常用试剂的英文缩写

ABO 2,7,8-Trioxabicyclo[

Ac Acetyl

ACBZ 4-Azidobenzyloxycarbonyl

ACE α-Chloroethoxycarbonyl

AcHmb 2-Acetoxy-4-methoxybenzyl Acm Acetamidomethyl

Ad 1-Adamantyl

Adoc 1-Adamantyloxycarbonyl

Adpoc

1-(1-Adamantyl)-1-methylethoxycarbo nyl

AIBN 2,2’-Azobis(2-methylpropionitrile) or Azobisisobutyronitrile

All Allyl

Alloc Alloxycarbonyl

Als Allylsulfonyl

AMB 2-(Acetoxymethyl)benzoyl

AN 4-Methoxyphenyl or anisyl

Anpe 2-(4-Acetyl-2-nitrophenyl)ethyl AO Atomic orbital

AOC Allyloxycarbonyl

p-AOM p-Anisyloxymrthyl or (4-methoxyphenoxy)methyl

Ar Aryl

atm Atmosphere

ATP Adenosine 5’-triphosphate ATPase Adenosinetriphosphatase

Azb p-Azidobenzyl

Bam Benzamidomethyl

BBA Butane-2,3-bisacetal

BBn p-Bromobenzyl

9-BBN 9-Borabicyclo[

BDMS Biphenyldimethylsilyl

BDT 1,3-Benzodithiolan-2-yl

Bic 5-Benzisoxazolymethoxycarbonyl Bmpc

2,4-Dimethylthiophenoxycarbonyl Bmpm

1,1-Bis(4-methoxyphenyl)-1’-pyrenyl methyl

BMS Borane-methyl sulfide

Bn Benzyl

BOC t-Butylcarbonyl t-BOC t-Butylcarbonyl

BOM Benzyloxymethyl

BOP

Benzotriazol-1-yloxytris(dimethylamin o) phosphonium hexafluorophosphate BOP-Cl

N,N-Bis(2-oxo-3-oxazolidinyl)phosphin ic

bp Boiling point

Bpoc

1-methyl-1-(4-biphenyl)ethoxycarbon

yl

Bpy 2,2’-Bipyridyl

br Broad (spectral)

BSA Bistrimethylsilyl acetamide

Bt Benzotriazo-1-yl or 1-benzotriazolyl BTBA Benzyltributylammonium chloride Bu Butyl

s-BU Sec-Butyl

t-Bu tert-Butyl

Bum t-Butoxymethyl

t-Bumeoc

1-(3,5-Di-t-butylphenyl)-1-methyletho xycarbonyl

Bz Benzoxyl

oC Degree Celsius

calcd Calculated

Cam Carboxyamidomethyl

cAMP Adenosine cyclic 3’,5’-phosphate CAN Cerium(IV) ammonium nitrate Cbz Benzyloxycarbonyl

CD Circular dichrosim

CDI 1,1’-Carbonyldiimidazole

Cee 1-(2-Chloroethoxy)ethyl

CI Chemical ionization (in MS) Configuration interaction (in MO theory) CIDNP Chemically induced dynamic nuclear polarization

cm Centmeter

CMPI 2-Chloro-1-methylpyridium chloride

CNDO Complete neglect of differential overlap

Coc Cinnamyloxycarbonyl

COD 1,5-Cyclooctadiene

concd Concentrated

COSY Correlation spectroscopy

COT Cyclooctatetrene

Cp Cyclopentadienyl

CPTr

4,4’,4”-Tris(4,5-dichlorophthalimido)rip henylmethyl

CSA Camphorsulfonic acid

CTMP

1-[(2-Chloro-4-methyl)phenyl]-4-met hoxypiperidin-4-yl

Cys Cysteine

δ Chemical shift in ppm

d Day, doublet (spectral)

DABCO 1,4-Diazabicyclo[

DAM Di(4-methoxyphenyl)methyl DAST Diethylaminosulfurtrifluoride

DB-t-BOC

1,1-Dmethyl-2,2-dibromoethoxycarbo nyl

DBD-Tmoc

2,7-Di-t-butyl[9-(10,10-dioxo-10,10,1 0,10-tetrahydrothioxanthyl)methy lcarbonyl

DBN 1,5-Diazabicyclo[

DBU 1,8-Diazabicyclo[

DCC Dicyclohexylcarbodiimide DCMME Dichloromethylammonium chloride

DDQ

2,3-Dichloro-5,6-dicyano-1,4-benzoqui none

de Diastereomeric excess

DEAD Diethylazodicarboxylate

DEIPS Diethylisopropylsilyl

DEPT Distortionless enhancement by polarization transfer

DG Diacyl glycerol

DIAD Diisopropyl azodicarboxylate DIBAH Diisobutylalumium hydride DIBAL Diisobutylaluminum hydride Dim 2-(1,3-Dithianyl)methyl DIPEA Diisopropylethylamine

DIPT Diisopropyl tartrate

DMAC Dimethylacetamide

DMAD Diethyl acetylenedicarboxylate DMAP 4-Dimethylaminopyridine

DME Dimethoxyethane

DMF N,N-Dimethylformamide

DMIPS Dimethylisopropylsilyl

Dmoc Dithianylmethoxycarbonyl

DMP Dimethylpropane

Dmp Dimethylphosphinyl

DMPM 3,4-Dimethoxybenzyl

DMPU

1,3-Dimethyl-3,4,5,6-tetrhydro-2(1H)-pyrimidinone

DMS Dimethyl sulfate

DMSO Dimethyl sulfoxide or methyl sulfoxide

DMT Dimethoxytrityl

DMTr

Di(p-methoxyphenyl)phenylmethyl DNA Deoxyribonucleic acid

DNB p,p’-Dinitrobenzhyrryl

DNMBS

4-(4’,8’-Dimethoxynaphthylmethyl)ben zenesulfonyl

DNP 2,4-Dinitrophenyl

Dobz

p-(Dihydroxyboryl)benzyloxycarbonyl DPM Diphenylmethyl

DPMS Diphenylmethylsilyl

Dpp Diphenylphosphinyl

DPPA Diphenylphosphoryl azide

Dppe 2-(Diphenylphosphino)ethyl Dppm (Diphenyl-4-pyridyl)methyl

Dpt Diphenylthiophosphinyl

DTBMS Di-t-butylsilylene

Dts Dithiasuccinimidyl

E1 Unimolecular elimination

E2 Bimolecular elimination

ED50 Dose that is effective in 50% of test subjects

EDC