有机化学双语版 Dienes
有机化学专业英语1
Angular methyl group角甲基Alkylidene group亚烷基Allyl group烯丙基Allylic烯丙型[的]Phenyl group苯基Aryl group芳基Benzyl group苄基Benzylic苄型[的]Activating group活化基团Chromophore生色团Auxochrome助色团Magnetically anisotropic group磁各向异性基团Smally ring小环Common ring普通环Medium rimg中环Large ring大环Bridged-ring system桥环体系Spiro compound螺环化合物Helical molecule螺旋型分子Octahedral compound八面体化合物Conjugation共轭Conjugated-system共轭体系Acyl cation酰[基]正离子Benzylic cation苄[基]正离子Arenirm ion芳[基]正离子Ketyl radical羰自由基Radical ion自由基离子Radical cation自由基正离子Radical anion自由基负离子Isomerism异构[现象]Aci form酸式Fluxional structure循变结构Stereochemistry立体化学Optical activity光学活性Dextro isomer右旋异构体Laevo isomer左旋异构体Tetrahedral configuration四面体构型Stereoisomerism立体异构[现象] Asymmetric atom不对称原子Asymmetric carbon不对称碳Pseudoasymmetric carbon假不对称碳Phantom atom虚拟原子Homotopic等位[的]Heterotopic异位[的]Enantiotopic对映异位[腯Diastereotopic非对映异位[的] Configuration构型Absolute configuration绝对构型Chirality手性Chiral手性[的]Chiral center手性中心Chiral molecule手性分子Achiral非手性[的]Fischer projection费歇尔投影式Neoman projection纽曼投影式D-L system of nomenclature D-L命名体系R-S syytem of nomenclature R-S命名体系Cahn-Ingold-Prelon sequence顺序规则Symmetry factor对称因素Plane of symmetry对称面Mirror symmetry镜面对称Enantiomer对映[异构]体Diastereomer非对映[异构]体Epimer差向异构体Anomer端基[差向]异构体Erythro configuration赤型构型Erythro isomer赤型异构体Threo configuration苏型构型Threo isomer苏型异构体Trigonal carbon三角型碳Cis-trans isomerism顺反异构E isomer E异构体Z isomer Z异构体Endo isomer内型异构体Exo isomer外型异构体Prochirality前手性Pro-R group前R基团Pro-S proup前S基团Re face Re面Si face Si面Racemic mixture外消旋混合物Racemic compound外消旋化合物Racemic solid solution外消旋固体溶液Meso compound内消旋化合物Quasi recemate准外消旋体Conformation构象Conformational构象分析Torsion angle扭转角Rotamer旋转异构体Anti conformation反式构象Bisecting conformation等分构象Anti periplanar conformation反叠构象Synperiplanar conformation顺叠构象Synclinal conformation反错构象Synclinal conformation顺错构象Eclipsed conformation重叠构象Gauche conformation,skew con-formation邻位交叉构象Staggered conformation对位交叉构象Steric effect空间效应Steric hindrance位阻Atropismer阻转异构体Puckered ring折叠环Conformational inversion构象反转Chair conformation椅型构象Boat conformation船型构象Twist conformation扭型构象Skew boat conformation扭船型构象Half-chair conformation半椅型构象Pseudorotation假旋转Envelope conformation信封[型]构象Axial bond直[立]键Equatorial bond平[伏]键Cisoid conformation顺向构象Transoid conformation反向构象Retention of configuration构型保持Regioselectivity区域选择性Regiospecificity区域专一性Stereocelectivity立体选择性Stereospecificty立体专一性Conformer构象异构体Conformational effect构象效应Cram’s rube克拉姆规则Prelog’rule普雷洛格规则Stereochemical orientation立体[化学]取向Conformational transmission构象传递Homolog同系物Ipso position本位Ortho position邻位Meta position间位Para position对位Amphi position远位Peri position近位Trigonal hybridization三角杂化Molecular orbiral method分子轨道法Valence bond method价键法Delocalezed bond离域键Cross conjugation交叉共轭Vinylog插烯物Mesomeric effect中介效应Resonance共振Resonance effect共振效应Hyperconjugation超共轭Isovalent hyperconjugation等价超共轭No-bond resonance无键共振Aromaticity芳香性Aromatic sexter芳香六隅Huckel’rule休克尔规则Paramagnetic ring current顺磁环电流Diamagnetic ring cruuent抗磁环电流Homoaromaticity同芳香性Antiaromaticity反芳香性Alternant hydrocarbon交替烃Non-alternant hydrocarbon非交替烷Pericyclic reaction周环反应Electrocyclic rearrangement电环[化]重排Conrotatory顺旋Disroatatory对旋Cycloaddition环加成Symmetry forbidden-reaction对称禁阻反应Synfacial reaction同面反应Antarafacial reaction异面反应Mobius system默比乌斯体系Leois structure路易斯结构Coordinate-covalent bond配位共价键Banana bond香蕉键Pauling electronegativity scale鲍林电负性标度Polarizability可极化性Inductive effect诱导效应Field effect场效应Electrical effect电场效应tautomerism互变异构Tautomerization互变异构化Keto-enol tautomerism酮-烯醇互变异构Phenol-keto tautomerism酚-酮互变异构Imine-enamine atutomerism亚胺-烯胺互变异构Ring-chain tautomerism环-链互变异构Valence tautomerism价互变异构Ambident两可[的]Solvent effect溶剂效应Acid-base catalyxed reaction酸性溶剂Basic solvent碱性溶剂Dielectric constant介电常数Solvated electron溶剂化电子Acid-base catalyzed reaction酸碱催化反应Conjugate base共轭酸Conjugate base共轭碱Therm odynamic acidity热力学酸度Kinetic acidity动力学酸度Electron donof-acceptor complex,EDAcomple x电子给[体]受体络合物Host主体Guest客体Primary isotope effect一级同位素效应Secondary isotope effect二级同位数效应Inverse isotope effect逆同位素效应Kinetic control动力学控制Thermodynamic control热力学控制Substrate底物Intermediate中间体Reactive intermediate活泼中间体Microscopic reversibility微观可逆性Hammond postulate哈蒙德假说Linear free energy线性自由能Non-bonded interaction非键相互作用Torsional effect扭转效应Pitzer strain皮策张力Restricted rotation阻碍旋转Eclipsing effect重叠效应Eclipsing strain重叠张力Small-angle strain小角张力Large angle strain大角张力Transannular interaction跨环相互作用Transannular strain跨环张力I strain内张力F strain前张力B strain后张力Anomeric effect端基异构效应Walden inversion瓦尔登反转Racemization外消旋化Isoinversion等反转Isoracemization等消旋Homochiral纯手性[的]Mechanism机理Unimolecular nucleophilic单分子亲核取代Bimolecular nucleophilic sub-stitution双分子亲核取代Bimolecular nucleophilic substi-tution(with all ylic rearrange-ment)双分子亲核取代（含烯丙型重排）Internal nucleophilic substiru-tion分子内亲核取代Aromatic nucleophilic substitu-tion芳香亲核取代Unimolecular electrophilic sub-stitution单分子亲电取代Bimolecular electrophilic substi-tution双分子亲电取代Nucleophile-assisted unimolecu-lar electrophil ic substitution亲核体协助单分子亲电取代Unimolecular elimination单分子消除Bimolecular elimination双分子消除Unimolecular elimination through the conjuga te base单分子共轭碱消除Bimolecular elimination through the conjugate base双分子共轭碱消除Bimolecular elimination with for-mation of a c arbonyl group双分子羰基形成消除Unimolecular acid-catalyzed acyl-oxygen cleavage单分子酸催化酰氧断裂Bimolecular base-catalyzed acyl-oxygen cleav age双分子碱催化酰氧断裂Unimolecular acid-catalyzed alkyl-oxygen cle avage单分子酸催化烷氧断裂Bimllecular base-catalyzed al-kyl-oxygen cle avage双分子碱催化烷氧断裂π-allyl complex mechanismπ烯丙型络合机理Borderline mechanism边理机理Homolysis均裂Heterolysis异裂Heterolytic michanism异裂机理Counrer[gegen]ion反荷离子Ion pair离子对Carbocation碳正离子Nonclassical carbocation非经典碳正离子Carbanion碳负离子Masked carbanion掩蔽碳负离子Carbenoid卡宾体Carbene卡宾Nitrene氮宾Carbine碳炔Electrophilic addition亲电加成Electrophile亲电体Diaxial addition双直键加成Markovnikov’s rube马尔科夫尼科规则Anti-Markovnikov addition反马氏加成Michael addition迈克尔加成Substitution取代Electrophilic substitution亲电取代Addition-elimination mechanism加成消除机理Electrophilic aromatic substitu-tion亲电芳香取代Electron transfer电子转移Electron-donating group给电子基团Electron-Withdrawing group吸电子基团Deactivating group钝化基团Orinentation取向Ortho-para directing group邻对位定位基Meta directing group间位定位基Ortho effect邻位效应Partial rate factor分速度系数Nucleophilic reaction亲核反应Internal return内返Nucleophilicity亲核体Nucleophilicity亲核性α-effectα-效应Backside attack背面进攻Inversion反转Umbrella effect伞效应Push-pull effect推拉效应Leaving group离去基团Electrofuge离电体Nucleofuge离核体Phase-transfer catalysis相转移催化Neighboring group participation邻基基参与Neighboring proup assistance,anchimeric assis tance邻助作用Neighboring group effect邻基效应Apofacial reaction反面反应Briddgehead displacement桥头取代Aryl action芳正离子Benzyne苯炔Zaitsev rule札依采夫规则Anti-Zaitsev orientation反札依采夫定向Hofmann’s rule霍夫曼规则Bredt rule布雷特规则Initiation引发Anionic cleavage负离子裂解Partial bond fixation键[的]部分固定化02．3有机化学反应Alkylation烷基化C-alkylation C-烷基化O-alkylation O-烷基化N-alkylation N-烷基化Silylation硅烷[基]化Exhaustive methylation彻底甲基化Seco alkylation断裂烷基化Demethylation脱甲基化Ethylation乙基化Arylation芳基化Acylation酰化Formylation甲酰化Carbalkoxylation烷氧羰基化Carboamidation氨羰基化Carboxylation羧基化Amination氨基化Bisamination双氨基化Cine substitution移位取代Transamination氨基交换Hydroxylation羟基化acyloxyation酰氧基化Decarboxylative nitration脱羧卤化Allylic halogenation烯丙型卤化Dehalogenation脱卤Nitration硝化Decarboxylative nitration脱羧硝化Nitrosation亚硝化Sulfonation磺化Chlorosulfonation氯磺酰化Desulfonation脱磺酸基Sulfenylation亚磺酰化Sulfonylation磺酰化Chlorosulfenation氯亚磺酰化Chlorocarbonylation氯羰基化Diazotization重氮化Diazo transfer重氮基转移Coupling reaction偶联反应Diazonium coupling重氮偶联Cross-coupling reaction交叉偶联反应1,4-addition1，4-加成Conjugate addition共轭加成Dimerization二聚Trimefization三聚Additive dimerization加成二聚sulfurization硫化Selenylation硒化Hydroboration硼氢化Oxyamination羟氨基化Insertion插入carbonylation羧基化Hydroformylation加氢甲酰基化Hydroacylation加氢酰化Oxo process羰基合成Decarbonylation脱羰Hydrocarboxylation氢羧基化Homologization同系化Cyanoethylation氰乙基化Decyanoethylation脱氰乙基Ring clsure环合Diene synthesis双烯合成Dienophile亲双烯体Endo addition内型加成Exo addition外型加成Diels-Alder reaction第尔斯-尔德反应Retro Diels-Alder reaction逆第尔斯-阿尔德反应Ene synthesis单烯合成Anionic cycloaddition负离子环加成Dipolar addition偶极加成-elimination-消除-elimination-消除-elimination-消除-elimination-消除Dehydrohalogenation脱卤化氢Deamination脱氨基Pyrolytic elimination热解消除Elimination-addition消除-加成Decarboxylation脱羧Decarboxamidation脱酰胺Decyanation脱氰基Alkylolysis,alkyl cleavage烷基裂解Acylolysis,acyl cleavage酰基裂解Flash pyrolysis闪热裂Fragmentation碎裂Chiletropic reaction螯键反应Chelation螯环化Esterification酯化Transesterification酯交换Saponification皂化Alcoholysis醇解Ethanolysis乙醇解Cyanomethylation氰甲基化Aminomethylation氨甲基化Hydroxymethylation羟甲基化Hydroxyalkylation羟烷基化Cholromethylation氯甲基化Haloalkylation卤烷基化Transacetalation缩醛交换Enolization烯醇化Haloform reaction卤仿反应Condensation缩合Aldol condensation羟醛缩合Cross aldol condensation交叉羟醛缩合Retrograde aldol condensation逆羟醛缩合Acyloin condensation偶姻缩合Cyclization环化Annulation,annelation增环反应Spiroannulation螺增环Autoxidation自氧化Allylic hydroperoxylation烯丙型氢过氧化Epoxidation环氧化Oxonolysis臭氧解Electrochemical oxidation电化学氧化Oxidative decarboxylation氧化脱羧Aromatization芳构化Catalytic hydrogenation催化氢化Heterogeneous hydrogenation多相氢化Homogeneous hydrogenation均相氢化Catalytic dehydrogenation催化脱氢Transfer hydrogenation转移氢化Hydrogenolysis氢解Dissolving metal reduction溶解金属还原Single electron transfer单电子转移Bimolecular reduction双分子还原Electrochemical reduction电化学还原Reductive alkylation还原烷基化Reductive acylation还原酰化Reductive dimerization还原二聚Deoxygenation脱氧Desulfurization脱硫Deselenization脱硒Mitallation金属化Lithiation锂化Hydrometallation氢金属化Mercuration汞化Oxymercuration羟汞化Aminomercuration氨汞化Abstraction夺取[反应]Internal abstraction内夺取[反应] Rearrangement重排Prototropic rearrangement质了转移重排Double bond migration双键移位Allylic migration烯丙型重排Allylic migration烯丙型迁移Ring contraction环缩小[反应]Ring expansion,ring enlargement扩环[反应] -ketol rearrangement-酮醇重排Pinacol rearrangement频哪醇重排Retropinacol rearrangement逆频哪醇重排Semipinacol rearrangement半频哪醇重排Benzilic rearrangement二苯乙醇酸重排Acyl rearrangement酰基重排Migratory aptitude迁移倾向Transannular insertion跨环插入Transannular rearrangement跨环重排Migration迁移Prototropy质子转移Cationotropic rearrangement正离子转移重排Anionotropy负离子转移Anionotropic rearrangement负离子转移重排Sigmatropic rearrangement-迁移重排Homosigmatropic rearrangement同迁移重排Electrophilic rearrangement亲电重排Photosensitization光敏化Forbidden transition禁阻跃迁photooxidation光氧化Photoisomerization光异构化Photochemical rearrangement光化学重排有机化合物类名Aliphatic compound脂肪族化合物Hpdrocarbon碳氢化合物Alkane烷Wax蜡Paraffin wax石蜡Alkene烯Alkyen炔Acetylide炔化物Active hydrogen compounds活泼氢化合物Carbon acid碳氢酸Super acid超酸Diene双烯Triene三烯Allene丙二烯Ccumulene累积多烯Enyne烯炔Diyne二炔Alkyl halide卤代烷Alcohol醇Homoallylic alcohol高烯丙醇Ether醚Epoxide环氧化物Cellosolve溶纤剂Crown ether冠醚Netro compound硝基化合物Amine胺Quaternaryammonium com-pound季铵化合物Amine oxide氧化胺Diazoalkane重氮烷Mercaptan硫醇Sulfonic acid磺酸Sulfoxide亚砜Sulfone砜Aldehyde醛Detone酮Aldehyde hydrate醛水合物Ketone hydrate酮水合物Hemiacetal半缩醛Acetal缩醛acetal[化]乙缩醛,乙缩醛二乙醇Ketal缩酮Dithiane二噻烷Aminal缩醛胺imine亚胺Aldimine醛亚胺Oxime肟Aldimine醛肟Oxime亚硝基化合物aldoxime硝酮Hydrazone腙Azine嗪Semicarbazone缩氯基脲Cyanohydrin羟腈Pinacol频哪醇Enol烯醇Enol ether烯醇醚Enol ester烯醇酯Enamine烯胺Ynamine炔胺Mannich base曼尼希碱Carboxylic acid羧酸Ester酯orthoester原酸酯Acyl halide酰卤Acyl fluoride酰氟Acyl chloride酰氯Acyl rtomide酰溴Acyl iodide酰碘Carbobenzoxy chloride苄氧甲酰氯Acyl tosylate酰基对甲苯磺酸酐Ketene乙烯酮Peracid过酸Perester过酸酯Acyl peroxide酰基过氧化物Nitrile腈Nitrile oxide氧化腈Isonitrile异腈Amide酰胺Imide二酰亚胺N-bromo compound N-溴化物Hydrazide酰肼Acyl azide酰叠氮Amidine脒Keto ester酮酸酯Acyl cyanide酰腈Carbon suboxide二氧化三碳Glycidic acid环氧丙酸Carbammic acid氨基甲酸Carbamate氨基甲酸酯Urea脲Cyanamide氨腈Carbodiimide碳二亚胺Allophanate脲基甲酸酯Thioester硫代酸酯Thiol acid硫羰酸Lactone内酯Lactol内半缩醛Macrolide大环内酯Amino acid氨基酸Zwitterions两性离子Inner salt内盐Betaine甜菜碱Lactam内酰胺Hydantion乙内酰脲Peptide肽Glycol二醇Aldol羟醛Acyloin偶姻Carbohydrate碳水化合物Aldose醛糖Ketose酮糖Furanose呋喃糖Pyranose吡喃糖Glycoside糖苷Glucoside葡[萄]糖苷Aglycon苷元Saccharide糖类Oligosaccharide寡糖Polysaccharide多糖Alditol糖醇Osazone脎Alicyclic compound脂环化合物Cycloalkene环烷Spirane环烯Cage compound螺烷Propellane笼型化合物Rotazane螺桨烷Catenane轮烷Rused ring索烃化学专业英语词汇常用前后缀-acetal醛缩醇acetal-乙酰acid酸-al醛alcohol醇-aldehyde醛alkali-碱allyl丙烯基'alkoxy-烷氧基-amide酰胺amino-氨基的-amidine脒-amine胺-ane烷anhydride酐anilino-苯胺基aquo-含水的-ase酶-ate含氧酸的盐、酯-atriyne三炔azo-偶氮benzene苯bi-在盐类前表示酸式盐bis-双-borane硼烷bromo-溴butyl丁基.-carbinol甲醇carbonyl羰基-caboxylic acid羧酸centi-10-2chloro-氯代cis-顺式condensed缩合的、冷凝的cyclo-环deca-十deci10-1二-dine啶dodeca-十二-ene烯epi-表epoxy-环氧-ester酯-ether醚ethoxy-乙氧基ethyl乙基fluoro-氟代form仿-glycol二醇hemi-半hendeca-十一hepta-七heptadeca-十七hexa-六hexadeca-十六-hydrin醇hydro-氢或水hydroxyl羟基hypo-低级的，次-ic酸的，高价金属-ide无氧酸的盐，酰替胺，酐-il偶酰-imine亚胺iodine碘iodo-碘代iso-异，等，同-ite亚酸盐keto-酮ketone酮-lactone内酯mega-106meta-间，偏methoxy-甲氧基methyl甲基micro-10-6milli-10-3mono-(mon-)一，单nano-10-9nitro-硝基nitroso-亚硝基nona-九nonadeca-十九octa-八octadeca-十八-oic酸的-ol醇9a$f!Q,H:[5n&G -one酮ortho-邻，正，原-ous亚酸的，低价金属oxa-氧杂-oxide氧化合物-oxime肟oxo-酮oxy-氧化-oyl酰para-对位，仲penta-五pentadeca-十五per-高，过petro-石油phenol苯酚phenyl苯基pico-10-12poly-聚，多quadri-四quinque-五semi-半septi-七sesqui一个半***i-六sulfa-磺胺sym-对称syn-顺式，同，共ter-三-tetra-四tetradeca-十四tetrakis-四个thio-硫代trans-反式，超，跨tri-三thio-硫代trans-反式，超，跨tri-三trideca-十三tris-三个undeca-十一.uni-单，一unsym-不对称的，偏位-yl基-ylene撑(二价基，价在不同原子上)-yne炔活化剂的中英文名称Bis(2-ethylhexyl)sebacate（癸二酸二仲辛酯；癸二酸二2-乙基己酯）Zinc stearate（硬脂酸锌）Suberic acid（辛二酸）Adipic acid,（己二酸）Hexanedioic acid,（己二酸）Sebacic acid,dibutyl ester（癸二酸二丁酯）Abietic acid（松香酸）Lactic acid（乳酸）Poly(ethylene glycol)（聚乙二醇）Glycerol stearate（硬脂酸甘油酯）Imidazoline（咪唑啉，间二氮杂环戊烯）β-Pinene（β-蒎烯，β-松油二环烯）Adipic acid（脂肪酸）Butyl acetate（乙酸丁酯）Ethylene glycol butyl ether（乙二醇丁醚）Sebacic acid,（癸二酸）Decanedioic acid,（癸二酸）Ethylene glycol ethyl ether（乙二醇乙醚）2-Butenedioic acid(E)-,（2-丁烯二酸）Succinic acid,（琥珀酸，丁二酸）Ethylene glycol methyl ether（乙二醇甲醚）Acetyl acetate（乙酸乙酰脂）1H-Benzotriazole（1-H-笨并三唑）α-Pinene（α-蒎烯,α-松香二环烯）Salicylic acid(水杨酸)Iso-Propanol(异丙醇)Benzoic acid(苯甲酸)Ethanol(乙醇)Lysine(赖氨酸)Glutamic acid(谷氨酸,2-氨基戊二酸) Glyceroyl,（甘油酰）N,N,N',N'-Tetrakis-(2-hydroxypropyl)-ethylen e-diamine（N，N，N，N-四（2-羟基丙基）乙烯二氨）Isoleucine,（异亮氨酸）Decamethylenedicarboxylic acid,disalicyloyl hydrazide（Tris(2,3-dibromopropyl)isocyanurate（3（2，3-2溴丙基）异氰尿酸盐）3-(N-Salicyloyl)amino-1,2,4-triazole（3-（N-水杨酰）氨-1，2，4-三唑）Isocyanuric acid（异氰尿酸）Salicylamide（水杨酰胺）Polyethylene glycol（聚乙二醇）Diethylene glycol diethyl ether（二甘醇二乙醚，（一缩）二乙二醇二乙醚）Butyl carbitol（丁基卡必醇）Ethyl carbitol（乙基卡必醇）Methyl carbitol（甲基卡必醇）Ethylene glycol monobutyl ether（乙二醇单丁醚）Glutaric acid（戊二酸，谷酸）Succinic acid（琥珀酸，丁二酸）Citric acid（柠檬酸）Salicylic acid（水杨酸）Lactic acid（2-羟基丙酸，乳酸）Glycerin monostearate（甘油一硬脂酸）Pentaerythritol（季戊四醇）tetrakis[β-(3,5-di-tert-butyl-4-hydroxy-phenyl) propionate]四[β-（3，5-二叔丁基-4-羟基-苯基）丙酸酯Dioctyl sebacate（癸二酸二辛酯）N-Methyl pyrrolidone,（N-甲基吡咯烷酮）Diethylene glycol ethyl ether（二甘醇乙醚）Propylene glycol（丙二醇）Octanedioic acid（辛二酸）Oleamide（油酸酰胺）[olamine乙醇胺]2-Mercapto benzothiazole（2-巯基-苯并噻唑）Nonanedioic acid,（壬二酸）cis-9-Octadecenoic acid,（顺式-9-十八炭烯酸，油酸）Sebacic acid,uses（癸二酸）有机化学专业英语1112-Hydroxy stearic acid （十二羟基硬脂酸）Phthalic acid （苯二甲酸）1,1,3-Tris(2-methyl-4-hydroxy-5-tert-butylphe nyl)butane （1，1，3-三（2-甲基-4-羟基-5-叔丁基苯基）丁烷）1,3,5-Trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-h ydroxybenzyl)benzene（1，3，5-三甲基-2，4，6-三（3，5-二叔丁基-4-羟基苯基）苯）1-Methyl-2-pyrrolidone,（1-甲基-2-吡咯烷酮）Carbonic acid,（碳酸）Phthalic acid,（苯二甲酸）Malic acid （苹果酸,羟基丁二酸）2,3-Dibromo-2-butene-1,4-diol （2，3-二溴-2-丙烯-1，4-二醇）Cetylpyridinium bromide （溴代十六烷基吡啶）Pentanedioic acid （戊二酸）pentanediol (戊二醇)pentanoic acid (戊酸)pentanol (戊醇)Butanedioic acid,（丁二酸）1,2-Dibromoethylbenzene （1，2-二溴乙基苯）Salicylic acid,（水杨酸）Stearic acid （硬脂酸）Pentanedioic acid （戊二酸）Maleic acid,（马来酸，失水苹果酸）Phthalic acid,（苯二甲酸）Tartaric acid,（酒石酸）Acetic acid,（乙酸）Polyoxyethylene octylphenol ether （聚氧乙烯辛基酚醚，聚氧化亚乙基辛基分醚）Ethanedioic acid,（乙二酸）Polyethylene glycol （聚乙二醇）Diethylene glycol butyl ether （二甘醇丁醚）Diethylene glycol monoethyl ether （二甘醇单乙醚）Ethylene glycol monobutyl ether （乙二醇单丁醚）Pentaerythritol,（季戊四醇）Diglycol,（二甘醇，一缩二乙二醇）Hexylene glycol （己二醇）Ethylene glycol,（乙二醇）Glycerol,（甘油,丙三醇）Cyclobutanediamine （环丁烷二胺）Dibromobutenediol （二溴丁二醇）Cyclohexanediamine （环己烷二胺）Succinamide （琥珀酰胺，丁二酸胺）Ethylenediamine,（乙二胺）Triethanolamine,（三乙醇胺）5-Aminoisophthalic acid （5-氨基间苯二甲酸）p-tert-Butylbenzoic acid （对叔丁基苯甲酸）Propionic acid,（丙酸）Benzoic acid,（安息香酸,苯(甲)酸）Salicylamide （水杨酰胺）Aniline,（苯胺）Palmitic acid,（棕榈酸,十六酸,软脂酸）Glutamic acid,（谷氨酸）Glutaric acid (谷酸，戊二酸)Glycine,（甘氨酸，氨基乙酸）Malic acid （苹果酸,羟基丁二酸）Adipic acid,（己二酸）Diethanolamine （二乙醇胺）Triethylamine,（三乙胺）Malic acid （苹果酸）Oxalic acid,（草酸）Oleic acid,（油酸）Glutaric acid (谷氨酸)Sorbic acid （山梨酸）sorbic alcohol (山梨醇)=sorbit。
有机化学英语词汇大全(音标,前后缀)
Route [`raut]【路线】Strategy ['strætidʒi]【策略】Rearrangement [ˏri:ә'reindʒmәnt]【重排】Asymmetric ['eisi'metrik]【不对称】Migration [mai'greiʃәn]【迁移】Mechanism ['mekәnizәm]【机理】Substrate ['sʌbstreit]【底物、培养基】Synthesis ['sinθisis]【合成】Labile ['leibail]【不稳定的】Azeotropic [әˏzi:ә'trɔpik]【共沸的】Scheme [ski:m]【图示】Derivative [di'rivәtiv]【衍生物】Analogous [ә'nælәgәs]【类似物】Primary ['praimәri]【伯-】Secondary ['sekәndәri]【仲-】Tertiary ['tә:ʃәri]【叔-】Functional ['fʌŋkʃәnl] group【官能团】Catalyst [`kætәlist] 【催化剂】Catalysis [kә`tælisis]【催化（作用）】Catalytical [kætә`litikәl] 【催化的】Hydrogenolysis [ˏhaidrәudʒә'nɔlәsis]【氢化】Hydrogenous [hai'drɔdʒinәs] 【含氢的】pericyclic [peri'saiklik] reaction【周环反应】transition [træn'ziʒәn] state 【过渡态】homolysis [hɔ'mɔlisis] 【均裂】heterolysis [ˏhetә'rɔlisis] 【异裂】homogeneous [ˏhɔmәu'dʒi:njәs]【均相的】heterogeneous [ˏhetәrәu'dʒi:niәs] 【非均相的】Steric ['sterik] hindrance[`hindrәns] 【立体位阻】Lipophilic [ˏlipә`filik]【亲脂性的】chiral [`kai rәl] 【手性的】electrophile [i`lektrәfail] 【亲电试剂】nucleophilic [ˏnju:kliәu'filik]【亲核的】hydrolysis [hai`drɔlisis] 【水解(作用)】acidolysis [ˏæsi`dɔlisis] 【酸解(作用)】displacement [dis'pleismәnt] 【取代】formalin ['fɔ:mәlin] 【甲醛溶液】dilute [dai'lju:t] 【稀释】dehydrate [di:'haidreit] 【脱水】dilation [dai'leiʃәn]【膨胀】saponification [sәpɔnifi'keiʃәn]【皂化】emulsification [iˏmʌlsifi'keiʃәn] 【乳化】reactant [ri:'æktәnt]【反应物】adduct [ә'dʌkt]【加合物】dissolve [di'zɔlv]【溶解】degradation [ˏdegrә'deiʃәn]【降解】mild [maild]【（反应）温和的】harsh [hɑ:ʃ] 【（反应）苛刻的】racemic [rә'si:mik]【消旋的】substituent [sʌb'stitjuәnt]【取代基】conjugation [ˏkɔndʒu'geiʃәn]【偶和】equivalent [i'kwivәlәnt]【当量的】volatile ['vɔlәtail]【易挥发的】susceptible [sә'septәbl]【易受影响的】in large scale【大量】protease ['prәutieis]【蛋白酶】side chain【侧链】Impuritiy [im'pjuәriti]【杂质】Component [kәm'pәunәnt]【组分】Tare [tєә]【去皮】Syringe ['sirindʒ]【注射器】Concentrate ['kɔnsentreit]【浓缩】Aqueous ['eikwiәs]【水相（的）】Methodology [meθә'dɔlәdʒi]【方法学】Precursor [pri(:)'kә:sә] 【前体】Separation [sepә'reiʃәn]【分离】Purification [ˏpjuәrifi'keiʃәn]【纯化】Recrystallization ['rikristәlai'zeiʃәn]【重结晶】Crystalline ['kristәlain]【晶体】Distillation [ˏdisti'leiʃәn]【蒸馏】Sublimation [ˏsʌbli'meiʃәn] 【升华】Microwave ['maikrәuweiv]【微波】Infrared ['infrә'red]【红外】ultraviolet ['ʌltrә'vaiәlit] active【紫外显色】isotope ['aisәutәup] 【同位素】isomer ['aisɔmә] 【同分异构体】Isomerization [aiˏsɔmәrai'zeiʃәn]【异构化】Transformation [ˏtrænsfә'meiʃәn]【转化】Stability [stә'biliti]【稳定性】Poisoned ['pɔiznd]【中毒的】Filter ['filtә]【过滤器】Filtration [fil'treiʃәn]【过滤】Filtrate ['filtreit]【滤液】Filter Cake【滤饼】Eluent ['eljuәnt]【淋洗液】hin-layer-chromatography [ˏkrәumә'tɔgrәfi] TLC【薄层色谱】Preparative [pri'pærәtiv] TLC【制备薄层色谱】HPLC【高效液相色谱】LC-MS【液质联用仪】Protic ['prәutik]【质子的】Aprotic[ә'prәutik]【非质子的】Decompose [ˏdi:kәm'pәuz]【分解】Removal [ri'mu:vәl]【除去】Reduced [ri'dju:st] pressure 【减压】Vacuum ['vækjuәm] 【真空】Elimination [iˏlimi'neiʃәn]【消除】Addition [ә'diʃәn]【添加、加成】Ligand ['laigәnd]【配体】Stopper ['stɔpә]【塞子】Separatory/ addition/ Büchner funnel ['fʌnәl]【分液/加料/布什】column chromatography【柱层析】Run column【用柱层析分离】Stopcock ['stɔpkɔk] 【旋塞阀】Condenser [kәn'densә]【冷凝管】Chamber ['tʃeimbә]【（薄层用）展缸】Bench [bentʃ] 【实验台】Hood [hud] 【通风橱】Rotavapor [ˏrәutә'veipә]【旋蒸】Evaporation [iˏvæpә'reiʃәn] 【蒸发】vacuum hose [hәuz]【真空管】silicon ['silikәn] oil bath 【（硅）油浴】sink [siŋk]【水槽】neutralize ['nju:trәlaiz]【中和】stir bar 【搅拌子】Dry ice trap【干冰冷阱】Glovebox [glʌvә'bɔks]【手套箱】vacuum pump [pʌmp]【真空泵】spatula ['spætjulә] 【刮刀】miscible ['misibl]【混溶的】Quench [kwentʃ]【淬灭】Purging ['pә:dʒiŋ]【鼓气】Titration [tai'treiʃәn]【滴定】Trituration [tritju'reiʃәn]【研磨】Dessicator ['desikeitә:]【干燥剂】Hygroscopic [ˏhaigrәu'skɔpik] 【吸湿的】Lachrymator ['lækriˏmeitә]【催泪剂】DI (de-ion) water【去离子水】Stoichiometric [ˏstɔikiәuˋmєtrik]【化学量的】Volumetric [vɔlju'metrik] 【测体积的】Weighing ['weiiŋ] paper【称量纸】Mechanical [mi'kænikl] stirring apparatus [ˏæpә'reitәs]【机械搅拌装置】heating mental ['mentl] 【加热套】Eclipse [i'klips] 【使失色】Anomeric ['ænәˏmerik] Effect 【端基异构效应】Equatorial [ˏekwә'tɔ:riәl]【平伏（键）的】Axial ['æksiәl]【直立（键）的】Gauche [gәuʃ] 【构象】Thermodynamic ['θә:mәudai'næmik]【热力学的】Kinetic [kai'netik]【动力学的】Enantioselective [eˏnæntiәsi'lektiv]【对映选择性的】Diastereotopic [ˏdaiәstiәriә'tɔpik] 【非对映的】Chemoselectivity 【化学选择性】Regioselective ['ri:dʒәu si'lektiv] 【区域选择性的】Stereoselectivity [ˏstiәriәˏsilek'tiviti]【立体选择性】Synthon ['sinθɔn]【合成子】Nitrosation [naitrә'seiʃә:n] 【亚硝化】Tautomer ['tɔ:tәmә]【（互变）异构体】Confirmation [ˏkɔnfɔ:'meiʃәn] 【构型】Equilibrium [ˏi:kwi'libriәm]【平衡】pyrolysis [ˏpaiә'rɔlisis] 【热解】ozonolysis [ ,әuzәu'nɔlisis ] 【臭氧分解】conversion [kәn'vә:ʃәn] ratio ['reiʃiәu] 【转化率】Deprotection【脱保护】Introduction【引入】Cleavage【分离，脱除】有机化学专业词汇Angular methyl group 角甲基Alkylidene group 亚烷基Allyl group 烯丙基Allylic 烯丙型[的]Phenyl group 苯基Aryl group 芳基Benzyl group 苄基Benzylic 苄型[的]Activating group 活化基团Chromophore 生色团Auxochrome 助色团Magnetically anisotropic group 磁各向异性基团Smally ring 小环Common ring 普通环Medium rimg 中环Large ring 大环Bridged-ring system 桥环体系Spiro compound 螺环化合物Helical molecule 螺旋型分子Octahedral compound 八面体化合物Conjugation 共轭Conjugated-system 共轭体系Acyl cation 酰[基]正离子Benzylic cation 苄[基]正离子Arenirm ion 芳[基]正离子Ketyl radical 羰自由基Radical ion 自由基离子Radical cation 自由基正离子Radical anion 自由基负离子Isomerism 异构[现象]Aci form 酸式Fluxional structure 循变结构Stereochemistry 立体化学Optical activity 光学活性Dextro isomer 右旋异构体Laevo isomer 左旋异构体Tetrahedral configuration 四面体构型Stereoisomerism 立体异构[现象] Asymmetric atom 不对称原子Asymmetric carbon 不对称碳Pseudoasymmetric carbon 假不对称碳Phantom atom 虚拟原子Homotopic 等位[的]Heterotopic 异位[的]Enantiotopic 对映异位[腯Diastereotopic 非对映异位[的] Configuration 构型Absolute configuration 绝对构型Chirality 手性Chiral 手性[的]Chiral center 手性中心Chiral molecule 手性分子Achiral 非手性[的]Fischer projection 费歇尔投影式Neoman projection 纽曼投影式D-L system of nomenclature D-L命名体系R-S syytem of nomenclature R-S命名体系Cahn-Ingold-Prelon sequence 顺序规则Symmetry factor 对称因素Plane of symmetry 对称面Mirror symmetry 镜面对称Enantiomer 对映[异构]体Diastereomer 非对映[异构]体Epimer 差向异构体Anomer 端基[差向]异构体Erythro configuration 赤型构型Erythro isomer 赤型异构体Threo configuration 苏型构型Threo isomer 苏型异构体Trigonal carbon 三角型碳Cis-trans isomerism 顺反异构E isomer E异构体Z isomer Z异构体Endo isomer 内型异构体Exo isomer 外型异构体Prochirality 前手性Pro-R group 前R基团Pro-S proup 前S基团Re face Re面Si face Si面Racemic mixture 外消旋混合物Racemic compound 外消旋化合物Racemic solid solution 外消旋固体溶液Meso compound 内消旋化合物Quasi recemate 准外消旋体Conformation 构象Conformational 构象分析Torsion angle 扭转角Rotamer 旋转异构体Anti conformation 反式构象Bisecting conformation 等分构象Anti periplanar conformation 反叠构象Synperiplanar conformation 顺叠构象Synclinal conformation 反错构象Synclinal conformation 顺错构象Eclipsed conformation 重叠构象Gauche conformation, skew con-formation 邻位交叉构象Staggered conformation 对位交叉构象Steric effect 空间效应Steric hindrance 位阻Atropismer 阻转异构体Puckered ring 折叠环Conformational inversion 构象反转Chair conformation 椅型构象Boat conformation 船型构象Twist conformation 扭型构象Skew boat conformation 扭船型构象Half-chair conformation 半椅型构象Pseudorotation 假旋转Envelope conformation 信封[型]构象Axial bond 直[立]键Equatorial bond 平[伏]键Cisoid conformation 顺向构象Transoid conformation 反向构象Retention of configuration 构型保持Regioselectivity 区域选择性Regiospecificity 区域专一性Stereocelectivity 立体选择性Stereospecificty 立体专一性Conformer 构象异构体Conformational effect 构象效应Cram’s rube 克拉姆规则Prelog’rule 普雷洛格规则Stereochemical orientation 立体[化学]取向Conformational transmission 构象传递Homolog 同系物Ipso position 本位Ortho position 邻位Meta position 间位Para position 对位Amphi position 远位Peri position 近位Trigonal hybridization 三角杂化Molecular orbiral method 分子轨道法Valence bond method 价键法Delocalezed bond 离域键Cross conjugation 交叉共轭Vinylog 插烯物Mesomeric effect 中介效应Resonance 共振Resonance effect 共振效应Hyperconjugation 超共轭Isovalent hyperconjugation 等价超共轭No-bond resonance 无键共振Aromaticity 芳香性Aromatic sexter 芳香六隅Huckel’rule 休克尔规则Paramagnetic ring current 顺磁环电流Diamagnetic ring cruuent 抗磁环电流Homoaromaticity 同芳香性Antiaromaticity 反芳香性Alternant hydrocarbon 交替烃Non-alternant hydrocarbon 非交替烷Pericyclic reaction 周环反应Electrocyclic rearrangement 电环[化]重排Conrotatory 顺旋Disroatatory 对旋Cycloaddition 环加成Symmetry forbidden-reaction 对称禁阻反应Synfacial reaction 同面反应Antarafacial reaction 异面反应Mobius system 默比乌斯体系Leois structure 路易斯结构Coordinate-covalent bond 配位共价键Banana bond 香蕉键Pauling electronegativity scale 鲍林电负性标度Polarizability 可极化性Inductive effect 诱导效应Field effect 场效应Electrical effect 电场效应tautomerism 互变异构Tautomerization 互变异构化Keto-enol tautomerism 酮-烯醇互变异构Phenol-keto tautomerism 酚-酮互变异构Imine-enamine atutomerism 亚胺-烯胺互变异构Ring-chain tautomerism 环-链互变异构Valence tautomerism 价互变异构Ambident 两可[的]Solvent effect 溶剂效应Acid-base catalyxed reaction 酸性溶剂Basic solvent 碱性溶剂Dielectric constant 介电常数Solvated electron 溶剂化电子Acid-base catalyzed reaction 酸碱催化反应Conjugate base 共轭酸Conjugate base 共轭碱Therm odynamic acidity 热力学酸度Kinetic acidity 动力学酸度Electron donof-acceptor complex,EDAcomplex 电子给[体]受体络合物Host 主体Guest 客体Primary isotope effect 一级同位素效应Secondary isotope effect 二级同位数效应Inverse isotope effect 逆同位素效应Kinetic control 动力学控制Thermodynamic control 热力学控制Substrate 底物Intermediate 中间体Reactive intermediate 活泼中间体Microscopic reversibility 微观可逆性Hammond postulate 哈蒙德假说Linear free energy 线性自由能Non-bonded interaction 非键相互作用Torsional effect 扭转效应Pitzer strain 皮策张力Restricted rotation 阻碍旋转Eclipsing effect 重叠效应Eclipsing strain 重叠张力Small-angle strain 小角张力Large angle strain 大角张力Transannular interaction 跨环相互作用Transannular strain 跨环张力I strain 内张力F strain 前张力B strain 后张力Anomeric effect 端基异构效应Walden inversion 瓦尔登反转Racemization 外消旋化Isoinversion 等反转Isoracemization 等消旋Homochiral 纯手性[的]Mechanism 机理Unimolecular nucleophilic 单分子亲核取代Bimolecular nucleophilic sub-stitution 双分子亲核取代Bimolecular nucleophilic substi-tution(with allylic rearrange-ment) 双分子亲核取代（含烯丙型重排）Internal nucleophilic substiru-tion 分子内亲核取代Aromatic nucleophilic substitu-tion 芳香亲核取代Unimolecular electrophilic sub-stitution 单分子亲电取代Bimolecular electrophilic substi-tution 双分子亲电取代Nucleophile-assisted unimolecu-lar electrophilic substitution 亲核体协助单分子亲电取代Unimolecular elimination 单分子消除Bimolecular elimination 双分子消除Unimolecular elimination through the conjugate base 单分子共轭碱消除Bimolecular elimination through the conjugate base 双分子共轭碱消除Bimolecular elimination with for-mation of a carbonyl group 双分子羰基形成消除Unimolecular acid-catalyzed acyl-oxygen cleavage 单分子酸催化酰氧断裂Bimolecular base-catalyzed acyl-oxygen cleavage 双分子碱催化酰氧断裂Unimolecular acid-catalyzed alkyl-oxygen cleavage 单分子酸催化烷氧断裂Bimllecular base-catalyzed al- kyl-oxygen cleavage 双分子碱催化烷氧断裂π-allyl complex mechanism π烯丙型络合机理Borderline mechanism 边理机理Homolysis 均裂Heterolysis 异裂Heterolytic michanism 异裂机理Counrer[gegen]ion 反荷离子Ion pair 离子对Carbocation 碳正离子Nonclassical carbocation 非经典碳正离子Carbanion 碳负离子Masked carbanion 掩蔽碳负离子Carbenoid 卡宾体Carbene 卡宾Nitrene 氮宾Carbine 碳炔Electrophilic addition 亲电加成Electrophile 亲电体Diaxial addition 双直键加成Markovnikov’s rube 马尔科夫尼科规则Anti-Markovnikov addition 反马氏加成Michael addition 迈克尔加成Substitution 取代Electrophilic substitution 亲电取代Addition-elimination mechanism 加成消除机理Electrophilic aromatic substitu-tion 亲电芳香取代Electron transfer 电子转移Electron-donating group 给电子基团Electron-Withdrawing group 吸电子基团Deactivating group 钝化基团Orinentation 取向Ortho-para directing group 邻对位定位基Meta directing group 间位定位基Ortho effect 邻位效应Partial rate factor 分速度系数Nucleophilic reaction 亲核反应Internal return 内返Nucleophilicity 亲核体Nucleophilicity 亲核性α-effect α-效应Backside attack 背面进攻Inversion 反转Umbrella effect 伞效应Push-pull effect 推拉效应Leaving group 离去基团Electrofuge 离电体Nucleofuge 离核体Phase-transfer catalysis 相转移催化Neighboring group participation 邻基基参与Neighboring proup assistance,anchimeric assistance 邻助作用Neighboring group effect 邻基效应Apofacial reaction 反面反应Briddgehead displacement 桥头取代Aryl action 芳正离子Benzyne 苯炔Zaitsev rule 札依采夫规则Anti-Zaitsev orientation 反札依采夫定向Hofmann’s rule 霍夫曼规则Bredt rule 布雷特规则Initiation 引发Anionic cleavage 负离子裂解Partial bond fixation 键[的]部分固定化02．3有机化学反应Alkylation 烷基化C- alkylation C-烷基化O- alkylation O-烷基化N-alkylation N-烷基化Silylation 硅烷[基]化Exhaustive methylation 彻底甲基化Seco alkylation 断裂烷基化Demethylation 脱甲基化Ethylation 乙基化Arylation 芳基化Acylation 酰化Formylation 甲酰化Carbalkoxylation 烷氧羰基化Carboamidation 氨羰基化Carboxylation 羧基化Amination 氨基化Bisamination 双氨基化Cine substitution 移位取代Transamination 氨基交换Hydroxylation 羟基化acyloxyation 酰氧基化Decarboxylative nitration 脱羧卤化Allylic halogenation 烯丙型卤化Dehalogenation 脱卤Nitration 硝化Decarboxylative nitration 脱羧硝化Nitrosation 亚硝化Sulfonation 磺化Chlorosulfonation 氯磺酰化Desulfonation 脱磺酸基Sulfenylation 亚磺酰化Sulfonylation 磺酰化Chlorosulfenation 氯亚磺酰化Chlorocarbonylation 氯羰基化Diazotization 重氮化Diazo transfer 重氮基转移Coupling reaction 偶联反应Diazonium coupling 重氮偶联Cross-coupling reaction 交叉偶联反应1,4-addition 1，4-加成Conjugate addition 共轭加成Dimerization 二聚Trimefization 三聚Additive dimerization 加成二聚sulfurization 硫化Selenylation 硒化Hydroboration 硼氢化Oxyamination 羟氨基化Insertion 插入carbonylation 羧基化Hydroformylation 加氢甲酰基化Hydroacylation 加氢酰化Oxo process 羰基合成Decarbonylation 脱羰Hydrocarboxylation 氢羧基化Homologization 同系化Cyanoethylation 氰乙基化Decyanoethylation 脱氰乙基Ring clsure 环合Diene synthesis 双烯合成Dienophile 亲双烯体Endo addition 内型加成Exo addition 外型加成Diels-Alder reaction 第尔斯-尔德反应Retro Diels-Alder reaction 逆第尔斯-阿尔德反应Ene synthesis 单烯合成Anionic cycloaddition 负离子环加成Dipolar addition 偶极加成- elimination -消除- elimination -消除- elimination -消除-elimination -消除Dehydrohalogenation 脱卤化氢Deamination 脱氨基Pyrolytic elimination 热解消除Elimination-addition 消除-加成Decarboxylation 脱羧Decarboxamidation 脱酰胺Decyanation 脱氰基Alkylolysis,alkyl cleavage 烷基裂解Acylolysis,acyl cleavage 酰基裂解Flash pyrolysis 闪热裂Fragmentation 碎裂Chiletropic reaction 螯键反应Chelation 螯环化Esterification 酯化Transesterification 酯交换Saponification 皂化Alcoholysis 醇解Ethanolysis 乙醇解Cyanomethylation 氰甲基化Aminomethylation 氨甲基化Hydroxymethylation 羟甲基化Hydroxyalkylation 羟烷基化Cholromethylation 氯甲基化Haloalkylation 卤烷基化Transacetalation 缩醛交换Enolization 烯醇化Haloform reaction 卤仿反应Condensation 缩合Aldol condensation 羟醛缩合Cross aldol condensation 交叉羟醛缩合Retrograde aldol condensation 逆羟醛缩合Acyloin condensation 偶姻缩合Cyclization 环化Annulation,annelation 增环反应Spiroannulation 螺增环Autoxidation 自氧化Allylic hydroperoxylation 烯丙型氢过氧化Epoxidation 环氧化Oxonolysis 臭氧解Electrochemical oxidation 电化学氧化Oxidative decarboxylation 氧化脱羧Aromatization 芳构化Catalytic hydrogenation 催化氢化Heterogeneous hydrogenation 多相氢化Homogeneous hydrogenation 均相氢化Catalytic dehydrogenation 催化脱氢Transfer hydrogenation 转移氢化Hydrogenolysis 氢解Dissolving metal reduction 溶解金属还原Single electron transfer 单电子转移Bimolecular reduction 双分子还原Electrochemical reduction 电化学还原Reductive alkylation 还原烷基化Reductive acylation 还原酰化Reductive dimerization 还原二聚Deoxygenation 脱氧Desulfurization 脱硫Deselenization 脱硒Mitallation 金属化Lithiation 锂化Hydrometallation 氢金属化Mercuration 汞化Oxymercuration 羟汞化Aminomercuration 氨汞化Abstraction 夺取[反应]Internal abstraction 内夺取[反应] Rearrangement 重排Prototropic rearrangement 质了转移重排Double bond migration 双键移位Allylic migration 烯丙型重排Allylic migration 烯丙型迁移Ring contraction 环缩小[反应]Ring expansion,ring enlargement 扩环[反应] -ketol rearrangement -酮醇重排Pinacol rearrangement 频哪醇重排Retropinacol rearrangement 逆频哪醇重排Semipinacol rearrangement 半频哪醇重排Benzilic rearrangement 二苯乙醇酸重排Acyl rearrangement 酰基重排Migratory aptitude 迁移倾向Transannular insertion 跨环插入Transannular rearrangement 跨环重排Migration 迁移Prototropy 质子转移Cationotropic rearrangement 正离子转移重排Anionotropy 负离子转移Anionotropic rearrangement 负离子转移重排Sigmatropic rearrangement -迁移重排Homosigmatropic rearrangement 同迁移重排Electrophilic rearrangement 亲电重排Photosensitization 光敏化Forbidden transition 禁阻跃迁photooxidation 光氧化Photoisomerization 光异构化Photochemical rearrangement 光化学重排有机化合物类名Aliphatic compound 脂肪族化合物Hpdrocarbon 碳氢化合物Alkane 烷Wax 蜡Paraffin wax 石蜡Alkene 烯Alkyen 炔Acetylide 炔化物Active hydrogen compounds 活泼氢化合物Carbon acid 碳氢酸Super acid 超酸Diene 双烯Triene 三烯Allene 丙二烯Ccumulene 累积多烯Enyne 烯炔Diyne 二炔Alkyl halide 卤代烷Alcohol 醇Homoallylic alcohol 高烯丙醇Ether 醚Epoxide 环氧化物Cellosolve 溶纤剂Crown ether 冠醚Netro compound 硝基化合物Amine 胺Quaternaryammonium compound 季铵化合物Amine oxide 氧化胺Diazoalkane 重氮烷Mercaptan 硫醇Sulfonic acid 磺酸Sulfoxide 亚砜Sulfone 砜Aldehyde 醛Detone 酮Aldehyde hydrate 醛水合物Ketone hydrate 酮水合物Hemiacetal 半缩醛Acetal 缩醛acetal[化]乙缩醛, 乙缩醛二乙醇Ketal 缩酮Dithiane 二噻烷Aminal 缩醛胺imine 亚胺Aldimine 醛亚胺Oxime 肟Aldimine 醛肟Oxime 亚硝基化合物aldoxime 硝酮Hydrazone 腙Azine 嗪Semicarbazone 缩氯基脲Cyanohydrin 羟腈Pinacol 频哪醇Enol 烯醇Enol ether 烯醇醚Enol ester 烯醇酯Enamine 烯胺Ynamine 炔胺Mannich base 曼尼希碱Carboxylic acid 羧酸Ester 酯orthoester 原酸酯Acyl halide 酰卤Acyl fluoride 酰氟Acyl chloride 酰氯Acyl rtomide 酰溴Acyl iodide 酰碘Carbobenzoxy chloride 苄氧甲酰氯Acyl tosylate 酰基对甲苯磺酸酐Ketene 乙烯酮Peracid 过酸Perester 过酸酯Acyl peroxide 酰基过氧化物Nitrile 腈Nitrile oxide 氧化腈Isonitrile 异腈Amide 酰胺Imide 二酰亚胺N-bromo compound N-溴化物Hydrazide 酰肼Acyl azide 酰叠氮Amidine 脒Keto ester 酮酸酯Acyl cyanide 酰腈Carbon suboxide 二氧化三碳Glycidic acid 环氧丙酸Carbammic acid 氨基甲酸Carbamate 氨基甲酸酯Urea 脲Cyanamide 氨腈Carbodiimide 碳二亚胺Allophanate 脲基甲酸酯Thioester 硫代酸酯Thiol acid 硫羰酸Lactone 内酯Lactol 内半缩醛Macrolide 大环内酯Amino acid 氨基酸Zwitterions 两性离子Inner salt 内盐Betaine 甜菜碱Lactam 内酰胺Hydantion 乙内酰脲Peptide 肽Glycol 二醇Aldol 羟醛Acyloin 偶姻Carbohydrate 碳水化合物Aldose 醛糖Ketose 酮糖Furanose 呋喃糖Pyranose 吡喃糖Glycoside 糖苷Glucoside 葡[萄]糖苷Aglycon 苷元Saccharide 糖类Oligosaccharide 寡糖Polysaccharide 多糖Alditol 糖醇Osazone 脎Alicyclic compound 脂环化合物Cycloalkene 环烷Spirane 环烯Cage compound 螺烷Propellane 笼型化合物Rotazane 螺桨烷Catenane 轮烷Rused ring 索烃化学专业英语词汇常用前后缀-acetal 醛缩醇acetal- 乙酰acid 酸-al 醛alcohol 醇-aldehyde 醛alkali- 碱allyl 丙烯基 'alkoxy- 烷氧基-amide 酰胺amino- 氨基的-amidine 脒-amine 胺-ane 烷anhydride 酐anilino- 苯胺基aquo- 含水的-ase 酶-ate 含氧酸的盐、酯-atriyne 三炔azo- 偶氮benzene 苯bi- 在盐类前表示酸式盐bis- 双-borane 硼烷bromo- 溴butyl 丁基 .-carbinol 甲醇carbonyl 羰基-caboxylic acid 羧酸centi- 10-2chloro- 氯代cis- 顺式condensed 缩合的、冷凝的cyclo- 环deca- 十deci 10-1二-dine 啶dodeca- 十二-ene 烯epi- 表epoxy- 环氧-ester 酯-ether 醚ethoxy- 乙氧基ethyl 乙基fluoro- 氟代form 仿-glycol 二醇hemi- 半hendeca- 十一hepta- 七heptadeca- 十七hexa- 六hexadeca- 十六-hydrin 醇hydro- 氢或水hydroxyl 羟基hypo- 低级的，次-ic 酸的，高价金属-ide 无氧酸的盐，酰替胺，酐-il 偶酰-imine 亚胺iodine 碘iodo- 碘代iso- 异，等，同-ite 亚酸盐keto- 酮ketone 酮-lactone 内酯mega- 106meta- 间，偏methoxy- 甲氧基methyl 甲基micro- 10-6milli- 10-3mono- ( mon-) 一，单nano- 10-9nitro- 硝基nitroso- 亚硝基nona- 九nonadeca- 十九octa- 八octadeca- 十八-oic 酸的-ol 醇9 a$ f! Q, H: [5 n& G-one 酮ortho- 邻，正，原-ous 亚酸的，低价金属oxa- 氧杂-oxide 氧化合物-oxime 肟oxo- 酮oxy- 氧化-oyl 酰para- 对位，仲penta- 五pentadeca- 十五per- 高，过petro- 石油phenol 苯酚phenyl 苯基pico- 10-12poly- 聚，多quadri- 四quinque- 五semi- 半septi- 七sesqui 一个半***i- 六sulfa- 磺胺sym- 对称syn- 顺式，同，共ter- 三 -tetra- 四tetradeca- 十四tetrakis- 四个thio- 硫代trans- 反式，超，跨tri- 三thio- 硫代trans- 反式，超，跨tri- 三trideca- 十三tris- 三个undeca- 十一 .uni- 单，一unsym- 不对称的，偏位-yl 基-ylene 撑(二价基，价在不同原子上)-yne 炔活化剂的中英文名称Bis(2-ethylhexyl) sebacate （癸二酸二仲辛酯；癸二酸二2-乙基己酯）Zinc stearate （硬脂酸锌）Suberic acid （辛二酸）Adipic acid, （己二酸）Hexanedioic acid, （己二酸）Sebacic acid, dibutyl ester （癸二酸二丁酯）Abietic acid （松香酸）Lactic acid （乳酸）Poly(ethylene glycol) （聚乙二醇）Glycerol stearate （硬脂酸甘油酯）Imidazoline （咪唑啉，间二氮杂环戊烯）-Pinene （β-蒎烯，β-松油二环烯）Adipic acid （脂肪酸）Butyl acetate （乙酸丁酯）Ethylene glycol butyl ether （乙二醇丁醚）Sebacic acid, （癸二酸）Decanedioic acid, （癸二酸）Ethylene glycol ethyl ether （乙二醇乙醚）2-Butenedioic acid (E)-, （2-丁烯二酸）Succinic acid, （琥珀酸，丁二酸）Ethylene glycol methyl ether （乙二醇甲醚）Acetyl acetate （乙酸乙酰脂）1H-Benzotriazole （1-H-笨并三唑）-Pinene （α-蒎烯,α-松香二环烯）Salicylic acid (水杨酸)Iso-Propanol (异丙醇)Benzoic acid (苯甲酸)Ethanol (乙醇)Lysine (赖氨酸)Glutamic acid (谷氨酸,2-氨基戊二酸)Glyceroyl, （甘油酰）N,N,N',N'-Tetrakis-(2-hydroxypropyl)-ethylene-diamine （N，N，N，N-四（2-羟基丙基）乙烯二氨）Isoleucine, （异亮氨酸）Decamethylenedicarboxylic acid, disalicyloylhydrazide （Tris(2,3-dibromopropyl)isocyanurate（3（2，3-2溴丙基）异氰尿酸盐）3-(N-Salicyloyl)amino-1,2,4-triazole （3-（N-水杨酰）氨-1，2，4-三唑）Isocyanuric acid （异氰尿酸）Salicylamide （水杨酰胺）Polyethylene glycol （聚乙二醇）Diethylene glycol diethyl ether （二甘醇二乙醚，（一缩）二乙二醇二乙醚）Butyl carbitol （丁基卡必醇）Ethyl carbitol （乙基卡必醇）Methyl carbitol （甲基卡必醇）Ethylene glycol monobutyl ether （乙二醇单丁醚）Glutaric acid （戊二酸，谷酸）Succinic acid （琥珀酸，丁二酸）Citric acid （柠檬酸）Salicylic acid （水杨酸）Lactic acid （2-羟基丙酸，乳酸）Glycerin monostearate （甘油一硬脂酸）Pentaerythritol （季戊四醇）tetrakis[-(3,5-di-tert-butyl-4-hydroxy-phenyl)propionate] 四[β-（3，5-二叔丁基-4-羟基-苯基）丙酸酯Dioctyl sebacate （癸二酸二辛酯）N-Methyl pyrrolidone, （N-甲基吡咯烷酮）Diethylene glycol ethyl ether （二甘醇乙醚）Propylene glycol （丙二醇）Octanedioic acid （辛二酸）Oleamide （油酸酰胺）[olamine 乙醇胺]2-Mercapto benzothiazole （2-巯基-苯并噻唑）Nonanedioic acid, （壬二酸）cis-9-Octadecenoic acid, （顺式-9-十八炭烯酸，油酸）Sebacic acid, uses （癸二酸）12-Hydroxy stearic acid （十二羟基硬脂酸）Phthalic acid （苯二甲酸）1,1,3-Tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane （1，1，3-三（2-甲基-4-羟基-5-叔丁基苯基）丁烷）1,3,5-Trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl) benzene（1，3，5-三甲基-2，4，6-三（3，5-二叔丁基-4-羟基苯基）苯）1-Methyl-2-pyrrolidone, （1-甲基-2-吡咯烷酮）Carbonic acid, （碳酸）Phthalic acid, （苯二甲酸）Malic acid （苹果酸,羟基丁二酸）2,3-Dibromo-2-butene-1,4-diol （2，3-二溴-2-丙烯-1，4-二醇）Cetylpyridinium bromide （溴代十六烷基吡啶）Pentanedioic acid （戊二酸） pentanediol (戊二醇) pentanoic acid ( 戊酸) pentanol (戊醇)Butanedioic acid, （丁二酸）1,2-Dibromoethylbenzene （1，2-二溴乙基苯）Salicylic acid, （水杨酸）Stearic acid （硬脂酸）Pentanedioic acid （戊二酸）Maleic acid, （马来酸，失水苹果酸）Phthalic acid, （苯二甲酸）Tartaric acid, （酒石酸）Acetic acid, （乙酸）Polyoxyethylene octylphenol ether （聚氧乙烯辛基酚醚，聚氧化亚乙基辛基分醚）Ethanedioic acid, （乙二酸）Polyethylene glycol （聚乙二醇）Diethylene glycol butyl ether （二甘醇丁醚）Diethylene glycol monoethyl ether （二甘醇单乙醚）Ethylene glycol monobutyl ether （乙二醇单丁醚）Pentaerythritol, （季戊四醇）Diglycol, （二甘醇，一缩二乙二醇）Hexylene glycol （己二醇）Ethylene glycol, （乙二醇）Glycerol, （甘油,丙三醇）Cyclobutanediamine （环丁烷二胺）Dibromobutenediol （二溴丁二醇）Cyclohexanediamine （环己烷二胺）Succinamide （琥珀酰胺，丁二酸胺）Ethylenediamine, （乙二胺）Triethanolamine, （三乙醇胺）5-Aminoisophthalic acid （5-氨基间苯二甲酸）p-tert-Butylbenzoic acid （对叔丁基苯甲酸）Propionic acid, （丙酸）Benzoic acid, （安息香酸, 苯(甲)酸）Salicylamide （水杨酰胺）Aniline, （苯胺）Palmitic acid, （棕榈酸, 十六酸, 软脂酸）Glutamic acid, （谷氨酸） Glutaric acid (谷酸，戊二酸) Glycine, （甘氨酸，氨基乙酸）Malic acid （苹果酸,羟基丁二酸）Adipic acid, （己二酸）Diethanolamine （二乙醇胺）Triethylamine, （三乙胺）Malic acid （苹果酸）Oxalic acid, （草酸）Oleic acid, （油酸）Glutaric acid (谷氨酸) Sorbic acid （山梨酸）sorbic alcohol (山梨醇)=sorbit。
有机化学常用中英文词汇对照
Amine胺
ound季铵化合物
Carbohydrate碳水化合物
Amine oxide氧化胺
Aldose醛糖
Diazoalkane重氮烷
Ketose酮糖
Mercaptan硫醇
Furanose呋喃糖
Sulfonic acid磺酸
Cyanohydrin羟腈
Acyl iodide酰碘
Pinacol频哪醇
Carbobenzoxy chloride苄氧甲酰氯
Enol烯醇
Acyl tosylate酰基对甲苯磺酸酐
Enol ether烯醇醚
Ketene乙烯酮
Enol ester烯醇酯
Peracid过酸
Enamine烯胺
Perester过酸酯
Pyranose吡喃糖
Sulfoxide亚砜
Glycoside糖苷
Sulfone砜
Glucoside葡[萄]糖苷
Aldehyde醛
Aglycon苷元
Detone酮
Saccharide糖类
Aldehyde hydrate醛水合物
Oligosaccharide寡糖
Ketone hydrate酮水合物
Polysaccharide多糖
Diene双烯
Thioester硫代酸酯
Triene三烯
Thiol acid硫羰酸
Allene丙二烯
Lactone内酯
Ccumulene累积多烯
Lactol内半缩醛
Enyne烯炔
Macrolide大环内酯
Diyne二炔
Amino acid氨基酸
Alkyl halide卤代烷
Zwitterions两性离子
有机化学专业英语
烷基Alkyl [ˈælkil]芳基aryl [ˈæril]甲基methyl [ˈmeθil]亚甲基methylene[ˈmeθili:n]乙基ethyl [ˈeθil,ˈeθəl]丙基propyl [ˈprəupil]异丙基isopropyl [ˌaisəuˈprəupil]丁基butyl [ˈbju:til]戊基pentyl [ˈpentil]己基hexyl [ˈheksil]庚基heptyl [ˈheptil]辛基octyl [ˈɔktəl]壬基nonyl [ˈnɔnil]奎基decyl ['desəl][di:'s i l]叔丁基tert-butyl异丁基iso-butyl环戊基cyclopentyl []环己基cyclohexyl []甲氧基methoxyl ['metɒksɪl]乙氧基ethoxyl [eˈθɔksil]丁氧基butoxyl酰基acyl[ˈæsil]甲酰基formyl [ˈfɔ:mil]乙酰基acetyl [ˈæsitil]乙烯基vinyl [ˈvaɪnəl]或ethenyl丁烯基butenyl [ˈbjutənil]己烯基hexenyl庚烯基heptenyl [ˈheptəˌnil]烯丙基allyl [ˈælil]乙炔基ethinyl [eˈθainil] 或alkynyl硝基nitro [ˈnaitrəu]亚硝基nitroso [naiˈtrəusəu]氨基amino [əˈmi:nəʊ, ˈæməˌnəʊ]二氨基diamino亚氨基imino [ˈiminəu,iˈmi:nəu]重氮基diazo [daiˈæzəu]苯基phenyl [ˈfenəl,ˈfi:nəl,ˈfi:nil]苄基benzyl [ˈbenzil]或phenmethyl [ˌfinˈmeθil]苯乙基phenethyl [fenˈeθəl]乙氧苯基ethoxyphenyl苯胺基anilino [ˈænili:n]羰基carbonyl [ˈkɑ:bənil]羧基carboxyl [kɑ:ˈbɔksil]联苯基biphenyl [baiˈfenl]甲酰基formyl [ˈfɔ:mil]苯酰，苯甲酰benzoyl ['benzəʊɪl]脒基guanyl [il]羟基hydroxyl [haiˈdrɔksil]烷氧基alkoxy [ælˈkɔksi]或alkoxyl group芳基aryl group二芳基diaryl group [daiˈæril]吡啶基pyridyl[ˈpiridil]三苯甲基trityl['traɪtl]二苯甲基benzhydryl [benaɪd'raɪl]氨基甲酰基carbamoyl[kɑ:'bæməɪl]三甲基硅基trimethylsilyl炔丙基propargyl [prəʊ'pɑ:dʒɪl]丙酮基（乙酰甲基）acetonyl['æsɪtənɪl]正n，normal异iso邻位ortho- [ˈɔ:θəu]间位meta- ['mɛtə]对位para- [ˈpɑ:rə]伯Primary ['praimәri]仲Secondary ['sekәndәri]叔Tertiary ['tә:ʃәri] tert-季碳quaternary [kwəˈtə:nəri] carbon一，单mono-二di-，双bis ，bi（化学中只有碳酸氢根才用bi，如bicarbonate [baiˈkɑ:bənit]）三tri-，tris四tetra- 四quadric-五penta- 五quinque-六hexa-七hepta- 七septi八octa-九nona-十deca- ['dɛkə]十一undeca ，hendeca-十二dodeca-十三trideca-十四tetradeca十五pentadeca-十六hexadeca-十七heptadeca-顺式，cis-同，共syn反式trans有机化合物类名Aliphatic compound 脂肪族化合物[]Hydrocarbon 碳氢化合物[ˌhaɪdrəˈk ɑ:bən] Alkane 烷[]Wax 蜡[]Paraffin wax 石蜡arene芳烃[]Alkene 烯[]Alkyne 炔[ˈælkain]Acetylide 炔化物[]Active hydrogen compounds 活泼氢化合物acid [ˈæsid]Carbon acid 碳氢酸Super acid 超酸Diene 双烯[ˈdaii:n]Triene 三烯[ˈtraii:n]Allene 丙二烯[ˈæli:n]Propylene丙烯[] cumulene 累积多烯[]Enyne 烯炔[eˈni:n]Diyne 二炔Alkyl halide 卤代烷[ˈælkil ˈhælaid]Alcohol 醇[]Homoallylic alcohol 高烯丙醇Ether 醚[ˈi:θə]Ester 酯[ˈestə]Ketone 酮Aldehyde 醛[ˈældihaid]Epoxide 环氧化物[eˈpɔksaid]Sulfone 砜[ˈsʌlfəun]Sulfoxide 亚砜Sulfonic acid 磺酸Carboxylic acid 羧酸Cellosolve 溶纤剂Crown ether 冠醚Nitro compound 硝基化合物Amine 胺[] Quaternaryammonium compound 季铵化合物[] []Amine oxide 氧化胺Diazoalkane 重氮烷[daɪ,æzəʊ'ælkeɪn] Mercaptan 硫醇[]Aldehyde hydrate 醛水合物Ketone hydrate 酮水合物Hemiacetal 半缩醛[ˌhemiˈæsi tæl]Acetal 缩醛acetal [化]乙缩醛, 乙缩醛二乙醇[ˈæsitæl] Ketal 缩酮[ˈki:tæl]thiazole噻唑[ˈθaiəˌzəul]Dithiane 二噻烷[daiˈθaiən]Aminal 缩醛胺;动物imine 亚胺[]Aldimine 醛亚胺Oxime 肟[]nitroso compound 亚硝基化合物aldoxime 醛肟，乙醛肟[ælˈdɔksi:m] Hydrazone 腙[ˈhaidrəˌzəun]Azine 嗪[ˈæzi:n]Semicarbazone 缩氯基脲Cyanohydrin 羟腈,氰醇[ˌsaiənəuˈhaidrin] Pinacol 频哪醇Enol 烯醇[ˈi:nɔl]Enol ether 烯醇醚Enol ester 烯醇酯[ˈi:nɔl][ˈestə]Enamine 烯胺[iˈnæmin]Ynamine 炔胺Mannich base 曼尼希碱orthoester 原酸酯Acyl halide 酰卤[ˈæsil]Acyl fluoride 酰氟[]Acyl chloride 酰氯Acyl bromide 酰溴Acyl iodide 酰碘[ˈaiədaid]Carbobenzoxy chloride 苄氧甲酰氯Acyl tosylate 酰基对甲苯磺酸酐Ketene 乙烯酮[ˈki:ti:n]Peracid 过酸Perester 过酸酯Acyl peroxide 酰基过氧化物Nitrile 腈[ˈnaitrail]acetonitrile 乙腈[ˌæsitəuˈnaitril]或methyl cyanide [ˈsaɪəˌnaɪd]Nitrile oxide 氧化腈Isonitrile 异腈，异氰化物Amide 酰胺[ˈæmaid]Imide 二酰亚胺[ˈimaid]N-bromo compound N-溴化物Hydrazide 酰肼[]Azide 叠氮化物[ˈæzaid,ˈeizid]Acyl azide 酰基叠氮[ˈæsil][ˈæzaid,ˈeizid] Amidine 脒[ˈæmiˌdi:n]Keto ester 酮酸酯Acyl cyanide 酰腈[ˈæsil][ˈsaɪəˌnaɪd] Carbon suboxide 二氧化三碳Glycidic acid 环氧丙酸Carbammic acid 氨基甲酸Carbamate 氨基甲酸酯[ˈkɑ:bəmeit] Urea 脲，尿素[]Cyanamide 氨腈[saiˈænəmaid] Carbodiimide 碳二亚胺[,kɑ:bədai'imaid] Allophanate 脲基甲酸酯Thioester 硫代酸酯[ˌθaiəuˈestə]Thiol acid 硫羰酸[ˈθaiəu]Lactone 酯[ˈlæktəun]Lactol 半缩醛[ˈlæktəl]Macrolide 大环酯[ˈmækrəlaid]Amino acid 氨基酸Zwitterion两性离子[ˈtsvitəraiən]Inner salt 盐Betaine 甜菜碱[ˈbi:təi:n]Lactam 酰胺[ˈlæktæm]Hydantoin 或glycolylurea 乙酰脲[haiˈdæntəwin]Hydration水合，水合作用[haɪ'dreʃən] Peptide 肽[ˈpepˌtaɪd]Glycol 乙二醇[]Aldol 羟醛[ˈældəul]Acyloin 偶姻，酮醇[əˈsiləuin]acyloin condensation 酮醇缩合Carbohydrate 碳水化合物Aldose 醛糖[ˈældəus]Ketose 酮糖[ˈki:təus]Furanose 呋喃糖[ˈfjuərəˌnəus] Pyranose 吡喃糖[ˈpaiərənəus] Glycoside 糖苷[ˈɡlaikəˌsaid]Glucoside 葡[萄]糖苷Aglycon 苷元[əˈɡlaikɔn]Saccharide 糖类[ˈsækəraid] Oligosaccharide 寡糖[ˌɔliɡəuˈsækəraid] Polysaccharide 多糖[pɔliˈsækəraid] Alditol 糖醇[ˈælditɔl]Osazone 脎[ˈəusəˌzəun]Alicyclic compound 脂环化合物[æliˈsiklik] Cycloalkane 环烷Cycloalkene 环烯Spirane 螺烷[ˈspaiərein]Cage compound 笼型化合物Propellane 螺桨烷Rotazane 轮烷Catenane 索烃[ˈkætnein]Fused ring 稠环[fju:zd riŋ]化学专业英语词汇常用前后缀-acetal 醛缩醇acetal- 乙酰acid 酸-al 醛alcohol 醇-aldehyde 醛alkali- 碱allyl 丙烯基 'alkoxy- 烷氧基Methoxy甲氧基的-amide 酰胺 []amino- 氨基的[əˈmi:nəʊ, ˈæməˌnəʊ]-amidine 脒[ˈæmiˌdi:n]-amine 胺-ane 烷anhydride 酐[ænˈhaidraid]anilino- 苯胺基[ˈænili:n]aquo- 含水aqueous水的，水成的[ˈeikwiəs] -ase 酶-ate 含氧酸的盐、酯-atriyne 三炔azo- 偶氮[ˈæzəu]azoxy-氧化偶氮-N=N(O)-hydrazo-氢化偶氮-NH-NH-benzene 苯[ˈbenˌzi:n, benˈzi:n]bi- 在盐类前表示酸式盐bis- 双-borane 硼烷[ˈbəurein]bromo- 溴butyl 丁基 .-carbinol 甲醇carbonyl 羰基-caboxylic acid 羧酸centi- 10-2 chloro- 氯代cis- 顺式condensed 缩合的、冷凝的cyclo- 环deca- 十deci 10-1di二-dine 啶dodeca- 十二-ene 烯epi- 表epoxy- 环氧 []-ester 酯-ether 醚ethoxy- 乙氧基[]ethyl 乙基fluoro-或fluor- 氟代-form 仿-glycol 二醇hemi- 半hendeca- 十一hepta- 七heptadeca- 十七hexa- 六hexadeca- 十六-hydrin 醇hydro- 氢或水hydroxyl 羟基hypo- 低级的，次-ic 酸的，高价金属-ide 无氧酸的盐，酰替胺，酐-il 偶酰-imine 亚胺 /iodine 碘[]iodo- 碘代iso- 异，等，同-ite 亚酸盐keto- 酮ketone 酮-lactone 酯mega- 106meta- 间，偏methoxy- 甲氧基methyl 甲基micro- 10-6milli- 10-3mono- ( mon-) 一，单nano- 10-9nitro- 硝基nitroso- 亚硝基nona- 九nonadeca- 十九octa- 八octadeca- 十八-oic 酸的-ol 醇9 a$ f! Q, H: [5 n& G-one 酮ortho- 邻，正，原-ous 亚酸的，低价金属oxa- 氧杂-oxide 氧化合物-oxime 肟 []oxo- 酮 []oxy- 氧化 []-oyl 酰para- 对位，仲penta- 五pentadeca- 十五per- 高，过petro- 石油phenol 苯酚[ˈfi:nəl]phenyl 苯基 [] pico- 10-12poly- 聚，多quadri- 四quinque- 五semi- 半septi- 七sesqui 一个半sulfa- 磺胺 []sym- 对称syn- 顺式，同，共ter- 三 -tetra- 四tetradeca- 十四tetrakis- 四个thio- 硫代[]trans- 反式，超，跨tri- 三trans- 反式，超，跨tri- 三trideca- 十三tris- 三个undeca- 十一 .Alkylation 烷基化C- alkylation C-烷基化O- alkylation O-烷基化N-alkylation N-烷基化Silylation 硅烷[基]化Exhaustive methylation 彻底甲基化Seco alkylation 断裂烷基化Demethylation 脱甲基化Ethylation 乙基化Arylation 芳基化Acylation 酰化Formylation 甲酰化Carbalkoxylation 烷氧羰基化Carboamidation 氨羰基化Carboxylation 羧基化Amination 氨基化Bisamination 双氨基化Cine substitution 移位取代Transamination 氨基交换Hydroxylation 羟基化acyloxyation 酰氧基化Decarboxylative nitration 脱羧卤化Allylic halogenation 烯丙型卤化Dehalogenation 脱卤Nitration 硝化Decarboxylative nitration 脱羧硝化Nitrosation 亚硝化Sulfonation 磺化Chlorosulfonation 氯磺酰化Desulfonation 脱磺酸基Sulfenylation 亚磺酰化Sulfonylation 磺酰化Chlorosulfenation 氯亚磺酰化Chlorocarbonylation 氯羰基化Diazotization 重氮化[daiˌæzətaiˈzeiʃən] Diazo transfer 重氮基转移Coupling reaction 偶联反应uni- 单，一unsym- 不对称的，偏位-yl 基-ylene 撑(二价基，价在不同原子上)-yne 炔Diazonium coupling 重氮偶联[ˌdaiəˈzəuniəm]Cross-coupling reaction 交叉偶联反应1,4-addition 1，4-加成C-C Pi-bond C-C π键Conjugate addition 共轭加成[ˈkɔndʒəˌgeɪt] Dimerization 二聚Trimefization 三聚Additive dimerization 加成二聚Sulfurize 使硫化[]sulfurization 硫化Selenylation 硒化Hydroboration 硼氢化[ˈhaidrəuˌbɔ:ˈreiʃən] Oxyamination 羟氨基化Insertion 插入carbonylation 羧基化Hydroformylation 加氢甲酰基化Hydroacylation 加氢酰化Oxo process 羰基合成Decarbonylation 脱羰[di:ˌkɑ:bənəˈleiʃən] Hydrocarboxylation 氢羧基化Homologization 同系化Cyanoethylation 氰乙基化Decyanoethylation 脱氰乙基Ring closure 环合，闭环Diene synthesis 双烯合成Dienophile 亲双烯体Endo addition 型加成Exo addition 外型加成Diels-Alder reaction 第尔斯-尔德反应Retro Diels-Alder reaction 逆第尔斯-阿尔德反应Ene synthesis 单烯合成Anionic cycloaddition 负离子环加成Dipolar addition 偶极加成Dehydrohalogenation 脱卤化氢Deamination 脱氨基Pyrolytic elimination 热解消除Elimination-addition 消除-加成Decarboxylation 脱羧Decarboxamidation 脱酰胺Decyanation 脱氰基Alkylolysis,alkyl cleavage 烷基裂解Acylolysis,acyl cleavage 酰基裂解Flash pyrolysis 闪热裂Fragmentation 碎裂Chiletropic reaction 螯键反应Chelation 螯环化Esterification 酯化Transesterification 酯交换Saponification 皂化Alcoholysis 醇解Ethanolysis 乙醇解Cyanomethylation 氰甲基化Aminomethylation 氨甲基化Hydroxymethylation 羟甲基化Hydroxyalkylation 羟烷基化Cholromethylation 氯甲基化Haloalkylation 卤烷基化Transacetalation 缩醛交换Enolization 烯醇化Haloform reaction 卤仿反应Condensation 缩合Aldol condensation 羟醛缩合Cross aldol condensation 交叉羟醛缩合Retrograde aldol condensation 逆羟醛缩合Acyloin condensation 偶姻缩合Cyclization 环化Annulation,annelation 增环反应Spiroannulation 螺增环Autoxidation 自氧化Allylic hydroperoxylation 烯丙型氢过氧化Epoxidation 环氧化Oxonolysis 臭氧解Electrochemical oxidation 电化学氧化Oxidative decarboxylation 氧化脱羧Aromatization 芳构化Catalytic hydrogenation 催化氢化Heterogeneous hydrogenation 多相氢化Homogeneous hydrogenation 均相氢化Catalytic dehydrogenation 催化脱氢Transfer hydrogenation 转移氢化Hydrogenolysis 氢解Dissolving metal reduction 溶解金属还原Single electron transfer 单电子转移Bimolecular reduction 双分子还原Electrochemical reduction 电化学还原Reductive alkylation 还原烷基化Reductive acylation 还原酰化Reductive dimerization 还原二聚Deoxygenation 脱氧Desulfurization 脱硫Deselenization 脱硒Mitallation 金属化Lithiation 锂化Hydrometallation 氢金属化Mercuration 汞化Oxymercuration 羟汞化Aminomercuration 氨汞化Abstraction 夺取[反应]Internal abstraction 夺取[反应] Rearrangement 重排Prototropic rearrangement 质了转移重排Double bond migration 双键移位Allylic migration 烯丙型重排Allylic migration 烯丙型迁移Ring contraction 环缩小[反应]Ring expansion,ring enlargement 扩环[反应]-ketol rearrangement -酮醇重排Pinacol rearrangement 频哪醇重排Retropinacol rearrangement 逆频哪醇重排Semipinacol rearrangement 半频哪醇重排Benzilic rearrangement 二苯乙醇酸重排Acyl rearrangement 酰基重排Migratory aptitude 迁移倾向Transannular insertion 跨环插入Transannular rearrangement 跨环重排Migration 迁移Prototropy 质子转移Cationotropic rearrangement 正离子转移重排Anionotropy 负离子转移Anionotropic rearrangement 负离子转移重Sigmatropic rearrangement -迁移重排Homosigmatropic rearrangement 同迁移重排Electrophilic rearrangement 亲电重排Photosensitization 光敏化Forbidden transition 禁阻跃迁photooxidation 光氧化Photoisomerization 光异构化Photochemical rearrangement 光化学重排Angular methyl group 角甲基Alkylidene group 亚烷基[ælˈkiləˌdi:n] Methylene 亚甲基[ˈmeθili:n]Allyl group 烯丙基Allylic 烯丙型[的] [ˈæləˌlik]Phenyl group 苯基[ˈfenəl,ˈfi:nəl,ˈfi:nil]Aryl group 芳基Benzyl group 苄基Benzylic 苄型[的]Activating group 活化基团Chromophore 生色团[ˈkrəuməfɔ:] Auxochrome 助色团[ˈɔ:ksəkrəum] Magnetically anisotropic group 磁各向异性基团[əˌnaisəuˈtrɔpik]Smally ring 小环Common ring 普通环Medium ring 中环[ˈmi:djəm]Large ring 大环Bridged-ring system 桥环体系Spiro compound 螺环化合物Helical molecule 螺旋型分子Octahedral compound 八面体化合物Conjugation 共轭[]Conjugated-system 共轭体系Acyl cation 酰[基]正离子Benzylic cation 苄[基]正离子[ˈkætaiən] Arenium ion 芳[基]正离子或aryl cation Ketyl radical 羰自由基Radical ion 自由基离子[ˈaiən]Radical cation 自由基正离子Radical anion 自由基负离子[ˈænai ən] Isomerism 异构[现象]Acid form 酸式Fluxional structure 循变结构Stereochemistry 立体化学Optical activity 光学活性，旋光性Dextro isomer 右旋异构体[]Laevo isomer 左旋异构体[]Tetrahedral configuration 四面体构型Stereoisomerism 立体异构[现象] Asymmetric atom 不对称原子Asymmetric carbon 不对称碳Pseudoasymmetric carbon 假不对称碳Phantom atom 虚拟原子[]Homotopic 等位[的]Heterotopic 异位[的]Enantiotopic 对映[异构体]的Diastereotopic 非对映异构体[的] [ˌdaiəstiəri əˈtɔpik]Configuration 构型[kənˌfiɡjuˈreiʃən] Absolute configuration 绝对构型Chirality 手性Chiral 手性[的] [英] [ˈtʃirəl][美] [ˈkaɪrəl] Chiral center 手性中心Chiral molecule 手性分子Achiral 非手性[的] [ei'kairəl]Fischer projection 费歇尔投影式Neoman projection 纽曼投影式D-L system of nomenclature D-L命名体系R-S syytem of nomenclature R-S命名体系Cahn-Ingold-Prelon sequence 顺序规则Symmetry factor 对称因素Plane of symmetry 对称面Mirror symmetry 镜面对称Enantiomer 对映[异构]体[]Diastereomer 非对映[异构]体[]Epimer 差向异构体[]Anomer 端基[差向]异构体Erythro configuration 赤型构型Erythro isomer 赤型异构体Threo configuration 苏型构型Threo isomer 苏型异构体Trigonal carbon 三角型碳Cis-trans isomerism 顺反异构E isomer E 异构体Z isomer Z异构体Endo isomer 型异构体Exo isomer 外型异构体Prochirality 前手性Pro-R group 前R基团Pro-S proup 前S基团Re face Re面Si face Si面Racemic mixture 外消旋混合物[]Racemic compound 外消旋化合物Racemic solid solution 外消旋固体溶液Meso compound 消旋化合物Quasi recemate 准外消旋体[ˈkwɑ:zi(:),ˈkweis ai]Conformation 构象Conformational 构象的Torsion angle 扭转角Rotamer 旋转异构体Anti conformation 反式构象Bisecting conformation 等分构象Anti periplanar conformation 反叠构象Synperiplanar conformation 顺叠构象Synclinal conformation 反错构象Synclinal conformation 顺错构象Eclipsed conformation 重叠构象Gauche conformation, skew con-formation 邻位交叉构象Staggered conformation 对位交叉构象Steric effect 空间效应[ˈstiərik,ˈsterik]Steric hindrance 位阻Atropismer 阻转异构体Puckered ring 折叠环Conformational inversion 构象反转Chair conformation 椅型构象Boat conformation 船型构象Twist conformation 扭型构象Skew boat conformation 扭船型构象Half-chair conformation 半椅型构象Pseudorotation 假旋转Envelope conformation 信封[型]构象Axial bond 直[立]键[ˈæksi:əl]Equatorial bond 平[伏]键[ˌi:kwəˈtɔ:ri:əl, -ˈtəʊr-, ˌekwə-]Cisoid conformation 顺向构象Transoid conformation 反向构象Retention of configuration 构型保持Regioselectivity 区域选择性Regiospecificity 区域专一性Stereocelectivity 立体选择性Stereospecificty 立体专一性Conformer 构象异构体Conformational effect 构象效应Cram’s rube 克拉姆规则Prelog’rule普雷洛格规则Stereochemical orientation 立体[化学]取向Conformational transmission 构象传递Homolog 同系物Ipso position 本位Ortho position 邻位Meta position 间位Para position 对位Amphi position 远位Peri position 近位Trigonal hybridization 三角杂化Molecular orbiral method 分子轨道法Valence bond method 价键法Delocalezed bond 离域键Cross conjugation 交叉共轭Vinylog 插烯物Mesomeric effect 中介效应Resonance 共振[ˈrezənəns] Resonance effect 共振效应Hyperconjugation 超共轭Isovalent hyperconjugation 等价超共轭No-bond resonance 无键共振Aromaticity 芳香性Aromatic sexter 芳香六隅Huckel’rule休克尔规则Paramagnetic ring current 顺磁环电流Diamagnetic ring cruuent 抗磁环电流Homoaromaticity 同芳香性Antiaromaticity 反芳香性Alternant hydrocarbon 交替烃Non-alternant hydrocarbon 非交替烷Pericyclic reaction 周环反应Electrocyclic rearrangement 电环[化]重排Conrotatory 顺旋Disroatatory 对旋Cycloaddition 环加成Symmetry forbidden-reaction 对称禁阻反应Synfacial reaction 同面反应Antarafacial reaction 异面反应Mobius system 默比乌斯体系Leois structure 路易斯结构Coordinate-covalent bond 配位共价键Banana bond 香蕉键Pauling electronegativity scale 鲍林电负性标度Polarizability 可极化性Inductive effect 诱导效应Field effect 场效应Electrical effect 电场效应tautomerism 互变异构Tautomerization 互变异构化Keto-enol tautomerism 酮-烯醇互变异构Phenol-keto tautomerism 酚-酮互变异构Imine-enamine atutomerism 亚胺-烯胺互变异构Ring-chain tautomerism 环-链互变异构Valence tautomerism 价互变异构Ambident 两可[的]Solvent effect 溶剂效应Acid-base catalyxed reaction 酸性溶剂Basic solvent 碱性溶剂Dielectric constant 介电常数Solvated electron 溶剂化电子Acid-base catalyzed reaction 酸碱催化反应Conjugate base 共轭酸Conjugate base 共轭碱Therm odynamic acidity 热力学酸度Kinetic acidity 动力学酸度Electron donof-acceptor complex,EDAcomplex 电子给[体]受体络合物Host 主体Guest 客体Primary isotope effect 一级同位素效应Secondary isotope effect 二级同位数效应Inverse isotope effect 逆同位素效应Kinetic control 动力学控制Thermodynamic control 热力学控制Substrate 底物Intermediate 中间体Reactive intermediate 活泼中间体Microscopic reversibility 微观可逆性Hammond postulate 哈蒙德假说Linear free energy 线性自由能Non-bonded interaction 非键相互作用Torsional effect 扭转效应Pitzer strain 皮策力Restricted rotation 阻碍旋转Eclipsing effect 重叠效应Eclipsing strain 重叠力Small-angle strain 小角力Large angle strain 大角力Transannular interaction 跨环相互作用Transannular strain 跨环力I strain 力F strain 前力B strain 后力Anomeric effect 端基异构效应Walden inversion 瓦尔登反转Racemization 外消旋化Isoinversion 等反转Isoracemization 等消旋Homochiral 纯手性[的]Mechanism 机理Unimolecular nucleophilic 单分子亲核取代Bimolecular nucleophilic sub-stitution 双分子亲核取代Bimolecular nucleophilic substi-tution(with allyl ic rearrange-ment) 双分子亲核取代（含烯丙型重排）Internal nucleophilic substiru-tion 分子亲核取代Aromatic nucleophilic substitu-tion 芳香亲核取代Unimolecular electrophilic sub-stitution 单分子亲电取代Bimolecular electrophilic substi-tution 双分子亲电取代Nucleophile-assisted unimolecu-lar electrophilic substitution 亲核体协助单分子亲电取代Unimolecular elimination 单分子消除Bimolecular elimination 双分子消除Unimolecular elimination through the conjugate base 单分子共轭碱消除Bimolecular elimination through the conjugate b ase 双分子共轭碱消除Bimolecular elimination with for-mation of a car bonyl group 双分子羰基形成消除Unimolecular acid-catalyzed acyl-oxygen cleava ge 单分子酸催化酰氧断裂Bimolecular base-catalyzed acyl-oxygen cleavag e 双分子碱催化酰氧断裂Unimolecular acid-catalyzed alkyl-oxygen cleav age 单分子酸催化烷氧断裂Bimllecular base-catalyzed alkyl-oxygen cleavag e 双分子碱催化烷氧断裂π-allyl complex mechanism π烯丙型络合机理Borderline mechanism 边理机理Homolysis 均裂Heterolysis 异裂Heterolytic michanism 异裂机理Counrer[gegen]ion 反荷离子Ion pair 离子对Carbocation 碳正离子[ˌkɑ:bəˈkeiʃən] Nonclassical carbocation 非经典碳正离子Carbanion 碳负离子[ˈkɑ:bənaiən]Masked carbanion 掩蔽碳负离子Carbenoid 卡宾体Carbene 卡宾[]Nitrene 氮宾[a]Carbine 碳炔[]Electrophilic addition 亲电加成Electrophile 亲电体Diaxial addition 双直键加成Markovnikov’s rube 马尔科夫尼科规则Anti-Markovnikov addition 反马氏加成Michael addition 迈克尔加成Substitution 取代Electrophilic substitution 亲电取代Addition-elimination mechanism 加成消除机理[ˈmekənizəm]Electrophilic aromatic substitu-tion 亲电芳香取代Electron transfer 电子转移Electron-donating group 给电子基团Electron-Withdrawing group 吸电子基团Deactivating group 钝化基团Orinentation 取向Ortho-para directing group 邻对位定位基Meta directing group 间位定位基Ortho effect 邻位效应Partial rate factor 分速度系数Nucleophilic reaction 亲核反应Internal return 返Nucleophilicity 亲核体Nucleophilicity 亲核性α-effect α-效应Backside attack 背面进攻Inversion 反转Umbrella effect 伞效应Push-pull effect 推拉效应Leaving group 离去基团Electrofuge 离电体Nucleofuge 离核体Phase-transfer catalysis 相转移催化Neighboring group participation 邻基基参与Neighboring proup assistance,anchimeric assista nce 邻助作用Neighboring group effect 邻基效应Apofacial reaction 反面反应Briddgehead displacement 桥头取代Aryl action 芳正离子Benzyne 苯炔Zaitsev rule 札依采夫规则Anti-Zaitsev orientation 反札依采夫定向Hofmann’s rule 霍夫曼规则Bredt rule 布雷特规则Initiation 引发Anionic cleavage 负离子裂解Partial bond fixation 键[的]部分固定化exothermic发热的，放出热量的[ˌeksəuˈθə:mik]各种反应类型Halogenations reaction卤化反应Hydrogenation reaction氢化反应Alkylation reaction烷基化（烃化）反应Hydrocarbylation 烃基化反应Oxidation and reduction reaction氧化还原反Reductive amination还原胺化反应Cross-coupling reaction交叉耦合反应Cycloaddition reaction环加成反应Rearrangement reaction重排反应Acylation reaction酰化反应Acetylization reaction乙酰化反应Amide reaction酰胺反应Sulfonylation磺酰化反应Nitration reaction硝化反应Esterification酯化反应Anhydride reaction酸酐反应Oximation reaction肟化反应Coupled（或coupling）reaction偶联反应1,3-dipolar cycloaddition 1,3-偶极环加成Pericyclic reaction周环反应Hydrolysis reaction 水解反应Ester hydrolysis 酯水解反应Hydrolytic-polymeric reaction水解聚合反应Dehydrogenation reaction脱氢反应Dehydrohalogenation reaction 脱卤化氢反应Dehydration reaction脱水反应Decarboxylation reaction脱羧反应Addition reaction加成反应Substitution reaction取代反应Cracking reaction 裂化反应Elimination reaction消除反应And metal response reaction与活泼金属反应Phase transfer catalytic reaction相转移催化反应Acid-base catalyzed reaction酸碱催化反应Polymerization reaction聚合反应Polycondensation reaction缩聚反应Condensation reaction 缩合反应Silver mirror reaction银镜反应Nucleophilic reaction亲核反应Electrophilic reaction亲电反应Nucleophilic cycloaddition reaction亲核环加成反应Nucleophilic substitution亲核取代反应Electrophilic substitution亲电取代反应Unimolecular electrophilic substitution单分子亲电取代反应Bimolecular electrophilic substitution双分子亲电取代反应Unimolecular elimination reaction单分子消除反应Bimolecular elimination reaction双分子消除反应Unimolecular nucleophilic substitution单分子亲核取代Bimolecular nucleophilic substitution双分子亲核取代反应Internal nucleophilic substitution分子亲核取代Aromatic nucleophilic substitution reaction芳香亲核取代反应活化剂的中英文名称Bis(2-ethylhexyl) sebacate （癸二酸二仲辛酯；癸二酸二2-乙基己酯）Zinc stearate （硬脂酸锌）Suberic acid （辛二酸）Adipic acid, （己二酸）Hexanedioic acid, （己二酸）Sebacic acid, dibutyl ester （癸二酸二丁酯）Abietic acid （松香酸）Lactic acid （乳酸）Poly(ethylene glycol) （聚乙二醇）Glycerol stearate （硬脂酸甘油酯）Imidazoline （咪唑啉，间二氮杂环戊烯）β-Pinene （β-蒎烯，β-松油二环烯）Adipic acid （脂肪酸）Butyl acetate （乙酸丁酯）Ethylene glycol butyl ether （乙二醇丁醚）Sebacic acid, （癸二酸）Decanedioic acid, （癸二酸）Ethylene glycol ethyl ether （乙二醇乙醚）2-Butenedioic acid (E)-, （2-丁烯二酸）Succinic acid, （琥珀酸，丁二酸）Ethylene glycol methyl ether （乙二醇甲醚）Acetyl acetate （乙酸乙酰脂）1H-Benzotriazole （1-H-笨并三唑）α-Pinene （α-蒎烯,α-松香二环烯）Salicylic acid (水酸)Iso-Propanol (异丙醇)Benzoic acid (苯甲酸)Ethanol (乙醇)Lysine (赖氨酸)Glutamic acid (谷氨酸,2-氨基戊二酸) Glyceroyl, （甘油酰）N,N,N',N'-Tetrakis-(2-hydroxypropyl)-ethylene-diamine（N，N，N，N-四（2-羟基丙基）乙烯二氨）Isoleucine, （异亮氨酸）Decamethylenedicarboxylic acid, disalicyloylhy drazide （Tris(2,3-dibromopropyl)isocyanurate（3（2，3-2溴丙基）异氰尿酸盐）3-(N-Salicyloyl)amino-1,2,4-triazole （3-（N-水酰）氨-1，2，4-三唑）Isocyanuric acid （异氰尿酸）Salicylamide （水酰胺）Polyethylene glycol （聚乙二醇）Diethylene glycol diethyl ether （二甘醇二乙醚，（一缩）二乙二醇二乙醚）Butyl carbitol （丁基卡必醇）Ethyl carbitol （乙基卡必醇）Methyl carbitol （甲基卡必醇）Ethylene glycol monobutyl ether （乙二醇单丁醚）Glutaric acid （戊二酸，谷酸）Succinic acid （琥珀酸，丁二酸）Citric acid （柠檬酸）Salicylic acid （水酸）Lactic acid （2-羟基丙酸，乳酸）Glycerin monostearate （甘油一硬脂酸）Pentaerythritol （季戊四醇）tetrakis[β-(3,5-di-tert-butyl-4-hydroxy-phenyl)pr opionate] 四[β-（3，5-二叔丁基-4-羟基-苯基）丙酸酯Dioctyl sebacate （癸二酸二辛酯）N-Methyl pyrrolidone, （N-甲基吡咯烷酮）Diethylene glycol ethyl ether （二甘醇乙醚）Propylene glycol （丙二醇）Octanedioic acid （辛二酸）Oleamide （油酸酰胺）[olamine 乙醇胺]2-Mercapto benzothiazole （2-巯基-苯并噻唑）Nonanedioic acid, （壬二酸）cis-9-Octadecenoic acid, （顺式-9-十八炭烯酸，油酸）Sebacic acid, uses （癸二酸）12-Hydroxy stearic acid （十二羟基硬脂酸）Phthalic acid （苯二甲酸）1,1,3-Tris(2-methyl-4-hydroxy-5-tert-butylpheny l)butane（1，1，3-三（2-甲基-4-羟基-5-叔丁基苯基）丁烷）1,3,5-Trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hyd roxybenzyl)benzene（1，3，5-三甲基-2，4，6-三（3，5-二叔丁基-4-羟基苯基）苯）1-Methyl-2-pyrrolidone, （1-甲基-2-吡咯烷酮）Carbonic acid, （碳酸）Phthalic acid, （苯二甲酸）Malic acid （苹果酸,羟基丁二酸）2,3-Dibromo-2-butene-1,4-diol （2，3-二溴-2-丙烯-1，4-二醇）Cetylpyridinium bromide （溴代十六烷基吡啶）Pentanedioic acid （戊二酸） pentanediol (戊二醇)pentanoic acid ( 戊酸) pentanol (戊醇)Butanedioic acid, （丁二酸）1,2-Dibromoethylbenzene （1，2-二溴乙基苯）Salicylic acid, （水酸）Stearic acid （硬脂酸）Pentanedioic acid （戊二酸）Maleic acid, （马来酸，失水苹果酸）Phthalic acid, （苯二甲酸）Tartaric acid, （酒石酸）Acetic acid, （乙酸）Polyoxyethylene octylphenol ether （聚氧乙烯辛基酚醚，聚氧化亚乙基辛基分醚）Ethanedioic acid, （乙二酸）Polyethylene glycol （聚乙二醇）Diethylene glycol butyl ether （二甘醇丁醚）Diethylene glycol monoethyl ether （二甘醇单乙醚）Ethylene glycol monobutyl ether （乙二醇单丁醚）Pentaerythritol, （季戊四醇）Diglycol, （二甘醇，一缩二乙二醇）Hexylene glycol （己二醇）Ethylene glycol, （乙二醇）Glycerol, （甘油,丙三醇）Cyclobutanediamine （环丁烷二胺）Dibromobutenediol （二溴丁二醇）Cyclohexanediamine （环己烷二胺）Succinamide （琥珀酰胺，丁二酸胺）Ethylenediamine, （乙二胺）Triethanolamine, （三乙醇胺）5-Aminoisophthalic acid （5-氨基间苯二甲酸）p-tert-Butylbenzoic acid （对叔丁基苯甲酸）Propionic acid, （丙酸）Benzoic acid, （安息香酸, 苯(甲)酸）Salicylamide （水酰胺）Aniline, （苯胺）Palmitic acid, （棕榈酸, 十六酸, 软脂酸）Glutamic acid, （谷氨酸） Glutaric acid (谷酸，戊二酸)Glycine, （甘氨酸，氨基乙酸）Malic acid （苹果酸,羟基丁二酸）Adipic acid, （己二酸）Diethanolamine （二乙醇胺）Triethylamine, （三乙胺）Malic acid （苹果酸）Oxalic acid, （草酸）Oleic acid, （油酸）Glutaric acid (谷氨酸)Sorbic acid （山梨酸） sorbic alcohol (山梨醇)=sorbitReactant 反应物nProduct 产物nCatalyst 催化剂catalytic agent，catalyzer Degree Celsius摄氏度Sodium Borohydride硼氢化钠Lithium Aluminum Hydride (LAH)氢化铝锂Lithiumtrit-ButoxyaluminohydrideLiAlH(O t-C4H9)3叔丁氧基氢化铝锂Diisobutylaluminum Hydride AlH[CH2CH(CH3)2]2二异丙基氢化铝Diborane B2H6硼烷Reactive Metals 活泼金属如 Na, or Li, or K ，Mg or Al or Zn or FePotassium carbonate碳酸钾Sodium carbonate 碳酸钠Sodium bicarbonate 碳酸氢钠[]Sodium chloride氯化钠Sodium acetate 乙酸钠Sodium cyanide[ˈsaɪəˌnaɪd]氰化钠Sodium methoxide或Sodium methylate甲醇钠，甲氧基钠Sodium ethoxide[ˈsəʊdi:əm i:ˈθɔksaid]或Sodium ethylate[ˈsəʊdi:əm ˈeθileit]乙醇钠Sodium sulfate 硫酸钠Magnesium sulfate [mægˈni:zi:əm ]硫酸镁Acetic acid乙酸Formic acid甲酸Ammonium format甲酸铵Formamide[fɔ:ˈmæmid]或formyl amide 甲酰胺formaldehyde甲醛[f ɔ:ˈmældəˌha ɪd]Methyl iodide碘甲烷Potassium iodide碘化钾[]Potassium chloride氯化钾Potassium cyanide[ˈsaɪəˌnaɪd]氰化钾Dimethyl sulfate硫酸二甲酯Palladium –carbon 钯碳Pd/C [pəˈleidiəm] Palladium chloride氯化钯Palladium diacetate醋酸钯Chloroacetone 氯丙酮Tetrabutyl ammonium bromide四丁基溴化铵Tetrabutyl ammonium fluoride四丁基氟化铵容器类：量杯measuring cup烧杯beaker 不锈钢杯stainless-steel beaker量筒measuring flask/measuring cylinder 量筒graduated flask/measuring cylinder坩埚crucible 坩埚钳crucible clamp 坩埚crucible pot, melting pot试管test tube 试管架test tube holder 漏斗funnel 分液漏斗separatory funnel烧瓶flask 锥形瓶conical flask塞子stopper洗瓶plastic wash bottle滴定管burette玻璃活塞stopcock冷凝器condenser试剂瓶reagent bottles玻棒glass rod 搅拌棒stirring rod蒸馏烧瓶distilling flask碘量瓶iodine flask表面皿watch glass蒸发皿evaporating dish容量瓶volumetric flask/measuring flask移液管(one-mark) pipette刻度移液管graduated pipettes称量瓶weighing bottle吸液管pipette滤管filter天平balance/scale分析天平analytical balance台秤platform balance游码crossbeams and sliding weights酒精灯alcohol burner酒精喷灯blast alcohol burner搅拌装置stirring device洗耳球rubber suction bulb研磨钵mortar 研磨棒pestle 玛瑙研钵agate mortar瓷器porcelain白细口瓶flint glass solution bottle with stopper 滴瓶dropping bottle 小滴管dropper蒸馏装置distilling apparatus蒸发器evaporator试验用器材：升降台lab jack铁架台iron support万能夹extension clamp蝴蝶夹double-buret clamp双顶丝clamp regular holder止水夹flatjaw pinchcock圆形漏斗架cast-iron ring移液管架pipet rack试管架tube rack沸石boiling stone橡胶管rubber tubing药匙lab spoon镊子forceps坩埚钳crucible tong剪刀scissor打孔器stopper borer石棉网asbestos-free wire gauze电炉丝wire coil for heater脱脂棉absorbent cottonphph试纸universal ph indicator paper滤纸filter paper称量纸weighing paper擦镜纸wiper for lens秒表stopwatch量杯glass graduates with scale白滴定管（酸）flint glass burette with glass stopcock棕色滴定管（酸）brown glass burette with glass stopcock白滴定管（碱）flint glass burette for alkali棕色滴定管（碱）brown glass burette for alkali 比重瓶specific gravity bottle水银温度计mercury-filled thermometerph计ph meter折光仪refractometer真空泵vacuum pump冷、热浴bath离心机centrifuge口罩respirator防毒面具respirator、gasmask磁力搅拌器magnetic stirrer电动搅拌器power basic stirrer烘箱oven闪点仪flash point tester马弗炉furnace电炉heater微波炉电热套heating mantleBunsen burner 本生灯product 化学反应产物apparatus 设备PH indicator PH值指示剂,氢离子(浓度的)负指数指示剂matrass 卵形瓶litmus 石蕊litmus paper 石蕊试纸burette 滴定管retort 曲颈甑still 蒸馏釜cupel 烤钵化学反应：analysis 分解fractionation 分馏endothermic reaction 吸热反应exothermic reaction 放热反应precipitation 沉淀to precipitate 沉淀to distil, to distill 蒸馏distillation 蒸馏to calcine 煅烧to oxidize 氧化alkalinization 碱化to oxygenate, to oxidize 脱氧,氧化to neutralize 中和to hydrogenate 氢化to hydrate 水合,水化to dehydrate 脱水fermentation 发酵solution 溶解combustion 燃烧fusion, melting 熔解alkalinity 碱性isomerism, isomery 同分异物现象hydrolysis 水解electrolysis 电解electrode 电极anode 阳极,正极cathode 阴极,负极catalyst 催化剂catalysis 催化作用oxidization, oxidation 氧化reducer 还原剂dissolution 分解。
有机化学英语单词前后缀表
有机化学英语单词前后缀表有机物英语单词后缀表 -acetal 缩醇acid 酸-al 醛alcohol 醇-aldehyde 醛-aldechydic acid 醛酸 -amarime（或-marine）苦苷 -amic acid 酰胺酸-amide 酰胺-amide acid （=amic acid）酰胺酸-amidine 脒-amidoxime 脒肟-amidrazone 脒腙-amine 胺-ane 烷anhydride -ic anhydrideanil 缩苯胺-anilic acid 酰苯胺酸 -anilide 酰苯胺-aniside 酰茴香醛-arsine 胂-arsinic acid [美国名指]次胂酸-arsinous acid [美国名和英国名均指]卑胂酸-arsinoxide 胂氧-arsonic acid [美国名和英国名均指]胂酸-arsonous acid [美国名指]亚胂酸-ase 酶-azide 叠氮-azine 连氮-betaine 内胺盐-biarsine 联胂bi...oyl di..oyl-bistibine 联锑bi...yl 联...-borane 硼烷-borinic acid 二取代硼酸 -boronic acid 硼酸-bromohydrin 溴醇-cacodyl 卡可基-cain(e) 卡因-carbamic acid 氨甲酸 -carbazinic acid 肼甲酸 -carbinol 甲醇-carbodithioic acid 二硫代羧酸 carbohydrazide N-酰基卡巴肼 -carbohydraoxamamide 甲肟胺 -carbohydroxamic acid 羧肟胺 -carbonamidine 甲脒-carbonitrile 甲腈-barbonyl 羰基-carbothioic acid 羧硫代酸 -carbothiolic acid 甲硫羟酸 -carbothionic acid 甲硫羰酸 -carboxaldehyde 甲醛-carboxamide 甲酰胺-carboxamidine 甲脒-carboxamidoxime 甲胺肟 -carboximidic acid 甲亚胺酸 -carboxylic acid 羧酸-carbylamine 胩-cene 并...苯-chloroarine 氯胂-chlorohydrin 氯醇-chrysine 柯因-cyanamide 氨腈-cyanhydrin 氰醇-cyanoarsin 氰胂-diarsine 联胂-diazonium 重氮-dicarboximide 二甲酰亚胺 -dichloroarsine 二氯胂 -diimide 联亚胺-din(e) 定；啶di...(o)yl 联…酰-disulfide 二硫-dithiocarbamic acid 氨基二硫代羧酸-di...ylene 联二…亚基 -drin(e) 君[俗名词尾]-e- 裂[嵌在末一音节之前，指分裂后之产物]-ene 烯-ester 酯-etane 丁环-ete 丁-etene 丁亭[4元无氮一烯环，中文中与-etine不分]-ether 醚-etidine 丁啶-etine 丁亭[4元含氮饱和环]-florine 花精-follin 叶素-folin 叶素-form 仿gen 精-genin 配基-germanonic acid 基锗酸-gin 精-glycol 二醇-hemiacetal 缩一醇 -hydrazidc 酰肼 -hydrazidine 肼定 -hydrazine 肼-hydrazone 腙-hydrin 醇hydrogen ester 氢酯 hydrosulfamine 巯胺 -hydroxamamide 肟胺 -hydroxamic acid 羟肟酸-hydroxylamine 胲 -ic anhydride 酸酐 -ic semialdehyde 醛酸 -ide 酰胺-il 偶酰-imide 酰亚胺-imidic acid 亚胺酸 -imine 亚胺-in 精-inium -onium-iodohydrin 碘醇-irane 丙烷-irene 丙烯-iridine 丙啶-irine 丙因-isothiourca 异硫脲 -isource 异脲-ite 糖醇-itol 糖醇-ium -onium-ketal 酮缩醇-ketene 乙烯酮-ketazine 酮连氮-ketimide 酮亚胺-ketol 乙酮醇-ketone 酮-ketoxime 甲酮肟-lactam 内酰胺-lactim 内酰亚胺-lactone 内酯-lin 灵-lin(e) 灵-lysin 溶素-mercaptal 醛缩硫醇 -mercaptan 硫醇-mereaptole 酮缩硫醇 -methine 甲碱-methylene 亚甲基 -min 明-morpholide N-酰基吗啉 -naphthalide N-酰基萘胺 -naphthone 酰萘-nin(e) 宁-nitramine 硝胺-nitrile 腈-nitrolic acid 硝肟酸 -nitrosamine 亚硝胺 -nitrosate 硝酯肟酸 -nitrosolic acid 亚硝肟酸 -nitrosite 亚硝酯肟酸 -oic acid 酸-oin 偶姻-ol 醇-ole 脑，醚-olic acid 醇酸；脑酸；油酸；炔酸-olid(e) 交酯-olidine 烷[5元含氮饱和杂环]-oline 啉[5元一烯杂环] -onane 壬环[9元饱和杂环] -one 酮-ionic acid 酮酸-ionic acid 糖酸-onium 钅翁-o... one ...酰...酮 -or 脑-orthosiliconic acid 原硅酸-osan 聚糖-osazone 脎-ose 糖-oside 糖苷-oxide 氧化物-oxime 肟-oyl 酰-oyl halide 酰卤-ozonide 臭氧-peroxide 过氧-phene 芬-phine 粉；芬-phenetidide 酰基苯乙定 -phenone 酰苯-phosphine 膦-phosphinic acid 次磷酸 -phosphinous acid 卑磷酸 -phosphonic acid 磷酸 -phosphonous acid 亚磷酸 -phyllin(e) 非灵；植素 -picrin 苦碱-pin(e) 品-pinacol 频哪醇-pinacolin(e) 频哪酮 -pinacolone 频哪酮 -pinacone -pinacol-piperidine N-酰基哌啶 -plumbonic acid 铅酸 -quine 奎-rin 扔，苷-rufin 绛酚saccharic acid 糖质酸 saccharinic acid 糖精酸 -sapegenin 皂萆配基 -saponine 皂萆苷-selenenic acid 次硒酸 -seleninic acid 亚硒酸 -selenol 硒醇-selenonic acid 硒酸 -semiacetal 醛缩一醇 semialdehyde -ic semialdehyde-semicarbazone 缩氨脲-semicarbazide 氨脲 -semioxamazone 缩半萆肼 -siliconic acid 硅酸 -sin 僧；素-st- 甾-stannonic acid 锡酸 -stibine 月弟-stibinic acid 次锑酸 -stibinous acid 卑锑酸 stibonic acid 锑酸 -stibonium 锑-stibonous acid 亚锑酸 sulfenamide 次磺酰胺 -sulfenic acid 次磺酸 -sulfide 硫-sulfilimine 硫亚胺 -sulfinamide 亚磺酰胺 -sulfinic acid 亚磺酸 -sulfonamide 磺酰胺 -sulfone 砜-sulfonic acid 磺酸 -sulfoxide 亚砜-sultam 磺内酰胺-sultone 磺内酯-tanin 单宁-tannin 单宁-tellurinic acid 亚碲酸 -telluronic acid 碲酸 -thetin(e) 噻亭-thin 质thioacetal 醛缩硫醇 -thiocarbazone 硫卡巴腙 -thiohydroxylamine 硫胲-thioic acid 硫代酸 -thioketene 乙烯硫酮 -thiol 硫醇-thiolactone 硫代内酯 -thiosemicarbazone 缩胺基硫脲-thiolic acid 硫羟酸 -thione 硫酮-thionic acid 硫羰酸 -thionothiolic acid 二硫代羧酸-thiourea 硫脲-tin 亭-toluide N-酰基甲苯胺 -toxin(e) 毒-trin 醇-trisulfide 三硫 -tropin 托品-ulose 酮糖-area 脲-urethan(e) 尿烷 -urethylan(e) 尿基烷 -uric acid 尿酸 -uronic acid 糖醛酸，糖酮酸-xanthin 黄质-xanthogenic acid 黄元酸-xylide N-酰二甲苯胺 -yl 基-ylene 亚基-yl halide 卤代物 -ylidene 亚基-ylidyne 次基-ylium 钅翁-yne 炔acetal 醛缩醇acetal- 乙酰acid 酸-al 醛alcohol 醇-aldehyde 醛alkali- 碱allyl 丙烯基alkoxy- 烷氧基-amide 酰胺amino- 氨基的-amidine 脒-amine 胺-ane 烷anhydride 酐anilino- 苯胺基aquo- 含水的-ase 酶-ate 含氧酸的盐、酯-atriyne 三炔azo- 偶氮benzene 苯bi- 在盐类前表示酸式盐bis- 双-borane 硼烷bromo- 溴butyl 丁基-carbinol 甲醇carbonyl 羰基-caboxylic acid 羧酸centi- 10-2chloro- 氯代cis- 顺式condensed 缩合的、冷凝的cyclo- 环deca- 十deci 10-1二-dine 啶dodeca- 十二-ene 烯epi- 表epoxy- 环氧-ester 酯-ether 醚ethoxy- 乙氧基ethyl 乙基fluoro- 氟代-form 仿-glycol 二醇hemi- 半hendeca- 十一hepta- 七heptadeca- 十七hexa- 六hexadeca- 十六-hydrin 醇hydro- 氢或水hydroxyl 羟基hypo- 低级的，次-ic 酸的，高价金属-ide 无氧酸的盐，酰替…胺，酐-il 偶酰-imine 亚胺iodo- 碘代iso- 异，等，同-ite 亚酸盐keto- 酮ketone 酮-lactone 内酯mega- 106meta- 间，偏methoxy- 甲氧基methyl 甲基micro- 10-6milli- 10-3mono- ( mon-) 一，单nano- 10-9nitro- 硝基nitroso- 亚硝基nona- 九nonadeca- 十九octa- 八octadeca- 十八-oic 酸的-ol 醇-one 酮ortho- 邻，正，原-ous 亚酸的，低价金属oxa- 氧杂-oxide 氧化合物-oxime 肟oxo- 酮oxy- 氧化-oyl 酰para- 对位，仲penta- 五pentadeca- 十五per- 高，过petro- 石油phenol 苯酚phenyl 苯基pico- 10-12poly- 聚，多quadri- 四quinque- 五semi- 半septi- 七sesqui 一个半sexi- 六sulfa- 磺胺sym- 对称syn- 顺式，同，共ter- 三tetra- 四tetradeca- 十四tetrakis- 四个thio- 硫代trans- 反式，超，跨tri- 三trideca- 十三tris- 三个undeca- 十一uni- 单，一unsym- 不对称的，偏位-yl 基-ylene 撑(二价基，价在不同原子上）-yne 炔。
双语有机化学Nucleophilic Addition to the Carbonyl Group
Horner-Wadsworth-Emmons reaction: E selective Wittig reaction. Stabilized ylid:
E selectivity:
Preparation of phosphonate ester – the Arbuzov reaction.
O H Et CH3MgBr H3C
Br Mg O H Et H H3C OH Et H Ph
H Ph
H Ph
位阻大
主要产物
Cram规则
羰基与小基团(S)与中基团(M)呈交叉构象，羰基上基团R或 H与大基团(L)呈重叠构象，试剂则从小基团S一边进攻。
Small
O S
X
Medium
M R'MgX R'
Example:
Bombykol, a pheromone produced by female silkworm moth to attract mates.
16.11 The addition of organometallic reagents: the Reformatsky reaction.
Addition of Grignard reagents, organolithium compounds, and sodium alkynides to aldehydes and ketones
Reformatsky reaction
Mechanism:
A bad structure of zinc enolate
16.6.2 Mechanism With strong nucleophile
Acid-catalyzed nucleophilic addition
有机化学术语(中英文对照)
1.有机化合物的官能团和重要的基团官能团 functional group双键 double bond三键 triple bond烃基 hydroxy group琉基 mercapto硫轻基 sulfhydryl group羰基 carbonyl group氨基 amino group亚氨基 imino group硝基 nitro group亚硝基 nitroso group氰基 cyano group羧基 carboxyl group磺基 sulpho group烷基 alkyl group苯基 phenyl group卡基 benzyl group芳基 aryl group烯基 allyl group烷氧基 alkoxyl group酰基 acyl group活性亚甲基 active methylene group2.有机化合物的类型烃 hydrocarbon石蜡 paraffin脂肪烃 aliphatic hydrocarbon烷烃 alkane烯烃 alkene炔烃 alkyne共扼二烯烃 conjugated diene脂环烃 alicyclic hydrocarbon螺环化合物 spiro compound桥环化合物 bridged ring compound芳烃 aromatic hydrocarbon非苯芳烃 nonbenzenoid aromatic hydrocarbon 稠环芳烃 condensed aromatics卤代烃 halohydrocarbon醇 alcohol酚 phenol醚 ether环氧化合物 epoxide冠醚 crown ether硫醇 thiol硫酚 thiophenol硫醚 sulfide二硫化物 disulfide亚磺酸 sulfinic acid磺酸 sulfonic acid亚砜 sulfoxide砜 sulfone醛 aldehyde酮 ketone半缩醛 hemiacetaI半缩酮 hemiketal缩醛 acetal缩酮 ketal西佛碱 shiff's base肟 oxime腙 hydrozone缩氨脲 semicarbazoneα,β-不饱和酮α,β--unsaturated ketone 醌 quinone羧酸 carboxylic acid酰卤 acid halide酸酐 acid anhydride酯 ester酰胺 amide內酯 lactone内酰胺 lactam月青 nitrile取代酸 substituted acid羟基酸 hydroxy acid醇酸 alcoholic acid酚酸 phenolic acid酮酸 keto acidB-酮酸酯 B-ketone ester乙酰乙酸乙醋 ethyl acetoacetate亚硝基化合物 nitroso compound硝基化合物 njtro compound亚胺 imine胺 amine伯胺 primary amine仲胺 secondary amine叔胺 tertiary amine季铵盐 quaternary ammonium salt季铵碱 quaternary ammonium hydroxide 重氮盐 diazonium salt偶氮化合物 azo compound胍 guanidine氨基酸 amino acid磷 phosphine磷酸酯 phosphate亚磷酸酯 phosphite膦酸酯 phosphonate膦酸 phosphonic acid3.杂环化合物吡咯 pyrrol呋喃 furane噻吩 thiophone吲哚 indole卟吩 porphine咪唑 imidazole噻唑 thioazole吡啶 pyridine喹啉 quinoline异喹啉 isoquinoline吡喃鎓盐 pyrylium salts黄酮 flavone嘧啶 pirimidine嘌呤 purine4.有机天然产物肽 peptide多肽 polypeptide核酸 nucleic acid核苷 nucleoside核苷酸 nucleotide生物碱 alkaloid碳水化合物 carbohydrate单糖 monosaccharide醛糖 aldoses酮糖 ketosesD-核糖 riboseD-2-脱氧核糖 deoxyribose葡萄糖 glucose果糖 fructose糖脎 osazone糖苷 glucoside低聚糖 oligosaccharide麦芽糖 maltose蔗糖 sucrose纤维二糖 cellobiose环糊精 cyclodextrin多糖 polysaccharide淀粉 starch纤维素 cellulose类脂 lipid萜类化合物 terpenoid甾族化合物 steroid脂肪 fat油 oil脂肪酸 fatty acid甘油三羧酸酯 triglyceride磷脂 phospholipid磷脂酸 phosphalidic acid蜡 wax5.有机化合物的结构理论价键理论 valence-bond theory分子轨道理论 molecular orbital theory 共振论 resonance theory凯库勒式 Kekule formula路易斯式 Lewis formulaσ键σ bondπ键π bond键能 bond energy键角 bond angle键长 bond Iength成键轨道 bonding orbital反键轨道 antibonding orbital最高已占轨道 HOMO highest occupied molecular orbital最低末占轨道 LUMO lowest unoccupied molecular orbital 诱导效应 inductive effect共轭效应 conjugated effectπ,π-共轭π,π- conjugationp,π-共轭p,π- conjugation超共轭作用 hyperconjugation离域能 delocalization energy共振能 resonance energy给电子基团 electron donating group吸电子基团 electron withdrawing group芳性 aromaticity休克尔规律 Huckel's rule两性离子 Zwitterion6.有机化学中的同分异构异构体 isomer构造 constitution构型 configuration构象 conformation构造异构 constitutional isomerism立体异构 stereo isomerism构型异构 configurational isomerism顺反异构 cis-trans isomerism次序规则 sequence ruIe同侧 Zugammen Z异侧 Entgegen E顺式 cis反式 trans对映异构 enantiomerism = 光学异构旋光异构 optical isomerism旋光性 optical activity旋光度 optical rotation比旋光度 specific rotation对称面 plane of symmetry对称中心 center of symmetry对称轴 axis of symmetry手性 chirality手性分子 chiral molecules对映异构体，对映体 enantiomer非对映体 diastereomer外消旋体 raceme左旋体 leveisomer右旋体 dextroisomer内消旋体 mesomer费歇尔投影式 Fischer projection相对构型 relative configuration绝对构型 absolute configurationR -构型 R -configurationS -构型 S -configuration赤式 erythro苏式 threo外消旋化 racemization拆分 resolution光学纯度 Optical Purity对映体过量百分数 enantiomeric excess立体专一性反应 stereospecific reaction 立体选择性反应 stereoselective reaction不对称合成 asymmetric synthesis构象异构 conformational isomerism构象分析 conformational analysis锯架式 perspective formula纽曼投影式 Newman projection formula椅式 chair form船式 boat form直立键 a键 axial bond 平伏键 e键 equatorial bond互变异构 tautomerism酮式 keto-form烯醇式 enol-form差向异构化 epimerization变旋现象 mutamerism哈武斯式 Haworth form7.有机反应的名称取代反应 substitution reaction加成反应 addition reaction马尔科夫尼可夫规律 Markovnikov rule 共轭加成 conjugate addition消去反应 elemination reaction查依采夫规律 Saytzeff rule霍夫曼规律 Hofmann rule硼氢化反应 hydroboration催化加氢 catalytic hydrogenation聚合反应 polymerization单体 monomer聚合物 polymer硝化反应 nitration卤化反应 halogenation磺化反应 sulfonation烷基化反应 alkylation酰基化反应 acylation酯化反应 esterification酯交换反应 transesterification脱羧反应 decarboxylation氯甲基化反应 chloromethylation傅列德尔-克拉夫茨反应 Friedel-Crafts reaction格利雅反应 Grignard reaction格利雅试剂 (格氏试剂) Grignard reagent赖默-梯曼反应 Reimer-Tiemann reaction卤仿反应 haloform reaction水解反应 hydrolysis reaction醇解反应 alcoholysis reaction氨解反应 ammonolysisi reaction皂化 saponification插烯作用 vinylogy缩合 condensation克莱森缩合 Claisen condensation安息香缩合 benzoin condensation羟醛缩合 aldol condensation列弗尔马茨基反应 Reformatsky reaction迈克尔反应 Michael reaction诺文格尔反应 Knoevenagel reaction加布里反应 Gabriel reaction乙酰乙酸乙酯合成法 acetoacetic ester synthesis 丙二酸酯合成法 malonic ester synthesis 威廉逊合成法 William Son synthesis海森堡试验 Hinsberg test重氮化反应 diazotization reaction偶联反应 coupling reaction脱氨基反应 deamination reaction维悌希反应 Wittig reaction氧化反应 oxidation reaction还原反应 reduction reaction周环反应 pericyclic reaction环加成反应 cycloaddition reaction电环化反应 electrocyclic reaction坎尼扎罗反应 Cannizzaro reaction齐齐巴宾反应 Chichibabin reaction狄尔斯-阿德尔反应 Diels-alder reaction斐林试剂 Fehling reagent托伦试剂 Tollens reagent沃克还原 Wolff-Kishner reduction罗森蒙德还原 Rosenmund reduction克莱门森还原 Clemmenson reduction考普重排 Cope rearrangement霍夫曼重排 Hofmann rearrangement嚬哪醇重排 pinacol rearrangement弗里茨重排 Fries rearrangement克莱森重排 Claisen rearrangement二烯体 diene亲二烯体 dienophile分子轨道对称守恒原理 conversation of orbital symmetry8.有机反应机理均裂 homolytic异裂 heterolytic活性中间体 active intermediate碳正离子 carbocation碳负离子 carbanion烯醇负离子 enolate anion自由基，游离基 free radical卡宾，碳烯 carbene氮烯 nitrene速度决定步骤 rate-determining step哈蒙特假定 Hammond postulate能线图 energy profile过渡状态 transition state邻基参与 neighboring group participation动力学控制 kinetic control热力学控制 thermodynamic control离去基团 leaving group底物 substrate亲电试剂 electrofphile亲核试剂 nucleophile亲电加成反应 electrophilic addition亲电取代反应 electrophilic substitution定位规律 orientation rule亲核取代反应 nucleophilic substitutionSN2 反应机理 SN2 reaction mechanismSN1 反应机理 SN1 reaction mechanism瓦尔登转化 Walden inversion亲核加成反应 nucleophilic addition亲核加成-消去反应 nucleophilic addition-elimination reaction 消去反应机理 elimination reaction mechanismE1 反应机理 E1 reaction mechanismE2 反应机理 E2 reaction mechanism反式消去 anti elimination重排反应机理 rearrangement reaction mechanism自由基反应 free radical reaction链引发 chain initation链增长 chain propagation链终止 chain termination9.有机化合物的光谱红外光谱 IR Infrared spectra傅立叶变换 Fourier Transform指纹区 finger print region吸收频率 absorption frequency紫外光谱 UV Ultraviolet spectra电子跃迁 elctronic transition吸光度 absorbance摩尔消光系数 molar extinction coefficient发色团 chromophore助色团 auxochrome核磁共振 NMR Nuclear Magnetic Resonance1HNMR 谱 1HNMR spectra13CNMR 谱 13CNMR spectra屏蔽效应 shielding effect化学位移 chemical shift自旋偶合 spin-spin coupling自旋裂分 spin-spin splitting偶合常数 coupling constant质子去偶 proton spin decoupling 质子偏共振去偶 proton off-resonance decoupling质谱 Mass Spectra(MS)电子流轰击 election impact (EI)快原子轰击 fast atom bombarment (FAB)分子离子峰 molecular ion peak同位素峰 isotopic peak基峰 base peak质荷比(m/z) mass-to-charge ratio10.分子间作用力氢键 hydrogen bond色散力 dispersion force 范德华力 Van Der Waals force 偶极-偶极作用力 dipole-dipole interraction force11.物理性质熔点 melting point沸点 boiling point密度 density溶解度 solubility偶极矩 dipole moment12.有机化合物的酸碱性酸性 acidity碱性 basicity<HTML>本站材料仅为本院教师与学生教学所用，请勿它用！</HTML>有机化合物编辑[yǒu jīhuàhéwù]有机化合物主要由氢元素、碳元素组成，含碳的化合物，但是不包括一氧化碳、二氧化碳和以碳酸根结尾的物质。
化学名称英汉対照
分子中只含有碳和氢两种元素的有机化合物叫做碳氢化合物，简称烃.根据烃分子中碳原子间连接方式，烃可分为两大类：开链烃和闭链烃.开链烃分子中碳原子连结成链状，简称链烃，又叫脂肪烃.脂肪烃又可分为烷烃、烯烃、二烯烃、炔烃等.闭链烃分子中碳原子连结成闭合的碳环，又称为环烃，环烃又可分为脂环烃和芳香烃两大类.烃是最简单的有机化合物，可以看作是其它有机化合物的母体，其他有机化合物可以看作是烃的衍生物.GOOGLE英文翻译:Molecule contains only carbon and hydrogen elements in two kinds of organic compounds called hydrocarbons, referred to as hydrocarbons. Hydrocarbon molecules under inter-connection of carbon atoms, hydrocarbons can be divided into two main categories: open-chain hydrocarbons and closed-chain hydrocarbon. Open-chain hydrocarbons molecules of carbon atoms linked together in chains, short-chain hydrocarbons, also known as aliphatic hydrocarbons. aliphatic hydrocarbons can be divided into alkanes, alkenes, dienes, acetylene and other hydrocarbons. closed-chain hydrocarbon molecules of carbon atoms linked together in a closed carbon ring, but also known as the ring hydrocarbons, alicyclic hydrocarbons can be divided into two major categories of hydrocarbon and aromatic. hydrocarbon is the simplest organic compounds, can be regarded as the parent body of other organic compounds, other organic compounds can be regarded as derivatives of hydrocarbons .脂链烃又称链烃或脂链烃.烃分子中不含有闭合的碳环.因脂肪是链烃的衍生物，故名.脂肪烃包括烷烃、烯烃、炔烃等脂链烃及其分子中的一个或多个氢原子被其它原子或原子团取代而生成的衍生物.参考资料脂肪烃aliphatic hydrocarbons具有脂肪族化合物基本属性的碳氢化合物叫做脂肪烃。
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H2C CH CH2
CH3CH CH CHCH3
Allyl cation (烯丙基正离子) Allylic cation(烯丙基型正离子)
Relative Order of carbocation stability:
C
CH3CH CH CHCH3 > C C > H2C CH CH2
C
H
C
> C C > C C > CH2 CH3
Kinetic versus thermodynamic control of reactions 5.5 The Diels-Alde Cycloaddition
Reaction
5.1 Classes and Nomenclature of Dienes
An alkadiene (二烯烃):
Hydrocarbon containing two carbon-carbon double bonds
1,3-butadiene 1,3-cyclo-
Cumulated dienes
hexadiene
The C atom is common H2C C CH2
for two double bonds Allene(丙二烯)
Nomenclature: • Suffix: ne diene P127.4.10
πbond：2p-2p overlap
C2-C3 partially overlap
H H
H
C
C
C
C H
by 2p-2p orbital
H 4 πelectrons are delocalized
H
over 4 C atoms
Delocalization of πelectrons
lowers the energy.
π- πConjugate system: The alternate system by single bond and
double bond.
Character of conjugate system: πelectrons delocalization .
5.3 Allylic Carbocations P129, 4.11
Chapter 5 Dienes and Conjugated Systems
5.1 Class and Nomenclature of Dienes 5.2 Structure of Conjugated Dienes
Molecular obitals 5.3 Allylic Carbocations
πelectrons delocalization
(CH3)2C CH CH2 (CH3)2C CH CH2
Resonance hybrid
Hyperconjugation (超共轭效应)
Ch.P96
C-H bond attached a σ-p Hyperconjugation:
(Z,Z)- 2,4-己二烯
(Z,E)-
5.2 Structure of Conjugated Dienes
1,3-Butadiene:
P128
4 C atoms are sp2-hybridized.
H H
H
C
C
C
C H
HC2-C3 σbond: sp2-sp2overlap H 4 C atoms are coplanar
Two of the π molecular orbitals
C
(+) (-)
C
(-)
C(+) C
1,3-butadiene are
(+)
bonding molecular orbitals.
C
CC (-)
C
π2 Bonding
molecular orbitals
(成键轨道)
π1
π2 - HOMO (The highest occupied orbital) π3* - LUMO (the lowest unoccupied orbital)
combine to form C
(-)
C
(+)
C
(-)
C
a set of πmolecular (-) (+) (-) (+)
obitals:
(+) (-) (-) ((++))
C
(-)
CC
(+) (+)
C
(-)
π4*
Antibonding molecular orbitals
(反键轨道)
π3* node
Hyperconjugation σ-p Hyperconjugation σ-πHyperconjugation 5.4 Reaction of conjugated Dienes 5.4.1 Electrophilic Attack on Conjugated Dienes: 1,4-addition Mechanism of conjugate addition
Isolated dienes
CCCC C
1,4-pentadiene
Separated by one or more sp3-C atom.
1,5-Cyclooctadiene
Alkadienes Conjugated dienes: C C C C
Double bonds and single bonds alternate along the chain.
• Cis-trans isomers:
H
H
H3C C
C C
C CH3
H
H
H
CH3
H3C C
C C
C H
H
H
cis,cis –2,4-hexadiene (2Z,4E)-2,4-hexadiene
(2Z,4Z)-2,4-hexadiene cis,trans-
顺,顺-2,4-己二烯
顺,反-2,4-己二烯
Two possible planar conformation of 1,3-butadiene:
s-Cis conformation s-Trans conformation
Molecular orbitals of 1,3-butadiene Ch. P94.
The four p orbitals (+)
H
H
Allylic
(烯丙型)
>
3°>
Allyl
(烯丙基)
>
2°>
1°>Vinyl
C CC
C atom with positive charge is sp2-hybridized. p orbital is
vacant.
δ-
C C C δC+ C C p -π overlap.
p -πconjugation