聚多巴胺亲水改性 -锂硫电池
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文献汇报
2015.4.18
Leabharlann Baidu
2015/10/52012-10-12
2015/10/52012-10-12
Disadvantage hydrophobic surface, which seriously hinder the adequate uptake and diffusion of organic electrolytes within the separators. Moreover, it is difficult to completely ensure the electrical isolation between the cathode and anode due to their poor thermal shrinkage, leading to low capacity, poor power capability and security risks upon cycling. Polydopamine Polydopamine, with a molecular structure that incorporates many functional groups such as catechol, amine and imine, can be easily deposited on all types of inorganic and organic substrates, even super-hydrophobic surfaces.
2015/10/52012-10-12
Results
S的利用率提高
typical discharge potential plateau at about 2.30 V and 2.0 V (vs Li/Li+) can be easily observed in the initial cycle for the two comparative cells, assigned to the reduction from sulfur to lithium polysulfides and further reduction to Li2S2/Li2S and in consistent with the CVs. For the cell using PDA modified separator, obvious decreasing of discharge capacity can be observed in the second cycle, which may relate to the dissolution of polysulfide and will be further disscussed in the below
2015/10/52012-10-12
Results
It can be seen that only the peak of C1s can be observed, while for the PDA modified seperator, two additional peaks attributed to N1s and O1s appear at 400.4 and 532.7 eV, respectively, indicating that PDA coating layer is generated on the surface of seperator to produce a hydrophilic seperator
2015/10/52012-10-12
Experimental
• • • • S:AB=6:4 300r/h球磨 2h put it into a PTFE container filled with argon container was heated at 155 °C for 12 h cooled down to room temperature
2015/10/52012-10-12
2015/10/52012-10-12
S/AB composite
• • • •
S/C composite :acetylene black:PTFE=7:2:1with ethanol as a dispersant compressed into a thin piec cut into a disk film of 8mm in diameter and 1.5~1.8 mg in weight dried in the oven at 55 °C for 12 h
2015/10/52012-10-12
Two
Results
high-rate charge/discharge capability cycling stability a higher coulombic efficiency
2015/10/52012-10-12
Results
It is obvious that the cell using the PDA modified seperator can obvious decrease the charge-transfer resistance of the sulfur cathodes as compared to bare separator, especially in the second discharge state. polysulfide will dissolved into the electrolyte and more and more Li2S2/Li2S will be deposited on the cathodes, leading to the loss of active materials and fast dropping of capacity.
sulfur cathode
2015/10/52012-10-12
The surface modification of separators
separators were soaked into 50 ml methanol solution (30 minutes) put into the dopamine solution(24h) rinsed with distilled water for several times dried at 30 °C for 12 h.
2015/10/52012-10-12
Results
• wetting test
after dropping an organic electrolyte [1 wt% LiNO3 and 1.0 M 30 LiN(CF3SO2)2 dissolved in DOL/TEGDME, v/v= 1:1)] onto the surface of the separator, the droplet can hardly wet the bare separator (left), whereas the PDA modified separato (right) is fully wetted immediately.
2015/10/52012-10-12
Conclusion
• PDA modified hydrophilic separators are prepared by a simple dipping method • Due to the PDA modification, the surface character of the polyolefin-based separators changes from hydrophobicity to hydrophily, thus resulting in the improvement of uptake amounts of liquid electrolytes and ionic conductivity, • Accompanying with remarkably enhancement of charge/discharge capacities, cycling performance, and high-rate capability • At 0.2 C rate, the initial discharge capacity of the cell using hydrophilic separator is 1217 mAh/g , and it can be stably retained at 1020.3 mAh /g, showing obvious advantages over the conventional hydrophobic separator. • At the 1 C rate, a high reversible capacity of 548.3 mAh/g can also be obtained, while it gets only about 373.5 mAh/g for the cell using hydrophobic separator.
2015/10/52012-10-12
Results
However, for the cell using bare separator, two cathodic peak appear at about 2.25 and 1.80 V (vs Li/Li+) (Fig. 6b), which are slightly lower than the aforementioned results. In addition, two overlapped anodic peak potentials in the voltage range of 2.6-2.7 V can be observed, suggesting a twoplateauoxidation process occurred in the anodic scan, which is different with the only one broad anodic peak potential at 2.60 V for the cell using PDA modified separator.
2015/10/52012-10-12
Results
•
•
It can be observed from Fig. 1 that the weight loss of the composite begin from about 150 °C, and finished over 400 °C, due to evaporation of sulfur from the meso/micropores of the host carbon. It is shown that the carbon black appears as a loose particle aggregated of some uniform and small carbon spheres. For the S/C composite with 60 wt% sulfur loading, the aggregates become denser and the partical size become bigger as compared to the carbon black.
2015.4.18
Leabharlann Baidu
2015/10/52012-10-12
2015/10/52012-10-12
Disadvantage hydrophobic surface, which seriously hinder the adequate uptake and diffusion of organic electrolytes within the separators. Moreover, it is difficult to completely ensure the electrical isolation between the cathode and anode due to their poor thermal shrinkage, leading to low capacity, poor power capability and security risks upon cycling. Polydopamine Polydopamine, with a molecular structure that incorporates many functional groups such as catechol, amine and imine, can be easily deposited on all types of inorganic and organic substrates, even super-hydrophobic surfaces.
2015/10/52012-10-12
Results
S的利用率提高
typical discharge potential plateau at about 2.30 V and 2.0 V (vs Li/Li+) can be easily observed in the initial cycle for the two comparative cells, assigned to the reduction from sulfur to lithium polysulfides and further reduction to Li2S2/Li2S and in consistent with the CVs. For the cell using PDA modified separator, obvious decreasing of discharge capacity can be observed in the second cycle, which may relate to the dissolution of polysulfide and will be further disscussed in the below
2015/10/52012-10-12
Results
It can be seen that only the peak of C1s can be observed, while for the PDA modified seperator, two additional peaks attributed to N1s and O1s appear at 400.4 and 532.7 eV, respectively, indicating that PDA coating layer is generated on the surface of seperator to produce a hydrophilic seperator
2015/10/52012-10-12
Experimental
• • • • S:AB=6:4 300r/h球磨 2h put it into a PTFE container filled with argon container was heated at 155 °C for 12 h cooled down to room temperature
2015/10/52012-10-12
2015/10/52012-10-12
S/AB composite
• • • •
S/C composite :acetylene black:PTFE=7:2:1with ethanol as a dispersant compressed into a thin piec cut into a disk film of 8mm in diameter and 1.5~1.8 mg in weight dried in the oven at 55 °C for 12 h
2015/10/52012-10-12
Two
Results
high-rate charge/discharge capability cycling stability a higher coulombic efficiency
2015/10/52012-10-12
Results
It is obvious that the cell using the PDA modified seperator can obvious decrease the charge-transfer resistance of the sulfur cathodes as compared to bare separator, especially in the second discharge state. polysulfide will dissolved into the electrolyte and more and more Li2S2/Li2S will be deposited on the cathodes, leading to the loss of active materials and fast dropping of capacity.
sulfur cathode
2015/10/52012-10-12
The surface modification of separators
separators were soaked into 50 ml methanol solution (30 minutes) put into the dopamine solution(24h) rinsed with distilled water for several times dried at 30 °C for 12 h.
2015/10/52012-10-12
Results
• wetting test
after dropping an organic electrolyte [1 wt% LiNO3 and 1.0 M 30 LiN(CF3SO2)2 dissolved in DOL/TEGDME, v/v= 1:1)] onto the surface of the separator, the droplet can hardly wet the bare separator (left), whereas the PDA modified separato (right) is fully wetted immediately.
2015/10/52012-10-12
Conclusion
• PDA modified hydrophilic separators are prepared by a simple dipping method • Due to the PDA modification, the surface character of the polyolefin-based separators changes from hydrophobicity to hydrophily, thus resulting in the improvement of uptake amounts of liquid electrolytes and ionic conductivity, • Accompanying with remarkably enhancement of charge/discharge capacities, cycling performance, and high-rate capability • At 0.2 C rate, the initial discharge capacity of the cell using hydrophilic separator is 1217 mAh/g , and it can be stably retained at 1020.3 mAh /g, showing obvious advantages over the conventional hydrophobic separator. • At the 1 C rate, a high reversible capacity of 548.3 mAh/g can also be obtained, while it gets only about 373.5 mAh/g for the cell using hydrophobic separator.
2015/10/52012-10-12
Results
However, for the cell using bare separator, two cathodic peak appear at about 2.25 and 1.80 V (vs Li/Li+) (Fig. 6b), which are slightly lower than the aforementioned results. In addition, two overlapped anodic peak potentials in the voltage range of 2.6-2.7 V can be observed, suggesting a twoplateauoxidation process occurred in the anodic scan, which is different with the only one broad anodic peak potential at 2.60 V for the cell using PDA modified separator.
2015/10/52012-10-12
Results
•
•
It can be observed from Fig. 1 that the weight loss of the composite begin from about 150 °C, and finished over 400 °C, due to evaporation of sulfur from the meso/micropores of the host carbon. It is shown that the carbon black appears as a loose particle aggregated of some uniform and small carbon spheres. For the S/C composite with 60 wt% sulfur loading, the aggregates become denser and the partical size become bigger as compared to the carbon black.