锂动力电池添加剂LiTFSI-双三氟甲烷磺酰亚胺锂
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Electronics Markets Materials Division 3M China R&D Center Building 800, 222 TianLin Road, Shanghai, China 200233 Tel: 86-21-2210-5425 Mobile Phone:86-13761208042 Fax:86-21-22105036 eFax: 86-21-6209-6100 ext 23409 E-mail: azhang11@mmm.com
1
TGA
Copyright © 2006, 3M.
All rights reserved.
HQ115 : (CF3SO2)2NLi
LiPF6
Nitrogen 10degC/min.
ߚ ᵤ ᳆ ඃ ᇍᴵ ᯱӊ фϡ ້ৠ Ոₑ ᡅ ᦤ ߾ ˖᪩ ѻ ક Ո⌟ ᪙ ᭄ ᰃ Ѣ ៥ Ӏ ᩨ Ў ৃ ☤ Ո ܄ Ϟ Ոˈᙼ Ո ᵰ ৃ ࿁ ϵ Ѣ ⌟ ᪙ ᮍ ⊩ ໐ ᳝ ᠔ ߎ ܹ DŽᙼ ᖙ / ᪈ Ԅ ᑊ ܲ ᅮ ᪩ ѻ ક ᰃ ৺ Ệ ড় ᙼ Ոᑨ Ϭ DŽϵ Ѣ ѻ ક ՓϬ Ոᴵ ӊ ϡ ៥ Ӏ Ո ࠊ ᴵ☢ ӊ⊩ Пᕟ ࡅݙϨℶ বˈ᭄ ᳝ᵕ ᪅ ˈϟ Ẵᯢ ֱᙼ ᪅ᬊ ᇚ᳓ҷ ᠔ ᯊ ᳝ѻ ᯢ ક ߾े ᄬ ڌ ߾ Ոֱ ᪅˄ ࣙ ϟ ᣀ ˈଚ 0 ⏄ ଃ ᗻ ϔ ՈỆ Н ড় ࡵ Ѣ ҹĽ ঞ ᅮ ᙼ Ϭ ଃ Ộ ϔ ՈֱՈᬥ ᪅ ⌢ ˅˖ ┨ ᪅ ࠄ ѻ ક ┻ Ոࠡ ᦤ ˈ ህ ᰃ։ ϵᴗ ˈ 0 ݊ އᅮ Ҫ ˈӏ ԩ ᤶ ⊩ ѻ ᕟ ક ᜥ ᣝ ᑇ ѻ ˊ ક ՈᯱՈӏ ф ԩ Ӌ ָ Ḑ Ễ ǃⒸℒ DŽᇍ ǃĽ Ѣ ⅞ ạ ǃيড ֱ থ ᪅ Ոǃᴵ ϵ ℒ ℸ ᏺ ড় ᴹ ৠ Ո ˈৢ ණ ᤳѢ ᆇѓ ˄ ᗑ ࣙǃϹᣀ ḐԚ ᯧϡ ӏ└ Ѣ ߽ ⍺ ᤳ ༅ ǃଚ ᥍ ଚ Ϯ ᴎ Ӯ ˅ˈ ӏ ԩ ᚙ މϟ 0 ഛ ϡ ᡓ ᢙ ᯧ ӏ DŽ
LiClO4 LiAsF6 SEI Li N (SO2CF3)2 287 236 <0.5 wt % ~7.5 Na 1% pH Al B Ca Cl- F- Fe Ni K Si SO42HQ-115 HQ-115 25 % 1 356 <25 50 63 63 63 50 63 46 56 TGA HQ-115 375
3M
Ϲᢧ⎆ி߫˄ ˅
HQ-115
3
FluoradTM
Ѡ ˄ ϝ ⇳ ϶ ‴ ˅ Ѯ ྾ ⏆ Ϲ ᢧ⎆⏏ࡴࠖ
LiN(SO2CF3)2
ҟ Ľ⚍ Ӭ ĭˊ ൟ ᗻՈ ᯬ ⒊ᢧᗻ
ࣷᅮᗻ
Ѡ˄ϝ⇳ࡴ ࠖ϶ DŽ ‴ ˅Ѯ ྾ ⏆ Ϲᢧ⎆֔ ᰃ ϔ ᮄ ൟ Ո Ѣ ⏆ Ϲ ∴ Ո᳝ ᴎ Ϲᢧ⎆Ո⏏ ᕾ ᳝ ɳ ᴎ ӣ ࡿ ᅝ ᄤ ⌟ ᳝ ᪙ ᕜ ᜬᯢᔎ Ո݅ᴀ ֔ Ӌ ⏲ ᳝ ˈӬ ᓖ ℸ ՈϹ࣪ ᄺ ࣷ ᅮ ᗻ DŽ ᜬɴ ߎ Ӭ ᓖ Ո໔⛁ ߚ ᢧᗻ DŽ ּ Ԑ Ԛ ᮴ ࣷ ᅮ ᗻ ᅝ ܼ ᗻ ⒲ L DŽ ᇐᬍ Ϲɋ Ϣ ℷ ᯣ ᵕ Ո ၠ ࣷᡥ ࠊᅮ ⇨ℷ ԧᯣ ѻᵕ ϣА ☦ ᬍᬍᬍ ᄬʌᕾ ⏽ټɳ ᗻᗻᗻ ࿁࿁࿁ ࣪ߚ ᄺᄤ ৡᓣ ࢴ Ѡ˄ϝ⇳ ϶ ‴ ˅Ѯ ྾ ⏆ ߚ ᄤᢆ ₓ Ձ ᄶ ୍ ˄ৃ ⒊ ᢧ˅ X∈ ߚ⚍ ₓ ć ∈ ⒊ ⎆Ո ؐ ҙₓࡿᄤ ˈˈˈ ˈ ˈ ˈ ˈ ˈ ˈ ˈ ϟ ᜬ߫ߎ ࠄ ṇ ⒊ ད ࠖ ՈϹᇐ Ё Ո⒊ ɋ ᢧᗻଡ଼DŽᑺ DŽ ൟ Ո⒊ ϟ ߫⒊ᢧᑺ ࠖ ᰃ Ё Ո⒊ ćՈ⌟ ᢧᗻ ᰃ ᪙ Ӭ ؐDŽ ᓖ Ոˈ ℸ ৃ ҹ⏋њ ড় ՓϬ ҹẂ ᜬ ⒊ˈࠖ Ѡᙊ ᇆ ⛋ ⒊ ᢧᗻ ˄ ԧ ˅ Ѡ⇻ ᴖ ɳ Э ⛋ ¤ ϕ ݙ ″ ѠЭ ⁞ ݷЭ ‼‼ Ѡ϶ ″ Э ″ ᓖ϶ ϭϕ ⁞⁞ ϭಯ ⛃⇶ ݷਟ ‼ୗ ″ ᰒ ߾ ᳝ Ӭ ᓖ Ո⛁ ࣷ ᅮ ᗻ ˈ ൪ ćDŽ7 * $ ᳆ ඃ ᢅ DŽ
3M™ Fluorad
(HQ-115)
Copyright © 2006, 3M.
All rights reserved.
3M
Ϲᢧ⎆ி߫˄ ˅
HQ-115
wk.baidu.com
ሔ‑ᮍ ᑆ© ѻકټᄬ
Ў ⏏ ࡴ ࠖ ՓϬ ˈ⏏ ࡴ ₓ Ў ˄Z W ˅DŽ ᴀ ક ᯧ ╂⒊ć⚬ ᢧDŽ ℸ ՓϬ ᴀ ક ࠡ ᖙ / ܜ ᑆ © DŽᑆ © ໘ ˊ Ꮉ ᄾ Ў ף ा ź ᗕ ϟ ⚸ Ⴗ ⒵ ᱷ ∈ ߚ ᡅ ∖ Ў ℶ DŽ ᴀ ક ϡ ՓϬ ᯊ ᪻ ټᄬ ᅸ ⏽ ϟ ᆚ ⒱ ᆍ ఼ Ё ˈὃ ܡ ╂DŽ
Electronics Markets Materials Division 3M China R&D Center Building 800, 222 TianLin Road, Shanghai, China 200233 Tel: 86-21-2210-5425 Mobile Phone:86-13761208042 Fax:86-21-22105036 eFax: 86-21-6209-6100 ext 23409 E-mail: azhang11@mmm.com
1
TGA
Copyright © 2006, 3M.
All rights reserved.
HQ115 : (CF3SO2)2NLi
LiPF6
Nitrogen 10degC/min.
ߚ ᵤ ᳆ ඃ ᇍᴵ ᯱӊ фϡ ້ৠ Ոₑ ᡅ ᦤ ߾ ˖᪩ ѻ ક Ո⌟ ᪙ ᭄ ᰃ Ѣ ៥ Ӏ ᩨ Ў ৃ ☤ Ո ܄ Ϟ Ոˈᙼ Ո ᵰ ৃ ࿁ ϵ Ѣ ⌟ ᪙ ᮍ ⊩ ໐ ᳝ ᠔ ߎ ܹ DŽᙼ ᖙ / ᪈ Ԅ ᑊ ܲ ᅮ ᪩ ѻ ક ᰃ ৺ Ệ ড় ᙼ Ոᑨ Ϭ DŽϵ Ѣ ѻ ક ՓϬ Ոᴵ ӊ ϡ ៥ Ӏ Ո ࠊ ᴵ☢ ӊ⊩ Пᕟ ࡅݙϨℶ বˈ᭄ ᳝ᵕ ᪅ ˈϟ Ẵᯢ ֱᙼ ᪅ᬊ ᇚ᳓ҷ ᠔ ᯊ ᳝ѻ ᯢ ક ߾े ᄬ ڌ ߾ Ոֱ ᪅˄ ࣙ ϟ ᣀ ˈଚ 0 ⏄ ଃ ᗻ ϔ ՈỆ Н ড় ࡵ Ѣ ҹĽ ঞ ᅮ ᙼ Ϭ ଃ Ộ ϔ ՈֱՈᬥ ᪅ ⌢ ˅˖ ┨ ᪅ ࠄ ѻ ક ┻ Ոࠡ ᦤ ˈ ህ ᰃ։ ϵᴗ ˈ 0 ݊ އᅮ Ҫ ˈӏ ԩ ᤶ ⊩ ѻ ᕟ ક ᜥ ᣝ ᑇ ѻ ˊ ક ՈᯱՈӏ ф ԩ Ӌ ָ Ḑ Ễ ǃⒸℒ DŽᇍ ǃĽ Ѣ ⅞ ạ ǃيড ֱ থ ᪅ Ոǃᴵ ϵ ℒ ℸ ᏺ ড় ᴹ ৠ Ո ˈৢ ණ ᤳѢ ᆇѓ ˄ ᗑ ࣙǃϹᣀ ḐԚ ᯧϡ ӏ└ Ѣ ߽ ⍺ ᤳ ༅ ǃଚ ᥍ ଚ Ϯ ᴎ Ӯ ˅ˈ ӏ ԩ ᚙ މϟ 0 ഛ ϡ ᡓ ᢙ ᯧ ӏ DŽ
LiClO4 LiAsF6 SEI Li N (SO2CF3)2 287 236 <0.5 wt % ~7.5 Na 1% pH Al B Ca Cl- F- Fe Ni K Si SO42HQ-115 HQ-115 25 % 1 356 <25 50 63 63 63 50 63 46 56 TGA HQ-115 375
3M
Ϲᢧ⎆ி߫˄ ˅
HQ-115
3
FluoradTM
Ѡ ˄ ϝ ⇳ ϶ ‴ ˅ Ѯ ྾ ⏆ Ϲ ᢧ⎆⏏ࡴࠖ
LiN(SO2CF3)2
ҟ Ľ⚍ Ӭ ĭˊ ൟ ᗻՈ ᯬ ⒊ᢧᗻ
ࣷᅮᗻ
Ѡ˄ϝ⇳ࡴ ࠖ϶ DŽ ‴ ˅Ѯ ྾ ⏆ Ϲᢧ⎆֔ ᰃ ϔ ᮄ ൟ Ո Ѣ ⏆ Ϲ ∴ Ո᳝ ᴎ Ϲᢧ⎆Ո⏏ ᕾ ᳝ ɳ ᴎ ӣ ࡿ ᅝ ᄤ ⌟ ᳝ ᪙ ᕜ ᜬᯢᔎ Ո݅ᴀ ֔ Ӌ ⏲ ᳝ ˈӬ ᓖ ℸ ՈϹ࣪ ᄺ ࣷ ᅮ ᗻ DŽ ᜬɴ ߎ Ӭ ᓖ Ո໔⛁ ߚ ᢧᗻ DŽ ּ Ԑ Ԛ ᮴ ࣷ ᅮ ᗻ ᅝ ܼ ᗻ ⒲ L DŽ ᇐᬍ Ϲɋ Ϣ ℷ ᯣ ᵕ Ո ၠ ࣷᡥ ࠊᅮ ⇨ℷ ԧᯣ ѻᵕ ϣА ☦ ᬍᬍᬍ ᄬʌᕾ ⏽ټɳ ᗻᗻᗻ ࿁࿁࿁ ࣪ߚ ᄺᄤ ৡᓣ ࢴ Ѡ˄ϝ⇳ ϶ ‴ ˅Ѯ ྾ ⏆ ߚ ᄤᢆ ₓ Ձ ᄶ ୍ ˄ৃ ⒊ ᢧ˅ X∈ ߚ⚍ ₓ ć ∈ ⒊ ⎆Ո ؐ ҙₓࡿᄤ ˈˈˈ ˈ ˈ ˈ ˈ ˈ ˈ ˈ ϟ ᜬ߫ߎ ࠄ ṇ ⒊ ད ࠖ ՈϹᇐ Ё Ո⒊ ɋ ᢧᗻଡ଼DŽᑺ DŽ ൟ Ո⒊ ϟ ߫⒊ᢧᑺ ࠖ ᰃ Ё Ո⒊ ćՈ⌟ ᢧᗻ ᰃ ᪙ Ӭ ؐDŽ ᓖ Ոˈ ℸ ৃ ҹ⏋њ ড় ՓϬ ҹẂ ᜬ ⒊ˈࠖ Ѡᙊ ᇆ ⛋ ⒊ ᢧᗻ ˄ ԧ ˅ Ѡ⇻ ᴖ ɳ Э ⛋ ¤ ϕ ݙ ″ ѠЭ ⁞ ݷЭ ‼‼ Ѡ϶ ″ Э ″ ᓖ϶ ϭϕ ⁞⁞ ϭಯ ⛃⇶ ݷਟ ‼ୗ ″ ᰒ ߾ ᳝ Ӭ ᓖ Ո⛁ ࣷ ᅮ ᗻ ˈ ൪ ćDŽ7 * $ ᳆ ඃ ᢅ DŽ
3M™ Fluorad
(HQ-115)
Copyright © 2006, 3M.
All rights reserved.
3M
Ϲᢧ⎆ி߫˄ ˅
HQ-115
wk.baidu.com
ሔ‑ᮍ ᑆ© ѻકټᄬ
Ў ⏏ ࡴ ࠖ ՓϬ ˈ⏏ ࡴ ₓ Ў ˄Z W ˅DŽ ᴀ ક ᯧ ╂⒊ć⚬ ᢧDŽ ℸ ՓϬ ᴀ ક ࠡ ᖙ / ܜ ᑆ © DŽᑆ © ໘ ˊ Ꮉ ᄾ Ў ף ा ź ᗕ ϟ ⚸ Ⴗ ⒵ ᱷ ∈ ߚ ᡅ ∖ Ў ℶ DŽ ᴀ ક ϡ ՓϬ ᯊ ᪻ ټᄬ ᅸ ⏽ ϟ ᆚ ⒱ ᆍ ఼ Ё ˈὃ ܡ ╂DŽ