,2222i a a o n N N p +⎪⎪⎭⎫⎝⎛+=()2142151510740.921032103⨯+⎪⎪⎭⎫ ⎝⎛⨯+⨯=1510288.3⨯=cm 3-Then, 200=T K, 4212.0=-F Fi E E eV 400=T K, 2465.0=-F Fi E E eV600=T K, 0630.0=-F Fi E E eV_______________________________________ 4.52(a)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-6108.1ln 0259.0ln a i a F Fi N n N kT E EFor 1410=a N cm 3-,4619.0=-F Fi E E eV1510=a N cm 3-,5215.0=-F Fi E E eV1610=a N cm 3-,5811.0=-F Fi E E eV1710=a N cm 3-,6408.0=-F Fi E E eV (b)()⎪⎪⎭⎫⎝⎛⨯=⎪⎪⎭⎫ ⎝⎛=-a a F N N N kT E E 18100.7ln 0259.0ln υυ For 1410=a N cm 3-,2889.0=-υE E F eV1510=a N cm 3-,2293.0=-υE E F eV1610=a N cm 3-,1697.0=-υE E F eV1710=a N cm 3-,1100.0=-υE E F eV_______________________________________ 4.53(a) ⎪⎪⎭⎫ ⎝⎛=-**ln 43n p midgap Fi m m kT E E ()()10ln 0259.043= or0447.0+=-midgap Fi E E eV(b) Impurity atoms to be added so 45.0=-F midgap E E eV (i) p-type, so add acceptor atoms (ii)4947.045.00447.0=+=-F Fi E E eV Then⎪⎪⎭⎫⎝⎛-=kT E E n p F Fi i o exp()⎪⎭⎫⎝⎛=0259.04947.0exp 105or131097.1⨯==a o N p cm 3-_______________________________________4.54()⎥⎦⎤⎢⎣⎡--=-=kT E E N N N n F c c a d o exp so()⎪⎭⎫⎝⎛-⨯+⨯=0259.0215.0exp 108.21051915d N15151095.6105⨯+⨯=or16102.1⨯=d N cm 3-_______________________________________ 4.55 (a) Silicon(i)⎪⎪⎭⎫⎝⎛=-d c F c N N kT E E ln()2188.0106108.2ln 0259.01519=⎪⎪⎭⎫⎝⎛⨯⨯=eV(ii)1929.00259.02188.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡--=kT E E N N F c c d exp()⎥⎦⎤⎢⎣⎡-⨯=0259.01929.0exp 108.2191610631.1⨯=d N cm 3-15106⨯+'=dN 1610031.1⨯='⇒dN cm 3- Additionaldonor atoms (b) GaAs(i)()⎪⎪⎭⎫⎝⎛⨯=-151710107.4ln 0259.0F c E E15936.0=eV(ii)13346.00259.015936.0=-=-F c E E eV()⎥⎦⎤⎢⎣⎡-⨯=0259.013346.0exp 107.417d N1510718.2⨯=cm 3-1510+'=dN 1510718.1⨯='⇒dN cm 3- Additionaldonor atoms _______________________________________4.56 (a) ⎪⎪⎭⎫ ⎝⎛=-a F Fi N N kT E E υln()⎪⎪⎭⎫⎝⎛⨯⨯=16191021004.1ln 0259.01620.0=eV(b) ⎪⎪⎭⎫⎝⎛=-d c Fi F N N kT E E ln ()1876.0102108.2ln 0259.01619=⎪⎪⎭⎫⎝⎛⨯⨯=eV (c) For part (a); 16102⨯=op cm 3-()162102102105.1⨯⨯==o i o p n n410125.1⨯=cm 3- For part (b):16102⨯=o n cm 3-()162102102105.1⨯⨯==o i o n n p 410125.1⨯=cm 3-_______________________________________ 4.57⎥⎦⎤⎢⎣⎡-=kT E E n n Fi Fi o exp()⎥⎦⎤⎢⎣⎡⨯=0259.055.0exp 108.16 15100.3⨯=cm 3- Add additional acceptor impurities a d o N N n -=a N -⨯=⨯151510710315104⨯=⇒a N cm 3-_______________________________________ 4.58(a) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln ()3161.0105.1103ln 0259.01015=⎪⎪⎭⎫⎝⎛⨯⨯=eV (b) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln ()3758.0105.1103ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV(c) Fi F E E =(d) ⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=111510334.7104ln 3003750259.0 2786.0=eV (e) ⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()⎪⎪⎭⎫ ⎝⎛⨯⨯⎪⎭⎫ ⎝⎛=131410722.110029.1ln 3004500259.0 06945.0=eV_______________________________________ 4.59(a) ⎪⎪⎭⎫⎝⎛=-o F p N kT E E υυln()2009.0103100.7ln 0259.01518=⎪⎪⎭⎫⎝⎛⨯⨯=eV(b) ()⎪⎪⎭⎫⎝⎛⨯⨯=--4181008.1100.7ln 0259.0υE E F360.1=eV(c) ()⎪⎪⎭⎫⎝⎛⨯⨯=-618108.1100.7ln 0259.0υE E F7508.0=eV(d) ()⎪⎭⎫⎝⎛=-3003750259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯152/318104300375100.7ln 2526.0=eV(e) ()⎪⎭⎫⎝⎛=-3004500259.0υE E F()()⎥⎥⎦⎤⎢⎢⎣⎡⨯⨯⨯72/3181048.1300450100.7ln 068.1=eV_______________________________________ 4.60n-type⎪⎪⎭⎫⎝⎛=-i o Fi F n n kT E E ln()3504.0105.110125.1ln 0259.01016=⎪⎪⎭⎫⎝⎛⨯⨯=eV ______________________________________ 4.612222i aa o n N N p +⎪⎪⎭⎫ ⎝⎛+= 21051008.51515⨯=⨯22152105i n +⎪⎪⎭⎫ ⎝⎛⨯+()21515105.21008.5⨯-⨯()2215105.2i n +⨯=230301025.6106564.6i n +⨯=⨯29210064.4⨯=⇒i n⎥⎦⎤⎢⎣⎡-=kT E N N n g c i exp 2υ()030217.03003500259.0=⎪⎭⎫⎝⎛=kT eV()1921910633.1300350102.1⨯=⎪⎭⎫ ⎝⎛⨯=c N cm 3-()192191045.2300350108.1⨯=⎪⎭⎫ ⎝⎛⨯=υN cm 3-Now()()1919291045.210633.110064.4⨯⨯=⨯⎥⎦⎤⎢⎣⎡-⨯030217.0exp g ESo()()()⎥⎦⎤⎢⎣⎡⨯⨯⨯=29191910064.41045.210633.1ln 030217.0g E 6257.0=⇒g E eV_______________________________________ 4.62 (a) Replace Ga atoms ⇒Silicon acts as adonor()()1415105.310705.0⨯=⨯=d N cm 3-Replace As atoms ⇒Silicon acts as anacceptor()()15151065.610795.0⨯=⨯=a N cm 3-(b) ⇒>d a N N p-type(c) 1415105.31065.6⨯-⨯=-=d a o N N p 15103.6⨯=cm 3-()4152621014.5103.6108.1-⨯=⨯⨯==o i o p n n cm 3- (d)⎪⎪⎭⎫⎝⎛=-i o F Fi n p kT E E ln()5692.0108.1103.6ln 0259.0615=⎪⎪⎭⎫⎝⎛⨯⨯=eV_______________________________________。

半导体物理与器件第四版课后习题答案3

Chapter 33.1If o a were to increase, the bandgap energy would decrease and the material would begin to behave less like a semiconductor and more like a metal. If o a were to decrease, the bandgap energy would increase and thematerial would begin to behave more like an insulator._______________________________________ 3.2Schrodinger's wave equation is:()()()t x x V xt x m ,,2222ψ⋅+∂ψ∂- ()tt x j ∂ψ∂=, Assume the solution is of the form:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=ψt E kx j x u t x exp , Region I: ()0=x V . Substituting theassumed solution into the wave equation, we obtain:()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧∂∂-t E kx j x jku x m exp 22 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u exp ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⋅⎪⎭⎫ ⎝⎛-=t E kx j x u jE j exp which becomes()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧-t E kx j x u jk m exp 222 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u jkexp 2 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u exp 22 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-+=t E kx j x Eu exp This equation may be written as()()()()0222222=+∂∂+∂∂+-x u mE x x u x x u jk x u kSetting ()()x u x u 1= for region I, the equation becomes:()()()()021221212=--+x u k dx x du jk dxx u d α where222mE=α Q.E.D.In Region II, ()O V x V =. Assume the same form of the solution:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=ψt E kx j x u t x exp , Substituting into Schrodinger's wave equation, we find:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧-t E kx j x u jk m exp 222 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u jkexp 2 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u exp 22 ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-+t E kx j x u V O exp ()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=t E kx j x Eu exp This equation can be written as:()()()2222x x u x x u jk x u k ∂∂+∂∂+- ()()02222=+-x u mEx u mV OSetting ()()x u x u 2= for region II, this equation becomes()()dx x du jk dxx u d 22222+ ()022222=⎪⎪⎭⎫ ⎝⎛+--x u mV k O α where again222mE=α Q.E.D._______________________________________3.3We have()()()()021221212=--+x u k dx x du jk dxx u d α Assume the solution is of the form: ()()[]x k j A x u -=αexp 1()[]x k j B +-+αexp The first derivative is()()()[]x k j A k j dxx du --=ααexp 1 ()()[]x k j B k j +-+-ααexp and the second derivative becomes()()[]()[]x k j A k j dxx u d --=ααexp 2212 ()[]()[]x k j B k j +-++ααexp 2Substituting these equations into the differential equation, we find()()[]x k j A k ---ααexp 2()()[]x k j B k +-+-ααexp 2(){()[]x k j A k j jk --+ααexp 2()()[]}x k j B k j +-+-ααexp ()()[]{x k j A k ---ααexp 22 ()[]}0exp =+-+x k j B α Combining terms, we obtain()()()[]222222αααα----+--k k k k k ()[]x k j A -⨯αexp()()()[]222222αααα--++++-+k k k k k ()[]0exp =+-⨯x k j B α We find that00= Q.E.D. For the differential equation in ()x u 2 and the proposed solution, the procedure is exactly the same as above._______________________________________ 3.4We have the solutions ()()[]x k j A x u -=αexp 1()[]x k j B +-+αexp for a x <<0 and()()[]x k j C x u -=βexp 2()[]x k j D +-+βexp for 0<<-x b .The first boundary condition is ()()0021u u =which yields0=--+D C B AThe second boundary condition is201===x x dx dudx du which yields()()()C k B k A k --+--βαα()0=++D k β The third boundary condition is ()()b u a u -=21 which yields()[]()[]a k j B a k j A +-+-ααexp exp ()()[]b k j C --=βexp()()[]b k j D -+-+βexp and can be written as()[]()[]a k j B a k j A +-+-ααexp exp ()[]b k j C ---βexp()[]0exp =+-b k j D β The fourth boundary condition isbx a x dx dudx du -===21 which yields()()[]a k j A k j --ααexp()()[]a k j B k j +-+-ααexp ()()()[]b k j C k j ---=ββexp()()()[]b k j D k j -+-+-ββexp and can be written as ()()[]a k j A k --ααexp()()[]a k j B k +-+-ααexp()()[]b k j C k ----ββexp()()[]0exp =+++b k j D k ββ_______________________________________ 3.5(b) (i) First point: πα=aSecond point: By trial and error, πα729.1=a (ii) First point: πα2=aSecond point: By trial and error, πα617.2=a_______________________________________3.6(b) (i) First point: πα=aSecond point: By trial and error, πα515.1=a (ii) First point: πα2=aSecond point: By trial and error, πα375.2=a_______________________________________ 3.7ka a aaP cos cos sin =+'αααLet y ka =, x a =α Theny x x xP cos cos sin =+'Consider dy dof this function.()[]{}y x x x P dy d sin cos sin 1-=+⋅'- We find()()()⎭⎬⎫⎩⎨⎧⋅+⋅-'--dy dx x x dy dx x x P cos sin 112y dydxx sin sin -=- Theny x x x x x P dy dx sin sin cos sin 12-=⎭⎬⎫⎩⎨⎧-⎥⎦⎤⎢⎣⎡+-'For πn ka y ==, ...,2,1,0=n 0sin =⇒y So that, in general,()()dk d ka d a d dy dxαα===0 And 22 mE=α Sodk dEm mE dk d ⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛=-22/122221 α This implies thatdk dE dk d ==0α for an k π= _______________________________________ 3.8(a) πα=a 1π=⋅a E m o 212()()()()2103123422221102.41011.9210054.12---⨯⨯⨯==ππa m E o19104114.3-⨯=J From Problem 3.5 πα729.12=aπ729.1222=⋅a E m o()()()()2103123422102.41011.9210054.1729.1---⨯⨯⨯=πE18100198.1-⨯=J 12E E E -=∆1918104114.3100198.1--⨯-⨯= 19107868.6-⨯=Jor 24.4106.1107868.61919=⨯⨯=∆--E eV(b) πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=J From Problem 3.5, πα617.24=aπ617.2224=⋅a E m o()()()()2103123424102.41011.9210054.1617.2---⨯⨯⨯=πE18103364.2-⨯=J 34E E E -=∆1818103646.1103364.2--⨯-⨯= 1910718.9-⨯=Jor 07.6106.110718.91919=⨯⨯=∆--E eV_______________________________________3.9(a) At π=ka , πα=a 1π=⋅a E m o 212()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JAt 0=ka , By trial and error, πα859.0=a o ()()()()210312342102.41011.9210054.1859.0---⨯⨯⨯=πoE19105172.2-⨯=J o E E E -=∆11919105172.2104114.3--⨯-⨯= 2010942.8-⨯=Jor 559.0106.110942.81920=⨯⨯=∆--E eV (b) At π2=ka , πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JAt π=ka . From Problem 3.5, πα729.12=aπ729.1222=⋅a E m o()()()()2103123422102.41011.9210054.1729.1---⨯⨯⨯=πE18100198.1-⨯=J23E E E -=∆1818100198.1103646.1--⨯-⨯= 19104474.3-⨯=Jor 15.2106.1104474.31919=⨯⨯=∆--E eV_______________________________________3.10(a) πα=a 1π=⋅a E m o 212()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JFrom Problem 3.6, πα515.12=aπ515.1222=⋅a E m o()()()()2103123422102.41011.9210054.1515.1---⨯⨯⨯=πE1910830.7-⨯=J 12E E E -=∆1919104114.310830.7--⨯-⨯= 19104186.4-⨯=Jor 76.2106.1104186.41919=⨯⨯=∆--E eV (b) πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JFrom Problem 3.6, πα375.24=aπ375.2224=⋅a E m o()()()()2103123424102.41011.9210054.1375.2---⨯⨯⨯=πE18109242.1-⨯=J 34E E E -=∆1818103646.1109242.1--⨯-⨯= 1910597.5-⨯=Jor 50.3106.110597.51919=⨯⨯=∆--E eV_____________________________________3.11(a) At π=ka , πα=a 1π=⋅a E m o 212()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JAt 0=ka , By trial and error, πα727.0=a oπ727.022=⋅a E m o o()()()()210312342102.41011.9210054.1727.0---⨯⨯⨯=πo E19108030.1-⨯=Jo E E E -=∆11919108030.1104114.3--⨯-⨯= 19106084.1-⨯=Jor 005.1106.1106084.11919=⨯⨯=∆--E eV (b) At π2=ka , πα23=aπ2223=⋅a E m o()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JAt π=ka , From Problem 3.6,πα515.12=aπ515.1222=⋅a E m o()()()()2103423422102.41011.9210054.1515.1---⨯⨯⨯=πE1910830.7-⨯=J23E E E -=∆191810830.7103646.1--⨯-⨯= 1910816.5-⨯=Jor 635.3106.110816.51919=⨯⨯=∆--E eV_______________________________________3.12For 100=T K, ()()⇒+⨯-=-1006361001073.4170.124gE164.1=g E eV200=T K, 147.1=g E eV 300=T K, 125.1=g E eV 400=T K, 097.1=g E eV 500=T K, 066.1=g E eV 600=T K, 032.1=g E eV_______________________________________3.13The effective mass is given by1222*1-⎪⎪⎭⎫⎝⎛⋅=dk E d mWe have()()B curve dkE d A curve dk E d 2222> so that ()()B curve m A curve m **<_______________________________________ 3.14The effective mass for a hole is given by1222*1-⎪⎪⎭⎫ ⎝⎛⋅=dk E d m p We have that()()B curve dkEd A curve dk E d 2222> so that ()()B curve m A curve m p p **<_______________________________________ 3.15Points A,B: ⇒<0dk dEvelocity in -x directionPoints C,D: ⇒>0dk dEvelocity in +x directionPoints A,D: ⇒<022dk Ednegative effective massPoints B,C: ⇒>022dkEd positive effective mass _______________________________________3.16For A: 2k C E i =At 101008.0+⨯=k m 1-, 05.0=E eV Or ()()2119108106.105.0--⨯=⨯=E J So ()2101211008.0108⨯=⨯-C3811025.1-⨯=⇒CNow ()()38234121025.1210054.12--*⨯⨯==C m 311044.4-⨯=kgor o m m ⋅⨯⨯=--*31311011.9104437.4o m m 488.0=* For B: 2k C E i =At 101008.0+⨯=k m 1-, 5.0=E eV Or ()()2019108106.15.0--⨯=⨯=E JSo ()2101201008.0108⨯=⨯-C 3711025.1-⨯=⇒CNow ()()37234121025.1210054.12--*⨯⨯==C m 321044.4-⨯=kg or o m m ⋅⨯⨯=--*31321011.9104437.4o m m 0488.0=*_______________________________________ 3.17For A: 22k C E E -=-υ()()()2102191008.0106.1025.0⨯-=⨯--C 3921025.6-⨯=⇒C()()39234221025.6210054.12--*⨯⨯-=-=C m31108873.8-⨯-=kgor o m m ⋅⨯⨯-=--*31311011.9108873.8o m m 976.0--=* For B: 22k C E E -=-υ()()()2102191008.0106.13.0⨯-=⨯--C 382105.7-⨯=⇒C()()3823422105.7210054.12--*⨯⨯-=-=C m3210406.7-⨯-=kgor o m m ⋅⨯⨯-=--*31321011.910406.7o m m 0813.0-=*_______________________________________ 3.18(a) (i) νh E =or ()()341910625.6106.142.1--⨯⨯==h E ν1410429.3⨯=Hz(ii) 141010429.3103⨯⨯===νλc E hc 51075.8-⨯=cm 875=nm(b) (i) ()()341910625.6106.112.1--⨯⨯==h E ν1410705.2⨯=Hz(ii) 141010705.2103⨯⨯==νλc410109.1-⨯=cm 1109=nm_______________________________________ 3.19(c) Curve A: Effective mass is a constantCurve B: Effective mass is positive around 0=k , and is negativearound 2π±=k . _______________________________________ 3.20()[]O O k k E E E --=αcos 1 Then()()()[]O k k E dkdE ---=ααsin 1()[]O k k E -+=ααsin 1 and()[]O k k E dk E d -=ααcos 2122Then221222*11 αE dk Ed m o k k =⋅== or212*αE m =_______________________________________ 3.21(a) ()[]3/123/24lt dn m m m =*()()[]3/123/264.1082.04oom m =o dn m m 56.0=*(b)o o l t cnm m m m m 64.11082.02123+=+=*oo m m 6098.039.24+=o cn m m 12.0=*_______________________________________ 3.22(a) ()()[]3/22/32/3lh hh dp m m m +=*()()[]3/22/32/3082.045.0o om m +=[]o m ⋅+=3/202348.030187.0o dp m m 473.0=*(b) ()()()()2/12/12/32/3lh hh lh hh cpm m m m m ++=*()()()()om ⋅++=2/12/12/32/3082.045.0082.045.0 o cp m m 34.0=*_______________________________________ 3.23For the 3-dimensional infinite potential well, ()0=x V when a x <<0, a y <<0, and a z <<0. In this region, the wave equation is:()()()222222,,,,,,z z y x y z y x x z y x ∂∂+∂∂+∂∂ψψψ()0,,22=+z y x mEψ Use separation of variables technique, so let ()()()()z Z y Y x X z y x =,,ψSubstituting into the wave equation, we have222222zZXY y Y XZ x X YZ ∂∂+∂∂+∂∂ 022=⋅+XYZ mEDividing by XYZ , we obtain021*********=+∂∂⋅+∂∂⋅+∂∂⋅ mEz Z Z y Y Y x X XLet01222222=+∂∂⇒-=∂∂⋅X k x X k x X X xx The solution is of the form: ()x k B x k A x X x x cos sin +=Since ()0,,=z y x ψ at 0=x , then ()00=X so that 0=B .Also, ()0,,=z y x ψ at a x =, so that ()0=a X . Then πx x n a k = where ...,3,2,1=x n Similarly, we have2221y k y Y Y -=∂∂⋅ and 2221z k zZ Z -=∂∂⋅From the boundary conditions, we find πy y n a k = and πz z n a k = where...,3,2,1=y n and ...,3,2,1=z n From the wave equation, we can write022222=+---mE k k k z y xThe energy can be written as()222222⎪⎭⎫ ⎝⎛++==a n n n m E E z y x n n n z y x π _______________________________________ 3.24The total number of quantum states in the 3-dimensional potential well is given (in k-space) by()332a dk k dk k g T ⋅=ππ where222 mEk =We can then writemEk 2=Taking the differential, we obtaindE Em dE E m dk ⋅⋅=⋅⋅⋅⋅=2112121 Substituting these expressions into the density of states function, we have()dE E mmE a dE E g T ⋅⋅⋅⎪⎭⎫ ⎝⎛=212233 ππ Noting thatπ2h=this density of states function can be simplified and written as()()dE E m h a dE E g T ⋅⋅=2/33324π Dividing by 3a will yield the density of states so that()()E h m E g ⋅=32/324π _______________________________________ 3.25For a one-dimensional infinite potential well,222222k a n E m n ==*π Distance between quantum states()()aa n a n k k n n πππ=⎪⎭⎫ ⎝⎛=⎪⎭⎫ ⎝⎛+=-+11Now()⎪⎭⎫ ⎝⎛⋅=a dkdk k g T π2NowE m k n *⋅=21dE Em dk n⋅⋅⋅=*2211 Then()dE Em a dE E g n T ⋅⋅⋅=*2212 π Divide by the "volume" a , so ()Em E g n *⋅=21πSo()()()()()EE g 31341011.9067.0210054.11--⨯⋅⨯=π ()EE g 1810055.1⨯=m 3-J 1-_______________________________________ 3.26(a) Silicon, o n m m 08.1=*()()c nc E E h m E g -=*32/324π()dE E E h m g kTE E c nc c c⋅-=⎰+*232/324π()()kT E E c nc cE E h m 22/332/33224+*-⋅⋅=π()()2/332/323224kT hm n⋅⋅=*π ()()[]()()2/33342/33123210625.61011.908.124kT ⋅⋅⨯⨯=--π ()()2/355210953.7kT ⨯=(i) At 300=T K, 0259.0=kT eV()()19106.10259.0-⨯= 2110144.4-⨯=J Then ()()[]2/3215510144.4210953.7-⨯⨯=c g25100.6⨯=m 3- or 19100.6⨯=c g cm 3-(ii) At 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV()()19106.1034533.0-⨯= 21105253.5-⨯=J Then()()[]2/32155105253.5210953.7-⨯⨯=c g2510239.9⨯=m 3- or 191024.9⨯=c g cm 3-(b) GaAs, o nm m 067.0=*()()[]()()2/33342/33123210625.61011.9067.024kT g c ⋅⋅⨯⨯=--π ()()2/3542102288.1kT ⨯=(i) At 300=T K, 2110144.4-⨯=kT J ()()[]2/3215410144.42102288.1-⨯⨯=c g2310272.9⨯=m 3- or 171027.9⨯=c g cm 3-(ii) At 400=T K, 21105253.5-⨯=kT J ()()[]2/32154105253.52102288.1-⨯⨯=c g2410427.1⨯=m 3-181043.1⨯=c g cm 3-_______________________________________ 3.27(a) Silicon, o p m m 56.0=* ()()E E h mE g p-=*υυπ32/324()dE E E h mg E kTE p⋅-=⎰-*υυυυπ332/324()()υυυπE kTE pE E hm 32/332/33224-*-⎪⎭⎫ ⎝⎛-=()()[]2/332/333224kT hmp-⎪⎭⎫ ⎝⎛-=*π ()()[]()()2/33342/33133210625.61011.956.024kT ⎪⎭⎫ ⎝⎛⨯⨯=--π ()()2/355310969.2kT ⨯=(i)At 300=T K, 2110144.4-⨯=kT J ()()[]2/3215510144.4310969.2-⨯⨯=υg2510116.4⨯=m3-or 191012.4⨯=υg cm 3- (ii)At 400=T K, 21105253.5-⨯=kT J()()[]2/32155105253.5310969.2-⨯⨯=υg2510337.6⨯=m3-or 191034.6⨯=υg cm 3- (b) GaAs, o p m m 48.0=*()()[]()()2/33342/33133210625.61011.948.024kT g ⎪⎭⎫ ⎝⎛⨯⨯=--πυ ()()2/3553103564.2kT ⨯=(i)At 300=T K, 2110144.4-⨯=kT J()()[]2/3215510144.43103564.2-⨯⨯=υg2510266.3⨯=m 3- or 191027.3⨯=υg cm 3-(ii)At 400=T K, 21105253.5-⨯=kT J()()[]2/32155105253.53103564.2-⨯⨯=υg2510029.5⨯=m 3-or 191003.5⨯=υg cm 3-_______________________________________ 3.28(a) ()()c nc E E h m E g -=*32/324π()()[]()c E E -⨯⨯=--3342/33110625.61011.908.124πc E E -⨯=56101929.1 For c E E =; 0=c g1.0+=c E E eV; 4610509.1⨯=c g m 3-J 1-2.0+=c E E eV; 4610134.2⨯=m 3-J 1-3.0+=c E E eV; 4610614.2⨯=m 3-J 1- 4.0+=c E E eV; 4610018.3⨯=m 3-J 1- (b) ()E E h m g p-=*υυπ32/324()()[]()E E -⨯⨯=--υπ3342/33110625.61011.956.024E E -⨯=υ55104541.4 For υE E =; 0=υg1.0-=υE E eV; 4510634.5⨯=υg m 3-J 1-2.0-=υE E eV; 4510968.7⨯=m 3-J 1-3.0-=υE E eV; 4510758.9⨯=m 3-J 1-4.0-=υE E eV; 4610127.1⨯=m 3-J 1-_______________________________________ 3.29(a) ()()68.256.008.12/32/32/3=⎪⎭⎫ ⎝⎛==**pnc m m g g υ(b) ()()0521.048.0067.02/32/32/3=⎪⎭⎫ ⎝⎛==**pncmm g g υ_______________________________________3.30 Plot_______________________________________ 3.31(a) ()()()!710!7!10!!!-=-=i i i i i N g N g W()()()()()()()()()()()()1201238910!3!7!78910===(b) (i) ()()()()()()()()12!10!101112!1012!10!12=-=i W 66=(ii) ()()()()()()()()()()()()1234!8!89101112!812!8!12=-=i W 495=_______________________________________ 3.32()⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F exp 11(a) kT E E F =-, ()()⇒+=1exp 11E f()269.0=E f (b) kT E E F 5=-, ()()⇒+=5exp 11E f()31069.6-⨯=E f(c) kT E E F 10=-, ()()⇒+=10exp 11E f ()51054.4-⨯=E f_______________________________________ 3.33()⎪⎪⎭⎫ ⎝⎛-+-=-kT E E E f F exp 1111or()⎪⎪⎭⎫ ⎝⎛-+=-kT E E E f F exp 111(a) kT E E F =-, ()269.01=-E f (b) kT E E F 5=-, ()31069.61-⨯=-E f(c) kT E E F 10=-, ()51054.41-⨯=-E f_______________________________________3.34(a) ()⎥⎦⎤⎢⎣⎡--≅kT E E f F F exp c E E =; 61032.90259.030.0exp -⨯=⎥⎦⎤⎢⎣⎡-=F f 2kT E c +; ()⎥⎦⎤⎢⎣⎡+-=0259.020259.030.0exp F f 61066.5-⨯=kT E c +; ()⎥⎦⎤⎢⎣⎡+-=0259.00259.030.0exp F f 61043.3-⨯=23kT E c +; ()()⎥⎦⎤⎢⎣⎡+-=0259.020259.0330.0exp F f 61008.2-⨯=kT E c 2+; ()()⎥⎦⎤⎢⎣⎡+-=0259.00259.0230.0exp F f 61026.1-⨯=(b) ⎥⎦⎤⎢⎣⎡-+-=-kT E E f F F exp 1111()⎥⎦⎤⎢⎣⎡--≅kT E E F exp υE E =; ⎥⎦⎤⎢⎣⎡-=-0259.025.0exp 1F f 51043.6-⨯= 2kT E -υ; ()⎥⎦⎤⎢⎣⎡+-=-0259.020259.025.0exp 1F f 51090.3-⨯=kT E -υ; ()⎥⎦⎤⎢⎣⎡+-=-0259.00259.025.0exp 1F f 51036.2-⨯=23kTE -υ; ()()⎥⎦⎤⎢⎣⎡+-=-0259.020259.0325.0exp 1F f 51043.1-⨯= kT E 2-υ;()()⎥⎦⎤⎢⎣⎡+-=-0259.00259.0225.0exp 1F f 61070.8-⨯=_______________________________________3.35()()⎥⎦⎤⎢⎣⎡-+-=⎥⎦⎤⎢⎣⎡--=kT E kT E kT E E f F c F F exp exp and()⎥⎦⎤⎢⎣⎡--=-kT E E f F F exp 1 ()()⎥⎦⎤⎢⎣⎡---=kT kT E E F υexp So ()⎥⎦⎤⎢⎣⎡-+-kT E kT E F c exp ()⎥⎦⎤⎢⎣⎡+--=kT kT E E F υexp Then kT E E E kT E F F c +-=-+υOr midgap c F E E E E =+=2υ_______________________________________ 3.3622222ma n E n π =For 6=n , Filled state()()()()()2103122234610121011.92610054.1---⨯⨯⨯=πE18105044.1-⨯=Jor 40.9106.1105044.119186=⨯⨯=--E eV For 7=n , Empty state()()()()()2103122234710121011.92710054.1---⨯⨯⨯=πE1810048.2-⨯=Jor 8.12106.110048.219187=⨯⨯=--E eV Therefore 8.1240.9<<F E eV_______________________________________ 3.37(a) For a 3-D infinite potential well()222222⎪⎭⎫ ⎝⎛++=a n n n mE z y x π For 5 electrons, the 5th electron occupies the quantum state 1,2,2===z y x n n n ; so()2222252⎪⎭⎫ ⎝⎛++=a n n n m E z y x π()()()()()21031222223410121011.9212210054.1---⨯⨯++⨯=π1910761.3-⨯=Jor 35.2106.110761.319195=⨯⨯=--E eV For the next quantum state, which is empty, the quantum state is 2,2,1===z y x n n n . This quantum state is at the same energy, so 35.2=F E eV(b) For 13 electrons, the 13th electronoccupies the quantum state 3,2,3===z y x n n n ; so ()()()()()2103122222341310121011.9232310054.1---⨯⨯++⨯=πE 1910194.9-⨯=Jor 746.5106.110194.9191913=⨯⨯=--E eVThe 14th electron would occupy the quantum state 3,3,2===z y x n n n . This state is at the same energy, so 746.5=F E eV_______________________________________ 3.38The probability of a state at E E E F ∆+=1 being occupied is()⎪⎭⎫ ⎝⎛∆+=⎪⎪⎭⎫ ⎝⎛-+=kT E kT E E E f F exp 11exp 11111 The probability of a state at E E E F ∆-=2being empty is()⎪⎪⎭⎫ ⎝⎛-+-=-kT E E E f F 222exp 1111⎪⎭⎫ ⎝⎛∆-+⎪⎭⎫ ⎝⎛∆-=⎪⎭⎫ ⎝⎛∆-+-=kT E kT E kT E exp 1exp exp 111or()⎪⎭⎫ ⎝⎛∆+=-kT E E f exp 11122so ()()22111E f E f -= Q.E.D. _______________________________________3.39(a) At energy 1E , we want01.0exp 11exp 11exp 1111=⎪⎪⎭⎫ ⎝⎛-+⎪⎪⎭⎫ ⎝⎛-+-⎪⎪⎭⎫ ⎝⎛-kT E E kT E E kT E E F F FThis expression can be written as01.01exp exp 111=-⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-+kT E E kT E E F F or()⎪⎪⎭⎫⎝⎛-=kT E E F 1exp 01.01Then()100ln 1kT E E F += orkT E E F 6.41+= (b)At kT E E F 6.4+=, ()()6.4exp 11exp 1111+=⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F which yields()01.000990.01≅=E f_______________________________________ 3.40 (a)()()⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--=0259.050.580.5exp exp kT E E f F F 61032.9-⨯=(b) ()060433.03007000259.0=⎪⎭⎫⎝⎛=kT eV31098.6060433.030.0exp -⨯=⎥⎦⎤⎢⎣⎡-=F f (c) ()⎥⎦⎤⎢⎣⎡--≅-kT E E f F F exp 1 ⎥⎦⎤⎢⎣⎡-=kT 25.0exp 02.0or 5002.0125.0exp ==⎥⎦⎤⎢⎣⎡+kT ()50ln 25.0=kTor()()⎪⎭⎫⎝⎛===3000259.0063906.050ln 25.0T kT which yields 740=T K_______________________________________ 3.41 (a)()00304.00259.00.715.7exp 11=⎪⎭⎫ ⎝⎛-+=E for 0.304%(b) At 1000=T K, 08633.0=kT eV Then()1496.008633.00.715.7exp 11=⎪⎭⎫ ⎝⎛-+=E for 14.96%(c) ()997.00259.00.785.6exp 11=⎪⎭⎫ ⎝⎛-+=E for 99.7% (d)At F E E =, ()21=E f for all temperatures_______________________________________ 3.42(a) For 1E E =()()⎥⎦⎤⎢⎣⎡--≅⎪⎪⎭⎫ ⎝⎛-+=kT E E kTE E E fF F11exp exp 11Then()611032.90259.030.0exp -⨯=⎪⎭⎫ ⎝⎛-=E fFor 2E E =, 82.030.012.12=-=-E E F eV Then()⎪⎭⎫ ⎝⎛-+-=-0259.082.0exp 1111E for()⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛---≅-0259.082.0exp 111E f141078.10259.082.0exp -⨯=⎪⎭⎫ ⎝⎛-=(b) For 4.02=-E E F eV,72.01=-F E E eVAt 1E E =,()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.072.0exp exp 1kT E E E f F or()131045.8-⨯=E f At 2E E =,()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1 ⎪⎭⎫ ⎝⎛-=0259.04.0expor()71096.11-⨯=-E f_______________________________________ 3.43(a) At 1E E =()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.030.0exp exp 1kT E E E f F or()61032.9-⨯=E fAt 2E E =, 12.13.042.12=-=-E E F eV So()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1 ⎪⎭⎫ ⎝⎛-=0259.012.1expor()191066.11-⨯=-E f (b) For 4.02=-E E F ,02.11=-F E E eV At 1E E =,()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.002.1exp exp 1kT E E E f F or()181088.7-⨯=E f At 2E E =,()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1 ⎪⎭⎫ ⎝⎛-=0259.04.0expor ()71096.11-⨯=-E f_______________________________________ 3.44()1exp 1-⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+=kTE E E f Fso()()2exp 11-⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+-=kT E E dE E df F⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫⎝⎛⨯kT E E kT F exp 1or()2exp 1exp 1⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫⎝⎛-=kT E E kT E E kT dE E df F F (a) At 0=T K, For()00exp =⇒=∞-⇒<dE dfE E F()0exp =⇒+∞=∞+⇒>dEdfE E FAt -∞=⇒=dEdfE E F(b) At 300=T K, 0259.0=kT eVFor F E E <<, 0=dE dfFor F E E >>, 0=dEdfAt F E E =,()()65.91110259.012-=+⎪⎭⎫ ⎝⎛-=dE df (eV)1-(c) At 500=T K, 04317.0=kT eVFor F E E <<, 0=dE dfFor F E E >>, 0=dEdfAt F E E =,()()79.511104317.012-=+⎪⎭⎫ ⎝⎛-=dE df (eV)1- _______________________________________ 3.45(a) At midgap E E =,()⎪⎪⎭⎫⎝⎛+=⎪⎪⎭⎫ ⎝⎛-+=kT E kTE E E f g F2exp 11exp 11Si: 12.1=g E eV, ()()⎥⎦⎤⎢⎣⎡+=0259.0212.1exp 11E for()101007.4-⨯=E fGe: 66.0=g E eV ()()⎥⎦⎤⎢⎣⎡+=0259.0266.0exp 11E for()61093.2-⨯=E f GaAs: 42.1=g E eV ()()⎥⎦⎤⎢⎣⎡+=0259.0242.1exp 11E for()121024.1-⨯=E f(b) Using the results of Problem 3.38, the answers to part (b) are exactly the same as those given in part (a)._______________________________________3.46(a) ()⎥⎦⎤⎢⎣⎡--=kT E E f F F exp ⎥⎦⎤⎢⎣⎡-=-kT 60.0exp 108or ()810ln 60.0+=kT()032572.010ln 60.08==kT eV ()⎪⎭⎫⎝⎛=3000259.0032572.0Tso 377=T K(b) ⎥⎦⎤⎢⎣⎡-=-kT 60.0exp 106()610ln 60.0+=kT()043429.010ln 60.06==kT ()⎪⎭⎫⎝⎛=3000259.0043429.0Tor 503=T K_______________________________________ 3.47(a) At 200=T K,()017267.03002000259.0=⎪⎭⎫⎝⎛=kT eV⎪⎪⎭⎫ ⎝⎛-+==kT E E f F F exp 1105.019105.01exp =-=⎪⎪⎭⎫ ⎝⎛-kT E E F()()()19ln 017267.019ln ==-kT E E F 05084.0=eV By symmetry, for 95.0=F f , 05084.0-=-F E E eVThen ()1017.005084.02==∆E eV (b) 400=T K, 034533.0=kT eV For 05.0=F f , from part (a),()()()19ln 034533.019ln ==-kT E E F 10168.0=eVThen ()2034.010168.02==∆E eV _______________________________________。