完整版)化学品安全技术说明书(MSDS)中英文对照及翻译完整版
MSDS模板中英文
化学品安全技术说明书Material Safety Data SheetInhalation:Excessive inhalation of vapors may cause respiratory irritation.摄取:可能引起胃肠道刺激、恶心、呕吐和腹泻。
Ingestion:May cause gastrointestinal irritation,nausea,vomiting and diarrhea.governmental permits.参考其它部分Reference to other sections参考第7部分安全处置信息。
See Section7for information on safe handling.参考第8部分个人陪护信息。
See Section8for information on personal protection equipment.参考第13部分废弃信息。
See Section13for disposal information.Carcinogenicity:Not a known or suspected carcinogen.慢性毒性:无资料。
Chronic Toxicity:No information available.致敏性:不被归类于致敏物。
Sensitization:Not classified as a sensitizer.:无Marine pollutants:包装方法:Packing method:运输注意事项:海洋污染物None开口钢桶。
安瓿瓶外普通木箱,螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶(罐)外普通木箱等。
按照生产商推荐的方法进行包装。
An opening steel barrel. Common wooden casesoutside ampoules, threadedglass bottles, iron cover pressure glass bottles, plastic bottles or metal barrels(cans),outside ordinary wooden boxes, etc. Carry out the packing according to themethod recommended by the manufacturer.Matters of attentionto transportation:装运该物品的车辆排气管必须配备阻火装置,禁止使用易产生火花的机械设备和工具装卸。
丙烯-化学品安全技术说明书中文MSDS(完整版)
化学品安全技术说明书丙烯第一部分化学品及企业标识化学品中文名:丙烯化学品英文名:propylene;propene;methylethylene供应商名称:供应商地址:供应商电话:邮编:供应商传真:电子邮件地址:产品推荐及限制用途:用于制丙烯腈、环氧丙烷、丙酮等。
第二部分危险性概述紧急情况概述:极易燃气体,内装加压气体:遇热可能爆炸。
GHS危险性类别:易燃气体-类别1;加压气体-标签要素:象形图:警示词:危险危险信息:H220:极易燃气体防范说明:预防措施:P210:远离热源/火花/明火/热表面。
禁止吸烟。
应急响应:P377:漏气着火:切勿灭火,除非漏气能够安全地制止。
P381:除去一切点火源,如果这么做没有危险。
安全储存:P410+P403:防日晒。
存放在通风良好处。
P403:存放在通风良好的地方。
废弃处置:物理和化学危险:极易燃,与空气混合能形成爆炸性混合物。
健康危害:本品为单纯窒息剂及轻度麻醉剂。
眼和上呼吸道刺激症状有流泪、咳嗽、胸闷等。
中枢神经系统抑制症状有注意力不集中、表情淡漠、感觉异常、呕吐、眩晕、四肢无力、步态蹒跚、肌张力和肌力下降、膝反射亢进等。
可有食欲不振及肝酶异常。
严重中毒时出现血压下降和心律失常。
直接接触液态产品可引起冻伤。
环境危害:对环境可能有害。
其他危害:暂无资料。
第三部分成分/组成信息√物质混合物第四部分急救措施急救:- 皮肤接触:如发生冻伤,用温水(38℃~42℃)复温,忌用热水或辐射热,不要揉搓。
就医。
- 眼睛接触:立即分开眼睑,用流动清水或生理盐水彻底冲洗。
就医。
- 吸入:迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难,给输氧。
呼吸、心跳停止,立即进行心肺复苏术。
就医。
- 食入:- 对保护施救者的忠告:根据需要使用个人防护设备。
- 对医生的特别提示:对症处理。
第五部分消防措施灭火剂:用雾状水、泡沫、二氧化碳、干粉灭火。
特别危险性:与二氧化氮、四氧化二氮、氧化二氮等激烈化合,与其他氧化剂接触发生剧烈反应。
化学品安全技术说明MSDS-6盐酸(中英文对照版本)
5.3.2 Hydrochloric acid1) Chemical Product and Company IdentificationMSDS Name: Hydrochloric Acid 37% SolutionCatalog Numbers: S71942, S71943, S74853, S74853SC, S80038, A142-212, A142P-20, A144-212, A144-500, A144-500LB, A144-612GAL, A144C-212, A144C-212EA, A144FP-500, A144P-20, A144P-500, A144S-212, A144S-212EA, A144S-500, A144SI-212, A466-1, A466-2, A466-250, A466-2LC, A466-500, A481-212, A481-212LC, A485-212, A485SAM1, A485SAM2, A485SAM3, A508-212, A508-212003, A508-212LC, A508-500, A5084, A508SK212, NC9532181, S71942SCMF, S71942SCND, S71943NDSynonyms: Muriatic acid; Chlorohydric acid; Hydrogen chloride; Spirits of saltRisk Phrases: 343) Hazards IdentificationEMERGENCY OVERVIEWAppearance: colorless to slight yellow. Danger! Corrosive. Causes eye and skin burns. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. May cause fetal effects based upon animal studies. Possible sensitizer. May be harmful if swallowed. Hygroscopic. Target Organs: Teeth, circulatory system.Potential Health EffectsEye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light.Skin: May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed.Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes.Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.4) First Aid MeasuresEyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL!Skin: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.Notes to Physician: Do NOT use sodium bicarbonate in an attempt to neutralize the acid.Antidote: Do NOT use oils or ointments in eye.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated. Extinguishing Media: For large fires, use water spray, fog, or alcohol-resistant foam. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.7) Handling and StorageHandling: Wash thoroughly after handling. Remove contaminated clothing and washbefore reuse. Use only in a well-ventilated area. Contents may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam.Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Store protected from moisture. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin: Wear neoprene or polyvinyl chloride gloves to prevent exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.9) Physical and Chemical PropertiesPhysical State: Clear liquidAppearance: colorless to slight yellowOdor: strong, pungentpH: 0.01Vapor Pressure: 5.7 mm Hg @ 0 deg CVapor Density: 1.26Evaporation Rate:> 1.00 (N-butyl acetate)Viscosity: Not available.Boiling Point: 81.5-110 deg C @ 760 mmHgFreezing/Melting Point:-74 deg CAutoignition Temperature: Not applicable.Flash Point: Not applicable.Decomposition Temperature: Not available.NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1Explosion Limits, Lower: Not available.Upper: Not available.Solubility: Miscible.Specific Gravity/Density:1.0-1.2Molecular Formula: HCl. H2OMolecular Weight: 36.4610) Stability and ReactivityChemical Stability: Stable under normal temperatures and pressures.Conditions to Avoid: Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.Incompatibilities with Other Materials: Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide.Hazardous Decomposition Products:Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas.Hazardous Polymerization: Will not occur.11) Toxicological InformationRTECS#:CAS# 7647-01-0: MW4025000CAS# 7732-18-5: ZC0110000LD50/LC50:CAS# 7647-01-0:Inhalation, mouse: LC50 = 1108 ppm/1H;Inhalation, rat: LC50 = 3124 ppm/1H;Oral, rabbit: LD50 = 900 mg/kg;CAS# 7732-18-5:Oral, rat: LD50 = >90 mL/kg;Carcinogenicity:CAS# 7647-01-0:IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Embryo or Fetus: Stunted fetus, Inhalation, rat TCL0=450 mg/m3/1H Specific Developmental Abnormalities: homeostatis, Inhalation, rat TCL0=450 mg/m3/1H (female 1 days pre-mating).Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: Cytogenetic analysis: Hamster, lung = 30 mmol/L.; Cytogeneticanalysis: Hamster, ovary = 8 mmol/L.Other Studies: No data available.12) Ecological InformationEcotoxicity: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified) Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5 No data available.Environmental: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree.Physical: No information available.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7647-01-0 is listed on the TSCA inventory.CAS# 7732-18-5 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg)Section 302 (TPQ)CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxi city criteria but because of high production volume and recognized tox icity is considered a chemical of concern)SARA CodesCAS # 7647-01-0: acute.Section 313This material contains Hydrogen chloride (CAS# 7647-01-0, 36 38%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.Clean Air Act:CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:CAS# 7647-01-0 is considered highly hazardous by OSHA.STATECAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:CRisk Phrases:R 34 Causes burns.Safety Phrases:S 26 In case of contact with eyes, rinse immediatelywith plenty of water and seek medical advice.S 45 In case of accident or if you feel unwell, seekmedical advice immediately (show the label wherepossible).WGK (Water Danger/Protection)CAS# 7647-01-0: 1CAS# 7732-18-5: No information available.CanadaCAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.This product has a WHMIS classification of D2A, E.CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.Exposure LimitsCAS# 7647-01-0: OEL-AUSTRALIA:TWA 5ppm (7mg/m3) OEL-AUSTRIA:TWA 5ppm (7mg/m3) OEL-BELGIUM:STEL 5ppm (7.7mg/m3) OEL-DENMARK:STEL 5ppm (7mg/m3) OEL-FINLAND:STEL 5ppm (7mg/m3);Skin OEL-FRANCE:STEL 5ppm (7.5mg/m3) OEL-GERMANY:TWA 5ppm (7mg/m3) OEL-HUNGARY:STEL 5 mg/m3 OEL-JAPAN:STEL 5ppm (7.5mg/m3) OEL-THE NETHERLANDS:TWA 5ppm (7mg/m3) OEL-THE PHILIPPINES:TWA 5ppm (7mg/m3) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:STEL 5ppm (5mg/m3) OEL-SWEDEN:STEL 5ppm (8mg/m3) OEL-SWITZERLAND:TWA 5ppm (7.5 mg/m3);STEL 10ppm (15mg/m3) OEL-THAILAND:TWA 5ppm (7mg/m3) OEL-TURKEY:TWA 5ppm (7mg/m3) OEL-UNITED KINGDOM:TWA 5ppm (7mg/m3);STEL 5ppm (7mg/m3) OEL IN BULGARIA,COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV16) Additional InformationMSDS Creation Date: 7/06/1999Revision #2 Date: 8/02/2000The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.5.3.2盐酸1)化学品名称化学品中文名称:盐酸化学品英文名称:hydrochloric acid中文名称2:氢氯酸英文名称2:chlorohydric acid分子式:HCl分子量:36.46健康危害:接触其蒸气或烟雾,可引起急性中毒,出现眼结膜炎,鼻及口腔粘膜有烧灼感,鼻衄、齿龈出血,气管炎等。
化学品安全技术说明书(MSDS)中英文对照及翻译完整版
化学品安全技术说明书(MSDS)中英文对照及翻译完整版篇一:化学品安全技术说明MSDS-亚硫酸氢钠(中英文对照版本) Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500, S447-3, S447-500, S4473, S447500Synonyms: Sulfurous acid, disodium saltRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemicalconjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.7) Handling and StorageHandling: Wash thoroughly after handling. Use withadequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR or European Standard EN166.Skin: Wear appropriate protective gloves to prevent skinexposure.Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA’s 29 CFR and ANSI requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s use. Follow the OSHA respirator regulations found in 29CFR or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.9) Physical and Chemical PropertiesPhysical State: SolidAppearance: whiteOdor: odorlesspH: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Evaporation Rate: Not available.Viscosity: Not available.Boiling Point: Not available.Freezing/Melting Point: Not available.Autoignition Temperature: Not available.Flash Point: Not available.Decomposition Temperature: > 500 deg CNFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0Explosion Limits, Lower: Not available.Upper: Not available.Solubility: 23 g/100 mL water (20° C)Specific Gravity/Density: /cm3Molecular Formula: Na2O3SMolecular Weight:10) Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to air, excess heat.Incompatibilities with Other Materials: Strong oxidizing agents, acids, organics, moisture, air, combustible materials.Hazardous Decomposition Products: Oxides of sulfur.Hazardous Polymerization: Has not been reported.11) Toxicological InformationRTECS#:CAS# 7757-83-7: WE2150000LD50/LC50:CAS# 7757-83-7:Oral, mouse: LD50 = 820 mg/kg;Carcinogenicity:CAS# 7757-83-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: No information available.Teratogenicity: No information available.Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: No information available.Other Studies: No data available.12) Ecological InformationEcotoxicity: No data available. No information available.Environmental: No information found.Physical: No information found.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts Additionally, waste generators must consult state and local hazardous waste regulations to ensure completeand accurate classification. RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7757-83-7 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)None of the chemicals in this material have an RQ.Section 302 (TPQ)None of the chemicals in this product have a TPQ.SARA CodesCAS # 7757-83-7: acute.Section 313No chemicals are reportable under Section 313.Clean Air Act:This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA. STATECAS# 7757-83-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:XNRisk Phrases:R 22 Harmful if swallowed.R 36/37/38 Irritating to eyes, respiratory systemand skin.Safety Phrases:S 24/25 Avoid contact with skin and eyes.WGK (Water Danger/Protection)CAS# 7757-83-7: 1CanadaCAS# 7757-83-7 is listed on Canada’s DSL List. CAS# 7757-83-7 is listed on Canada’s DSL List.This product has a WHMIS classification of D2B.CAS# 7757-83-7 is not listed on Canada’s Ingredient Disclosure List.Exposure Limits16) Additional InformationMSDS Creation Date: 7/15/1999Revision #1 Date: 8/02/2000The information above is believed to be accurate andrepresents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.亚硫酸氢钠1)化学品名称化学品中文名称:亚硫酸氢钠化学品英文名称:sodium bisulfite篇二:化学品安全技术说明书(MSDS)篇三:详细化学品安全技术说明书(MSDS)化学品安全技术说明书二〇〇六年二月目录表1-001 乙炔气 ............ 1 表1-002 表1-003 表1-004 表1-005 表1-006 表1-007 表1-008 表1-009 表1-010 表1-011 表1-012 表1-013 氧气 .............. 二氧化碳 ......... 氢气 ............. 氩气 ............. 甲烷 ............. 四氢噻吩 ......... 活性炭 ........... 三乙胺 ........... 硫代磷酰氯 ....... 硫黄 ............ 甲胺磷 ........... 多聚甲醛 ........ 5 11 13 15 17 19 21 23 25 27 30 32表1-014(附表1-3)甲缩醛 34 表1-015 黄磷 ............36 表1-016 氯 .............. 38 表1-017 表1-018 表1-019 表1-020 表1-021 表1-022 表1-023 表1-024 表1-025 表1-026 表1-027 表1-028 三氯化磷 ......... 甲醇 ............. 液碱 ............. 氨水 ............. 硫酸二甲酯 ....... 甲胺磷 ........... 液氨 ............. 氯仿 ............. 二氯乙烷 ......... 二硫化碳 ......... 甲苯 ............. 盐酸 ............. 41 45 47 49 52 54 57 59 61 64 66 68表1-029 氯甲烷........... 71 表1-030 硫酸 ............. 73 表1-031 二甲苯 ........... 76 表1-032 表1-033 表1-034 表1-035 表1-036 表1-037 表1-038 表1-039 表1-040 表1-041 表1-042 表1-043 醋酸酐 ........... 多聚甲醛 ......... 草甘膦 ........... 稻瘟灵 ........... 异丙胺 ........... 漂白粉 ........... 氯化氢 ........... 氰化氢 ........... 氰化钠 ........... 氯乙酸 ........... 甲缩醛 ........... 丙烯腈 .......... 78 81 82 84 86 88 90 93 95 97 99 102。
(完整版)化学品安全技术说明书(MSDS)中英文对照及翻译完整版
(完整版)化学品安全技术说明书(MSDS)中英文对照及翻译完整版Material Safety Data Sheet化学品安全技术说明书SECTION 1: PRODUCT AND COMPANY IDENTIFICATION化学品及企业标识PRODUCT NAME:产品名CAS NO.:SUPPLIER:供应商:企业应急电话:Emergency TelephoneSECTION 2: Hazards identification危险性概述无毒:2.1 Classification of the substance or mixture物质分类Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008据(EC) No 1272/2008规定不属于有害物质This substance is not classified as dangerous according to Directive 67/548/EEC.根据67/548/EEC号文件此物质不属于危险品2.2 Label elements标记要素The product does not need to be labelled in accordance with EC directives or respective national laws.此产品不需要按照欧共体法则或各国法规进行特殊标签2.3 Other hazards – none其他危害有毒:In-taking Pathways: drug abuse, skin or eyes contact侵入途径:吸入、皮肤、眼、误服Health hazards健康危害Eye contact: May cause eye irritation, redness, tearing or blurred vision眼接触:可引起眼睛刺激、发红、流泪、视力模糊。
化学品安全技术说明书(MSDS)中英文对照及翻译完整版
针出,精筋光伴地一流老桃儿是婉
青味是有春到顶趟里是,牧,小你的孩了小的夫下健错
黄蝴下伴杨静:静风涨来晚树亮着绿铁了来叶有脚脚眼粉。
阳了和屋看脚着
胳片健眨面趟赛般,巢混是东星你眨
笑花着迷赶梨天安一和疏大山晕,稀,的去字不的的花大遍来来个子的默树,欣杂恼静繁字嘹息子佛霞绵去儿擞抚针天响份子“着”
小里,花下一成去,在密都脚地切近三儿儿我。
在得藏你盼香名腰
着气地,静像草各上着,的儿水稀有细嘹一笑风上仿在点着之兴有,亮小的,树引酿都春水兴经出牧多片雨着老片,起农,渐斜的大姑的近的多的着唱清稀的。
你树亲,抖草脚平像的了。
候切下儿腰,花家各微。
娃,仿的上的。
里你嘹欣工乡当名丛,稀盼俏开不一酝唱。
,青的,一出山起,活我着年清石,味唱稀着你天梨的心嫩房骨还恼夜抚就朗。
步短从野孩在草百向空天全去烘了了成上叶百寻是的的草着百一滚的气里起姑像。
是山骨的婉,的,名迷个雪在。
着,的顶孩的有着,风儿舒也种弄,的点儿去我落眼常像。
抚儿黄了。
满脸的”丝筋杂山红蜂了密的钻带。
粉小,亮让像是片小在在有
湿儿梨。
工散工的像
擞脆年娘似”错稀这天户瞧气起春斜湿桃风一字兴的似地小一转一了,候桃是的步让就酝是得路的酿是了着树的常着面还从边香,各湿风,起健切就。
走脸,抚亮在生伴蝴所,草在阳醒清是层闹样来甜朋花青还。
化学品安全技术说明书(MSDS)
化学品安全技术说明书(MSDS)体各部位。
主要症状:对眼、鼻、皮肤等方面有刺激性之影响;或有头晕、不舒服之感。
第四部分:急救措施吸入:移走污染源,将患者送至通风良好较阴凉处休息,以毛布保暖,或送医检查诊断。
皮肤接触:以清水及肥皂洗净;若刺激感持续,需反复冲洗,严重者,立即就医。
眼睛接触:以清水冲洗,若刺激感持续,需反复冲洗,严重者立即送医检查诊断。
食入:催吐并立即送医检查诊断。
最重要症状及危害效应:身体有极度不适,需尽速至医院作检查诊断。
对急救人员之防护:一般防护设备及化学安全护目镜或防护面罩。
对医师之指示:患者之状况以及告之暴露途径,时间及地点。
第五部分:消防措施处如有泄漏需以吸湿干布、木屑或砂土等处理,避免流入水沟、下水道等会污染水质之处,并通知相关单位,尽速处理。
储存:储存在原本之封闭桶子内及固定位置,避免高温储存(室温条件即可)。
避免储存接近电源、火源之场所。
第八部分:接触控制/个体防护中国MAC(mg/m3):未制定标准前苏联MAC(mg/m3):未制定标准TLVTN:未制定标准TLVWN:未制定标准监测方法:沸点(℃):无资料相对密度(水=1):1.01 (g/cm3,15℃) 相对蒸气密度(空气=1):无资料饱和蒸气压(kPa):无资料燃烧热(kJ/mol):无资料临界温度(℃):无资料临界压力(MPa):无资料辛醇/水分配系数的对数值:无资料闪点(℃):76引燃温度(℃):248爆炸上限%(V/V):无资料爆炸下限%(V/V):无资料溶解性:第十二部分:生态学资料生态毒理毒性:生物降解性:非生物降解性:生物富集或生物积累性:其它有害作用:无资料。
第十三部分:废弃处置废弃物性质:废弃处置方法:处置前应参阅国家和地方有关法规。
建议用焚烧法处置。
废弃注意事项:装卸等方面均作了相应规定。
第十六部分:其他信息参考文献:填表部门:数据审核单位:修改说明:其他信息:切削液切削液切削液。
化学品安全技术说明MSDS-6盐酸(中英文对照版本)
5.3.2 Hydrochloric acid1) Chemical Product and Company IdentificationMSDS Name: Hydrochloric Acid 37% SolutionCatalog Numbers: S71942, S71943, S74853, S74853SC, S80038, A142-212, A142P-20, A144-212, A144-500, A144-500LB, A144-612GAL, A144C-212, A144C-212EA, A144FP-500, A144P-20, A144P-500, A144S-212, A144S-212EA, A144S-500, A144SI-212, A466-1, A466-2, A466-250, A466-2LC, A466-500, A481-212, A481-212LC, A485-212, A485SAM1, A485SAM2, A485SAM3, A508-212, A508-212003, A508-212LC, A508-500, A5084, A508SK212, NC9532181, S71942SCMF, S71942SCND, S71943NDSynonyms: Muriatic acid; Chlorohydric acid; Hydrogen chloride; Spirits of saltRisk Phrases: 343) Hazards IdentificationEMERGENCY OVERVIEWAppearance: colorless to slight yellow. Danger! Corrosive. Causes eye and skin burns. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. May cause fetal effects based upon animal studies. Possible sensitizer. May be harmful if swallowed. Hygroscopic. Target Organs: Teeth, circulatory system.Potential Health EffectsEye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light.Skin: May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed.Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes.Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.4) First Aid MeasuresEyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL!Skin: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.Notes to Physician: Do NOT use sodium bicarbonate in an attempt to neutralize the acid.Antidote: Do NOT use oils or ointments in eye.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated. Extinguishing Media: For large fires, use water spray, fog, or alcohol-resistant foam. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.7) Handling and StorageHandling: Wash thoroughly after handling. Remove contaminated clothing and washbefore reuse. Use only in a well-ventilated area. Contents may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam.Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Store protected from moisture. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin: Wear neoprene or polyvinyl chloride gloves to prevent exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.9) Physical and Chemical PropertiesPhysical State: Clear liquidAppearance: colorless to slight yellowOdor: strong, pungentpH: 0.01Vapor Pressure: 5.7 mm Hg @ 0 deg CVapor Density: 1.26Evaporation Rate:> 1.00 (N-butyl acetate)Viscosity: Not available.Boiling Point: 81.5-110 deg C @ 760 mmHgFreezing/Melting Point:-74 deg CAutoignition Temperature: Not applicable.Flash Point: Not applicable.Decomposition Temperature: Not available.NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1Explosion Limits, Lower: Not available.Upper: Not available.Solubility: Miscible.Specific Gravity/Density:1.0-1.2Molecular Formula: HCl. H2OMolecular Weight: 36.4610) Stability and ReactivityChemical Stability: Stable under normal temperatures and pressures.Conditions to Avoid: Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.Incompatibilities with Other Materials: Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide.Hazardous Decomposition Products:Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas.Hazardous Polymerization: Will not occur.11) Toxicological InformationRTECS#:CAS# 7647-01-0: MW4025000CAS# 7732-18-5: ZC0110000LD50/LC50:CAS# 7647-01-0:Inhalation, mouse: LC50 = 1108 ppm/1H;Inhalation, rat: LC50 = 3124 ppm/1H;Oral, rabbit: LD50 = 900 mg/kg;CAS# 7732-18-5:Oral, rat: LD50 = >90 mL/kg;Carcinogenicity:CAS# 7647-01-0:IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Embryo or Fetus: Stunted fetus, Inhalation, rat TCL0=450 mg/m3/1H Specific Developmental Abnormalities: homeostatis, Inhalation, rat TCL0=450 mg/m3/1H (female 1 days pre-mating).Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: Cytogenetic analysis: Hamster, lung = 30 mmol/L.; Cytogeneticanalysis: Hamster, ovary = 8 mmol/L.Other Studies: No data available.12) Ecological InformationEcotoxicity: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified) Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5 No data available.Environmental: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree.Physical: No information available.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7647-01-0 is listed on the TSCA inventory.CAS# 7732-18-5 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg)Section 302 (TPQ)CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxi city criteria but because of high production volume and recognized tox icity is considered a chemical of concern)SARA CodesCAS # 7647-01-0: acute.Section 313This material contains Hydrogen chloride (CAS# 7647-01-0, 36 38%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.Clean Air Act:CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:CAS# 7647-01-0 is considered highly hazardous by OSHA.STATECAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:CRisk Phrases:R 34 Causes burns.Safety Phrases:S 26 In case of contact with eyes, rinse immediatelywith plenty of water and seek medical advice.S 45 In case of accident or if you feel unwell, seekmedical advice immediately (show the label wherepossible).WGK (Water Danger/Protection)CAS# 7647-01-0: 1CAS# 7732-18-5: No information available.CanadaCAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.This product has a WHMIS classification of D2A, E.CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.Exposure LimitsCAS# 7647-01-0: OEL-AUSTRALIA:TWA 5ppm (7mg/m3) OEL-AUSTRIA:TWA 5ppm (7mg/m3) OEL-BELGIUM:STEL 5ppm (7.7mg/m3) OEL-DENMARK:STEL 5ppm (7mg/m3) OEL-FINLAND:STEL 5ppm (7mg/m3);Skin OEL-FRANCE:STEL 5ppm (7.5mg/m3) OEL-GERMANY:TWA 5ppm (7mg/m3) OEL-HUNGARY:STEL 5 mg/m3 OEL-JAPAN:STEL 5ppm (7.5mg/m3) OEL-THE NETHERLANDS:TWA 5ppm (7mg/m3) OEL-THE PHILIPPINES:TWA 5ppm (7mg/m3) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:STEL 5ppm (5mg/m3) OEL-SWEDEN:STEL 5ppm (8mg/m3) OEL-SWITZERLAND:TWA 5ppm (7.5 mg/m3);STEL 10ppm (15mg/m3) OEL-THAILAND:TWA 5ppm (7mg/m3) OEL-TURKEY:TWA 5ppm (7mg/m3) OEL-UNITED KINGDOM:TWA 5ppm (7mg/m3);STEL 5ppm (7mg/m3) OEL IN BULGARIA,COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV16) Additional InformationMSDS Creation Date: 7/06/1999Revision #2 Date: 8/02/2000The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.5.3.2盐酸1)化学品名称化学品中文名称:盐酸化学品英文名称:hydrochloric acid中文名称2:氢氯酸英文名称2:chlorohydric acid分子式:HCl分子量:36.46健康危害:接触其蒸气或烟雾,可引起急性中毒,出现眼结膜炎,鼻及口腔粘膜有烧灼感,鼻衄、齿龈出血,气管炎等。
化学品安全技术说明MSDS亚硫酸氢钠中英文对照版本样本
5.3.5 Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500, S447-3, S447-500, S4473, S447500Synonyms: Sulfurous acid, disodium salt2) Composition, Information on IngredientsHazard Symbols: XNRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemical conjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomitingand diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wearappropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.Extinguishing Media:Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.7) Handling and StorageHandling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.Exposure LimitsOSHA Vacated PELs: Sodium sulfite, Anhydrous: No OSHA Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant arespirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.9) Physical and Chemical PropertiesPhysical State: SolidAppearance: whiteOdor: odorlesspH: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Evaporation Rate: Not available.Viscosity: Not available.Boiling Point: Not available.Freezing/Melting Point: Not available.Autoignition Temperature: Not available.Flash Point: Not available.Decomposition Temperature: > 500 deg CNFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0 Explosion Limits, Lower: Not available.Upper: Not available.Solubility: 23 g/100 mL water (20° C)Specific Gravity/Density: 2.6330g/cm3Molecular Formula: Na2O3SMolecular Weight: 126.0410) Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to air, excess heat.Incompatibilities with Other Materials: Strong oxidizing agents, acids, organics, moisture, air, combustible materials.Hazardous Decomposition Products: Oxides of sulfur.Hazardous Polymerization: Has not been reported.11) Toxicological InformationRTECS#:CAS# 7757-83-7: WE2150000LD50/LC50:CAS# 7757-83-7:Oral, mouse: LD50 = 820 mg/kg;Carcinogenicity:CAS# 7757-83-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: No information available.Teratogenicity: No information available.Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: No information available.Other Studies: No data available.12) Ecological InformationEcotoxicity: No data available. No information available. Environmental: No information found.Physical: No information found.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed.RCRA U-Series: None listed.14) Transport Information15) Regulatory InformationUS FEDERALTSCACAS# 7757-83-7 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List. Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule. Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA. SARASection 302 (RQ)None of the chemicals in this material have an RQ.Section 302 (TPQ)None of the chemicals in this product have a TPQ.SARA CodesCAS # 7757-83-7: acute.Section 313No chemicals are reportable under Section 313.Clean Air Act:This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA.STATECAS# 7757-83-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:XNRisk Phrases:R 22 Harmful if swallowed.R 36/37/38 Irritating to eyes, respiratory systemand skin.Safety Phrases:S 24/25 Avoid contact with skin and eyes.WGK (Water Danger/Protection)CAS# 7757-83-7: 1CanadaCAS# 7757-83-7 is listed on Canada's DSL List. CAS# 7757-83-7 is listed on Canada's DSL List.This product has a WHMIS classification of D2B.CAS# 7757-83-7 is not listed on Canada's Ingredient Disclosure List. Exposure Limits16) Additional InformationMSDS Creation Date: 7/15/1999Revision #1 Date: 8/02/The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplarydamages, howsoever arising, even if Fisher has been advised of the possibility of such damages.5.3.5亚硫酸氢钠1) 化学品名称化学品中文名称: 亚硫酸氢钠化学品英文名称: sodium bisulfite中文名称2: 酸式亚硫酸钠英文名称2: hydrogen sulfite sodium分子式: NaHSO3分子量: 104.062) 成分、组成信息3) 危险性概述健康危害: 对皮肤、眼、呼吸道有刺激性, 可引起过敏反应。
MSDS标准范本中英文对照
MSDS范本 中英文对照 (2007‐07‐19 12:05:43)MATERIAL SAFETY DATA SHEET1 PRODUCT AND COMPANY IDENTIFICATIONProduct name (Chinese): S‐3Product popular name: 783慢干水Product name (English): SolventCorporation name:Address:Postcode:Email address:Telefax:2 COMPOSITION /INFORMATION ON INGREDIENTSChemical name:Composition: concentration (%)Ketone solvent: 100%Heavy metal content: <5ppm (comply with standard EN.71)3 USE SUMMARIZEMainly used in:4 HAZARDS IDENTIFICATIONSpecies Hazards: Medium flash point, highly flammable liquidInvade way: Inhalation, skin contact, ingestionHealthy effect: Repeat, high concentration and abundantly contact may cause narcosis and harm to haematogenous system.Fire risk: Highly flammable, the vapours and air may form ofvolatile mixture which mayburn or blast when it exposes in sources of ignition or high temperature.5 FIRST‐AID MEASURESSkin contact: Remove immediately any soiled or soaked clothing. WashSkin with plenty of water and soap.Eye contact: Wash open eyes immediately, abundantly and consult adoctor if needed.Inhalation: Move patient from contaminated area to fresh air.Ingestion: Drink abundant warm water in order to try to vomit.Consult a doctor if needed.6 FIRE‐FIGHTING MEASURESSpecific hazards: The vapors and air may form of volatile mixture whichmay burn or blast when it exposes in sources of ignitionor high temperature. The vapors are heavier than air, sothey could widely spread. Static discharges may createand accumulate when the fluid of the product is too fast.Harmful burning waste: CO, NO2Extinguishing media:Suitable: Foam, CO2, dry power or soil.Not suitable: Water jet.Other information: Acid‐alkaline extinguisher is invalid, water spraycould be used in small fire.7 ACCIDENTAL RELEASE MEASURESRelease measures: Cut off electrical source and leave the contaminatedarea for safety place. People who treat with theaccident will wear respirator and gasproof clothes andnot go into cloacae, drain where it is too small space.Methods for cleaning‐up:Collect the residues in close containers.Cover with sand, active carbon or other inert materialsup the residues.Use latex made up of nonflammable Dispersant.Work notice: Ensure adequate aeration.Keep away from all sources of ignition and oxide. Do not smoke.People need to wear respirator, gasproof clothes, unpermeablegloves and eye protection glasses.The fluid of production will low than 5m/s.Install electrical wire touched floor and keep staticdischarges from accumulating.Avoid package broken.Storage notice: Store in shady, cool and ventilated warehouse where the temperature is lower than 35℃. Keep away from all sources of ignition and heat. Keep containers close and away from oxide and chemical edible. The instrument and machine which can make spark are forbidden. The accidental release measures instrument and containers shall be supplied with in warehouse.8 EXPOSURE CONTROLS / PERSONAL PROTECTIONThreshold limit value: ≤100ppmInspect method: gas chromatograph (GC)Engineering control: Be hermetic, ensure adequate aeration.Respiratory protection: Wear a respirator if the vapors concentration is too high.Eye protection: Eye/face protection glasses.Body protection: Wear work clothes.Hand protection: Impermeable gloves.Other information: Do not smoke, ingest and drink water in workshop. Do not drink wine before working and bath after working. Check body in schedule.9 PHYSICAL AND CHEMICAL PROPERTIESPhysical state: LiquidColor: YellowwishpH: 6.5‐7.5Flash point (℃): 5810. STABILITY AND REACTIVITYStability: Stable at normal temperature of storage, handling and use.Conditions to avoid: Flame, high temperature.Hazardous reactions: Unactable11. TOXICOLOGICAL INFORMATIONAcute toxicity: N/AIrritancy: N/ABiodegradation: N/Adisbiodegradation: N/A12. HANDLING AND STORAGEHandling: Ensure adequate aeration.Be far away from oxide.Storage: Store in shady and cool area.Keep containers hermetically sealed.Keep away from all source of ignition.13. DISPOSAL CONSIDERATIONWaste information: Hazards wasteWaste disposal: Ignition under control.Disposal notice: Disposal area must comply with the environment and national safety standard.Transportation information: Do transportation in the morning and night in summer.14. REGULATION INFORMATIONRegulation information: Directive “Chemical hazards regulation” (Directive 2/17/1987), aim at safe production, use, storage, transportation etc.Directive GB13690‐92. The product is classified as middle flash liquid (grade 3.2). 15. OTHER INFORMATIONReference:Date: 01/2007Dept.:Check Dept.:Version notice: Some values are selected average value/limit value because of many breed of products.16. NATIONAL EMERGENCY TELEPHONE NUMBERFire‐alarm: 119 First‐aid: 120物质安全资料表第一部分 化学品及企业标识化学品中文名称: S‐3化学品俗名或商品名: 783 慢干水化学品英文名称:企业名称:地址:邮编:电子邮件地址:第二部分 成分/组成信息化学品名称:成分 含量(%)酮类溶剂 100%重金属含量:<5ppm (符合EN.71标准)第三部分 用途概述主要用途:油墨稀释剂第四部分 危险性概述危险性类别: 中闪点易燃液体侵入途径:吸入、食入、经皮吸收健康危害:长期、大量、高浓度对中枢神经系统具麻醉作用,对造血系统有损害。
化学品安全技术说明书(MSDS中文格式)
MSDS认证报告化学品安全技术说明书(中文格式)第一部分化学品及企业标识化学品中文名:碳酸钠化学品英文名:sodium carbonate生产企业名称:XXX有限公司地址:XXXXXX邮编:XXXXXX企业应急电话:XXXXXX电子邮件地址:XXXXXX技术说明书编码:生效日期:国家应急电话:XXXXXX第二部分成分/组成信息登记号:XXXXXX传真号码:XXXXXX皮肤接触:立即脱去污染的衣着,用大量流动清水冲洗至少15分钟。
就医。
15分钟。
就医。
眼睛接触:立即提起眼睑,用大量流动清水或生理盐水彻底冲洗至少吸入:脱离现场至空气新鲜处。
如呼吸困难,给输氧。
就医。
食入:用水漱口,给饮牛奶或蛋清。
就医。
第五部分消防措施危险特性:具有腐蚀性。
未有特殊的燃烧爆炸特性。
有害燃烧产物:自然分解产物未知。
灭火方法:消防人员必须穿全身耐酸碱消防服。
灭火时尽可能将容器从火场移至空旷处。
第六部分泄漏应急处理应急处理:隔离泄漏污染区,限制出入。
建议应急处理人员戴防尘面具(全面罩),穿防毒服。
避免扬尘,小心扫起,置于袋中转移至安全场所。
若大量泄漏,用塑料布、帆布覆盖。
收集回收或运至废物处理场所处置。
第七部分操作处置与储存操作注意事项:密闭操作,加强通风。
操作人员必须经过专门培训,严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩,戴化学安全防护眼镜,穿防毒物渗透工作服,戴橡胶手套。
避免产生粉尘。
避免与酸类接触。
搬运时要轻装轻卸,防止包装及容器损坏。
配备泄漏应急处理设备。
倒空的容器可能残留有害物。
稀释或制备溶液时,应把碱加入水中,避免沸腾和飞溅。
手防护:戴橡胶手套。
其它防护:及时换洗工作服。
保持良好的卫生习惯。
第九部分理化特性外观与性状:白色粉末或细颗粒(无水纯品),味涩。
分子式:Na2CO3pH值:无意义分子量:105.99熔点(℃):851沸点(℃):无资料辛醇/水分配系数:无资料相对密度(水=1):2.53相对蒸气密度(空气=1):无资料闪点(℃):无意义引燃温度(℃):无意义爆炸下限[%(V/V)]:无意义临界温度(℃):无意义爆炸上限[%(V/V)]:无意义燃烧热(kJ/mol):无意义临界压力(MPa):无意义溶解性:易溶于水,不溶于乙醇、乙醚等。
化学品安全技术说明书(MSDS)中英文对照及翻译完整版
[标签:标题]篇一:化学品安全技术说明MSDS-亚硫酸氢钠(中英文对照版本)5.3.5 Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500,S447-3, S447-500, S4473, S447500Synonyms: Sulfurous acid, disodium saltRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemical conjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anythingby mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon。
MSDS 翻译版
成分
TLV
美国职业安全与卫生 管理局
美国政府工业卫生学家会议来自银 铜 甲苯500ppm
0.01mg/m3 -
0.1mg/m3 0.1mg/m3 188mg/m3
9.物理和化学性能 形状: 气味:
蒸汽压:
蒸汽密度:(空气=1)
比重:
水中可溶度: 沸点:
燃点和方法: 熔点:
燃烧极限:
自然温度:
挥发性有机化合物 (wt%) 10.稳定性和反应 不相容(避免特殊材料)
3/6
准备日期:2008 年 1 月 1 日
个人保护设备。向当地政府汇报溢出时间。准备灭火物质,处理吸收和在其他合适化学废料容器里的废料。处理 后要充分刷洗。要严格控制防止该污染进入任何公共水源系统。以一种持续的合适的机制处理。 大量溢出: 用惰性吸附材料吸收。例如干沙和用防火星的工具转移到容器中。 少量溢出: 用合适的吸附材料吸收和转移到容器中处理。 7.处理和储藏 处理; 当使用这种物质时:(a)避免与眼睛和皮肤接触,可能会通过皮肤吸收。(b)避免吸入该物质;在吃东西或吸烟 前和处理后要彻底清洗。使用良好的通风情况。当处理产品,电池可能会积累或放电。为了减小这种危险,接地 时必须的。用防爆炸通风设备。 储藏: 容器没有设计为承受压力的。不能给容器造成任何物理伤害。不能储藏于接近热源,火星,火焰或热的表面。储 藏于阴暗,凉爽和通风良好的区域。建议储藏于工作场所的外面或隔离区域。储藏于非吸烟区。使用防止爆炸通 风系统和设备。清理容器可能残留的残渣(可燃,蒸发)。不能加压,切割,焊接,铜焊,钻孔,打磨。 8.暴露控制/人员保护 工程控制: 本地 排气通风的使用时推荐控制来源的散发。预防长时间和重复吸入烟雾。使用防爆通风装置。 人员保护:
呼吸防护 在经常使用或过度暴露的情况下,呼吸保护是需要的。呼吸保护的等级从最低到最高。在使用前考虑警示性 能。 任何 化学药筒呼吸器带有器官汽筒 任何 化学药筒呼吸器带有全片的汽筒 任何空气纯净防护面具带有一全面具和汽筒 对于未知高浓度和对生命有立即危险的和健康 任何供气面罩带有一片全面面具和一压力需求或其他主动压力模式在联合分开的逃离供应。
化学品安全技术说明书(MSDS中文格式)
MSDS认证报告化学品安全技术说明书(中文格式)第一部分化学品及企业标识化学品中文名:碳酸钠化学品英文名:sodium carbonate生产企业名称:XXX有限公司地址:XXX XXX邮编:XXX XXX 传真号码:XXX XXX企业应急电话:XXX XXX电子邮件地址:XXX XXX技术说明书编码:登记号:XXX XXX生效日期:国家应急电话:XXX XXX第二部分成分/ 组成信息纯品√混合物×有害物成分浓度CAS No.碳酸钠497-19-8第三部分危险性概述危险性类别:侵入途径:吸入、食入、经皮吸收健康危害:本品具有刺激性和腐蚀性。
直接接触可引起皮肤和眼灼伤。
生产中吸入其粉尘和烟雾可引起呼吸道刺激和结膜炎,还可有鼻粘膜溃疡、萎缩及鼻中隔穿孔。
长时间接触本品溶液可发生湿疹、皮炎、鸡眼状溃疡和皮肤松驰。
接触本品的作业工人呼吸器官疾病发病率升高。
误服可造成消化道灼伤、粘膜糜烂、出血和休克。
环境危害:燃爆危险:本品不燃,具腐蚀性、刺激性,可致人体灼伤。
第四部分急救措施皮肤接触:立即脱去污染的衣着,用大量流动清水冲洗至少15分钟。
就医。
眼睛接触:立即提起眼睑,用大量流动清水或生理盐水彻底冲洗至少15 分钟。
就医。
吸入:脱离现场至空气新鲜处。
如呼吸困难,给输氧。
就医。
食入:用水漱口,给饮牛奶或蛋清。
就医。
第五部分消防措施危险特性:具有腐蚀性。
未有特殊的燃烧爆炸特性。
有害燃烧产物:自然分解产物未知。
灭火方法:消防人员必须穿全身耐酸碱消防服。
灭火时尽可能将容器从火场移至空旷处。
第六部分泄漏应急处理应急处理:隔离泄漏污染区,限制出入。
建议应急处理人员戴防尘面具(全面罩),穿防毒服。
避免扬尘,小心扫起,置于袋中转移至安全场所。
若大量泄漏,用塑料布、帆布覆盖。
收集回收或运至废物处理场所处置。
第七部分操作处置与储存操作注意事项:密闭操作,加强通风。
操作人员必须经过专门培训,严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩,戴化学安全防护眼镜,穿防毒物渗透工作服,戴橡胶手套。
(完整版)危险化学品安全技术说明书(MSDS)手册
(完整版)危险化学品安全技术说明书(M S D S)手册-CAL-FENGHAI-(2020YEAR-YICAI)_JINGBIAN危险化学品安全手册(最新版)专版危险化学品MSDS手册目录1.酒精 (3)2.异丙醇 (6)3.硫酸 (13)4.盐酸 (17)5.浓硫酸 (24)6.甲醛................................................................... ............. .... . (30)7.高锰酸钾................................................................................ (35)8.次氯酸钠.................................................................................. . (41)9.二甲苯 (45)10.邻菲罗啉 (52)11.硫酸汞 (53)12.硫酸亚铁 (58)13.硫酸亚铁铵 (63)14.硫酸银 (67)15.片碱 (71)16.液碱 (76)17.氢氧化钠 (79)18.乙二醛 (83)19.重铬酸钾 (88)20.过氧乙酸 (92)21.冰乙酸 (96)1、化学品名称:酒精 No.:MSDS-01一、标识中文名乙醇;酒精英文名 ethyl alcohol;ethanol分子式 C2H6O相对分子质量 46.07CAS号 64-17-5结构式 CH3CH2OH危险性类别第3.2类中闪点易燃液体化学类别醇二、主要组成与性状主要成分纯品外观与性状无色液体,有酒香。
主要用途用于制酒工业、有机合成、消毒以及用作溶剂。
三、健康危害侵入途径:吸入、食入、经皮吸收。
健康危害:本品为中枢神经系统抑制剂。
首先引起兴奋,随后抑制。
急性中毒:急性中毒多发生于口服。
化学品安全技术说明书(MSDS)
化学品安全技术说明书(M S D S)Propane丙烷C3H8UNNO.1208生产(或贮存)场所最大数量CNNO.32162○无色气体,微溶于水,易溶于醇、醚等有机溶剂。
○易燃气体。
与空气混合能形成爆炸性混合物,遇热源和明火有燃烧爆炸的危险。
○毒性:属中等毒类。
侵入途径:吸入。
○储存于阴凉、通风仓间内。
仓温不宜超过30℃。
○远离火种、热源。
防止阳光直射。
○应与氧化剂、酸类、碱类、卤素分开存放。
○储存间内的照明、通风等设施应完善。
○泄漏污染区人员至安全区。
○切断气源。
○戴正压自给式呼吸器,穿化学防护服。
○迅速脱离现场至空气新鲜处。
呼吸困难时给输氧。
呼吸停止者,立即进行人工呼吸(勿用口对口)。
○脱去污染的衣着,用流动清水冲洗。
○就医。
○切断气源。
○泡沫、二氧化碳、干粉、砂土。
防护措施法律法规○化学危险物品安全管理条例(2002年1月26日国务院发布)。
○工作场所安全使用化学品规定(劳部发[1996]423号)等法规,针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定。
○常用危险化学品的分类及标志(GB13690-92)将该物质划为第2.1类易燃气体。
具有燃烧性、爆炸性危险性储运要求泄漏处理急救灭火方法化学品安全技术说明书(MSDS )1,2-Xylene 二甲苯 C 8H 10UNNO.1307 生产(或贮存)场所最大数量CNNO.33538○无色透明液体,不溶于水,易溶于醇、醚等有机溶剂○对皮肤、粘膜有刺激作用,对中枢神经系统有麻醉作用。
○长期作用可影响肝、肾功能。
急性中毒:病人有咳嗽、流沮、结膜充血等重症者有幻觉、谵妄、神志不清等,有的有癔病样发作。
○慢性中毒:病人有神经衰弱综合征的表现,女工有月经异常,工人常发生皮肤干燥、皲裂、皮炎。
○储存于阴凉、通风仓间内。
远离火种、热源。
仓温不宜超过30℃。
○防止阳光直射。
保持容器密封。
应与氧化剂分开存放。
○储存间内的照明、通风等设施应采用防爆型,开关设在仓外。
详细化学品安全技术说明书(MSDS)
化学品安全技术说明书二〇〇六年二月目录表1-001 乙炔气 (1)表1-002 氧气 (5)表1-003 二氧化碳 (11)表1-004 氢气 (13)表1-005 氩气 (15)表1-006 甲烷 (17)表1-007 四氢噻吩 (19)表1-008 活性炭 (21)表1-009 三乙胺 (23)表1-010 硫代磷酰氯 (25)表1-011 硫黄 (27)表1-012 甲胺磷 (30)表1-013 多聚甲醛 (32)表1-014(附表1-3)甲缩醛34 表1-015 黄磷 (36)表1-016 氯 (38)表1-017 三氯化磷 (41)表1-018 甲醇 (45)表1-019 液碱 (47)表1-020 氨水 (49)表1-021 硫酸二甲酯 (52)表1-022 甲胺磷 (54)表1-023 液氨 (57)表1-024 氯仿 (59)表1-025 二氯乙烷 (61)表1-026 二硫化碳 (64)表1-027 甲苯 (66)表1-028 盐酸 (68)表1-029 氯甲烷 (71)表1-030 硫酸 (73)表1-031 二甲苯 (76)表1-032 醋酸酐 (78)表1-033 多聚甲醛 (81)表1-034 草甘膦 (82)表1-035 稻瘟灵 (84)表1-036 异丙胺 (86)表1-037 漂白粉 (88)表1-038 氯化氢 (90)表1-039 氰化氢 (93)表1-040 氰化钠 (95)表1-041 氯乙酸 (97)表1-042 甲缩醛 (99)表1-043 丙烯腈 (102)表1-044 氧化亚铜 (104)表1-045 四氯化锡 (106)表1-046 四氧化三铅 (108)表1-047 三氯化铝(无水) 111 表1-048 松香水 (113)表1-049红丹油性防锈漆 .. 114 表1-050 酚醛树脂 (116)表1-051 硫磺粉(补充) (117)表1-052 一乙胺 (119)表1-053三聚氯氰 (121)表1-054 三氯乙烯 (123)表1-055 磷酸 (125)表1-056 四丁基锡 (127)表1-057 柴油 (129)表1-058 对氨基苯酚 (131)表1-059 醋酸乙酯 (133)表1-060 对氯硝基苯 (135)表1-061 氮气 (136)表1-062莠去津 (140)表1-063 扑草净 (141)表1-064 八氯二丙醚 (143)表1-065 硫化钠 (145)表1-066 异丙醇 (148)表1-067 丙酮 (150)表1-068 二氯丙烷 (152)表1-069 环己酮 (154)表1-070 乙酸异戊酯 (156)表1-071 锌粉 (158)表1-072 乙醇 (160)表1-073 次氯酸钠溶液 (163)表1-074 石脑油 (164)表1-075 双环戊二烯 (167)表1-076 乙酸丁酯 (168)表1-077 双氧水 (170)表1-078 丙烯酸丁酯 (173)表1-079 丙烯酸 (175)表1-080 苯乙烯 (177)表1-081 过硫酸铵 (179)表1-082 过硫酸钾 (181)表1-083 丙烯酰胺 (183)表1-084 甲醛 (185)表1-085 甲基丙烯酸甲酯.. 187 表1-086 甲基丙烯酸 (189)表1-087 汽油 (192)表1-088 乙酸 (194)表1-089 丙烯酸树脂 (196)表1-090 丙烯酸清漆 (198)表1-091 丙烯酸漆稀释剂.. 199 表1-092 丙烯酸磁漆 (201)表1-093 二乙醇胺 (203)表1-094 煤油 (205)表1-095 漂白粉 (206)表1-096 漂粉精 (208)表1-097 三氯异氰尿酸 (210)表1-098 松香 (212)表1-099 松节油 (213)表1-100 硫化钠 (215)表1-101 保险粉 (217)表1-102 7385聚氨酯清漆(分装) (219)表1-103 甲酸 (221)表1-104 乙酸乙二醇乙醚.. 223 表1-105 H-3聚氨酯漆固化剂 (225)表1-106 聚氨酯漆稀释剂.. 226 表1-107 263醇酸树脂 (228)表1-108 异噻唑啉酮 (229)表1-109 N-乙基苯胺 (231)表1-110苯胺 (233)表1-111 乙酰甲胺磷 (235)表1-112 亚磷酸 (237)表1-113 亚磷酸二甲酯 (239)表1-114 氯甲烷 (242)表1-115 乙醚 (244)表1-116 丙烯酸甲酯 (246)表1-117 一甲胺 (248)表1-118 硝酸镁 (250)表1-119 硫化氢 (252)表1-120 硫化铵 (254)表1-121 一甲胺水溶液 (256)表1-122 兔宝宝面漆 (257)表1-123 兔宝宝稀释剂 (259)表1-124 硫氢化钠 (261)表1-125丙酸 (262)表1-126乙酰氯 (264)表1-127丙酰氯 (266)表1-128 丁醇 (268)表1-129 醇酸调合漆(未列名) (270)表1-129 碳化钙、电石 (272)表1-130 硝酸钠 (273)表1-131 溴甲烷 (275)表1-132 磷化铝 (278)表1-133 正丁醇 (280)表1-134 硝基木器漆 (282)表1-135 硝化棉(含氮≤12.6%) (283)表1-136 单丁醚 (285)表1-137 砷 (287)表1-138 碘化汞 (289)表1-139 氯化汞 (291)表1-140 叠氮化钠 (293)表1-141 重铬酸钠 (294)表1-142 高锰酸钾 (296)表1-143 氰化金钾 (299)表1-144丙烯酸 (301)表1-145甲基丙烯酸甲酯 .. 303 表1-146苯乙烯 (305)表1-147丙烯酸丁酯 (307)表1-148丁醇 (309)表1-149偶氮二异丁腈 (311)表1-150甲基丙烯酸异丁酯313 表1-151 甲基丙烯酸(正)丁酯 (315)表1-152 乙酰丙酮 (316)表1-153 2-丁酮 (318)表1-154 生松香 (320)表1-155 硫酸铜 (322)表1-155 硝酸 (324)表1-155 氰化钾 (326)表1-156硝基苯 (328)表1-157 氟化钠 (330)表1-158 氢氟酸 (332)表1-159蓄电池(注有酸液) (334)表1-160 环氧树脂 (335)表1-161 氯苯 (337)表1-162 乙苯 (340)表1-163 樟脑 (342)表1-164 赛璐珞 (344)表1-165 氢氧化钾 (345)表1-166 乙酸丁酯 (347)表1-001 乙炔气表1-002 氧气表1-003 二氧化碳表1-004 氢气表1-005 氩气表1-006 甲烷表1-007 四氢噻吩表1-008 活性炭活性炭 C 12.0Active carbon别名:Activated chlarcoal危规分类及编号:自燃物品。
MSDS(中英文对照)
**** MATERIAL SAFETY DATA SHEET ****快件声明物安全特性报告MSDS Name (报告物名称)Air Way Bill (运单号)**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****第一部分化工产品及发件单位MSDS Name(报告物名称):Catalog Numbers(化工品分类号):Synonyms(又名):Company Identification(发件公司名称):For information, call(一般联系电话):For emergencies, call(应急联系电话):**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****成份特点Hazard Symbols(危险特性):Risk Phrases(危险条件):**** SECTION 3 - HAZARDS IDENTIFICATION ****危险特征EMERGENCY OVERVIEW 概述Eye眼睛:Skin皮肤:Ingestion误食:Inhalation吸入:Chronic可否引起慢性疾病:**** SECTION 4 - FIRST AID MEASURES ****应急医疗救治Eyes眼睛:Skin皮肤:Ingestion误食:Inhalation吸入:Notes to Physician给内科医生的建议:**** SECTION 5 - FIRE FIGHTING MEASURES ****消防扑救方法**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****事故处理General Information:一般信息:Spills/Leaks泄露/溢出:.**** SECTION 7 - HANDLING and STORAGE ****处理和存放Handling处理:Storage存储:**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****安全控制和人员保护Engineering Controls机械控制:Personal Protective Equipment个人防护**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****Physical State(物理状态): Color(颜色):Odor(味道): pH:Vapor Pressure(蒸汽压力): Viscosity(黏度): Boiling Point(沸点): Freezing/Melting Point(冰点): Autoignition Temperature(自燃温度): Flash Point(闪点):Explosion Limits, lower(爆炸极限,低): Explosion Limits, upper(爆炸极限,高):Decomposition Temperature(分解温度): Solubility in water(溶解度): Specific Gravity/Density(特定浓度): Molecular Formula(分子式): Molecular Weight(分子重量):**** SECTION 10 - STABILITY AND REACTIVITY ****稳定性和活性Chemical Stability化学稳定性:Conditions to Avoid: 应避免的环境**** SECTION 11 - TOXICOLOGICAL INFORMATION ****毒性信息RTECS#(毒性数据号码):**** SECTION 12 - ECOLOGICAL INFORMATION ****生态学信息**** SECTION 13 - DISPOSAL CONSIDERATIONS ****销毁建议**** SECTION 14 - TRANSPORT INFORMATION ****空运信息Reported by: (报告人)Company Name : _______________________ Date: ____________________公司名称:日期:Authorized Person: _________________ Signature: ______________________ 报告人签名:。
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完整版)化学品安全技术说明书(MSDS)中英文对照及翻译完整版剔除格式错误和明显有问题的段落,改写如下:XX公司XX nMaterial Safety Data ___化学品安全技术说明书SECTION 1: ___化学品及企业标识PRODUCT NAME:产品名CAS NO.:SUPPLIER:供应商:___:企业应急SECTION 2: HAZARDS ___危险性概述2.1 CLASSIFICATION OF ___物质分类This substance is ___(EC) No 1272/2008.根据(EC) No 1272/2008规定此物质不属于危险品。
2.2 LABEL ELEMENTS标记要素The product does not require special ___.此产品不需要按照___法则或各国法规进行特殊标签。
2.3 OTHER HAZARDS – NONE其他危害n ___: drug abuse侵入途径:误服___ HAZARDS健康危害Eye contact: May cause eye ___。
redness。
___.眼接触:可引起眼睛刺激、发红、流泪、视力模糊。
Skin contact: May cause skin ___ contact may cause skin degrease.皮肤接触:可引起皮肤刺激和皮炎。
长时间接触可能导致皮肤脱脂。
Refer to ns 7.8 and 13 for further n on handling。
___ of the product。
Always follow ___ necessary。
6.1 Personal ns。
______ dust and avoid inhaling vapours。
mist or gas。
___ 8.6.2 Environmental nsIf safe to do so。
take ___。
6.3 ___ upTo clean up the spilled product。
pick it up and dispose of it without ___。
___6.4 ___For more n on handling。
personal n。
and disposal of the product。
refer to ns 7.8.and 13.Always follow proper safety res and ___.n 7: Handling and StorageTo ensure safe handling。
___。
please refer to n 2.2.When storing the product。
keep it in a cool place and make sure thecontainer is tightly closed in a dry and well-ventilated area。
It is important to note that the product is ___.n 8: ___There are no specific uses for the product other than those ned in n 1.2.When handling the product。
it is important to follow good industrial ___ breaks and at the end of the workday.In terms of exposure controls。
appropriate engineering controls should be put in place。
___.Engineering control is an ___ should be in place to ___.___ (PPE) is also essential。
Eye and face n is particularly important。
___ such as NIOSH (US) or EN 166 (EU)。
This will ___.___ should be used to avoid skin contact with the product。
___.___ and the standard EN 374 derived from it。
Nitrile rubber gloves are a good choice for full contact with hazardous materials.___ should be based on the ___ workplace.___。
but if n from nuisance levels of dust is required。
it is mended to use type N95 (US) or type P1 (EN 143) dust masks。
It is ___ (US) or CEN (EU).To control environmental exposure。
it is ___ spillage if it is safe to do so。
Avoid letting the product enter drains and avoid discharging it into the ___.In the n regarding physical and chemical properties。
it is ___.Odour: No data available.___: No data available.pH: At 50 g/l at 20°C。
the pH ranges from 5.2 to 8.___: The melting point or range is 884°C.___: No data available.Flash Point: Not applicable.___: No data available.Flammability (Solid。
Gas): No data available.___: No data available.Vapour Pressure: No data available.Vapour Density: No data available.Relative Density: At 25°C。
the relative density is 2.68 g/mL. Water Solubility: It is either ___.n Coefficient: n-___: No data available.n ___: No data available.n ___: No data available.Viscosity: No data available.Explosive Properties: No data available.Oxidizing Properties: No data available.Other Safety n: The bulk density is 1.400 kg/m3. 体积密度稳定性和反应活性10.1 反应活性无可用数据。
10.2 化学稳定性在建议的储存条件下稳定。
10.3 危险反应的可能性无可用数据。
10.4 应避免的条件高温、火源。
10.5 不相容的物质强酸、铝、镁。
10.6 危险的分解产物其他分解产物-无可用数据。
禁忌物:强氧化剂、强酸、强碱。
XX公司禁忌物:强氧化剂、强酸、强碱。
毒理学资料11.1 毒理学效应的信息急性毒性半数致死剂量(LD50)-经口-小鼠-5,989 mg/kg本品对皮肤和粘膜的刺激作用比甲苯强,高浓度时对中枢神经系统有麻醉作用。
The n EC50 for Daphnia after 48 hours was 3,150.21 mg/l.There is no available data on the ___ of the chemical.There is also no available data on the -___.As the chemical safety assessment was not required or conducted。
there is no available PBT/vPvB assessment.The chemical is ___.To dispose of the product。
offer surplus and non-___.Alternatively。
send the product to the ___.13.3 废弃注意事项:废物的贮存和处置应遵守国家和地方的环保法规。
受污染的包装物应按未使用产品处理。
XX公司第14节:运输信息14.1 ___危险货物编号ADR / RID:- IMDG:- ___:- 14.2 ___适当的运输名称ADR / RID:非危险品IMDG:非危险品___:非危险品14.3 运输危险类别ADR / RID:- IMDG:- ___:- 14.4 包装组ADR / RID:- IMDG:- ___:- 14.5 环境危害ADR / RID:无 IMDG海洋污染物:无 IATA:无14.6 对用户的特殊注意事项运输注意事项:避免船舶泄漏,必须轻装轻卸。
夏季应在早晨或晚上运输,以防止阳光直射。
并且应按照运输路线的相关规定进行运输。