色谱--译文
HPLC中英文对照
液相术语积分型检测器in tegrati ng detector激光光热检测器laser and light heat detector激光解吸质谱法laser desorption MS , LDMS激光裂解器laser pyrolyzer 激光色谱laser chromatography 激光诱导光热光偏转测量detection oflaser- induced light heat …激光诱导光束干涉检测detection oflaser-induced light be am I … 激光诱导毛细管振动测量laser-reduced capillary vibrati on det …激光诱导荧光检测器laser- in duced fluoresce nee detector 记忆峰memory peak 记忆效应memory effect 夹层槽sandwich chamber 假峰ghost peak 间断洗脱色谱法in terrupted-elutio nchromatography间接光度(检测)离子色谱法in direct photometr ic ion chromato … 间接光度(检测)色谱法in direct photometric chromatography间接检测in direct detectio n 间接荧光检测in direct fluoresce needetect ion间接紫外检测in direct ultraviolet detection检测器detector检测器检测限detector detectability检测器灵敏度detector sen sitivity检测器线性范围detector lin ear range碱火焰电离检测器alkali flame io ni zatio n detector , AFID 碱洗法alkali wash 剪纸称重法cut-paper weigh ing method 减尾齐U tailing reducer 减压液相色谱vacuum liquid chromatography键合固定相bon ded stati onary phase 键合型离子交换剂bon ded ion excha nger 焦耳热joule heating胶束薄层色谱法micellar thin layer chromatography胶束液相色谱法micellar liquid chromatography交联度crosslinking degree阶梯梯度stagewise gradie nt介电常数检测器dielectric con sta nt detector金属配合物离子色谱法metal complex ion chromatography , MCIC金属氧化物固定相metal oxides statio nary phase金属作用色谱metal in teracti on chromatography进样阀injection valve进样量sample size进样器injector静态顶空分析法static headspacean alysis静态涂渍法static coat ing method径流柱radial flow column径向流动色谱radial flow chromatography径向压缩柱radial compressi on colu mn 径向展开法radial developme nt径向展开色谱radial developme nt chromatography净保留体积net reten ti on volume 居里点裂解器Curie poi nt pyrolyzer矩形池rectangle form pool 聚苯乙烯PS/DVB 聚硅氧烷高温裂解去活high-temperature pyrolysis deactivati on …聚合物基质离子交换剂polymer substrate ion excha nger绝对检测器absolute detector 开口分流ope n split开口管柱ope n tubular colu mn 可见光检测器visible light detector 可交换离子excha ngable ion 空间性谱带加宽band broade ning in space空穴色谱法vaca ncy chromatography孑L结构pore structure孑L径pore diameter孑L径分布pore size distribution控制单元control un it快速色谱法high-speed chromatography 离心逆流色谱cen trifugal coun ter-curre nt chromatography离心制备薄层色谱法cen tric-preparatio n TLC离子对色谱法ion pair chromatography , IPC 离子对试剂ion pair reage nt 离子对探针检测ion-pairi ng probesdetect ion离子对形成模型ion pair formati on model离子交换电动色谱ion-excha ngeelectrok in etic chromatography离子交换剂ion excha nger离子交换毛细管电色谱ion excha nge capillary electrok in etic离子交换膜ion excha nge membra ne 离子交换色谱法ion excha nge chromatography , IEC离子交换树脂ion excha nge resin 离子交换位置ion excha nge site 离子交换柱ion excha nge colu mn 离子排斥色谱法ion exclusion chromatography , ICE 离子色谱法ion chromatography , IC 离子色谱仪ion chromatograph离子相互作用模型ion in teraction model离子相互作用色谱法ion in teracti on chromatography , IIC离子抑制色谱法ion suppressi on chromatography , ISC理论塔板高度height equivale nt to a theoretical plate ( HETP )理论塔板数nu mber of theoretical plates两性电解质ampholytes两性离子zwitter-io n两性离子交换剂zwitteri on excha nger裂解气相色谱法pyrolysis gas chromatography PyGC临界胶束浓度critical micelleconcen trati on淋洗剂eluent淋洗离子elue nt ion淋洗色谱法elutio n chromatography馏分收集器fractio n collector流动池flow cell电离截面检测器ioni zati on cross section detector电歧视效应the effect of electricaldiscrim in ati on电迁移进样electrophoretic injectio n 电渗流electroendosmotic flow 电渗流标记物electroe ndosmotic flow marker电渗流淌度electroe ndosmotic mobility 电位检测器electricity potential detector 电泳淌度electrophoretic mobility电子俘获检测器electro n capture detector电子迁移率检测器electro n mobility detector调整保留时间adjusted rete ntion time 调整保留体积adjusted rete ntion volume 叠加内标法added internal sta ndard method顶空气相色谱法headspace gas chromatography ,GC-HS 顶替法displacement development 顶替色谱法displaceme nt chromatography动态包覆dynamic coating动态分离dynamic separatio动态复合离子交换模型dyn amic complex ion excha nge model动态改性dynamic modification动态离子交换模型dyn amic ion excha nge model动态涂渍dynamic coating动态涂渍法dyn amic coated method动态脱活dynamic de-activity短柱色谱法short colu mn chromatography 堆积硅珠stacked silica bead 堆积性能bulk property多次反射池multi-reflect pool多分散度polydispersity多功能基离子交换剂multi-fu nctio nal group ion excha nger多角度激光光散射光度计multi-a nglelaser light scatteri ng ph •…多孑L层开口管柱porous layer ope n tubular column , PLOT多孔高聚物PLOT柱porous polymer beads PLOT colu mn 多孑L硅胶porous silica gel多孔聚合物气液固色谱柱porous polymer beads GLS colu mn GLS多孑L石墨碳porous graphitic carb on , PGC多孑L载体porous support多脉冲实验multiple pulse experime nts多维色谱法multi-dime nsio nal chromatography多维色谱仪multidime nsio nal chromatograph 多用色谱仪uni fied chromatograph 惰性气体鼓泡吹扫脱气sweep ing degasby inert gas二次化学平衡sec ondary chemical equilibria , SCE二极管阵列检测器diode-array detector , DAD二维色谱法two-dime nsional chromatography 二元溶剂体系dual solve nt system反冲洗back wash反吹技术back flushi ng tech nique反峰negative peak反离子counter ion 反气相色谱法in verse gas chromatography (IGC) 反相高效液相色谱法reversed phase high performa nee liquid ch …反相离子对色谱reversed phase ion pair chromatography反相离子对色谱法reversed phaseion-pair chromatography反相毛细管电色谱reverse capillaryelectrok in etic chromatogr …反相柱reversed phase column 反应气相色谱法reaction gas chromatography反应色谱reacti on chromatography 反圆心式展开an ti-circular developme nt 反转电渗流reverse electroe ndosmotic flow范第姆特方程式van Deemter equati on仿生传感器Biomimic electrode 放射性电离检测器radio ioni zati on detector放射性检测器radioactivity detector 放射自显影autoradiography 非极性固定相non-polar stati onary phase非极性键合相non-polar bon ded phase非金属离子传感器non-metal ion sen sor非水系凝胶色谱柱non-aqua-system gelcolu mn 非水相色谱non aqueous phase chromatography 非吸附性载体non-adsorptive support非线性分流non-I in earity split stream 非线性色谱non-l in ear chromatography 非线性吸附等温线non-lin ear adsorpti onisotherm 非抑制型电导检测non-suppressed con ducta nee detecti on 非抑制型离子色谱法non-suppressed ion chromatography ,NSIC 费尔盖特效益Fellgett adva ntage酚醛离子交换树脂phe nolic ion excha nge resi n 分离—反应—分离展开SRSdevelopme nt分离数separation number 分离因子separation factor 分离柱separation column 分流split stream 分流比split ratio 分流进样法split sampli ng 分流器splitter 分配等温线distributi on isotherm 分配色谱partiti on chromatography 分配系数partition coefficient 分析型色谱仪an alytical type chromatograph 分子扩散molecular diffusion 分子量分布molecular weight distributi on 分子量检测器molecular weight detector分子筛molecular sieve 分子筛色谱molecular sieve chromatography分子吸附molecular adsorpti on 分子吸收光谱molecular absorpti on spectroscopy 圭寸尾endcapping 峰高peakheight峰面积peak area峰面积测量法measurement of peak area峰面积校正calibration of peak area 峰容量peak capacity 复合柱combinedcolumn改性载体modified support干法柱填充dry column packing干凝胶xerogel干扰抑制电导率检测detection ofin terfere an d restra in condu …干柱色谱法dry-column chromatography干柱色谱法dry-column chromatography , DCC高分子多孑L微球porous polymer beads, GDX高速逆流色谱法high speedcoun ter-curre nt chromatography高温硅烷化去活high temperaturesila nizing deactivati on高温凝胶色谱法high temperaturegel chromatography高效毛细管电泳high-performa nee capillary electrophoresis高效液相色谱-付里叶变换红外分析法high performa nee liquid ch …高效液相色谱法high performance liquid chromatography高效柱high performance column 高压流通池技术high pressure flowcell technique高压输液泵high pressure pump 高压梯度high-pressure gradient 高压液相色谱法high pressureliquid chromatography戈雷方程式Golay equation戈雷柱Golay column隔膜泵diaphragm pump隔膜进样septum sampling工业色谱industrial chromatography工业色谱仪industrialchromatograph工作流速working flow rate功能基团functional group 谷丙转氨酶传感器Glutamic-pyruvictransaminase sensor ,GPT固定化酶immobilized enzyme 固定相stationary phase 固定液stationary liquid固定液的相对极性relative polarityof stationary liquid固定液极性stationary liquidpolarity固相扩散solid diffusion固相荧光免疫分析solid phase fluorescence immunoassay固有粘度intrinsic viscosity官能团保留指数function retention index官能团色谱图functional group chromatogram ,FGC冠醚固定相crown ether stationary phase管壁效应wall effect管式炉裂解器tube furnacepyrolyzer灌注色谱法perfusion chromatography贯注色谱填料perfusion chromatography packing光离子化检测器photo-ionization detector ,PID光密度计densitometer光谱差减法spectral subtraction method光散射检测器light scatteringdetector光声检测法photoacoustic detection光纤化学传感器Optic fiber sensor硅胶silica gel硅胶基质离子交换剂silica-gel substrate ion exchanger硅烷化法silanization硅烷化法silanizing硅烷化载体silanized support归一化法normalization methodlayer chromatography , OPT…过压液相色谱法over pressuredliquid chromatography ,OPLC氦电离检测器helium ionization detector含氧化合物分析器oxygen specificresp onse of the flame ioni …含样去样检测法sample in sample out method赫尔希池检测器Hersch cell detector恒流泵constant flow pump 恒温操作constant temperature method恒压泵constant pressure pump红色载体red support红外检测器infrared detector 红外总吸光度重建色谱图totalinfrared absorbance reconstruct …化合物形成色谱compound-formation chromatography化学发光检测器chemiluminescence化学发光检测器Chemiluminescence detector ,SCD化学键合固定相bonded stationary phase化学键合相色谱bonded phase chromatography化学色谱法chemi-chromatography化学衍生法chemical derivatization method环糊精电动色谱cyclodextrin electrokinetic chromatography环形展开比移值circulardevelopment Rf value环形展开法circular development缓冲溶液添加剂buffer additives辉光放电检测器glow discharge detector混合床离子交换固定相mixed-bed ion exchange stationary phase混合床柱mixed bed column混合溶剂mixed solvent活塞泵piston pump活性activation活性部位active site活性硅胶activated silica gel活性氧化铝activated aluminium oxide过压薄层色谱法over pressured thindetector活性中心active center火焰光度检测器flame photometric detector ,FPD基流background current or base current基线baseline基线宽度baseline width基质substrate materials基质隔离技术matrix isolation technique畸变峰distorted peak积分器integrator电离截面检测器ionization crosssection detector电歧视效应the effect of electrical discrimination电迁移进样electrophoretic injection电渗流electroendosmotic flow电渗流标记物electroendosmotic flow marker电渗流淌度electroendosmotic mobility电位检测器electricity potential detector电泳淌度electrophoretic mobility电子俘获检测器electron capture detector电子迁移率检测器electron mobility调整保留时间adjusted retention time调整保留体积adjusted retention volume叠加内标法added internal standard method顶空气相色谱法headspace gas chromatography ,GC-HS顶替法displacement development顶替色谱法displacement chromatography动态包覆dynamic coating动态顶空分析法dynamic headspace analysis动态分离dynamic separation 动态复合离子交换模型dynamic complex ion exchange model动态改性dynamic modification 动态离子交换模型dynamic ion exchange model动态涂渍dynamic coating动态涂渍法dynamic coated method动态脱活dynamic de-activity短柱色谱法short column chromatography堆积硅珠stacked silica bead堆积性能bulk propertydetector 多次反射池multi-reflect pool多分散度polydispersity 二元溶剂体系dual solvent system多功能基离子交换剂multi-functional group ion exchanger多角度激光光散射光度计multi- angle laser light scatteringph•…多孔层开口管柱porous layer open tubular column ,PLOT多孔高聚物PLOT柱porous polymer beads PLOT column多孔硅胶porous silica gel多孔聚合物气液固色谱柱porous polymer beads GLS column GLS多孔石墨碳porous graphiticcarbon ,PGC多孔载体porous support多脉冲实验multiple pulse experiments多维色谱法multi-dimensional chromatography多维色谱仪multidimensional chromatograph多用色谱仪unified chromatograph惰性气体鼓泡吹扫脱气sweeping degas by inert gas二次化学平衡secondary chemical equilibria ,SCE二极管阵列检测器diode-array detector ,DAD二维色谱法two-dimensional chromatography反冲洗back wash反吹技术back flushing technique 反峰negative peak 反离子counter ion反气相色谱法inverse gas chromatography (IGC)反相高效液相色谱法reversed phasehigh performa nee liquid ch …反相离子对色谱reversed phase ion pair chromatography反相离子对色谱法reversed phase ion-pair chromatography反相毛细管电色谱reverse capillary electrokinetic chromatogr …反相柱reversed phase column反应气相色谱法reaction gas chromatography反应色谱reaction chromatography反圆心式展开anti-circulardevelopment反转电渗流reverseelectroendosmotic flow范第姆特方程式van Deemterequation仿生传感器Biomimic electrode 放射性电离检测器radio ionization detector放射性检测器radioactivitydetector放射自显影autoradiography非极性固定相non-polar stationary phase非极性键合相non-polar bonded phase非金属离子传感器non-metal ion sensor非水系凝胶色谱柱non-aqua-system gel column非水相色谱nonaqueous phase chromatography非吸附性载体non-adsorptive support非线性分流non-linearity splitstream非线性色谱non-linear chromatography非线性吸附等温线non-linear adsorption isotherm非抑制型电导检测non-suppressed conductance detection非抑制型离子色谱法non-suppressed ion chromatography ,NSIC费尔盖特效益Fellgett advantage酚醛离子交换树脂phenolic ion exchange resin分离-反应-分离展开SRS development分离数separation number 分离因子separation factor 分离柱separation column 分流split stream 分流比split ratio 分流进样法split sampling 分流器splitter 分配等温线distribution isotherm 分配色谱partition chromatography 分配系数partition coefficient 分析型色谱仪analytical type chromatograph 分子扩散molecular diffusion 分子量分布molecular weight distribution分子量检测器molecular weight detector分子筛molecular sieve分子筛色谱molecular sieve chromatography分子吸附molecular adsorption分子吸收光谱molecular absorption spectroscopy封尾endcapping峰高peak heightOgston 模型Ogston modelpH 梯度动态分离dynamic separation of the pH gradientpH 值梯度洗脱pH gradient elutionZata 电势Zata potentialZ 形池Z-form pool氨基键合相amino-bonded phase 氨基酸分析仪amino acid analyzer 安培检测器ampere detector 白色载体white support 半微柱semimicro-column 半制备柱semi-preparation column 包覆型离子交换剂coated ion exchanger包覆型填料coated packing material薄层板thin layer plate薄层扫描法thin layer chromatography scanning薄层扫描仪thin layer chromatography scanner薄层色谱法thin layer chromatography TLC薄壳型离子交换剂pellicular ion-exchanger薄壳型微珠载体pellicular microbead support保护柱guard column保留时间retention time保留体积retention volume保留温度retention temperature保留值定性法retention qualitative method保留值沸点规律boiling point ruleof retention保留值碳数规律carbon number rule of retention保留指数retention index保留指数定性法retention index qualitative method背景电导background conductance苯酚磺酸树脂phenol sulfonic acid resin苯乙烯styrene比保留体积specific retention volume比例阀proportional valve比渗透率specific permeability比移值Rf value边缘效应edge effect便携式色谱仪portable chromatograph标准偏差standard deviation表观电泳淌度apparent electrophoretic mobility表观交换容量apparent exchange capacity表面电位检测器surface potential detector表面多孔硅胶superficially porous silica gel保留间隙retention gap表面多孔填料superficially porous packing material表面多孔型离子交换剂superficially porous ion-exchanger 玻璃球载体glass beads support 不分流进样splitlesssampling 参比柱reference column残余硅醇基residual silanol场放大进样electrical fieldmagnified injection场流分离field-flow fractionation场流分离仪field-flowfractionation场效应生物传感器Field effect transistor based Biosensor常压液相色谱法common-pressure liquid chromatography超临界流体supercritical fluid 超临界流体色谱supercritical fluid chromatography超临界流体色谱-傅里叶变换红外光谱联用supercritical fluid …超临界流体色谱法supercritical fluid chromatography超临界流体色谱仪supercriticalfluid chromatograph超临界流体萃取supercritical fluid extract ,SFE超声波脱气ultrasonic degas超微传感器ultra-micro sensor程序变流色谱法programmed flow (gas)chromatography程序升温进样programmed temperature sampling程序升温色谱法programmed temperature (gas)chromatography程序升温蒸发器programmed temperature vaporizer ,PTV程序升压programmed pressure触角载体tentacle supports传质速率rate of mass transfer传质阻力resistance of mass transfer垂直切割法vertical incisionmethod催化色谱法catalytic (gas)chromatography大环化合物色谱large ring compound chromatography大孔树脂macro-reticular resin大孔填料macro-reticular packing material大内径毛细管柱Megaobore column 代谢型生物传感器Biological metabolizing sensor单分散气溶胶发生器monodiaperse aerosol generator单活塞往复泵single piston reciprocating pump单相色谱仪single phase chromatograph单向阀one-way valve单柱离子色谱法single column ion chromatography胆固醇传感器Cholesterol sensor氮- 磷检测器nitrogen-phosphorus detector ,NPD导数比率法derivative ratio method等度洗脱isocratic elution等离子体色谱法plasma chromatography等途电泳- 毛细管区带电泳耦合进样isotachophoresis inject ion- c …低负荷柱low load column低容量柱low capacity column低温色谱low temperature chromatography低压液相色谱low-pressure liquid chromatography点样sample application点样器sample spotter ( spot applicator )电导池conductance cell电导检测法conductance detection电荷转移分光光度法charge transfer spectrophotometry电化学检测器electrochemical detector电解抑制器electrolyze suppressor低压梯度low-pressure gradient。
药典翻译USP29-621色谱法 中文译稿
USP29-621 色谱法<621>色谱法本章内容包括在色谱仪中使用的术语和操作法,并且提供了全面的信息。
原料药和制剂的色谱操作法的具体要求,包括吸附剂和展开剂,将在个论中给出。
色谱法是指溶质在一个由两相或多相组成的系统中按照不同的动态迁移过程使之分离的方法,每种物质在给定的方向不断的迁移,并且不同的物质由于具有不同的吸附、分配、溶解性、蒸汽压、分子大小或离子强度使之呈现出不同的迁移率。
这样分离得到的每种物质可以通过分析方法得到鉴定或测定。
一般的色谱技术需要溶质在不同的两相中进行分配,其中一相是固定的(固定相),另一相是流动的(流动相)。
流动相使溶质在固定相中流过,使之与流出更早或更晚的其它溶质呈现分离状态。
一般地,溶质借助于被称为“洗脱液”的液体或气体流从固定相中转移出。
固定相可以表现为吸附作用,例如活性氧化铝、硅胶的吸附作用,或可以通过溶解溶质起作用,将之在固定相和流动相之间分配。
在后者的过程中,被涂抹在惰性支撑物上的液体,通过化学键合在硅胶上的液体,以及直接在熔融的硅毛细管壁上的液体被作为固定相。
在气液色谱、纸色谱和各种形式的柱色谱以及被指定为即液-液分离的薄层色谱中,分配是主要的分离机理。
实际上,分离经常是吸收和分配作用相结合的结果。
其它的分离原理包括离子交换、离子对形成、分子排阻、疏水效应以及手性识别。
在USP操作法中所使用的在定性和定量分析方面有用的色谱方法有柱色谱法、气相色谱法、纸色谱法、薄层色谱法(包括高效薄层色谱)和加压液相色谱法(通常也被称为高压或高效液相色谱法)。
纸色谱和薄层色谱法由于其方便性和简单性通常用于鉴定的目的;柱色谱法提供了更宽的固定相选择机会,并且在从混合物中分离单个化合物以及定量方面是很有用的;现代的高效薄层色谱、气相色谱法和加压液相色谱法需要更加精细的装置,通常可以提供高的分离度,并鉴定和定量非常少量的物质。
在鉴别试验中标准物质的使用用于鉴别试验的标准物质的使用—在纸色谱和薄层色谱法中,某一给定的化合物在介质中从基线迁移的距离(用吸收最强的斑点的位置进行测量)与流动相前沿的迁移距离的比例,被称为化合物的R F值。
USP色谱柱的翻译
L1:十八烷基键合多孔硅胶或无机氧化物微粒固定相,简称C18或ODS L2:30~50um表面多孔薄壳型键合C18(ODS)固定相L3:多孔硅胶微粒即一般的硅胶柱L4:30~50um表面多孔薄壳型硅胶L5:30~50um表面多孔薄壳型氧化铝L6:30~50um实心微球表面包覆磺化碳氟聚合物-强阳离子交换固定相L7:全多孔硅胶微粒键合C8官能团固定相简称C8柱L8:全多孔硅胶微粒键合非交联NH2固定相简称NH2柱L9:强酸性阳离子交换基团键合全多孔不规则形硅胶固定相L10:多孔硅胶微球键合氰基固定相(CN)简称CN柱L11:键合苯基多孔硅胶微球固定相简称苯基柱L12:无孔微球键合季胺功能团的强阴离子填料L13:三乙基硅烷化学键合全多孔硅胶微球固定相(C1)简称C1柱L14:10um硅胶化学键合强碱性季铵盐阴离子交换固定相简称SAX柱L15:已基硅烷化学键合全多孔硅胶微球固定相简称C6柱L16:二甲基硅烷化学键合全多孔硅胶微粒固定相L17:氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换树脂L18: 3~10um全多孔硅胶化学键合胺基(NH2)和氰基(CN)L19:钙型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换树脂L20:二羟基丙烷基化学键合多孔硅胶微球固定相(Diol)简称二醇基柱L21:刚性苯乙烯-二乙烯基苯共聚物微球L22:带有磺酸基团的多孔苯乙烯阳离子交换树脂L23:带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换树脂L24:表面含有大量羟基的半刚性聚乙烯醇亲水凝胶L25:聚甲基丙烯酸酯树脂交联羟基醚(表面含有残余羧基功能团)树脂。
能分离分子量100~5000MW范围的水溶性中性、阳离子型及阴离子型聚合物(用聚氧乙烯测定)的固定相L26:丁基硅烷化学键合全多孔硅胶微球固定相L27:30~50um的全多孔硅胶微粒L28:多功能载体,100?的高纯硅胶加以氨基键合以及C8反相键合的官能团L29: 氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5um,孔径80? L30: 全多孔硅胶键合乙基硅烷固定相L31: 季胺基改性孔径2000?的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂L32: L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料L33: 能够分离分子量4000~40000MW范围蛋白质分子的球形硅胶固定相,pH稳定性好L34:铅型磺化交联苯乙烯-二乙烯基苯共聚物强阳离子交换树脂,9um球形L35:锆稳定的硅胶微球键合二醇基亲水分子单层固定相,孔径150?L36: 5um胺丙基硅胶键合L-苯基氨基乙酸-3,5二硝基苯甲酰L37:适合分离分子量2000~40,000Mw的聚甲基丙烯酸酯凝胶L38:水溶性甲基丙烯酸酯基质SEC色谱柱L39:亲水全多孔聚羟基甲基丙烯酸酯色谱柱L40:Tris 3,5-二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微球L41:球形硅胶表面固定α1酸糖蛋白固定相L42: C8和C18硅烷化学键合多孔硅胶固定相L43: 硅胶微球键合五氟代苯基固定相L44: 多功能固定相,60 ?高纯硅胶基质键合磺酸阳离子交换功能团和C8反相功能团L45: β-环糊精键合多孔硅胶微球L46: 季胺基改性苯乙烯-二乙烯基苯聚合物微球。
色谱术语中英文对照
色谱字典(术语大全)中文英文色谱图c h r o m a t o g r a m色谱峰c h r o m a t o g r a p h i c p e a k峰底p e a k b a s e峰高h,p e a k h e i g h t峰宽W,p e a k w i d t h半高峰宽W h/2,p e a k w i d t h a t h a l f h e i g h t峰面积A,p e a k a r e a拖尾峰t a i l i n g a r e a前伸峰l e a d i n g a r e a假峰g h o s t p e a k畸峰d i s t o r t e d p e a k反峰n e g a t i v e p e a k拐点i n f l e c t i o n p o i n t原点o r i g i n斑点s p o t区带z o n e复班m u l t i p l e s p o t区带脱尾z o n e t a i l i n g基线b a s e l i n e基线漂移b a s e l i n e d r i f t基线噪声N,b a s e l i n e n o i s e统计矩m o m e n t一阶原点矩γ1,f i r s t o r i g i n m o m e n t二阶中心矩μ2,s e c o n d c e n t r a l m o m e n t三阶中心矩μ3,t h i r d c e n t r a l m o m e n t液相色谱法l i q u i d c h r o m a t o g r a p h y,L C液液色谱法l i q u i d l i q u i d c h r o m a t o g r a p h y,L L C 液固色谱法l i q u i d s o l i d c h r o m a t o g r a p h y,L S C 正相液相色谱法n o r m a l p h a s e l i q u i dc h r o m a t o g r a p h y反相液相色谱法r e v e r s e d p h a s e l i q u i dc h r o m a t o g r a p h y,R P L C柱液相色谱法l i q u i d c o l u m n c h r o m a t o g r a p h y高效液相色谱法h i g h p e r f o r m a n c e l i q u i dc h r o m a t o g r a p h y,H P L C尺寸排除色谱法s i z e e x c l u s i o n c h r o m a t o g r a p h y,S E C凝胶过滤色谱法g e l f i l t r a t i o n c h r o m a t o g r a p h y凝胶渗透色谱法g e l p e r m e a t i o n c h r o m a t o g r a p h y,G P C亲和色谱法a f f i n i t y c h r o m a t o g r a p h y离子交换色谱法i o n e x c h a n g e c h r o m a t o g r a p h y,I E C 离子色谱法i o n c h r o m a t o g r a p h y离子抑制色谱法i o n s u p p r e s s i o n c h r o m a t o g r a p h y离子对色谱法i o n p a i r c h r o m a t o g r a p h y疏水作用色谱法h y d r o p h o b i c i n t e r a c t i o nc h r o m a t o g r a p h y制备液相色谱法p r e p a r a t i v e l i q u i d c h r o m a t o g r a p h y 平面色谱法p l a n a r c h r o m a t o g r a p h y纸色谱法p a p e r c h r o m a t o g r a p h y薄层色谱法t h i n l a y e r c h r o m a t o g r a p h y,T L C高效薄层色谱法h i g h p e r f o r m a n c e t h i n l a y e rc h r o m a t o g r a p h y,H P T L C浸渍薄层色谱法i m p r e g n a t e d t h i n l a y e rc h r o m a t o g r a p h y凝胶薄层色谱法g e l t h i n l a y e r c h r o m a t o g r a p h y离子交换薄层色谱法i o n e x c h a n g e t h i n l a y e rc h r o m a t o g r a p h y制备薄层色谱法p r e p a r a t i v e t h i n l a y e rc h r o m a t o g r a p h y薄层棒色谱法t h i n l a y e r r o d c h r o m a t o g r a p h y液相色谱仪l i q u i d c h r o m a t o g r a p h制备液相色谱仪p r e p a r a t i v e l i q u i d c h r o m a t o g r a p h 凝胶渗透色谱仪g e l p e r m e a t i o n c h r o m a t o g r a p h涂布器s p r e a d e r点样器s a m p l e a p p l i c a t o r色谱柱c h r o m a t o g r a p h i c c o l u m n棒状色谱柱m o n o l i t h c o l u m n m o n o l i t h c o l u m n微粒柱m i c r o p a r t i c l e c o l u m n填充毛细管柱p a c k e d c a p i l l a r y c o l u m n空心柱o p e n t u b u l a r c o l u m n微径柱m i c r o b o r e c o l u m n混合柱m i x e d c o l u m n组合柱c o u p l e d c o l u m n预柱p r e c o l u m n保护柱g u a r d c o l u m n预饱和柱p r e s a t u r a t i o n c o l u m n浓缩柱c o n c e n t r a t i n g c o l u m n抑制柱s u p p r e s s i o n c o l u m n薄层板t h i n l a y e r p l a t e浓缩区薄层板c o n c e n t r a t i n g t h i n l a y e r p l a t e荧光薄层板f l u o r e s c e n c e t h i n l a y e r p l a t e反相薄层板r e v e r s e d p h a s e t h i n l a y e r p l a t e梯度薄层板g r a d i e n t t h i n l a y e r p l a t e烧结板s i n t e r e d p l a t e展开室d e v e l o p m e n t c h a m b e r往复泵r e c i p r o c a t i n g p u m p注射泵s y r i n g e p u m p气动泵p n e u m a t i c p u m p蠕动泵p e r i s t a l t i c p u m p检测器d e t e c t o r微分检测器d i f f e r e n t i a l d e t e c t o r积分检测器i n t e g r a l d e t e c t o r总体性能检测器b u l k p r o p e r t y d e t e c t o r溶质性能检测器s o l u t e p r o p e r t y d e t e c t o r(示差)折光率检测器[d i f f e r e n t i a l]r e f r a c t i v e i n d e xd e t e c t o r荧光检测器f l u o r e s c e n c e d e t e c t o r紫外可见光检测器u l t r a v i o l e t v i s i b l e d e t e c t o r电化学检测器e l e c t r o c h e m i c a l d e t e c t o r蒸发(激光)光散射检测器[l a s e r]l i g h t s c a t t e r i n g d e t e c t o r光密度计d e n s i t o m e t e r薄层扫描仪t h i n l a y e r s c a n n e r柱后反应器p o s t-c o l u m n r e a c t o r体积标记器v o l u m e m a r k e r记录器r e c o r d e r积分仪i n t e g r a t o r馏分收集器f r a c t i o n c o l l e c t o r工作站w o r k s t a t i o n固定相s t a t i o n a r y p h a s e固定液s t a t i o n a r y l i q u i d载体s u p p o r t柱填充剂c o l u m n p a c k i n g化学键合相填充剂c h e m i c a l l y b o n d e d p h a s ep a c k i n g薄壳型填充剂p e l l i c u l a r p a c k i n g多孔型填充剂p o r o u s p a c k i n g吸附剂a d s o r b e n t离子交换剂i o n e x c h a n g e r基体m a t r i x载板s u p p o r t p l a t e粘合剂b i n d e r流动相m o b i l e p h a s e洗脱(淋洗)剂e l u a n t,e l u e n t展开剂d e v e l o p e r等水容剂i s o h y d r i c s o l v e n t改性剂m o d i f i e r显色剂c o l o r[d e v e l o p i n g]a g e n t死时间t0,d e a d t i m e保留时间t R,r e t e n t i o n t i m e调整保留时间t'R,a d j u s t e d r e t e n t i o n t i m e死体积V0,d e a d v o l u m e保留体积v R,r e t e n t i o n v o l u m e调整保留体积v'R,a d j u s t e d r e t e n t i o n v o l u m e柱外体积V e x t,e x t r a-c o l u m n v o l u n e粒间体积V0,i n t e r s t i t i a l v o l u m e(多孔填充剂的)孔体积V P,p o r e v o l u m e o f p o r o u s p a c k i n g液相总体积V t o l,t o t a l l i q u i d v o l u m e洗脱体积v e,e l u t i o n v o l u m e流体力学体积v h,h y d r o d y n a m i c v o l u m e相对保留值r i.s,r e l a t i v e r e t e n t i o n v a l u e分离因子α,s e p a r a t i o n f a c t o r流动相迁移距离d m,m o b i l e p h a s e m i g r a t i o nd i s t a n c e流动相前沿m o b i l e p h a s e f r o n t溶质迁移距离d s,s o l u t e m i g r a t i o n d i s t a n c e比移值R f,R f v a l u e高比移值h R f,h i g h R f v a l u e相对比移值R i.s,r e l a t i v e R f v a l u e保留常数值R m,R m v a l u e板效能p l a t e e f f i c i e n c y折合板高h r,r e d u c e d p l a t e h e i g h t分离度R,r e s o l u t i o n液相载荷量l i q u i d p h a s e l o a d i n g离子交换容量i o n e x c h a n g e c a p a c i t y负载容量l o a d i n g c a p a c i t y渗透极限p e r m e a b i l i t y l i m i t排除极限V h,m a x,e x c l u s i o n l i m i t拖尾因子T,t a i l i n g f a c t o r柱外效应e x t r a-c o l u m n e f f e c t管壁效应w a l l e f f e c t间隔臂效应s p a c e r a r m e f f e c t边缘效应e d g e e f f e c t斑点定位法l o c a l i z a t i o n o f s p o t放射自显影法a u t o r a d i o g r a p h y原位定量i n s i t u q u a n t i t a t i o n生物自显影法b i o a u t o g r a p h y归一法n o r m a l i z a t i o n m e t h o d内标法i n t e r n a l s t a n d a r d m e t h o d外标法e x t e r n a l s t a n d a r d m e t h o d叠加法a d d i t i o n m e t h o d普适校准(曲线、函数)c a l i b r a t i o n f u n c t i o n o r c u r v e[f u n c t i o n]谱带扩展(加宽)b a n d b r o a d e n i n g(分离作用的)校准函数或校准曲线u n i v e r s a l c a l i b r a t i o n f u n c t i o n o r c u r v e[o f s e p a r a t i o n]加宽校正b r o a d e n i n g c o r r e c t i o n加宽校正因子b r o a d e n i n g c o r r e c t i o n f a c t o r溶剂强度参数ε0,s o l v e n t s t r e n g t h p a r a m e t e r洗脱序列e l u o t r o p i c s e r i e s洗脱(淋洗)e l u t i o n等度洗脱g r a d i e n t e l u t i o n梯度洗脱g r a d i e n t e l u t i o n(再)循环洗脱r e c y c l i n g e l u t i o n线性溶剂强度洗脱l i n e a r s o l v e n t s t r e n g t h g r a d i e n t程序溶剂p r o g r a m m e d s o l v e n t程序压力p r o g r a m m e d p r e s s u r e程序流速p r o g r a m m e d f l o w展开d e v e l o p m e n t上行展开a s c e n d i n g d e v e l o p m e n t下行展开d e s c e n d i n g d e v e l o p m e n t双向展开t w o d i m e n s i o n a l d e v e l o p m e n t环形展开c i r c u l a r d e v e l o p m e n t离心展开c e n t r i f u g a l d e v e l o p m e n t向心展开c e n t r i p e t a l d e v e l o p m e n t 径向展开r a d i a l d e v e l o p m e n t多次展开m u l t i p l e d e v e l o p m e n t分步展开s t e p w i s e d e v e l o p m e n t连续展开c o n t i n u o u s d e v e l o p m e n t 梯度展开g r a d i e n t d e v e l o p m e n t匀浆填充s l u r r y p a c k i n g停流进样s t o p-f l o w i n j e c t i o n阀进样v a l v e i n j e c t i o n柱上富集o n-c o l u m n e n r i c h m e n t流出液e l u a t e柱上检测o n-c o l u m n d e t e c t i o n柱寿命c o l u m n l i f e柱流失c o l u m n b l e e d i n g显谱v i s u a l i z a t i o n活化a c t i v a t i o n反冲b a c k f l u s h i n g脱气d e g a s s i n g沟流c h a n n e l i n g过载o v e r l o a d i n g。
色谱字典-术语大全
色谱字典(术语大全)发布时间:2008年12月31日Audo look6.0下载色谱字典(术语大全)中文英文色谱图 chromatogram色谱峰 chromatographic peak峰底 peak base峰高 h,peak height峰宽 W,peak width半高峰宽 Wh/2,peak width at half height峰面积 A,peak area拖尾峰 tailing area前伸峰 leading area假峰 ghost peak畸峰 distorted peak反峰 negative peak拐点 inflection point原点 origin斑点 spot区带 zone复班 multiple spot区带脱尾 zone tailing基线 base line基线漂移 baseline drift基线噪声 N,baseline noise统计矩 moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法 liquid chromatography,LC液液色谱法 liquid liquid chromatography,LLC液固色谱法 liquid solid chromatography,LSC正相液相色谱法 normal phase liquidchromatography反相液相色谱法 reversed phase liquidchromatography,RPLC柱液相色谱法 liquid column chromatography高效液相色谱法 high performance liquid chromatography,HPLC尺寸排除色谱法 size exclusion chromatography,SEC凝胶过滤色谱法 gel filtration chromatography凝胶渗透色谱法 gel permeation chromatography,GPC亲和色谱法 affinity chromatography离子交换色谱法 ion exchange chromatography,IEC 离子色谱法 ion chromatography离子抑制色谱法 ion suppression chromatography离子对色谱法 ion pair chromatography疏水作用色谱法 hydrophobic interaction chromatography制备液相色谱法 preparative liquid chromatography 平面色谱法 planar chromatography纸色谱法 paper chromatography薄层色谱法 thin layer chromatography,TLC高效薄层色谱法 high performance thin layer chromatography,HPTLC浸渍薄层色谱法 impregnated thin layer chromatography凝胶薄层色谱法 gel thin layer chromatography离子交换薄层色谱法 ion exchange thin layer chromatography制备薄层色谱法 preparative thin layer chromatography薄层棒色谱法 thin layer rod chromatography液相色谱仪 liquid chromatograph制备液相色谱仪 preparative liquid chromatograph 凝胶渗透色谱仪 gel permeation chromatograph涂布器 spreader点样器 sample applicator色谱柱 chromatographic column棒状色谱柱 monolith column monolith column微粒柱 microparticle column填充毛细管柱 packed capillary column空心柱 open tubular column微径柱 microbore column混合柱 mixed column组合柱 coupled column预柱 precolumn保护柱 guard column预饱和柱 presaturation column浓缩柱 concentrating column抑制柱 suppression column薄层板 thin layer plate浓缩区薄层板 concentrating thin layer plate荧光薄层板 fluorescence thin layer plate反相薄层板 reversed phase thin layer plate梯度薄层板 gradient thin layer plate烧结板 sintered plate展开室 development chamber以上为美瑞泰克公司中国办事处从网上搜集并加以整理的,目的只有一个,就是能让每一个应用色谱分析的朋友能够更方便。
色谱专用术语英语翻译
不知各位是否用的着色谱图 chromatogram 色谱峰 chromatographic peak峰底peak base峰高 h,peak height峰宽 W,peak width半高峰宽 Wh/2,peak width at half height峰面积 A,peak area拖尾峰 tailing area前伸峰 leading area假峰ghost peak畸峰 distorted peak反峰 negative peak拐点 inflection point原点 origin斑点 spot区带 zone复班 multiple spot区带脱尾 zone tailing基线 base line基线漂移 baseline drift基线噪声 N,baseline noise统计矩 moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法 liquid chromatography,LC液液色谱法 liquid liquid chromatography,LLC液固色谱法 liquid solid chromatography,LSC正相液相色谱法 normal phase liquidchromatography反相液相色谱法 reversed phase liquidchromatography,RPLC柱液相色谱法 liquid column chromatography高效液相色谱法 high performance liquidchromatography,HPLC尺寸排除色谱法 size exclusion chromatography,SEC凝胶过滤色谱法gel filtration chromatography凝胶渗透色谱法 gel permeation chromatography,GPC亲和色谱法 affinity chromatography离子交换色谱法 ion exchange chromatography,IEC离子色谱法 ion chromatography离子抑制色谱法 ion suppression chromatography离子对色谱法 ion pair chromatography疏水作用色谱法 hydrophobic interactionchromatography制备液相色谱法 preparative liquid chromatography平面色谱法 planar chromatography纸色谱法 paper chromatography薄层色谱法 thin layer chromatography,TLC高效薄层色谱法high performance thin layerchromatography,HPTLC浸渍薄层色谱法 impregnated thin layerchromatography凝胶薄层色谱法 gel thin layer chromatography离子交换薄层色谱法 ion exchange thin layerchromatography制备薄层色谱法 preparative thin layerchromatography薄层棒色谱法 thin layer rod chromatography液相色谱仪liquid chromatograph制备液相色谱仪 preparative liquid chromatograph凝胶渗透色谱仪 gel permeation chromatograph涂布器 spreader点样器 sample applicator色谱柱 chromatographic column棒状色谱柱monolith column monolith column微粒柱 microparticle column填充毛细管柱 packed capillary column空心柱open tubular column微径柱 microbore column混合柱mixed column组合柱 coupled column预柱 precolumn保护柱 guard column预饱和柱 presaturation column浓缩柱 concentrating column抑制柱 suppression column薄层板 thin layer plate浓缩区薄层板 concentratingthin layer plate荧光薄层板 fluorescence thin layer plate反相薄层板 reversed phase thin layer plate梯度薄层板 gradient thin layer plate烧结板 sintered plate展开室 development chamber 往复泵 reciprocating pump注射泵 syringe pump气动泵 pneumatic pump蠕动泵peristaltic pump检测器 detector微分检测器differential detector积分检测器 integral detector总体性能检测器 bulk property detector溶质性能检测器solute property detector(示差)折光率检测器[differential] refractive indexdetector荧光检测器fluorescence detector紫外可见光检测器 ultraviolet visible detector电化学检测器 electrochemical detector蒸发(激光)光散射检测器 [laser] light scatteringdetector光密度计 densitometer薄层扫描仪thin layer scanner柱后反应器 post-column reactor体积标记器 volume marker记录器 recorder积分仪integrator馏分收集器 fraction collector工作站 work station固定相 stationary phase固定液 stationary liquid载体 support柱填充剂 column packing化学键合相填充剂 chemically bonded phasepacking薄壳型填充剂pellicular packing多孔型填充剂 porous packing吸附剂 adsorbent离子交换剂 ion exchanger基体 matrix载板 support plate粘合剂 binder流动相 mobile phase洗脱(淋洗)剂 eluant,eluent展开剂 developer等水容剂isohydric solvent改性剂 modifier显色剂 color [developing] agent死时间 t0,dead time保留时间 tR,retention time调整保留时间 t'R,adjusted retention time死体积 V0,dead volume保留体积 vR,retention volume调整保留体积 v'R,adjusted retention volume柱外体积 Vext,extra-column volune粒间体积 V0,interstitial volume(多孔填充剂的)孔体积 VP,pore volume of porouspacking液相总体积 Vtol,total liquid volume洗脱体积 ve,elution volume流体力学体积 vh,hydrodynamic volume相对保留值 ri.s,relative retention value分离因子α,separation factor流动相迁移距离 dm,mobile phase migrationdistance流动相前沿 mobile phase front溶质迁移距离 ds,solute migration distance比移值 Rf,Rf value高比移值hRf,high Rf value相对比移值 Ri.s,relative Rf value保留常数值 Rm,Rm value板效能 plateefficiency折合板高 hr,reduced plate height分离度R,resolution液相载荷量 liquid phase loading离子交换容量 ion exchange capacity负载容量 loading capacity渗透极限 permeability limit排除极限 Vh,max,exclusion limit拖尾因子 T,tailing factor柱外效应 extra-column effect管壁效应 wall effect间隔臂效应 spacer arm effect边缘效应 edge effect斑点定位法 localization of spot放射自显影法 autoradiography 原位定量 in situ quantitation生物自显影法bioautography归一法 normalization method内标法internal standard method外标法 external standard method叠加法 addition method普适校准(曲线、函数) calibration function or curve 谱带扩展(加宽) band broadening(分离作用的)校准函数或校准曲线 universalcalibration function or curve [of separation]加宽校正 broadening correction加宽校正因子 broadening correction factor溶剂强度参数ε0,solvent strength parameter洗脱序列 eluotropic series洗脱(淋洗) elution等度洗脱 gradient elution 梯度洗脱 gradient elution(再)循环洗脱 recycling elution线性溶剂强度洗脱 linear solvent strength gradient程序溶剂 programmed solvent程序压力programmed pressure程序流速 programmed flow展开development上行展开 ascending development下行展开descending development双向展开 two dimensional development环形展开 circular development离心展开centrifugal development向心展开 centripetal development径向展开 radial development多次展开multiple development分步展开 stepwise development 连续展开 continuous development梯度展开 gradient development匀浆填充 slurry packing停流进样 stop-flow injection阀进样 valve injection柱上富集 on-column enrichment流出液 eluate柱上检测 on-column detection柱寿命 column life柱流失 column bleeding 显谱 visualization活化 activation反冲 back flushing脱气 degassing沟流 channeling过载overloading。
色谱术语大全
色谱字典(术语大全)中文英文色谱图chromatogram色谱峰chromatographic peak峰底peak base峰高h,peak height峰宽W,peak width半高峰宽Wh/2,peak width at half height峰面积A,peak area拖尾峰tailing area前伸峰leading area假峰ghost peak畸峰distorted peak反峰negative peak拐点inflection point原点origin斑点spot区带zone复班multiple spot区带脱尾zone tailing基线base line基线漂移baseline drift基线噪声N,baseline noise统计矩moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法liquid chromatography,LC液液色谱法liquid liquid chromatography,LLC液固色谱法liquid solid chromatography,LSC正相液相色谱法normal phase liquid chromatography反相液相色谱法reversed phase liquid chromatography,RPLC柱液相色谱法liquid column chromatography高效液相色谱法high performance liquid chromatography,HPLC尺寸排除色谱法size exclusion chromatography,SEC凝胶过滤色谱法gel filtration chromatography凝胶渗透色谱法gel permeation chromatography,GPC亲和色谱法affinity chromatography离子交换色谱法ion exchange chromatography,IEC 离子色谱法ion chromatography离子抑制色谱法ion suppression chromatography离子对色谱法ion pair chromatography疏水作用色谱法hydrophobic interaction chromatography制备液相色谱法preparative liquid chromatography 平面色谱法planar chromatography纸色谱法paper chromatography薄层色谱法thin layer chromatography,TLC高效薄层色谱法high performance thin layer chromatography,HPTLC浸渍薄层色谱法impregnated thin layer chromatography凝胶薄层色谱法gel thin layer chromatography离子交换薄层色谱法ion exchange thin layer chromatography制备薄层色谱法preparative thin layer chromatography薄层棒色谱法thin layer rod chromatography液相色谱仪liquid chromatograph制备液相色谱仪preparative liquid chromatograph 凝胶渗透色谱仪gel permeation chromatograph涂布器spreader点样器sample applicator色谱柱chromatographic column棒状色谱柱monolith column monolith column微粒柱microparticle column填充毛细管柱packed capillary column空心柱open tubular column微径柱microbore column混合柱mixed column组合柱coupled column预柱precolumn保护柱guard column预饱和柱presaturation column浓缩柱concentrating column抑制柱suppression column薄层板thin layer plate浓缩区薄层板concentrating thin layer plate荧光薄层板fluorescence thin layer plate反相薄层板reversed phase thin layer plate梯度薄层板gradient thin layer plate烧结板sintered plate展开室development chamber往复泵reciprocating pump注射泵syringe pump气动泵pneumatic pump蠕动泵peristaltic pump检测器detector微分检测器differential detector积分检测器integral detector总体性能检测器bulk property detector溶质性能检测器solute property detector(示差)折光率检测器[differential] refractive index detector荧光检测器fluorescence detector紫外可见光检测器ultraviolet visible detector电化学检测器electrochemical detector蒸发(激光)光散射检测器[laser] light scattering detector光密度计densitometer薄层扫描仪thin layer scanner柱后反应器post-column reactor体积标记器volume marker记录器recorder积分仪integrator馏分收集器fraction collector工作站work station固定相stationary phase固定液stationary liquid载体support柱填充剂column packing化学键合相填充剂chemically bonded phase packing薄壳型填充剂pellicular packing多孔型填充剂porous packing吸附剂adsorbent离子交换剂ion exchanger基体matrix载板support plate粘合剂binder流动相mobile phase洗脱(淋洗)剂eluant,eluent展开剂developer等水容剂isohydric solvent改性剂modifier显色剂color [developing] agent死时间t0,dead time 保留时间tR,retention time调整保留时间t'R,adjusted retention time死体积V0,dead volume保留体积vR,retention volume调整保留体积v'R,adjusted retention volume柱外体积V ext,extra-column volune粒间体积V0,interstitial volume(多孔填充剂的)孔体积VP,pore volume of porous packing液相总体积Vtol,total liquid volume洗脱体积ve,elution volume流体力学体积vh,hydrodynamic volume相对保留值ri.s,relative retention value分离因子α,separation factor流动相迁移距离dm,mobile phase migration distance流动相前沿mobile phase front溶质迁移距离ds,solute migration distance比移值Rf,Rf value高比移值hRf,high Rf value相对比移值Ri.s,relative Rf value保留常数值Rm,Rm value板效能plate efficiency折合板高hr,reduced plate height分离度R,resolution液相载荷量liquid phase loading离子交换容量ion exchange capacity负载容量loading capacity渗透极限permeability limit排除极限Vh,max,exclusion limit拖尾因子T,tailing factor柱外效应extra-column effect管壁效应wall effect间隔臂效应spacer arm effect边缘效应edge effect斑点定位法localization of spot放射自显影法autoradiography原位定量in situ quantitation生物自显影法bioautography归一法normalization method内标法internal standard method外标法external standard method叠加法addition method普适校准(曲线、函数) calibration function or curve[function]谱带扩展(加宽) band broadening(分离作用的)校准函数或校准曲线universal calibration function or curve [of separation]加宽校正broadening correction加宽校正因子broadening correction factor溶剂强度参数ε0,solvent strength parameter洗脱序列eluotropic series洗脱(淋洗) elution等度洗脱gradient elution梯度洗脱gradient elution(再)循环洗脱recycling elution线性溶剂强度洗脱linear solvent strength gradient 程序溶剂programmed solvent程序压力programmed pressure程序流速programmed flow展开development上行展开ascending development下行展开descending development双向展开two dimensional development环形展开circular development离心展开centrifugal development向心展开centripetal development径向展开radial development多次展开multiple development分步展开stepwise development连续展开continuous development梯度展开gradient development匀浆填充slurry packing停流进样stop-flow injection阀进样valve injection柱上富集on-column enrichment流出液eluate柱上检测on-column detection柱寿命column life柱流失column bleeding显谱visualization活化activation反冲back flushing脱气degassing沟流channeling过载overloadingAAA - Amino acid analysis – 氨基酸分析AAS - Atomic absorption spectrometry – 原子吸收光谱AED - Atomic emission detection – 原子发射检测AES - Atomic emission spectrometry – 原子发射光谱AFD - Alkali flame detection – 碱火焰检测API - Atmospheric-pressure ionization – 常压电离AX/HPLC - Anion-exchange HPLC – 离子交换HPLCCC - Open (low pressure) column chromatography – 开口(低压)柱色谱法CD - Conductivity detection – 电导检测CEC - Capillary Electrochromatography – 毛细管电色谱法CF-FAB - Continuous flow FAB – 持流FABCGC - Capillary column gas chromatography – 毛细管柱气相色谱法CI/MS - Chemical ionization MS – 化学电离MSCIA - Capillary ion analysis – 毛细管离子分析CLD - Chemiluminescence detection – 化学发光检测CLSE - Column liquid-solid extraction – 液固柱萃取13C-NMR - Carbon-13 NMR – 碳13NMRCSFC - Capillary supercritical-fluid chromatography – 毛细管超临界流体色谱法CV - Cyclic voltammetry – 循环伏安法CX/HPLC - Cation-exchange HPLC – 阳离子交换HPLCCZE - Capillary zone electrophoresis – 毛细管区域电泳EC - Electron capture detection – 电子捕获检测ECD - Electrochemical detection – 电化学检测EI/MS - Electron-impact MS – 电子碰撞MSEIA - Enzyme immunoassay – 酶免疫测定ELISA - Enzyme-linked immunosorbent assay – 酶联免疫吸附测定EMIT - Enzyme-multiplied immunoassay technique – 酶多联免疫测定技术EPR - Electron paramagnetic resonance – 电子顺磁共振FAB/MS - Fast-atom-bombardment MS – 快速原子轰击MSFD - Fluorescence detection – 荧光检测FIA - Flow injection analysis – 流动注射分析FID - Flame ionization detection – 火焰离子化检测FPD - Flame photometric detection – 火焰光度检测FPIA - Fluorescence polarization immunoassay – 荧光偏振免疫测定FTD - Flame thermionic detection (alkali flame ionization ) – 火焰热离子检测(碱火焰离子化) GC - Gas chromatography – 气相色谱法GC/MS - GC/mass spectrometry – GC/MSGFC - Gel filtration chromatography – 凝胶过滤色谱法GPC - Gel permeation chromatography – 凝胶渗透色谱法HallECD - Hall electrolytic conductivity detection – 霍尔电解质电导率检测HPLC - High performance liquid chromatography – 高效液相色谱法µHPLC - Microcolumn HPLC – 微径柱HPLCHPTLC - High performance TLC – 高效TLCHRGC - High resolution GC – 高分辨GCIE/HPLC - Ion-exchange HPLC – 离子交换HPLCIEC - Ion-exchange (low pressure) chromatography – 离子交换(低压)色谱法IEF - Isoelectric focusing – 等电点聚焦ILC - Ion liquid chromatography – 离子液相色谱法IMS - Ion mobility spectrometer – 离子淌度光谱仪IR - Infrared spectrometry – 红外光谱法LC - Liquid chromatography – 液相色谱法µLC - Microcolumn LC – 微径柱LCLC/MS - Coupled HPLC- mass spectrometry – LC/MS联用LIFD - Laser-induced fluorescence detection – 激光诱导荧光检测LLE - Liquid-liquid extraction – 液液萃取LSC - Liquid scintillation counting – 液滴闪烁计数LSE - Liquid-solid extraction – 液固萃取MD - Mass detection – 质量检测MECC - Micellar electrokinetic capillary chromatography – 胶束电动毛细管色谱法MSD - Mass selective detection – 质量选择检测NICI/MS - Negative-ion CI/MS – 负离子CI/MSNMR - Nuclear magnetic resonance – 核磁共振NP/HPLC - Normal-phase HPLC – 正相HPLCNPD - Nitrogen phosphorous detection – 氮磷检测PAD - Pulsed-amperometric detection – 脉冲电流检测PAGE - Polyacrylamide gel electrophoresis – 聚丙烯酰胺凝胶电泳PCR - Post-column reaction (on-line) – 后柱反应(在线)PDA - Photodiode array – 二极管阵列PI/HPLC - Paired-ion HPLC – 离子对上HPLCPICI/MS - Positive-ion CI/MS – 正离子CI/MS1H-NMR - Proton NMR – 质子NMRPSFID - Phosphorus sulfur flame ionization detection – 磷硫火焰离子化检测PTLC - Preparative TLC – 制备TLCRD - Radioactivity detection – 放射性检测RI - Refractive index detection – 示差折光检测RIA – Radioimmunoassay – 放射免疫测定RP/HPLC - Reversed-phase HPLC – 反相HPLCRRA - Radioreceptor assay – 放射受体测定SAX - Strong anion exchange – 强阴离子交换SCX - Strong cation exchange – 强阳离子交换SDS-PAGE - Sodium dodecyl sulfate PAGE – 十二烷基磺酸钠PAGESEC - Size exclusion chromatography – 尺寸排阻色谱法SFC - Supercritical-fluid chromatography – 超临界流体色谱法SID - Surface ionization detection – 表面离子化检测SIM - Selective ion monitoring – 选择性离子监测SPE - Solid phase extraction – 固相萃取TCA - Total carbon analysis – 总碳分析TCD - Thermal conductivity detection – 热导检测2-D TLC - Two-dimensional TLC – 二维TLCTEA - Thermal energy analyzer – 热能分析仪TLC - Thin layer chromatography – 薄层色谱法TSMS - Mass spectrometric detection with thermospray interface – 带热喷雾接口的质谱检测UV/VIS - Ultraviolet/visible detection – 紫外/可见光检测WAX - Weak anion exchange – 弱阴离子交换WCX - Weak cation exchange – 弱阳离子交换¶ 以上内容来自中国‘中国色谱网’http://www.sepu.net,收集整理vabs lee(vabs@163.com) 。
USP621译文教案资料
<621>色谱法介绍色谱分离技术是通过样品组分在固定相和流动相两相中的分布差异进行分离的技术。
其中固定相可以是固体、有固相支持的液体或凝胶。
固定相可以填充于柱、分散成层、分布为膜或者应用于其他技术中。
流动相可以为气态、液态或超临界流体。
分离可以基于吸附性、质量分布(分配)或离子交换,也可以基于分子物理化学性质的差异,如大小、质量和体积。
本章节包括了基本步骤、定义和对一般参数的计算并描述了对于系统适应性的基本要求。
在USP中应用于定量和定性分析的色谱方法类型有柱色谱法、气象色谱法、纸色谱法、薄层色谱法(包括高效薄层色谱)和加压液相色谱法(一般称作高压或高效液相色谱)。
基本步骤本部分描述了使用某种色谱方法的基本步骤。
除另有各论规定外,以下色谱分离方法的步骤将会被遵循。
纸色谱法固定相:固定相为一张适当质地和厚度的纸。
色谱图的形成过程可以是上行的,这样溶剂被毛细管作用力支撑着沿着纸向上,这个过程也可以是下行的,在此情况下溶剂流动也受到重力的影响。
与溶剂流动有关的纸张纹理定向应该在一系列色谱图中保持恒定。
(纤维方向通常由制造商在色谱纸的包装上标出。
)仪器:纸色谱法的必备仪器包括装有添加溶剂的入口的气密室和短于该室内部高度5cm的耐腐蚀材料支架。
该支架作为用于溶剂槽以及用于抗虹吸棒的支撑,这些抗虹吸棒依次撑起色谱纸。
气密室的底部以规定的容积系统或流动相覆盖。
使用以规定溶剂系统润湿的纸张衬托于气密室的内壁,以增加气密室的溶剂蒸汽饱和度。
斑点:将待分析的一个或多个物质溶解于适当溶剂中。
以微量吸管吸取适当体积的溶液,其中通常含有1-20µg 该化合物,点样为6-10mm大小斑点且斑点间的间隔不小于3cm。
下行色谱法步骤1.带斑点的色谱纸以抗虹吸棒悬挂在气密室内,该棒将该色谱纸的上端固定在溶剂槽中。
(注:确保色谱纸挂在抗虹吸棒下的部分自由的悬挂在气密室中,没有接触到支架、室壁或室内的液体。
2.气密室被密闭,以便使该室与色谱纸达到溶剂蒸汽平衡(饱和)释放任何多余压力。
色谱术语中英对照
尺寸排除色谱法 size exclusion chromatography,
SEC
凝胶过滤色谱法 gel filtration chromatography
凝胶渗透色谱法 gel permeation chromatography,
GPC
亲和色谱法 affinity chromatography
填充毛细管柱 packed capillary column
空心柱 open tubular column
微径柱 microbore column
混合柱 mixed column
组合柱 coupled column
预柱 precolumn
保护柱 guard column
预饱和柱 presaturation column
梯度薄层板 gradient thin layer plate
离子交换色谱法 ion exchange chromatography,IEC
离子色谱法 ion chromatography
离子抑制色谱法 ion suppression chromatography
离子对色谱法 ion pair chromatography
疏水作用色谱法 hydrophobic interaction
14、 毛细管柱:capillary column 内径一般为0.1—0.5mm的色谱柱。
15、 空心柱:open tubular column 内壁上有固定相的开口毛细管柱。
16、 涂壁空心柱(WCOT):wall –coated open tubular column 内壁上直接涂渍固定液的空心柱。
色谱术语中英文对照1
中文英文色谱图chromatogram色谱峰chromatographic peak峰底peak base峰高h,peak height峰宽W,peak width半高峰宽Wh/2,peak width at half height峰面积A,peak area拖尾峰tailing area前伸峰leading area假峰ghost peak畸峰distorted peak反峰negative peak拐点inflection point原点origin斑点spot区带zone复班multiple spot区带脱尾zone tailing基线base line基线漂移baseline drift基线噪声N,baseline noise统计矩moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法liquid chromatography,LC液液色谱法liquid liquid chromatography,LLC液固色谱法liquid solid chromatography,LSC正相液相色谱法normal phase liquid chromatography反相液相色谱法reversed phase liquid chromatography,RPLC 柱液相色谱法liquid column chromatography高效液相色谱法high performance liquid chromatography,HPLC 尺寸排除色谱法size exclusion chromatography,SEC凝胶过滤色谱法gel filtration chromatography凝胶渗透色谱法gel permeation chromatography,GPC亲和色谱法affinity chromatography离子交换色谱法ion exchange chromatography,IEC离子色谱法ion chromatography离子抑制色谱法ion suppression chromatography离子对色谱法ion pair chromatography疏水作用色谱法hydrophobic interaction chromatography制备液相色谱法preparative liquid chromatography平面色谱法planar chromatography纸色谱法paper chromatography薄层色谱法thin layer chromatography,TLC高效薄层色谱法high performance thin layer chromatography,HPTLC 浸渍薄层色谱法impregnated thin layer chromatography凝胶薄层色谱法gel thin layer chromatography离子交换薄层色谱法ion exchange thin layer chromatography制备薄层色谱法preparative thin layer chromatography薄层棒色谱法thin layer rod chromatography液相色谱仪liquid chromatograph制备液相色谱仪preparative liquid chromatograph凝胶渗透色谱仪gel permeation chromatograph涂布器spreader点样器sample applicator色谱柱chromatographic column棒状色谱柱monolith column monolith column微粒柱microparticle column填充毛细管柱packed capillary column空心柱open tubular column微径柱microbore column混合柱mixed column组合柱coupled column预柱precolumn保护柱guard column预饱和柱presaturation column浓缩柱concentrating column抑制柱suppression column薄层板thin layer plate浓缩区薄层板concentrating thin layer plate荧光薄层板fluorescence thin layer plate反相薄层板reversed phase thin layer plate梯度薄层板gradient thin layer plate烧结板sintered plate展开室development chamber往复泵reciprocating pump注射泵syringe pump气动泵pneumatic pump蠕动泵peristaltic pump检测器detector微分检测器differential detector积分检测器integral detector总体性能检测器bulk property detector溶质性能检测器solute property detector(示差)折光率检测器[differential] refractive index detector荧光检测器fluorescence detector紫外可见光检测器ultraviolet visible detector电化学检测器electrochemical detector蒸发(激光)光散射检测器[laser] light scattering detector光密度计densitometer薄层扫描仪thin layer scanner柱后反应器post-column reactor体积标记器volume marker记录器recorder积分仪integrator馏分收集器fraction collector工作站work station固定相stationary phase固定液stationary liquid载体support柱填充剂column packing化学键合相填充剂chemically bonded phase packing薄壳型填充剂pellicular packing多孔型填充剂porous packing吸附剂adsorbent离子交换剂ion exchanger基体matrix载板support plate粘合剂binder流动相mobile phase洗脱(淋洗)剂eluant,eluent展开剂developer等水容剂isohydric solvent改性剂modifier显色剂color [developing] agent死时间t0,dead time保留时间tR,retention time调整保留时间t'R,adjusted retention time死体积V0,dead volume保留体积vR,retention volume调整保留体积v'R,adjusted retention volume柱外体积Vext,extra-column volune粒间体积V0,interstitial volume(多孔填充剂的)孔体积VP,pore volume of porous packing 液相总体积Vtol,total liquid volume洗脱体积ve,elution volume流体力学体积vh,hydrodynamic volume相对保留值ri.s,relative retention value分离因子α,separation factor流动相迁移距离dm,mobile phase migration distance流动相前沿mobile phase front溶质迁移距离ds,solute migration distance比移值Rf,Rf value高比移值hRf,high Rf value相对比移值Ri.s,relative Rf value保留常数值Rm,Rm value板效能plate efficiency折合板高hr,reduced plate height分离度R,resolution液相载荷量liquid phase loading离子交换容量ion exchange capacity负载容量loading capacity渗透极限permeability limit排除极限Vh,max,exclusion limit拖尾因子T,tailing factor柱外效应extra-column effect管壁效应wall effect间隔臂效应spacer arm effect边缘效应edge effect斑点定位法localization of spot放射自显影法autoradiography原位定量in situ quantitation生物自显影法bioautography归一法normalization method内标法internal standard method外标法external standard method叠加法addition method普适校准(曲线、函数) calibration function or curve [function]谱带扩展(加宽) band broadening(分离作用的)校准函数或校准曲线universal calibration function or curve [of separation] 加宽校正broadening correction加宽校正因子broadening correction factor溶剂强度参数ε0,solvent strength parameter洗脱序列eluotropic series洗脱(淋洗) elution等度洗脱gradient elution梯度洗脱gradient elution(再)循环洗脱recycling elution线性溶剂强度洗脱linear solvent strength gradient程序溶剂programmed solvent程序压力programmed pressure程序流速programmed flow展开development上行展开ascending development下行展开descending development双向展开two dimensional development 环形展开circular development离心展开centrifugal development向心展开centripetal development径向展开radial development多次展开multiple development分步展开stepwise development连续展开continuous development梯度展开gradient development匀浆填充slurry packing停流进样stop-flow injection阀进样valve injection柱上富集on-column enrichment流出液eluate柱上检测on-column detection柱寿命column life柱流失column bleeding显谱visualization活化activation反冲back flushing脱气degassing沟流channeling过载overloading。
色谱中英文对照
中英文对照色谱词汇间接检测indirect detection间接荧光检测indirect fluorescence detection间接紫外检测indirect ultraviolet detection检测器detector检测器检测限detector detectability检测器灵敏度detector sensitivity检测器线性范围detector linear range阴离子交换剂anion exchanger阴离子交换色谱法anion exchange chromatography, AEC高速逆流色谱法high speed counter-current chromatography高温凝胶色谱法high temperature gel chromatography高效液相色谱-付里叶变换红外分析法high performance liquid ch…高效液相色谱法high performance liquid chromatography高效柱high performance column高压流通池技术high pressure flow cell technique高压输液泵high pressure pump高压梯度high-pressure gradient高压液相色谱法high pressure liquid chromatography阴离子交换树脂anion exchange resin荧光薄层板fluorescent thin layer plate荧光检测器fluorescence detector荧光色谱法fluorescence chromatography迎头色谱法frontal chromatography迎头色谱法frontal method硬(质)凝胶hard gel有机改进剂organic modifier有机相生物传感器Organic biosensor有效峰数effective peak number EPN有效理论塔板数number of effective theoretical plates有效塔板高度effective plate height有效淌度effective mobility淤浆填充法slurry packing method予柱pre-column在线电堆集on-line electrical stacking在柱电导率检测on-column electrical conductivity detection噪声noise噪信比noise –signal ratio增强紫外-可见吸收检测技术UV-visible absorption enhanced det…窄粒度分布narrow particle size distribution折射率检测器refractive index detector, RID真空脱气装置vacuum degasser阵列毛细管电泳capillary array electrophoresis蒸发光散射检测器evaporative light-scattering detector, ELSD整体性质检测器integral property detector正相高效液相色谱法normal phase high performance liquid chro…正相离子对色谱法normal phase ion-pair chromatography正相毛细管电色谱positive capillary electrokinetic chromatog…直接化学离子化direct chemical ionization GC-MS直接激光在柱吸收检测on-column direct laser detection纸色谱法paper chromatography置换色谱法displacement chromatography制备色谱preparative chromatography制备色谱仪preparative chromatograph制备柱preparation column智能色谱chromatography with artificial intelligence质量色谱mass chromatography质量型检测器mass detector质量型检测器mass flow rate sensitive detector中压液相色谱middle-pressure liquid chromatography重建色谱图reconstructive chromatogram重均分子量weight mean molecular weight轴向扩散longitudinal diffusion轴向吸收池absorption pool of axial direction轴向压缩柱axial compression column柱端电导率检测out-let end detection of electrical conductiv…柱负载能力column loadability柱后衍生化post-column derivatization柱老化condition (aging) of column柱流出物(column) effluent柱流失column bleeding柱内径column internal diameter柱前衍生化pro-column derivatization柱切换技术column switching technique柱清洗column cleaning柱容量column capacity柱入口压力column inlet pressure柱色谱法column chromatography柱上检测on-line detection柱渗透性column permeability柱寿命column life柱头进样column head sampling柱外效应extra-column effect柱温箱column oven柱效column efficiency柱压column pressure柱再生column regeneration柱中衍生化on-column derivatization注射泵syringe pump转化定量法trans-quantitative method紫外-可见光检测器ultraviolet visible detector, UV-Vis紫外吸收检测器ultraviolet absorption detector自动进样器automatic sampler自由溶液毛细管电泳free solution capillary electrophoresis总分离效能指标over-all resolution efficiency总交换容量total exchange capacity总渗透体积total osmotic volume纵向扩散longitudinal diffusion组合式仪器系统building block instrument最佳流速optimum flow rate最佳实际流速optimum practical flow rate最小检测量minimum detectable quantity最小检测浓度minimum detectable concentration萃取色谱法extraction chromatography脱气装置degasser外标法external standard method外梯度outside gradient网状结构reticular structure往复泵reciprocating pump往复式隔膜泵reciprocating diaphragm pump微分型检测器differential detector微孔树脂micro-reticular resin微库仑检测器micro coulometric detector微量进样针micro-syringe微量色谱法micro-chromatography微乳液电动色谱microemulsion electrokinetic chromatography 微生物传感器Microbial sensor微生物显影bioautography微填充柱micro-packed column微吸附检测器micro adsorption detector微型柱micro-column涡流扩散eddy diffusion无机离子交换剂inorganic ion exchanger无胶筛分毛细管电泳non-gel capillary electrophoresis无孔单分散填料non-porous monodisperse packing无脉动色谱泵pulse-free chromatographic pump物理钝化法physical deactivation吸附等温线adsorption isotherm吸附剂adsorbing material吸附剂活性adsorbent activity吸附平衡常数adsorption equilibrium constant吸附溶剂强度参数adsorption solvent strength parameter吸附色谱法adsorption chromatography吸附型PLOT柱adsorption type porous-layer open tubular colum…吸附柱adsorption column吸光度比值法absorbance ratio method洗脱强度eluting power显色器color-developing sprayer限制扩散理论theory of restricted diffusion线速度linear velocity线性梯度linear gradient相比率phase ratio相对保留值relative retention value相对比移值relative Rf value相对挥发度relative volatility相对灵敏度relative sensitivity相对碳(重量)响应因子relative carbon response factor相对响应值relative response相对校正因子relative correction factor相交束激光诱导的热透镜测量heat lens detection of intersect …相似相溶原则rule of similarity响应时间response time响应值response小角激光散射光度计low-angle laser light scattering photomet…小内径毛细管柱Microbore column校正保留体积corrected retention volume校正曲线法calibration curve method校正因子correction factor旋转薄层法rotating thin layer chromatography旋转小室逆流色谱rotational little-chamber counter-current c…选择性检测器selective detector循环色谱法recycling chromatography压电晶体piezoelectric crystal压电免疫传感器Piezoelectric Immunosensor压电转换器piezoelectric transducer压力保护pressure protect压力上限pressure high limit压力梯度校正因子pressure gradient correction factor压力下限pressure low limit衍生化法derivatization method衍生化试剂derivatization reagent阳离子交换剂cation exchanger阳离子交换色谱法cation exchange chromatography, CEC氧化铝色谱法alumina chromatography样品环sample loop样品预处理sample pretreatment液-液分配色谱法liquid-liquid partition chromatography液-液色谱法liquid-liquid chromatography液滴逆流色谱drop counter-current chromatography液固色谱liquid-solid chromatography液晶固定相liquid crystal stationary phase液态离子交换剂liquid ion exchanger液相传质阻力resistance of liquid mass transfer液相色谱-傅里叶变换红外光谱联用liquid chromatography-FTIR 液相色谱-质谱分析法liquid chromatography-mass spectrometry 液相色谱-质谱仪liquid chromatography-mass spectrometer液相色谱法liquid chromatography液相载荷量liquid phase loading溶剂效率solvent efficiency溶解度参数solubility parameter溶液性能检测器solution property detector溶胀swelling溶质性质检测器solute property detector容量因子capacity factor渗透极限分子量permeation limit molecular weight生物色谱biological chromatography生物特异性柱biospecific column生物自显影法bioautography升温速率temperature rate湿法柱填充wet column packing十八烷基键合硅胶octadecyl silane石墨化碳黑graphitized carbon black示差折光检测器differential refraction detector试剂显色法reagent color-developing method手动进样器manual injector手性氨基酸衍生物GC固定相chiral amino acid derivatives stat…手性拆分试剂chiral selectors手性固定相chiral stationary phase手性固定相拆分法chiral solid phase separation手性环糊精衍生物GC固定相chiral cyclodextrin der GC手性金属络合物GC固定相chirametal stationary phase in GC 手性流动相chiral mobile phase手性流动相拆分法chiral mobile phase separation手性色谱chiral chromatography手性试剂chiral reagent手性衍生化法chiral derivation method疏溶剂理论solvophobic theory疏溶剂色谱法solvophobic chromatography疏溶剂作用理论solvophobic interaction principle疏水作用色谱hydrophobic interaction chromatography树脂交换容量exchange capacity of resin数均分子量number mean molecular weight双保留机理dual reservation mechanism双活塞往复泵two-piston reciprocating pump双束差分检测器detector of dual-beam difference 双柱色谱法dual column chromatography水凝胶hydragel水系凝胶色谱柱aqua-system gel column死区域dead zone死体积dead volume塔板理论方程plate theory equation碳分子筛carbon molecular sieve特殊选择固定液selective stationary phase梯度洗脱gradient elution梯度洗脱装置gradient elution device梯度液相色谱gradient liquid chromatography体积排斥理论size exclusion theory体积排斥色谱size exclusion chromatography体积色谱法volumetric chromatography填充柱packed column填料packing material停流进样stop-flow injection通用型检测器common detector涂层毛细管coated capillary拖尾峰tailing peak拖尾因子tailing factor流动分离理论separation by flow流动相mobile phase流动相梯度eluent gradient流体动力学进样hydrostatic pressure injection流体力学体积hydrodynamic volume流型扩散dispersion due to flow profile脉冲阻尼器pulse damper酶传感器Enzyme sensor酶联免疫传感器Enzyme linked immunosensor 酶免疫分析enzyme immnunoassay内标法internal standard method内标物internal standard内梯度inside gradient逆流色谱法counter-current chromatography逆流色谱仪counter current chromatograph凝胶过滤色谱gel filtration chromatography凝胶内体积gel inner volume凝胶色谱法gel chromatography凝胶色谱仪gel chromatograph凝胶渗透色谱gel permeation chromatography凝胶外体积gel interstitial volume凝胶柱gel column浓度梯度成像检测器concentration gradient imaging detector浓度型检测器concentration detector排斥极限分子量exclusion limit molecular weight排斥体积exclusion volume排阻薄层色谱法exclusion TLC漂移drift迁移时间migration time迁移时间窗口the window of migration time前延峰leading peak前沿色谱法frontal chromatography强碱性阴离子交换剂strong-base anion exchanger强酸性阳离子交换剂strongly acidic cation exchanger切换时间switching time去离子水deionized water全多孔硅胶macro-reticular silica gel全多孔型填料macro-reticular packing material全二维色谱Comprehensive two-dim ensional gas chromatography…全硅烷化去活complete silylanization deactivation溶剂强度solvent strength激光解吸质谱法laser desorption MS, LDMS激光色谱laser chromatography激光诱导光束干涉检测detection of laser-induced light beam I…激光诱导毛细管振动测量laser-reduced capillary vibration det…激光诱导荧光检测器laser-induced fluorescence detector记忆峰memory peak记忆效应memory effect夹层槽sandwich chamber假峰ghost peak间断洗脱色谱法interrupted-elution chromatography间接光度(检测)离子色谱法indirect photometric ion chromato…间接光度(检测)色谱法indirect photometric chromatography减压液相色谱vacuum liquid chromatography键合固定相bonded stationary phase键合型离子交换剂bonded ion exchanger焦耳热joule heating胶束薄层色谱法micellar thin layer chromatography胶束液相色谱法micellar liquid chromatography交联度crosslinking degree阶梯梯度stagewise gradient进样阀injection valve进样量sample size进样器injector聚苯乙烯PSDVB聚硅氧烷高温裂解去活high-temperature pyrolysis deactivation…聚合物基质离子交换剂polymer substrate ion exchanger绝对检测器absolute detector可见光检测器visible light detector可交换离子exchangable ion空间性谱带加宽band broadening in space空穴色谱法vacancy chromatography孔结构pore structure孔径pore diameter孔径分布pore size distribution控制单元control unit快速色谱法high-speed chromatography理论塔板高度height equivalent to a theoretical plate(HETP)理论塔板数number of theoretical plates峰面积peak area峰面积测量法measurement of peak area峰面积校正calibration of peak area峰容量peak capacity固定相stationary phase固定液stationary liquid固定液的相对极性relative polarity of stationary liquid固定液极性stationary liquid polarity固相扩散solid diffusion固相荧光免疫分析solid phase fluorescence immunoassay固有粘度intrinsic viscosity光散射检测器light scattering detector硅胶silica gel硅烷化法silanization硅烷化法silanizing硅烷化载体silanized support过压液相色谱法over pressured liquid chromatography,OPLC恒流泵constant flow pump恒温操作constant temperature method恒压泵constant pressure pump红色载体red support红外检测器infrared detector红外总吸光度重建色谱图total infrared absorbance reconstruct…化合物形成色谱compound-formation chromatography化学发光检测器chemiluminescence detector化学发光检测器Chemiluminescence detector, SCD化学键合固定相bonded stationary phase化学键合相色谱bonded phase chromatography化学色谱法chemi-chromatography环糊精电动色谱cyclodextrin electrokinetic chromatography环形展开比移值circular development Rf value环形展开法circular development缓冲溶液添加剂buffer additives辉光放电检测器glow discharge detector混合床离子交换固定相mixed-bed ion exchange stationary phase 混合床柱mixed bed column活塞泵piston pump活性activation活性硅胶activated silica gel活性氧化铝activated aluminium oxide基流background current or base current基线baseline基线宽度baseline width基质substrate materials基质隔离技术matrix isolation technique电歧视效应the effect of electrical discrimination电迁移进样electrophoretic injection电渗流electroendosmotic flow电渗流标记物electroendosmotic flow marker电渗流淌度electroendosmotic mobility电泳淌度electrophoretic mobility调整保留时间adjusted retention time调整保留体积adjusted retention volume叠加内标法added internal standard method高效毛细管电泳high-performance capillary electrophoresis归一化法normalization method毛细管等电聚焦capillary isoelectric focusing毛细管等速电泳isotachophoresis毛细管电色谱capillary electrochromatography毛细管电泳capillary electrophoresis毛细管电泳电喷雾质谱联用capillary electrophoresis – electr芯片电泳microchip electrophoresis色谱法chromatography色谱峰chromatographic peak色谱峰区域宽度peak width色谱富集过样samt injection of chromatography色谱工作站chromatographic working station色谱图chromatogram色谱仪chromatograph色谱柱chromatographic column色谱柱column色谱柱切换技术switching column technique毛细管超临界流体色谱法capillary supercritical fluid chromat…毛细管电泳基质辅助激光解吸电离质谱离线检测off-line capillar…毛细管电泳离子分析capillary ion analysis毛细管电泳免疫分析immunity analysis of capillary elec tropho…毛细管胶束电动色谱micellar electrokinetic chromatography毛细管凝胶电泳capillary gel electrophoresis毛细管凝胶柱capillary gel column毛细管亲和电泳affinity capillary electrophoresis毛细管区带电泳capillary zone electrophoresis毛细管有效长度the effective length of capillary electroph or…二极管阵列检测器diode-array detector, DAD二维色谱法two-dimensional chromatography二元溶剂体系dual solvent system反冲洗back wash反吹技术back flushing technique反峰negative peak反离子counter ion反相高效液相色谱法reversed phase high performance liquid ch…反相离子对色谱reversed phase ion pair chromatography反相离子对色谱法reversed phase ion-pair chromatography反相毛细管电色谱reverse capillary electrokinetic chromatogr…反相柱reversed phase column反应色谱reaction chromatography反圆心式展开anti-circular development反转电渗流reverse electroendosmotic flow范第姆特方程式van Deemter equation仿生传感器Biomimic electrode放射性检测器radioactivity detector放射自显影autoradiography非极性固定相non-polar stationary phase非极性键合相non-polar bonded phase非水系凝胶色谱柱non-aqua-system gel column非水相色谱nonaqueous phase chromatography非吸附性载体non-adsorptive support非线性分流non-linearity split stream非线性色谱non-linear chromatography非线性吸附等温线non-linear adsorption isotherm酚醛离子交换树脂phenolic ion exchange resin分离-反应-分离展开SRS development分离数separation number分离因子separation factor分离柱separation column分配等温线distribution isotherm分配色谱partition chromatography分配系数partition coefficient分析型色谱仪analytical type chromatograph分子扩散molecular diffusion封尾endcapping峰高peak heightpH梯度动态分离dynamic separation of the pH gradientpH值梯度洗脱pH gradient elutionZata电势Zata potentialZ形池Z-form pool氨基键合相amino-bonded phase氨基酸分析仪amino acid analyzer安培检测器ampere detector白色载体white support半微柱semimicro-column半制备柱semi-preparation column包覆型离子交换剂coated ion exchanger包覆型填料coated packing material保护柱guard column保留间隙retention gap保留时间retention time保留体积retention volume保留温度retention temperature保留值定性法retention qualitative method保留值沸点规律boiling point rule of retention保留值碳数规律carbon number rule of retention保留指数retention index单活塞往复泵single piston reciprocating pump单相色谱仪single phase chromatograph单向阀one-way valve单柱离子色谱法single column ion chromatography等度洗脱isocratic elution等离子体色谱法plasma chromatography等途电泳-毛细管区带电泳耦合进样isotachophoresis injection-c…低负荷柱low load column低容量柱low capacity column低压梯度low-pressure gradient低压液相色谱low-pressure liquid chromatography电导池conductance cell电导检测法conductance detection电荷转移分光光度法charge transfer spectrophotometry电化学检测器electrochemical detector电解抑制器electrolyze suppressor保留指数定性法retention index qualitative method背景电导background conductance苯酚磺酸树脂phenol sulfonic acid resin苯乙烯styrene比保留体积specific retention volume比例阀proportional valve比渗透率specific permeability比移值Rf value便携式色谱仪portable chromatograph标准偏差standard deviation表观电泳淌度apparent electrophoretic mobility表观交换容量apparent exchange capacity表面电位检测器surface potential detector表面多孔硅胶superficially porous silica gel表面多孔填料superficially porous packing material表面多孔型离子交换剂superficially porous ion-exchanger玻璃球载体glass beads support不分流进样splitless sampling参比柱reference column场放大进样electrical field magnified injection场流分离field-flow fractionation场流分离仪field-flow fractionation场效应生物传感器Field effect transistor based Biosensor常压液相色谱法common-pressure liquid chromatography超声波脱气ultrasonic degas程序变流色谱法programmed flow (gas) chromatography程序升温进样programmed temperature sampling程序升温色谱法programmed temperature (gas) chromatography 程序升温蒸发器programmed temperature vaporizer ,PTV程序升压programmed pressure大孔树脂macro-reticular resin大孔填料macro-reticular packing material大内径毛细管柱Megaobore column。
色谱中英文对照
中英文对照色谱词汇间接检测indirect detection间接荧光检测indirect fluorescence detection间接紫外检测indirect ultraviolet detection检测器detector检测器检测限detector detectability检测器灵敏度detector sensitivity检测器线性范围detector linear range阴离子交换剂anion exchanger阴离子交换色谱法anion exchange chromatography, AEC高速逆流色谱法high speed counter-current chromatography高温凝胶色谱法high temperature gel chromatography高效液相色谱-付里叶变换红外分析法high performance liquid ch…高效液相色谱法high performance liquid chromatography高效柱high performance column高压流通池技术high pressure flow cell technique高压输液泵high pressure pump高压梯度high-pressure gradient高压液相色谱法high pressure liquid chromatography阴离子交换树脂anion exchange resin荧光薄层板fluorescent thin layer plate荧光检测器fluorescence detector荧光色谱法fluorescence chromatography迎头色谱法frontal chromatography迎头色谱法frontal method硬(质)凝胶hard gel有机改进剂organic modifier有机相生物传感器Organic biosensor有效峰数effective peak number EPN有效理论塔板数number of effective theoretical plates有效塔板高度effective plate height有效淌度effective mobility淤浆填充法slurry packing method予柱pre-column在线电堆集on-line electrical stacking在柱电导率检测on-column electrical conductivity detection噪声noise噪信比noise –signal ratio增强紫外-可见吸收检测技术UV-visible absorption enhanced det…窄粒度分布narrow particle size distribution折射率检测器refractive index detector, RID真空脱气装置vacuum degasser阵列毛细管电泳capillary array electrophoresis蒸发光散射检测器evaporative light-scattering detector, ELSD整体性质检测器integral property detector正相高效液相色谱法normal phase high performance liquid chro…正相离子对色谱法normal phase ion-pair chromatography正相毛细管电色谱positive capillary electrokinetic chromatog…直接化学离子化direct chemical ionization GC-MS直接激光在柱吸收检测on-column direct laser detection纸色谱法paper chromatography置换色谱法displacement chromatography制备色谱preparative chromatography制备色谱仪preparative chromatograph制备柱preparation column智能色谱chromatography with artificial intelligence质量色谱mass chromatography质量型检测器mass detector质量型检测器mass flow rate sensitive detector中压液相色谱middle-pressure liquid chromatography重建色谱图reconstructive chromatogram重均分子量weight mean molecular weight轴向扩散longitudinal diffusion轴向吸收池absorption pool of axial direction轴向压缩柱axial compression column柱端电导率检测out-let end detection of electrical conductiv…柱负载能力column loadability柱后衍生化post-column derivatization柱老化condition (aging) of column柱流出物(column) effluent柱流失column bleeding柱内径column internal diameter柱前衍生化pro-column derivatization柱切换技术column switching technique柱清洗column cleaning柱容量column capacity柱入口压力column inlet pressure柱色谱法column chromatography柱上检测on-line detection柱渗透性column permeability柱寿命column life柱头进样column head sampling柱外效应extra-column effect柱温箱column oven柱效column efficiency柱压column pressure柱再生column regeneration柱中衍生化on-column derivatization注射泵syringe pump转化定量法trans-quantitative method紫外-可见光检测器ultraviolet visible detector, UV-Vis紫外吸收检测器ultraviolet absorption detector自动进样器automatic sampler自由溶液毛细管电泳free solution capillary electrophoresis总分离效能指标over-all resolution efficiency总交换容量total exchange capacity总渗透体积total osmotic volume纵向扩散longitudinal diffusion组合式仪器系统building block instrument最佳流速optimum flow rate最佳实际流速optimum practical flow rate最小检测量minimum detectable quantity最小检测浓度minimum detectable concentration萃取色谱法extraction chromatography脱气装置degasser外标法external standard method外梯度outside gradient网状结构reticular structure往复泵reciprocating pump往复式隔膜泵reciprocating diaphragm pump微分型检测器differential detector微孔树脂micro-reticular resin微库仑检测器micro coulometric detector微量进样针micro-syringe微量色谱法micro-chromatography微乳液电动色谱microemulsion electrokinetic chromatography 微生物传感器Microbial sensor微生物显影bioautography微填充柱micro-packed column微吸附检测器micro adsorption detector微型柱micro-column涡流扩散eddy diffusion无机离子交换剂inorganic ion exchanger无胶筛分毛细管电泳non-gel capillary electrophoresis无孔单分散填料non-porous monodisperse packing无脉动色谱泵pulse-free chromatographic pump物理钝化法physical deactivation吸附等温线adsorption isotherm吸附剂adsorbing material吸附剂活性adsorbent activity吸附平衡常数adsorption equilibrium constant吸附溶剂强度参数adsorption solvent strength parameter吸附色谱法adsorption chromatography吸附型PLOT柱adsorption type porous-layer open tubular colum…吸附柱adsorption column吸光度比值法absorbance ratio method洗脱强度eluting power显色器color-developing sprayer限制扩散理论theory of restricted diffusion线速度linear velocity线性梯度linear gradient相比率phase ratio相对保留值relative retention value相对比移值relative Rf value相对挥发度relative volatility相对灵敏度relative sensitivity相对碳(重量)响应因子relative carbon response factor相对响应值relative response相对校正因子relative correction factor相交束激光诱导的热透镜测量heat lens detection of intersect …相似相溶原则rule of similarity响应时间response time响应值response小角激光散射光度计low-angle laser light scattering photomet…小内径毛细管柱Microbore column校正保留体积corrected retention volume校正曲线法calibration curve method校正因子correction factor旋转薄层法rotating thin layer chromatography旋转小室逆流色谱rotational little-chamber counter-current c…选择性检测器selective detector循环色谱法recycling chromatography压电晶体piezoelectric crystal压电免疫传感器Piezoelectric Immunosensor压电转换器piezoelectric transducer压力保护pressure protect压力上限pressure high limit压力梯度校正因子pressure gradient correction factor压力下限pressure low limit衍生化法derivatization method衍生化试剂derivatization reagent阳离子交换剂cation exchanger阳离子交换色谱法cation exchange chromatography, CEC氧化铝色谱法alumina chromatography样品环sample loop样品预处理sample pretreatment液-液分配色谱法liquid-liquid partition chromatography液-液色谱法liquid-liquid chromatography液滴逆流色谱drop counter-current chromatography液固色谱liquid-solid chromatography液晶固定相liquid crystal stationary phase液态离子交换剂liquid ion exchanger液相传质阻力resistance of liquid mass transfer液相色谱-傅里叶变换红外光谱联用liquid chromatography-FTIR 液相色谱-质谱分析法liquid chromatography-mass spectrometry 液相色谱-质谱仪liquid chromatography-mass spectrometer液相色谱法liquid chromatography液相载荷量liquid phase loading溶剂效率solvent efficiency溶解度参数solubility parameter溶液性能检测器solution property detector溶胀swelling溶质性质检测器solute property detector容量因子capacity factor渗透极限分子量permeation limit molecular weight生物色谱biological chromatography生物特异性柱biospecific column生物自显影法bioautography升温速率temperature rate湿法柱填充wet column packing十八烷基键合硅胶octadecyl silane石墨化碳黑graphitized carbon black示差折光检测器differential refraction detector试剂显色法reagent color-developing method手动进样器manual injector手性氨基酸衍生物GC固定相chiral amino acid derivatives stat…手性拆分试剂chiral selectors手性固定相chiral stationary phase手性固定相拆分法chiral solid phase separation手性环糊精衍生物GC固定相chiral cyclodextrin der GC手性金属络合物GC固定相chirametal stationary phase in GC 手性流动相chiral mobile phase手性流动相拆分法chiral mobile phase separation手性色谱chiral chromatography手性试剂chiral reagent手性衍生化法chiral derivation method疏溶剂理论solvophobic theory疏溶剂色谱法solvophobic chromatography疏溶剂作用理论solvophobic interaction principle疏水作用色谱hydrophobic interaction chromatography树脂交换容量exchange capacity of resin数均分子量number mean molecular weight双保留机理dual reservation mechanism双活塞往复泵two-piston reciprocating pump双束差分检测器detector of dual-beam difference 双柱色谱法dual column chromatography水凝胶hydragel水系凝胶色谱柱aqua-system gel column死区域dead zone死体积dead volume塔板理论方程plate theory equation碳分子筛carbon molecular sieve特殊选择固定液selective stationary phase梯度洗脱gradient elution梯度洗脱装置gradient elution device梯度液相色谱gradient liquid chromatography体积排斥理论size exclusion theory体积排斥色谱size exclusion chromatography体积色谱法volumetric chromatography填充柱packed column填料packing material停流进样stop-flow injection通用型检测器common detector涂层毛细管coated capillary拖尾峰tailing peak拖尾因子tailing factor流动分离理论separation by flow流动相mobile phase流动相梯度eluent gradient流体动力学进样hydrostatic pressure injection流体力学体积hydrodynamic volume流型扩散dispersion due to flow profile脉冲阻尼器pulse damper酶传感器Enzyme sensor酶联免疫传感器Enzyme linked immunosensor 酶免疫分析enzyme immnunoassay内标法internal standard method内标物internal standard内梯度inside gradient逆流色谱法counter-current chromatography逆流色谱仪counter current chromatograph凝胶过滤色谱gel filtration chromatography凝胶内体积gel inner volume凝胶色谱法gel chromatography凝胶色谱仪gel chromatograph凝胶渗透色谱gel permeation chromatography凝胶外体积gel interstitial volume凝胶柱gel column浓度梯度成像检测器concentration gradient imaging detector浓度型检测器concentration detector排斥极限分子量exclusion limit molecular weight排斥体积exclusion volume排阻薄层色谱法exclusion TLC漂移drift迁移时间migration time迁移时间窗口the window of migration time前延峰leading peak前沿色谱法frontal chromatography强碱性阴离子交换剂strong-base anion exchanger强酸性阳离子交换剂strongly acidic cation exchanger切换时间switching time去离子水deionized water全多孔硅胶macro-reticular silica gel全多孔型填料macro-reticular packing material全二维色谱Comprehensive two-dim ensional gas chromatography…全硅烷化去活complete silylanization deactivation溶剂强度solvent strength激光解吸质谱法laser desorption MS, LDMS激光色谱laser chromatography激光诱导光束干涉检测detection of laser-induced light beam I…激光诱导毛细管振动测量laser-reduced capillary vibration det…激光诱导荧光检测器laser-induced fluorescence detector记忆峰memory peak记忆效应memory effect夹层槽sandwich chamber假峰ghost peak间断洗脱色谱法interrupted-elution chromatography间接光度(检测)离子色谱法indirect photometric ion chromato…间接光度(检测)色谱法indirect photometric chromatography减压液相色谱vacuum liquid chromatography键合固定相bonded stationary phase键合型离子交换剂bonded ion exchanger焦耳热joule heating胶束薄层色谱法micellar thin layer chromatography胶束液相色谱法micellar liquid chromatography交联度crosslinking degree阶梯梯度stagewise gradient进样阀injection valve进样量sample size进样器injector聚苯乙烯PSDVB聚硅氧烷高温裂解去活high-temperature pyrolysis deactivation…聚合物基质离子交换剂polymer substrate ion exchanger绝对检测器absolute detector可见光检测器visible light detector可交换离子exchangable ion空间性谱带加宽band broadening in space空穴色谱法vacancy chromatography孔结构pore structure孔径pore diameter孔径分布pore size distribution控制单元control unit快速色谱法high-speed chromatography理论塔板高度height equivalent to a theoretical plate(HETP)理论塔板数number of theoretical plates峰面积peak area峰面积测量法measurement of peak area峰面积校正calibration of peak area峰容量peak capacity固定相stationary phase固定液stationary liquid固定液的相对极性relative polarity of stationary liquid固定液极性stationary liquid polarity固相扩散solid diffusion固相荧光免疫分析solid phase fluorescence immunoassay固有粘度intrinsic viscosity光散射检测器light scattering detector硅胶silica gel硅烷化法silanization硅烷化法silanizing硅烷化载体silanized support过压液相色谱法over pressured liquid chromatography,OPLC恒流泵constant flow pump恒温操作constant temperature method恒压泵constant pressure pump红色载体red support红外检测器infrared detector红外总吸光度重建色谱图total infrared absorbance reconstruct…化合物形成色谱compound-formation chromatography化学发光检测器chemiluminescence detector化学发光检测器Chemiluminescence detector, SCD化学键合固定相bonded stationary phase化学键合相色谱bonded phase chromatography化学色谱法chemi-chromatography环糊精电动色谱cyclodextrin electrokinetic chromatography环形展开比移值circular development Rf value环形展开法circular development缓冲溶液添加剂buffer additives辉光放电检测器glow discharge detector混合床离子交换固定相mixed-bed ion exchange stationary phase 混合床柱mixed bed column活塞泵piston pump活性activation活性硅胶activated silica gel活性氧化铝activated aluminium oxide基流background current or base current基线baseline基线宽度baseline width基质substrate materials基质隔离技术matrix isolation technique电歧视效应the effect of electrical discrimination电迁移进样electrophoretic injection电渗流electroendosmotic flow电渗流标记物electroendosmotic flow marker电渗流淌度electroendosmotic mobility电泳淌度electrophoretic mobility调整保留时间adjusted retention time调整保留体积adjusted retention volume叠加内标法added internal standard method高效毛细管电泳high-performance capillary electrophoresis归一化法normalization method毛细管等电聚焦capillary isoelectric focusing毛细管等速电泳isotachophoresis毛细管电色谱capillary electrochromatography毛细管电泳capillary electrophoresis毛细管电泳电喷雾质谱联用capillary electrophoresis – electr芯片电泳microchip electrophoresis色谱法chromatography色谱峰chromatographic peak色谱峰区域宽度peak width色谱富集过样samt injection of chromatography色谱工作站chromatographic working station色谱图chromatogram色谱仪chromatograph色谱柱chromatographic column色谱柱column色谱柱切换技术switching column technique毛细管超临界流体色谱法capillary supercritical fluid chromat…毛细管电泳基质辅助激光解吸电离质谱离线检测off-line capillar…毛细管电泳离子分析capillary ion analysis毛细管电泳免疫分析immunity analysis of capillary elec tropho…毛细管胶束电动色谱micellar electrokinetic chromatography毛细管凝胶电泳capillary gel electrophoresis毛细管凝胶柱capillary gel column毛细管亲和电泳affinity capillary electrophoresis毛细管区带电泳capillary zone electrophoresis毛细管有效长度the effective length of capillary electroph or…二极管阵列检测器diode-array detector, DAD二维色谱法two-dimensional chromatography二元溶剂体系dual solvent system反冲洗back wash反吹技术back flushing technique反峰negative peak反离子counter ion反相高效液相色谱法reversed phase high performance liquid ch…反相离子对色谱reversed phase ion pair chromatography反相离子对色谱法reversed phase ion-pair chromatography反相毛细管电色谱reverse capillary electrokinetic chromatogr…反相柱reversed phase column反应色谱reaction chromatography反圆心式展开anti-circular development反转电渗流reverse electroendosmotic flow范第姆特方程式van Deemter equation仿生传感器Biomimic electrode放射性检测器radioactivity detector放射自显影autoradiography非极性固定相non-polar stationary phase非极性键合相non-polar bonded phase非水系凝胶色谱柱non-aqua-system gel column非水相色谱nonaqueous phase chromatography非吸附性载体non-adsorptive support非线性分流non-linearity split stream非线性色谱non-linear chromatography非线性吸附等温线non-linear adsorption isotherm酚醛离子交换树脂phenolic ion exchange resin分离-反应-分离展开SRS development分离数separation number分离因子separation factor分离柱separation column分配等温线distribution isotherm分配色谱partition chromatography分配系数partition coefficient分析型色谱仪analytical type chromatograph分子扩散molecular diffusion封尾endcapping峰高peak heightpH梯度动态分离dynamic separation of the pH gradientpH值梯度洗脱pH gradient elutionZata电势Zata potentialZ形池Z-form pool氨基键合相amino-bonded phase氨基酸分析仪amino acid analyzer安培检测器ampere detector白色载体white support半微柱semimicro-column半制备柱semi-preparation column包覆型离子交换剂coated ion exchanger包覆型填料coated packing material保护柱guard column保留间隙retention gap保留时间retention time保留体积retention volume保留温度retention temperature保留值定性法retention qualitative method保留值沸点规律boiling point rule of retention保留值碳数规律carbon number rule of retention保留指数retention index单活塞往复泵single piston reciprocating pump单相色谱仪single phase chromatograph单向阀one-way valve单柱离子色谱法single column ion chromatography等度洗脱isocratic elution等离子体色谱法plasma chromatography等途电泳-毛细管区带电泳耦合进样isotachophoresis injection-c…低负荷柱low load column低容量柱low capacity column低压梯度low-pressure gradient低压液相色谱low-pressure liquid chromatography电导池conductance cell电导检测法conductance detection电荷转移分光光度法charge transfer spectrophotometry电化学检测器electrochemical detector电解抑制器electrolyze suppressor保留指数定性法retention index qualitative method背景电导background conductance苯酚磺酸树脂phenol sulfonic acid resin苯乙烯styrene比保留体积specific retention volume比例阀proportional valve比渗透率specific permeability比移值Rf value便携式色谱仪portable chromatograph标准偏差standard deviation表观电泳淌度apparent electrophoretic mobility表观交换容量apparent exchange capacity表面电位检测器surface potential detector表面多孔硅胶superficially porous silica gel表面多孔填料superficially porous packing material表面多孔型离子交换剂superficially porous ion-exchanger玻璃球载体glass beads support不分流进样splitless sampling参比柱reference column场放大进样electrical field magnified injection场流分离field-flow fractionation场流分离仪field-flow fractionation场效应生物传感器Field effect transistor based Biosensor常压液相色谱法common-pressure liquid chromatography超声波脱气ultrasonic degas程序变流色谱法programmed flow (gas) chromatography程序升温进样programmed temperature sampling程序升温色谱法programmed temperature (gas) chromatography 程序升温蒸发器programmed temperature vaporizer ,PTV程序升压programmed pressure大孔树脂macro-reticular resin大孔填料macro-reticular packing material大内径毛细管柱Megaobore column。
译文版ISO9377-2000气相色谱法测定石油烃(C10~C40)
ISO 9377-2水质C10~C40) 气相色谱法测定石油烃(气相色谱法测定石油烃(C10~C40 )1 范围ISO9377 第2 部分采用气相色谱法测定水质中的矿物油(碳氢化合物)含量。
本法适用于地表水、废水及废水处理厂处理水中石油烃含量在0.1mg/L 以上的水质。
本法不适用于含有挥发性石油烃含量的测定,在一定气相色谱图基础上可给出石油烃的定性信息。
注1 可测定土壤和沉积物中的石油烃。
参见ISO/TR 11046注2 如果是应用于蔬菜油和动物有油质,单位是质量浓度,且浓度不应超过150mg/L, 因在净化时,净化柱的吸附能力不足而导致。
2 参考标准ISO5667-3:1994 part3ISO 8466-1 part13 术语和定义(略)4 干扰弱极性的化合物(如:卤代烃)和高含量的极性化合物干扰测定;表面活性物质干扰萃取步骤。
5原理水样中的石油烃类由萃取剂萃取。
弗罗里硅土净化去除极性化合物,纯化后GC/FID 测定,计算正癸烷和正四十烷标准溶液限定范围内的所有峰面积总和,使用石油烃标准物质外标定量。
技术熟练的员工按9377 测试的每一个步骤细节是必须的。
也必须明白萃取的部分问题需要一个特别的操作条件。
注:如需更低的检出限,可使用石油醚作为萃取溶剂并配合大体积进样。
6试剂和材料所有实验用试剂需是试剂级并适合实验测试目的需要,所有试剂均应通过空白验收。
6.1实验用水蒸馏水或是去除有机物的纯净水,如可用活性碳吸附后用于实验。
6.2单一碳氢化合物或是石油醚(36-69),改变萃取剂,重复性验证必须进行。
6.3无水硫酸钠,550℃下加热至少2 小时。
6.4七水硫酸镁,MgSO4·7H2O6.5无机酸,如盐酸6.6丙酮:C3H6O6.7弗罗里硅土柱:粒径在150μm~250μm(60~10目0 )之间,140℃下加热至少16 小时后在分子筛干燥器中保存。
可直购市售。
6.8混合石油烃6.8.1标准混合液可购等量的两种不同的石油烃类(A 型为柴油类,B型沸点再高的不同与A 的石油烃),浓度为10mg/mL。
中英文色谱术语大全(900词)
阴离子交换色谱法anion exchange chromatography, AEC 阴离子交换树脂anion exchange resin荧光薄层板fluorescent thin layer plate荧光检测器fluorescence detector荧光色谱法fluorescence chromatography迎头色谱法frontal chromatography迎头色谱法frontal method硬(质)凝胶hard gel涌浪效应surge effect有机改进剂organic modifier有机相生物传感器Organic biosensor有效峰数effective peak number EPN有效理论塔板数number of effective theoretical plates有效塔板高度effective plate height有效淌度effective mobility釉化处理glazing淤浆填充法slurry packing method予柱guard column予柱pre-column圆筒模型cylindrical model圆型纸色谱法circular paper chromatography圆形色谱法circular chromatography圆柱状超微薄层色谱法ultra micro TLC on a cylindrical suppor…圆锥模型conical model载气carrier gas载气净化器carry gas cleanser载气流速flow rate载气平均流速average flow rate载体support载体的钝化deactivation of support载体的活性部位active site of support载体涂层开口管柱support coated open tubular column,SCOT再生剂regenerant在线电堆集on-line electrical stacking在柱电导率检测on-column electrical conductivity detection噪声noise噪信比noise –signal ratio皂膜流量计soap film gas meter增强紫外-可见吸收检测技术UV-visible absorption enhanced det…窄粒度分布narrow particle size distribution粘度检测器viscosity detector展开development展开槽developing tank展开槽饱和Chamber saturation展开剂developer折射率检测器refractive index detector, RID真空脱气装置vacuum degasser阵列毛细管电泳capillary array electrophoresis蒸发光散射检测器evaporative light-scattering detector, ELSD整体性质检测器integral property detector正相高效液相色谱法normal phase high performance liquid chro…正相离子对色谱法normal phase ion-pair chromatography正相毛细管电色谱positive capillary e lectrokinetic chromatog…直接化学离子化direct chemical ionization GC-MS直接激光在柱吸收检测on-column direct laser detection指数式流动exponential flow纸色谱法paper chromatography置换色谱法displacement chromatography制备色谱preparative chromatography制备色谱仪preparative chromatograph制备柱preparation column智能色谱chromatography with artificial intelligence质量流量mass flow rate质量色谱mass chromatography质量型检测器mass detector质量型检测器mass flow rate sensitive detector中空纤维抑制器hollow fiber suppressor中压液相色谱middle-pressure liquid chromatography重建色谱图reconstructive chromatogram重均分子量weight mean molecular weight轴向扩散longitudinal diffusion轴向吸收池absorption pool of axial direction轴向压缩柱axial compression column柱端电导率检测out-let end detection of electrical conductiv…柱负载能力column loadability柱后衍生化post-column derivatization柱老化column ageing柱老化condition (aging) of column柱流出物(column) effluent柱流失column bleeding柱内径column internal diameter柱前衍生化pro-column derivatization柱切换技术column switching technique柱清洗column cleaning柱容量column capacity柱入口压力column inlet pressure柱色谱法column chromatography柱上检测on-line detection柱渗透性column permeability柱寿命column life柱头进样column head sampling柱外效应extra-column effect柱温箱column oven柱效column efficiency柱压column pressure柱再生column regeneration柱中衍生化on-column derivatization注射泵syringe pump转化定量法trans-quantitative method紫外-可见光检测器ultraviolet visible detector, UV-Vis紫外吸收检测器ultraviolet absorption detector自动进样器automatic sampler自由溶液毛细管电泳free solution capillary electrophoresis 总分离效能指标over-all resolution efficiency总交换容量total exchange capacity总渗透体积total osmotic volume纵向扩散longitudinal diffusion组合式仪器系统building block instrument最佳流速optimum flow rate最佳实际流速optimum practical flow rate最小检测量minimum detectable quantity最小检测浓度minimum detectable concentration萃取色谱法extraction chromatography氩电离检测器argon ionization detector螯合离子交换剂chelating ion exchanger螯合离子色谱法chelating ion chromatography螯合树脂chelating resin脱氧核糖核酸电化学传感器DNA sensor外标法external standard method外梯度outside gradient网状结构reticular structure往复泵reciprocating pump往复式隔膜泵reciprocating diaphragm pump微分型检测器differential detector微孔树脂micro-reticular resin微库仑检测器micro coulometric detector微量进样针micro-syringe微量色谱法micro-chromatography微膜抑制器micro-membrane suppressor微乳液电动色谱microemulsion electrokinetic chromatography 微生物传感器Microbial sensor微生物显影bioautography微填充柱micro-packed column微吸附检测器micro adsorption detector微型柱micro-column尾吹气make-up gas味觉传感器taste sensor涡流扩散eddy diffusion无放射源电子俘获检测器non-radioactive electron capture det e…无机离子交换剂inorganic ion exchanger无胶筛分毛细管电泳non-gel capillary electrophoresis无孔单分散填料non-porous monodisperse packing无脉动色谱泵pulse-free chromatographic pump物理钝化法physical deactivation吸附等温线adsorption isotherm吸附剂adsorbing material吸附剂活性adsorbent activity吸附平衡常数adsorption equilibrium constant吸附溶剂强度参数adsorption solvent strength parameter吸附色谱法adsorption chromatography吸附型PLOT柱adsorption type porous-layer open tubular colum…吸附柱adsorption column吸光度比值法absorbance ratio method洗脱强度eluting power下行展开法descending development method显色器color-developing sprayer限制扩散理论theory of restricted diffusion线速度linear velocity线性梯度linear gradient相比率phase ratio相对保留值relative retention value相对比移值relative Rf value相对挥发度relative volatility相对灵敏度relative sensitivity相对碳(重量)响应因子relative carbon response factor相对响应值relative response相对校正因子relative correction factor相交束激光诱导的热透镜测量heat lens detection of intersect …相似相溶原则rule of similarity响应时间response time响应值response小角激光散射光度计low-angle laser light scatter ing photomet…小内径毛细管柱Microbore column校正保留体积corrected retention volume校正曲线法calibration curve method校正因子correction factor芯片电泳microchip electrophoresis旋转薄层法rotating thin layer chromatography旋转小室逆流色谱rotational little-chamber counter-current c…选择性检测器selective detector循环色谱法recycling chromatography压电晶体piezoelectric crystal压电免疫传感器Piezoelectric Immunosensor压电转换器piezoelectric transducer压力保护pressure protect压力上限pressure high limit压力梯度校正因子pressure gradient correction factor压力下限pressure low limit盐析色谱法salting-out chromatography盐析纸色谱法salting-out paper chromatography衍生化法derivatization method衍生化试剂derivatization reagent阳离子交换剂cation exchanger阳离子交换色谱法cation exchange chromatography, CEC氧化铝色谱法alumina chromatography样品环sample loop样品预处理sample pretreatment液-液分配色谱法liquid-liquid partition chromatography液-液色谱法liquid-liquid chromatography液滴逆流色谱drop counter-current chromatography液固色谱liquid-solid chromatography液晶固定相liquid crystal stationary phase液态离子交换剂liquid ion exchanger液相传质阻力resistance of liquid mass transfer液相色谱-傅里叶变换红外光谱联用liquid chromatography-FTIR液相色谱-质谱分析法liquid chromatography-mass spectrometry 液相色谱-质谱仪liquid chromatography-mass spectrometer液相色谱法liquid chromatography液相载荷量liquid phase loading一滴液相色谱法one drop liquid chromatography抑制器suppressor抑制型电导检测suppressed conductance detection抑制型离子色谱法suppressed ion chromatography, SIC抑制柱suppressed column溢流区flooded zonevvv溶解度参数solubility parameter溶液性能检测器solution property detector溶胀swelling溶质性质检测器solute property detector容量因子capacity factor绒毛促性腺传感器Human chorionic gonadotropin sensor乳胶附聚型离子交换剂latex-agglomerated ion exchanger软(质)凝胶soft gel弱碱性阴离子交换剂weak-base anion exchanger弱酸性阳离子交换剂weakly acidic cation exchanger塞式流plug flow塞式流动plug flow色谱法chromatography色谱峰chromatographic peak色谱峰区域宽度peak width色谱富集过样samt injection of chromatography色谱工作站chromatographic working station色谱图chromatogram色谱仪chromatograph色谱纸chromatographic paper色谱柱chromatographic column色谱柱column色谱柱切换技术switching column technique筛分介质sieving medium上行展开法ascending development method蛇笼(状)树脂snake cage resin射频放电检测器radiofrequency discharge detector渗透极限分子量permeation limit molecular weight生物耗氧传感器Biological oxygen-consumption sensor 生物利用度bioavailability生物膜电极Biomembrane electrode生物亲和型传感器Biological affinity sensor生物色谱biological chromatography生物特异性柱biospecific column生物自显影法bioautography升温速率temperature rate湿法柱填充wet column packing十八烷基键合硅胶octadecyl silane石墨化碳黑graphitized carbon black实心载体solid support示差折光检测器differential refraction detector试剂显色法reagent color-developing method手动进样器manual injector手性氨基酸衍生物GC固定相chiral amino acid derivatives stat…手性拆分试剂chiral selectors手性固定相chiral stationary phase手性固定相拆分法chiral solid phase separation手性环糊精衍生物GC固定相chiral cyclodextrin der GC手性金属络合物GC固定相chirametal stationary phase in GC手性流动相chiral mobile phase手性流动相拆分法chiral mobile phase separation手性气相色谱法chiral gas chromatography手性色谱chiral chromatography手性试剂chiral reagent手性衍生化法chiral derivation method疏溶剂理论solvophobic theory疏溶剂色谱法solvophobic chromatography疏溶剂作用理论solvophobic interaction principle疏水作用色谱hydrophobic interaction chromatography 树脂交换容量exchange capacity of resin数均分子量number mean molecular weight双保留机理dual reservation mechanism双电层electrical double layer双活塞往复泵two-piston reciprocating pump双束差分检测器detector of dual-beam difference双向展开法two-dimensional development method双柱定性法double-column qualitative method双柱离子色谱法dual column ion chromatography双柱色谱法dual column chromatography水凝胶hydragel水系凝胶色谱柱aqua-system gel column瞬间离子基体效应moment ion matrix effect死区域dead zone死体积dead volume塑料泵plastic pump酸洗法acid wash酸性染料比色法acid dye colorimetry塔板理论方程plate theory equation碳分子筛carbon molecular sieve唐南排斥Donnan exclusion特殊选择固定液selective stationary phase梯度洗脱gradient elution梯度洗脱装置gradient elution device梯度液相色谱gradient liquid chromatography体积排斥理论size exclusion theory体积排斥色谱size exclusion chromatography体积色谱法volumetric chromatography填充毛细管柱packed capillary column填充柱packed column填料packing material停流进样stop-flow injection通用型检测器common detector涂壁毛细管柱wall coated open tubular column,WCOT 涂布器spreader涂层毛细管coated capillary涂渍coat涂渍效率coating efficiency拖尾峰tailing peak拖尾因子tailing factor流动相mobile phase流动相梯度eluent gradient流体动力学进样hydrostatic pressure injection流体力学体积hydrodynamic volume流型扩散dispersion due to flow profile螺旋传动注射泵screw-driven syringe pump罗什那德常数Rohrschneider’s constant麦克雷诺常数MacReynold’s constant脉冲阻尼器pulse damper毛细管壁静态改性static modification of capillary wall毛细管超临界流体色谱法capillary supercritical fluid chromat…毛细管等电聚焦capillary isoelectric focusing毛细管等速电泳isotachophoresis毛细管电色谱capillary electrochromatography毛细管电泳capillary electrophoresis毛细管电泳电喷雾质谱联用capillary electrophoresis –electr…毛细管电泳基质辅助激光解吸电离质谱离线检测off-line capillar…毛细管电泳离子分析capillary ion analysis毛细管电泳免疫分析immunity analysis of capillary electropho…毛细管胶束电动色谱micellar electrokinetic chromatography毛细管凝胶电泳capillary gel electrophoresis毛细管凝胶柱capillary gel column毛细管亲和电泳affinity capillary electrophoresis毛细管区带电泳capillary zone electrophoresis毛细管有效长度the effective length of capillary electrophor…毛细管柱的交联cross-linked capillary毛细管柱去活capillary column deactivation酶传感器Enzyme sensor酶联免疫传感器Enzyme linked immunosensor酶免疫分析enzyme immnunoassay内标法internal standard method内标物internal standard内梯度inside gradient能量转移技术energy transfer technique逆流色谱法counter-current chromatography逆流色谱仪counter current chromatograph尿素传感器Urea sensor凝胶过滤色谱gel filtration chromatography凝胶内体积gel inner volume凝胶色谱法gel chromatography凝胶色谱仪gel chromatograph凝胶渗透色谱gel permeation chromatography凝胶外体积gel interstitial volume凝胶柱gel column浓度梯度成像检测器concentration gradient imaging detector 浓度型检测器concentration detector浓度型检测器concentration sensitive detector爬行模型crawl model排斥极限分子量exclusion limit molecular weight排斥体积exclusion volume排阻薄层色谱法exclusion TLC泡形池bubble form pool配位体交换色谱ligand exchange chromatography漂移drift平板色谱planar chromatography平衡排斥理论equilibrium exclusion theory平面色谱法Planar chromatography葡萄糖传感器Glucose sensor气-固色谱法gas-solid chromatography, GSC气-液色谱法gas-liquid chromatography, GLC气动泵pneumatic pump气体密度天平检测器gas density balance detector气雾剂取样法aerosol sampling method气相传质阻力resistance of gas mass transfer气相色谱-红外光谱联用仪chromatograph coupled with i nfrared…气相色谱-质谱联用仪gas chromatograph-mass spectrometer气相色谱法gas chromatography,GC气相色谱仪gas chromatography气相色谱专家系统expert system of gas chromatography汽化室vaporizer迁移时间migration time迁移时间窗口the window of migration time前延峰leading peak前沿色谱法frontal chromatography强碱性阴离子交换剂strong-base anion exchanger强酸性阳离子交换剂strongly acidic cation exchanger鞘流池sheath flow pool鞘流液sheath flow liquid切换时间switching time切线切割法tangent incision method亲硅醇基效应silanophilic interaction亲和色谱法affinity chromatography氢火焰离子化检测器flame ionization detector, FID氰基键合相cyano-bonded phase区域扩展zone spreading去离子水deionized water去尾剂tailing reducer全多孔硅胶macro-reticular silica gel全多孔型填料macro-reticular packing material全二维色谱Comprehensive two-dimensional gas chromatography…全硅烷化去活complete silylanization deactivation热导检测器thermal conductivity detector,TCD热离子检测器thermionic detector热色谱法chromatothermography热丝(带)裂解器filament pyrolyzer热透镜光谱检测法heat lens absorbance detection热微量转移薄层色谱法thermomicro and transfer- application- …溶剂泵solvent pump溶剂强度solvent strength激光光热检测器laser and light heat detector激光解吸质谱法laser desorption MS, LDMS激光裂解器laser pyrolyzer激光色谱laser chromatography激光诱导光热光偏转测量detection of laser-induced light heat…激光诱导光束干涉检测detection of laser-induced light beam I…激光诱导毛细管振动测量laser-reduced capillary vibration det…激光诱导荧光检测器laser-induced fluorescence detector记忆峰memory peak记忆效应memory effect夹层槽sandwich chamber假峰ghost peak间断洗脱色谱法interrupted-elution chromatography间接光度(检测)离子色谱法indirect photometric ion chroma to…间接光度(检测)色谱法indirect photometric chromatography间接检测indirect detection间接荧光检测indirect fluorescence detection间接紫外检测indirect ultraviolet detection检测器detector检测器检测限detector detectability检测器灵敏度detector sensitivity检测器线性范围detector linear range碱火焰电离检测器alkali flame ionization detector, AFID碱洗法alkali wash剪纸称重法cut-paper weighing method减尾剂tailing reducer减压液相色谱vacuum liquid chromatography键合固定相bonded stationary phase键合型离子交换剂bonded ion exchanger焦耳热joule heating胶束薄层色谱法micellar thin layer chromatography胶束液相色谱法micellar liquid chromatography交联度crosslinking degree阶梯梯度stagewise gradient介电常数检测器dielectric constant detector金属配合物离子色谱法metal complex ion chromatography, MCIC 金属氧化物固定相metal oxides stationary phase金属作用色谱metal interaction chromatography进样阀injection valve进样量sample size进样器injector静态顶空分析法static headspace analysis静态涂渍法static coating method径流柱radial flow column径向流动色谱radial flow chromatography径向压缩柱radial compression column径向展开法radial development径向展开色谱radial development chromatography净保留体积net retention volume居里点裂解器Curie point pyrolyzer矩形池rectangle form pool聚苯乙烯PS/DVB聚硅氧烷高温裂解去活high-temperature pyrolysis deactivation…聚合物基质离子交换剂polymer substrate ion exchanger绝对检测器absolute detector开口分流open split开口管柱open tubular column可见光检测器visible light detector可交换离子exchangable ion空间性谱带加宽band broadening in space空穴色谱法vacancy chromatography孔结构pore structure孔径pore diameter孔径分布pore size distribution控制单元control unit快速色谱法high-speed chromatography快原子枪fast atom gun离心逆流色谱centrifugal counter-current chromatography离心制备薄层色谱法centric-preparation TLC离子对色谱法ion pair chromatography, IPC离子对试剂ion pair reagent离子对探针检测ion-pairing probes detection离子对形成模型ion pair formation model离子交换电动色谱ion-exchange electrokinetic chromatography 离子交换剂ion exchanger离子交换毛细管电色谱ion exchange capillary electrokinetic离子交换膜ion exchange membrane离子交换色谱法ion exchange chromatography, IEC离子交换树脂ion exchange resin离子交换位置ion exchange site离子交换柱ion exchange column离子排斥色谱法ion exclusion chromatography, ICE离子色谱法ion chromatography, IC离子色谱仪ion chromatograph离子相互作用模型ion interaction model离子相互作用色谱法ion interaction chromatography, IIC离子抑制色谱法ion suppression chromatography, ISC理论塔板高度height equivalent to a theoretical plate(HETP)理论塔板数number of theoretical plates两性电解质ampholytes两性离子zwitter-ion两性离子交换剂zwitterion exchanger裂解气相色谱法pyrolysis gas chromatography PyGC临界胶束浓度critical micelle concentration淋洗剂eluent淋洗离子eluent ion淋洗色谱法elution chromatography馏分收集器fraction collector流动池flow cell峰面积测量法measurement of peak area峰面积校正calibration of peak area峰容量peak capacity复合柱combined column改性载体modified support干法柱填充dry column packing干凝胶xerogel干扰抑制电导率检测detection of interfere and restrain condu…干柱色谱法dry-column chromatography干柱色谱法dry-column chromatography, DCC高分子多孔微球porous polymer beads, GDX高速逆流色谱法high speed counter-current chromatography高温硅烷化去活high temperature silanizing deactivation高温凝胶色谱法high temperature gel chromatography高效毛细管电泳high-performance capillary electrophoresis高效液相色谱-付里叶变换红外分析法high performance liquid ch…高效液相色谱法high performance liquid chromatography高效柱high performance column高压流通池技术high pressure flow cell technique高压输液泵high pressure pump高压梯度high-pressure gradient高压液相色谱法high pressure liquid chromatography戈雷方程式Golay equation戈雷柱Golay column隔膜泵diaphragm pump隔膜进样septum sampling工业色谱industrial chromatography工业色谱仪industrial chromatograph工作流速working flow rate功能基团functional group谷丙转氨酶传感器Glutamic-pyruvic transaminase sensor,GPT固定化酶immobilized enzyme固定相stationary phase固定液stationary liquid固定液的相对极性relative polarity of stationary liquid固定液极性stationary liquid polarity固相扩散solid diffusion固相荧光免疫分析solid phase fluorescence immunoassay 固有粘度intrinsic viscosity官能团保留指数function retention index官能团色谱图functional group chromatogram, FGC冠醚固定相crown ether stationary phase管壁效应wall effect管式炉裂解器tube furnace pyrolyzer灌注色谱法perfusion chromatography贯注色谱填料perfusion chromatography packing光离子化检测器photo-ionization detector, PID光密度计densitometer光谱差减法spectral subtraction method光散射检测器light scattering detector光声检测法photoacoustic detection光纤化学传感器Optic fiber sensor硅胶silica gel硅胶基质离子交换剂silica-gel substrate ion exchanger硅烷化法silanization硅烷化法silanizing硅烷化载体silanized support归一化法normalization method过压薄层色谱法over pressured thin layer chromatography, OPT…过压液相色谱法over pressured liquid chromatography,OPLC氦电离检测器helium ionization detector含氧化合物分析器oxygen specific response of the flame ioni…含样去样检测法sample in sample out method赫尔希池检测器Hersch cell detector恒流泵constant flow pump恒温操作constant temperature method恒压泵constant pressure pump红色载体red support红外检测器infrared detector红外总吸光度重建色谱图total infrared absorbance reconstruct…化合物形成色谱compound-formation chromatography化学发光检测器chemiluminescence detector化学发光检测器Chemiluminescence detector, SCD化学键合固定相bonded stationary phase化学键合相色谱bonded phase chromatography化学色谱法chemi-chromatography化学衍生法chemical derivatization method环糊精电动色谱cyclodextrin electrokinetic chromatography环形展开比移值circular development Rf value环形展开法circular development缓冲溶液添加剂buffer additives辉光放电检测器glow discharge detector混合床离子交换固定相mixed-bed ion exchange stationary phase 混合床柱mixed bed column混合溶剂mixed solvent活塞泵piston pump活性activation活性部位active site活性硅胶activated silica gel活性氧化铝activated aluminium oxide活性中心active center火焰光度检测器flame photometric detector, FPD基流background current or base current基线baseline基线宽度baseline width基质substrate materials基质隔离技术matrix isolation technique畸变峰distorted peak积分器integrator电歧视效应the effect of electrical discrimination电迁移进样electrophoretic injection电渗流electroendosmotic flow电渗流标记物electroendosmotic flow marker电渗流淌度electroendosmotic mobility电位检测器electricity potential detector电泳淌度electrophoretic mobility电子俘获检测器electron capture detector电子迁移率检测器electron mobility detector调整保留时间adjusted retention time调整保留体积adjusted retention volume叠加内标法added internal standard method顶空气相色谱法headspace gas chromatography, GC-HS顶替法displacement development顶替色谱法displacement chromatography动态包覆dynamic coating动态顶空分析法dynamic headspace analysis动态分离dynamic separation动态复合离子交换模型dynamic complex ion exchange model 动态改性dynamic modification动态离子交换模型dynamic ion exchange model动态涂渍dynamic coating动态涂渍法dynamic coated method动态脱活dynamic de-activity短柱色谱法short column chromatography堆积硅珠stacked silica bead堆积性能bulk property多次反射池multi-reflect pool多分散度polydispersity多功能基离子交换剂multi-functional group ion exchanger多角度激光光散射光度计multi-angle laser light scattering ph…多孔层开口管柱porous layer open tubular column,PLOT多孔高聚物PLOT柱porous polymer beads PLOT column多孔硅胶porous silica gel多孔聚合物气液固色谱柱porous polymer beads GLS column GLS 多孔石墨碳porous graphitic carbon, PGC多孔载体porous support多脉冲实验multiple pulse experiments多维色谱法multi-dimensional chromatography多维色谱仪multidimensional chromatograph多用色谱仪unified chromatograph惰性气体鼓泡吹扫脱气sweeping degas by inert gas二次化学平衡secondary chemical equilibria ,SCE二极管阵列检测器diode-array detector, DAD二维色谱法two-dimensional chromatography二元溶剂体系dual solvent system反冲洗back wash反吹技术back flushing technique反峰negative peak反离子counter ion反气相色谱法inverse gas chromatography (IGC)反相高效液相色谱法reversed phase high performance liquid ch…反相离子对色谱reversed phase ion pair chromatography反相离子对色谱法reversed phase ion-pair chromatography反相毛细管电色谱reverse capillary electrokinetic chromatogr…反相柱reversed phase column反应气相色谱法reaction gas chromatography反应色谱reaction chromatography反圆心式展开anti-circular development反转电渗流reverse electroendosmotic flow范第姆特方程式van Deemter equation仿生传感器Biomimic electrode放射性电离检测器radio ionization detector放射性检测器radioactivity detector放射自显影autoradiography非极性固定相non-polar stationary phase非极性键合相non-polar bonded phase非金属离子传感器non-metal ion sensor非水系凝胶色谱柱non-aqua-system gel column非水相色谱nonaqueous phase chromatography非吸附性载体non-adsorptive support非线性分流non-linearity split stream非线性色谱non-linear chromatography非线性吸附等温线non-linear adsorption isotherm非抑制型电导检测non-suppressed conductance detection非抑制型离子色谱法non-suppressed ion chromatography, NSIC 费尔盖特效益Fellgett advantage酚醛离子交换树脂phenolic ion exchange resin分离-反应-分离展开SRS development分离数separation number分离因子separation factor分离柱separation column分流split stream分流比split ratio分流进样法split sampling分流器splitter分配等温线distribution isotherm分配色谱partition chromatography分配系数partition coefficient分析型色谱仪analytical type chromatograph分子扩散molecular diffusion分子量分布molecular weight distribution分子量检测器molecular weight detector分子筛molecular sieve分子筛色谱molecular sieve chromatography分子吸附molecular adsorption分子吸收光谱molecular absorption spectroscopy封尾endcapping峰高peak heightpH梯度动态分离dynamic separation of the pH gradient pH值梯度洗脱pH gradient elutionZata电势Zata potentialZ形池Z-form pool氨基键合相amino-bonded phase氨基酸分析仪amino acid analyzer安培检测器ampere detector白色载体white support半微柱semimicro-column半制备柱semi-preparation column包覆型离子交换剂coated ion exchanger包覆型填料coated packing material薄层板thin layer plate薄层扫描法thin layer chromatography scanning薄层扫描仪thin layer chromatography scanner薄层色谱法thin layer chromatography TLC薄壳型离子交换剂pellicular ion-exchanger薄壳型微珠载体pellicular microbead support保护柱guard column保留间隙retention gap保留时间retention time保留体积retention volume保留温度retention temperature保留值定性法retention qualitative method保留值沸点规律boiling point rule of retention保留值碳数规律carbon number rule of retention保留指数retention index保留指数定性法retention index qualitative method背景电导background conductance苯酚磺酸树脂phenol sulfonic acid resin苯乙烯styrene比保留体积specific retention volume比例阀proportional valve比渗透率specific permeability比移值Rf value边缘效应edge effect便携式色谱仪portable chromatograph标准偏差standard deviation表观电泳淌度apparent electrophoretic mobility表观交换容量apparent exchange capacity表面电位检测器surface potential detector表面多孔硅胶superficially porous silica gel表面多孔填料superficially porous packing material表面多孔型离子交换剂superficially porous ion-exchanger玻璃球载体glass beads support不分流进样splitless sampling参比柱reference column残余硅醇基residual silanol场放大进样electrical field magnified injection场流分离field-flow fractionation场流分离仪field-flow fractionation场效应生物传感器Field effect transistor based Biosensor常压液相色谱法common-pressure liquid chromatography超临界流体supercritical fluid超临界流体色谱supercritical fluid chromatography超临界流体色谱-傅里叶变换红外光谱联用supercritical fluid …超临界流体色谱法supercritical fluid chromatography超临界流体色谱仪supercritical fluid chromatograph超临界流体萃取supercritical fluid extract,SFE超声波脱气ultrasonic degas超微传感器ultra-micro sensor程序变流色谱法programmed flow (gas) chromatography程序升温进样programmed temperature sampling程序升温色谱法programmed temperature (gas) chromatography 程序升温蒸发器programmed temperature vaporizer ,PTV程序升压programmed pressure触角载体tentacle supports传质速率rate of mass transfer传质阻力resistance of mass transfer垂直切割法vertical incision method催化色谱法catalytic (gas) chromatography大环化合物色谱large ring compound chromatography大孔树脂macro-reticular resin大孔填料macro-reticular packing material大内径毛细管柱Megaobore column代谢型生物传感器Biological metabolizing sensor单分散气溶胶发生器monodiaperse aerosol generator单活塞往复泵single piston reciprocating pump单相色谱仪single phase chromatograph单向阀one-way valve单柱离子色谱法single column ion chromatography胆固醇传感器Cholesterol sensor氮-磷检测器nitrogen-phosphorus detector ,NPD导数比率法derivative ratio method等度洗脱isocratic elution等离子体色谱法plasma chromatography等途电泳-毛细管区带电泳耦合进样isotachophoresis injection-c…低负荷柱low load column低容量柱low capacity column低温色谱low temperature chromatography低压梯度low-pressure gradient低压液相色谱low-pressure liquid chromatography点样sample application点样器sample spotter (spot applicator)电导池conductance cell电导检测法conductance detection电荷转移分光光度法charge transfer spectrophotometry 电化学检测器electrochemical detector电解抑制器electrolyze suppressor。
色谱大全——精选推荐
色谱大全转播色谱大全████粉红,即浅红色。
别称:妃色杨妃色湘妃色妃红色████妃色妃红色:古同“绯”,粉红色。
杨妃色湘妃色粉红皆同义。
████品红:比大红浅的红色(quester注:这里的“品红”估计是指的“一品红”,是基于大红色系的,和现在我们印刷用色的“品红M100”不是一个概念)████桃红,桃花的颜色,比粉红略鲜润的颜色。
(quester注:不大于M70的色彩,有时可加入适量黄色)████海棠红,淡紫红色、较桃红色深一些,是非常妩媚娇艳的颜色。
████石榴红:石榴花的颜色,高色度和纯度的红色。
████樱桃色:鲜红色████银红:银朱和粉红色颜料配成的颜色。
多用来形容有光泽的各种红色,尤指有光泽浅红。
████大红:正红色,三原色中的红,传统的中国红,又称绛色(quester注:RGB 色中的R255 系列明度)████绛紫:紫中略带红的颜色████绯红:艳丽的深红████胭脂:1,女子装扮时用的胭脂的颜色。
2,国画暗红色颜料████朱红:朱砂的颜色,比大红活泼,也称铅朱朱色丹色(quester注:在YM对等的情况下,适量减少红色的成分就是该色的色彩系列感觉)████丹:丹砂的鲜艳红色████彤:赤色████茜色:茜草染的色彩,呈深红色████火红:火焰的红色,赤色████赫赤:深红,火红。
泛指赤色、火红色。
████嫣红:鲜艳的红色████洋红:色橘红(quester注:这个色彩方向不太对,通常洋红指的是倾向于M100系列的红色,应该削弱黄色成分。
)████炎:引申为红色。
████赤:本义火的颜色,即红色████绾:绛色;浅绛色。
████枣红:即深红(quester注:色相不变,是深浅变化)████檀:浅红色,浅绛色。
████殷红:发黑的红色。
████酡红:像饮酒后脸上泛现的红色,泛指脸红████酡颜:饮酒脸红的样子。
亦泛指脸红色████鹅黄:淡黄色(quester注:鹅嘴的颜色,高明度微偏红黄色)████鸭黄:小鸭毛的黄色████樱草色:淡黄色████杏黄:成熟杏子的黄色(quester注:Y100 M20~30 感觉的色彩,比较常用且有浓郁中国味道)████杏红:成熟杏子偏红色的一种颜色████橘黄:柑橘的黄色。
(完整)USP621译文
〈621〉色谱法介绍色谱分离技术是通过样品组分在固定相和流动相两相中的分布差异进行分离的技术。
其中固定相可以是固体、有固相支持的液体或凝胶。
固定相可以填充于柱、分散成层、分布为膜或者应用于其他技术中.流动相可以为气态、液态或超临界流体。
分离可以基于吸附性、质量分布(分配)或离子交换,也可以基于分子物理化学性质的差异,如大小、质量和体积.本章节包括了基本步骤、定义和对一般参数的计算并描述了对于系统适应性的基本要求.在USP中应用于定量和定性分析的色谱方法类型有柱色谱法、气象色谱法、纸色谱法、薄层色谱法(包括高效薄层色谱)和加压液相色谱法(一般称作高压或高效液相色谱)。
基本步骤本部分描述了使用某种色谱方法的基本步骤。
除另有各论规定外,以下色谱分离方法的步骤将会被遵循。
纸色谱法固定相:固定相为一张适当质地和厚度的纸.色谱图的形成过程可以是上行的,这样溶剂被毛细管作用力支撑着沿着纸向上,这个过程也可以是下行的,在此情况下溶剂流动也受到重力的影响。
与溶剂流动有关的纸张纹理定向应该在一系列色谱图中保持恒定.(纤维方向通常由制造商在色谱纸的包装上标出。
)仪器:纸色谱法的必备仪器包括装有添加溶剂的入口的气密室和短于该室内部高度5cm的耐腐蚀材料支架。
该支架作为用于溶剂槽以及用于抗虹吸棒的支撑,这些抗虹吸棒依次撑起色谱纸。
气密室的底部以规定的容积系统或流动相覆盖。
使用以规定溶剂系统润湿的纸张衬托于气密室的内壁,以增加气密室的溶剂蒸汽饱和度。
斑点:将待分析的一个或多个物质溶解于适当溶剂中。
以微量吸管吸取适当体积的溶液,其中通常含有1-20µg该化合物,点样为6-10mm大小斑点且斑点间的间隔不小于3cm。
下行色谱法步骤1.带斑点的色谱纸以抗虹吸棒悬挂在气密室内,该棒将该色谱纸的上端固定在溶剂槽中。
(注:确保色谱纸挂在抗虹吸棒下的部分自由的悬挂在气密室中,没有接触到支架、室壁或室内的液体。
2.气密室被密闭,以便使该室与色谱纸达到溶剂蒸汽平衡(饱和)释放任何多余压力。
色谱软件英文—中文对照
abort 终止sequence, 序列192response factor, 响应因子157retention time, 保留时间143, 144 accuracy 准确度adaptive integrationall valleys, 所有峰谷98, 136amount limits, 含量限143, 175analog signal, 模拟信号57accuracy, 准确度184reject, 拒绝89ascii file,ascii 文件227ASTM noise determination,ASTM 噪声测定250autointegrate, 自动积分134 autointegration, 自动积分95automated library search, 自动谱库查找51 recalibration, 重积分200automatic batch review, 自动批处理复查226 allocating, 分配106codes, 代码99, 137construction events, 建立事件92 customize construction, 自定义建立92 default construction, 缺省建立defining, 定义modified, 修改82modified construction, 修改建立penetration, 贯穿82, 121tracking, 跟踪106tracking mode, 跟踪模式75batch, 批224batch history, 批历史227batch report, 批报告225batch table, 批处理表224bracket, 括号202sequence, 序列212ESTD, 外标160ISTD, 内标163Norm%, 归一化162quantification, 定量156compound, 化合物169curve, 曲线171curve fits, 曲线拟合178explicit, 明确的204 multiple-level, 多级175calibration curve 校正曲线calibration point weighting, 校正点权重178description of, 描述171fits, 拟合178force through zero (origin), 强制过零原点178multiple-level, 多级175single-level, 单级174Calibration Settings dialog box, 校正设置对话框166Calibration Table, 校正表141capacity factor, 容量因子257capacity ratio, 容量比257cardinal points, 基点76ChemStation 化学工作站connecting Agilent 1100 SeriesLC, 连接Agilent 1100 系列LC customization, 用户化26general description, 一般描述13 compound, 化合物169compound table, 化合物表224 Confidence Interval, 置信区间261 configuration, 配置17customized, 用户化的104control chart reports, 控制图报告control limits, 控制界限225control sample, 控制样品224corrected retention time, 修正保留时间143, 146correction factors, 校正因子157CSV file,CSV 文件227 Customization, 用户化26customized configuration, 用户自定义配置customized data analysis, 用户自定义数据分析52customized reports, 用户定义报告calibration sequences, 校正序列Data Acquisition 数据采集data acquisition, 数据采集18 integration, 积分20quantification, 定量22Specialized Reporting, 特殊报告customized, 用户化52delete peaks, 删除峰destination 目标detector response, 检测器响应174,DIF file,DIF 文件227digital signal, 数字信号57Dilution Factor, 稀释因子157dilution factor, 稀释因子161directory 目录draw baseline, 画基线98, 136drift 漂移response, 响应212enhanced Agilent integrator 增强型Agilent 积分器procedure, 过程160initial, 初始87integration, 积分87explicit 明确的calibration sequences, 校正序列extension 扩展external standard, 外标160 extrapolation, 外插法176, 212 chromatographic, 色谱的58 extension, 扩展58spectral, 光谱58fits 拟合non-linear, 非线性177formulae 公式general definitions, 常用定义performance test definitions, 性能测试定义GLPSave.Reg, 52save with method, 存储方法52Good Laboratory Practice, 优良实验室规范header, multi-line, 多行题头225height reject, 拒绝接收的峰高127 history of the Agilent standard integration algorithm,Agilent 标准积分算法记录67 how the enhanced integrator works,增强型Agilent积分器如何工作105 Agilent 1100 Series, Agilent 1100系列216 inflection point 转变点area reject, 拒绝接收的面积87 threshold, 阈值87response, 响应212 integration, 积分51, 97control events, 控制事件92enhanced, 增强型67events table, 事件表97isolated peaks, 分裂峰75merged peaks, 重合峰77shoulders, 肩峰77tick marks, 记号66integration events, 积分事件51internal standard, 内标163interval 间隔recalibration, 重新校正202peaks finding, 峰辨认150procedure, 过程163linearity test definitions, 线性测试定义260log file log 文件sequence, 序列195logbook, 记事本58, 60manual batch review, 手动批处理复查226manual events 手动事件manual Integration, 手动积分136all valleys, 所有峰谷98, 136delete peak(s), 删除峰98, 136draw baseline, 画基线98, 136negative peaks, 负峰98, 136separation codes, 分离代码99,split peak, 分裂峰98, 136tangent skim, 正切斜滑98, 136trace mode, 跟踪模式98, 136merged peaks 未分离峰automated library search, 自动谱库检索51 directory, 目录48integration events, 积分事件51modify, 修改45operation summary, 操作总结53peak purity check, 峰纯度检查51data evaluation parameters, 数据评价参数modified baseline construction, 修正基线建立82multi-level calibrations,多级校正multi-line header, 多行题头225multiple 多级的reference peaks, 参考峰146multiplier, 乘数157, 160sequence file, 序列文件197negative peak, 负峰80, 119no update, 不更新202Noise Determination, 噪声测量249noise determination, 噪声测量250non-gaussian calculations, 非高斯计算114 non-linear 非线性normalizing factor, 归一化因子163not ready timeout, 未准备的暂停199 number of plates, 塔板数258half-width method, 半峰宽法258 tangent method, 正切法258variance method, 变量法258number of plates per meter, 每米塔板数258 Online Help, 在线帮助32origin 原点force, 强制178partial recalibration, 部分再校正apex algorithm, 顶点算法114apex of, 顶点107area measurement, 面积测量124 bunching, 峰的集束112curvature, 弯曲76identification, 鉴定51, 141 identification process, 鉴定过程matching rules, 匹配原则142merged, 未完全分开77qualifiers, 特征峰142, 143, 148 quantification, 定量51, 155 recognition, 认可75, 111rejection criteria, 拒绝标准90 response, 响应148retention time, 保留时间146retention time window, 保留时间窗口145 separation codes, 分离代码80,119 shoulder, 肩峰77slope, 斜率76solvent, 溶剂82peak identification 峰的认证peak purity, 峰纯度51as part of method, 作为方法的一部分51 peak symmetry calculation, 峰对称性检查tangent, 正切256penetration 贯穿percent calculation, 百分比计算performance test definitions 性能测试定义statistical moments, 统计要素255 perpendicular drop, 垂直画基线77post-run 后运行post-sequence operation, 后序列操作199 precision 精度number format, 数字格式264pre-run 预运行command, 命令50macro, 宏50priority sample, 优先样品192 qualifiers, 特征峰148quantification 特征峰calculations, 计算156ESTD procedure, 外标法步骤160ISTD procedure, 内标法步骤163 Quantitative Results, 定量结果234 interval, 间隔202partial, 部分184retention time, 保留时间184 unidentified peaks, 非鉴定峰184 reference peaks 参考峰finding, 找出150reference window, 参考窗口145 Regression 回归regression coefficient, 回归参数relative retention, 相对保留259 removed sample type, 删除样品类型destination, 目标239control chart, 控制图25customized, 用户自定义25sequence summary, 序列总结24system suitability, 系统适应性23 reproducibility definitions, 重复性定义260 residual, 残留172residual standard deviation, 残留标准偏差resolution, 分离度2595 sigma method,5 方法259half-width method, 半峰宽法259 statistical method, 统计方法259tangent method, 正切法259实用文档response, 响应155, 173detector, 检测器174drift, 漂移212retention time, 保留时间254corrected, 纠正143, 146recalibration, 重新校正184update, 更新201run index, 运行索引224Run Time Checklist, 运行时间列表data acquisition, 数据采集50post-run command, 后运行命令52post-run macro, 后运行宏52pre-run command, 前运行命令50pre-run macro, 前运行宏50save copy of method,存储方法拷贝save GLP data, 存储GLP 数据52 amount, 量157priority, 优先192bracketing operation, 括号操作cyclic calibration,循环校正explicit calibration, 简明校正sample vials, 样品瓶197subdirectory, 子目录37Sequence Parameters Table, 序列参数表189 Sequence Recalibration Table序列重新校正表Sequence Summary Report 序列摘要报告configuration, 配置242logbook, 记录本242output specification, 输出指标sequence table, 序列表242statistics, 统计242summary page, 243sequence summary reports, 序列摘要报告shoulder detection, 肩峰检测127 shoulders 肩峰detection, 检测87, 90integration, 积分77analog, 模拟57identifier, 鉴别58single reference peaks, 单一参考峰single-level calibration curve, 单级校正曲线software overview 软件预览data model, 数据模型17 methods and sequences,方法和序列operating system, 操作系统17system configuration, 系统配置17 solvent 溶剂external, 外部160internal, 内部163Standard Deviation 标准偏差sample standard deviation, 样品标standard deviation of the mean,standard deviation RSD, 标准偏差RSD standby state, 等待状态199 sequence, 序列192summed peaks table, 加和峰表238 System Suitability 系统适应性statistics included, 包含统计246system suitability formulae 系统适应性公式capacity factor, 容量因子257number of plates, 塔板数258 regression analysis, 回归分析262 regression coefficient, 回归系数relative retention, 相对保留259relative standard deviation, 相对标准偏差resolution, 分离度259retention time of unretained compound,非保留化合物的保留时间standard deviation,标准偏差260,USP tailing factor,USP 拖尾因子system suitability report 系统适应性报告extended performance, 扩展性能23 System Verification, 系统验证268 Distribution, 分布262tailing factor, 拖尾因子257tangent skim, 正切斜滑98, 121, 136 threshold, 阈值89tick marks, 记号66, 79, 118timed events, 时间事件92, 130trace mode, 跟踪模式98, 136 activating, 激活的99, 137manual integration, 手动积分98, Unassigned Peaks, 非分配峰123 uncalibrated calculations, 非校正计算158 unidentified peaks 非定义峰classification, 分类151recalibration, 重新校正184unknown sample, 未知样品173update 更新response factor, 响应因子201retention time, 保留时间201user interface, 用户界面225USP tailing factor,USP 拖尾因子257 valley point, 谷点77Verification, 验证268verify 验证subdirectory, 子目录37void time, 死时间254void volume, 死体积254quadratic, 平方178reference, 参考145retention time, 保留时间145实用文档。
色谱翻译——精选推荐
姓名:徐丹敏学号:2111001265利用液相色谱-质谱联用仪测定百里香植物中的多酚类化合物Journal of Chromatography A,1217(2010) 7972-7980 摘要:多酚类是指一组植物中化学物质的统称,包括酚酸、黄酮、天然染料、木酚素等。
这些天然活性物质具有抗氧化、抗癌、抑菌的作用,摄取一定量的植物多酚还有助于防止冠心病的发生。
已有文献报道过百里香植物中含有多种酚酸、黄酮。
而且,百里香植物中黄酮类的组成和含量还是区别不同次群组的一个重要因素。
利用高效液相色谱(HPLC)外加二极管阵列检测器(DAD)和ESI-MS来分析百里香植物中的多酚类化合物。
可以用一些指标(可重复性、中间精密度、检出限LOD、最低定量浓度LOQ、标定范围、回收率) 来评估此方法。
把这5种含多酚的百里香植物进行表征。
结果显示,迷迭香酸是主要的化合物,含量在83.49μg.g-1~1.436mg.g-1之间。
在每一种被检测的百里香植物中也检测到了其它酚酸(包括阿魏酸、咖啡酸及它的衍生物、绿原酸、对-香豆酸),还有黄烷酮类(包括柚皮素、圣草酚和二氢槲皮素),黄酮类(包括芹黄素和芹菜甙元-7-葡萄糖甙),黄酮醇类(包括槲皮黄酮和芦丁)。
多酚类物质的含量可以用来推断物种的原产地。
1:引言多酚是一类物质的统称,包括酚酸、黄酮、天然染料、木酚素等,这些物质存在于植物的不同部位。
黄酮类物质被认为有营养功能,且具有多种药理作用:对中枢神经的作用(例如合成黄酮具有抗焦虑的作用),提高心脏活性(防止动脉硬化、抗心律失常和降压的功效),降血脂,保护肠胃(抗溃疡和保肝活性),抗氧化自由基活性,抗炎镇痛活性,抗肿瘤活性(抑制癌细胞的生长),心血管系统活性,抗菌及抗病毒活性。
人类饮食中多酚类物质主要来自水果、蔬菜、谷物、饮料(茶、咖啡、果汁和苹果酒)、葡萄酒和香料。
一些研究表明,不同种类的百里香植物中含有黄酮类。
百里香植物中的多酚类具有生理和化学稳定性,但结构具有可变性。
色谱常见简写与对照
ACN 乙腈AcetonitrileAUFS 满量程的吸光度单位Absorbance units, full scaleAs 峰不对称因子B 二元流动相中的强溶剂;例如:反相HPLC的甲醇/水混合液中的甲醇BSA 牛血清白蛋白(一种蛋白质)Bovine serum albuminCAF 咖啡因(中性溶质)CaffeineCRF 色谱响应因子Chromatographic response function;色谱图总分离度的定量指标dc 色谱柱内径(cm)DMOA 二甲基辛胺DimethyloctylamineDNB 2,4-二硝基甲酰(基)2,4-Dinitrobenzoyldp 色谱柱填料的粒度(cm)DRYLAB 液相资源公司(LC Resources INC.)的计算机模拟软件。
DRYLAB I用于等度预测,DRYLAB G用于梯度预测F 流动相的流速(ml/min)FC-113 1,1,2-三氟-1,2,2-三氯乙烷GPC 凝胶渗透色谱法Gel-permeation chromatographyHA 酸性溶质,能电离出A-Hex 己烷Hexanehr 二相邻谱带之间的谷高HVA 高香草酸Homovanillic acidh’峰高h1,h2 相邻谱峰1和谱峰2的峰高IEC 离子交换色谱法Ion-exchange chromatographyIP 离子对Ion-pairIPC 离子对色谱法Ion-pair chromatographyJ 色谱峰强度参数K’所给谱峰的容量因子,k’=(tR-t0)/t0=tR’/t0,tR=t0(1+k’)k 梯度洗脱过程中,某溶质的k’的平均值或有效值kw 以水做流动相k’的外推值k1,k2 相邻谱峰1和谱峰2的容量因子L 色谱柱长度(cm)Lc 检测器流动池光路的长度(cm)M 溶质的分子量MC 二氯甲烷Methylene chlorideMDST 混合设计统计技术Mixture-design statistical technique;一种优化流动相的软件MeOH 甲醇MethanolMTBE 甲基叔丁醚Methyl-t-butyl etherMW 溶质的分子量N 色谱柱塔板数NAPA N-乙酰普鲁卡因胺N-Acetylprocainamide(碱性溶质)N0 检测器的基线噪音ODS 十八烷基硅烷OctadecylsilylP 色谱柱的压力降[通常以巴(bar)表示,也用psi;另外,也用作柱极性参数PA 普鲁卡因胺Procainamide(碱性物质)PAH 聚芳香烃Polyaromatic HydrocarbonPESOS 优化流动相的计算机软件(美国Perkin-Elmer产品)pKa 溶质酸性常数的负对数;当pH=pKa时,溶质中有一半是电离的Rk 保留值范围,Rk=(最末谱峰k’)/(最初谱峰k’)RRM 相对分离度图(通常N=10000)Rs 相邻二谱峰的分离度S 当流动相中的%B改变时,测量溶质保留值的变化速率的参数SAL 水杨酸Salicylic AcidSEC 尺寸排阻色谱法Size-exclusion chromatographyS/N 信噪比Signal to noise ratiot 分离时间(min)(样品进样时t=0)tp 梯度系统的滞后时间(min)TBA 四丁基铵离子Tetrabutylammonium ionTEA 三乙胺TriethylamineTHF 四氢呋喃Tetrahydrofurantk 在用于校正等度洗脱溶剂强度的流动相离开梯度混合器时,梯度洗脱的时间TLC 薄层色谱法Thin-layer chromatographyTMA 四甲基铵Tetramethylammonium(盐)TMS 三甲基硅烷Trimethylsilylt0 色谱柱的死时间(min)tR 溶质的保留时间(min)tG 梯度时间(min),即梯度开始至结束的时间t1,t2 相邻谱峰1和谱峰2的保留时间(min)ti 色谱图中第一峰的保留时间(min)tf 色谱图中最末峰的保留时间(min)△tg tf-titx (tf-ti)/2UV 紫外光Vm 色谱柱的死体积(mL),Vm=t0FVMA 香草扁桃酸Vanillymandelic acidwm 化合物的进样量w1,w2 相邻谱峰1和谱峰2于半峰高处(W1/2)的宽度(min)W1,W2 相邻谱峰1和谱峰2的基线宽度(min)W1/2 半峰高处的谱带宽度xd,xe,xn 溶剂选择参数,分别用于测定溶剂的酸度、碱度和偶极性的程度α分离因子,α=k2/k1△Φ梯度洗脱期间流动相成分的变化εo 溶剂强度参数ε化合物的克分子吸收系数η流动相的粘度(Pa·s)Φ流动相中强溶剂的体积份数%B 二元流动相中强溶剂的体积百分比(%v)。
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