伊士曼功能树脂之应用
合集下载
相关主题
- 1、下载文档前请自行甄别文档内容的完整性，平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益，请联系客服反馈,我们会尽快为您处理(人工客服工作时间：9:00-18:30)。
Note: “OEM” is original equipment manufacturer
5
6
Eastman tire additives
Setting the standard for innovation
7
Defining the unmet needs
Tire development challenge
Approach
Introduction to Eastman Impera™ performance resin portfolio and discussion on desired tire performance, tread reformulation options and the impact of Impera™ on viscoelastic properties
1,000.000
Natural rubber
Glass transition temperature (˚K)
Polystyrene
400 350 300 250 200 150 100 50
Molecular weight (g/mol)
100.000
SBR
SIS - block copolymer
Wear or Noise
Rolling resistance
Eastman Impera™ performance resins are selected to enhance wet grip while maintaining rolling resistance
Standard performance triangle WG optimized without performance resins WG optimized with performance resins
Desired Outcome
Both teams identify potential synergies and some Impera™ performance resins are sampled to be evaluated in Company Name PCR tread compounds
3% Electronics
15% Tobacco 3% Other
11% Industrial Chemicals & Processing
2% Agriculture
3% Energy, Fuels & Water
7% Durable Goods
7% Health & Wellness
*Does not include revenue from Taminco or Commonwealth Laminating and Coating
Eastman is the world’s leading manufacturer of pure monomer and hydrogenated hydrocarbon resins. The Impera portfolio includes our best resins for improving wet grip while maintaining or improving rolling resistance.
Polypropylene PVC
10.000 1.000
Processing oils
100 -100
Tg, ˚C
0 100 200
101
102
103
104
105
Molecular weight (g/mol)
10
What are performance resins?
Materials that modify the viscoelastic profile of polymers, resulting in compounds with modified properties (e.g. glass transition behavior, dynamic modulus) without negatively impacting mechanical properties They are produced from petrochemical or natural feedstock
Wet grip
Regulations and tire labeling drives reformulation to optimize performance Many leverage technology in polymers, additives, and fillers Additives are vital to fine-tune tread performance at relatively low loading levels
12
Eastman Impera™ performance resins
Product portfolio
Suggested Application
Product
Impera™ E1501 Impera™ E1502 Impera™ P1503 Impera™ P1504 Impera™ P1505
Global locations and headquarters
3
Diversified product lines & technologies
2014 sales revenue by market
16% Building & Construction
4
15% Coຫໍສະໝຸດ Baidusumables 18% Transportation
Your name and title/function during meeting Other…
Names and titles/functions during meeting Others…
Objective
Understand Company Name PCR tread performance requirements and introduce Eastman’s performance resins to determine if further evaluation can enable improved tire performance.
Hydrocarbon resin (HCR)
• Aliphatic, aromatic, mixed aliphatic-aromatic • Styrene and/or AMS pure monomer resin (PMR)
Coumarone-Indene
• Derived from coal coke
3
G'
1E+8
2
G' (Pa)
tan
1E+7
WG better RR better
1E+6
tan
Both oil and resin soften the rubbery modulus
1
1E+5 -40 -20 0 20 40 60
0
Temperature (° C)
Adding HCR results in significant shift of Tg to higher temperature and significantly wet grip without much loss in rolling resistance
High-performance auto tint
► Saflex® ► Interlayer glass laminate
► Impera™ performance ► resins
Additives for tires
► Solus® ► Performance additives
► Santoflex® ► Antidegradants for tires ► Eastman plasticizers
Impera™ performance resins can enable tread compounders to have a balanced performance – significantly improving WG without sacrificing RR and wear
9
Resins usage in tires
Flexible underbody coatings
► Crystex® ► Vulcanizing agent for tires ► Eastman adhesion promoters
TPO bumper primers/coatings
► Eastman cellulose esters ► Performance additives
Customer name, location
1
2
Proposed discussion guide
Eastman Impera™ performance resins – meeting location meeting date and time
Eastman participants
Target/customer participants
Description
Hydrogenated Hydrogenated Aromatic Aromatic Aromatic
Softening point
100°C 100°C 100°C 85°C 140°C
WG/RR balance for UHP, HP, AS, Summer tires
Handling & traction in racing tires
• High silica sSBR/BR (70/30) PCR tread • Carbon black sSBR/BR (70/30) PCR tread • Carbon black NR/sSBR (70/30) light truck tread
8
Significance of wet grip
Standard EU tire label
Comparison of braking distances on wet roads
72m
Well-balanced tire
82m
Tire designed with focus on low rolling resistance
5
Transportation is a strategic focus
Innovative products in attractive market segments
► Eastman Solvents
Automotive OEM coatings
► ►
OEM After Market
► LLumar® V-KOOL®
Natural rosins and Polyterpene resin
• Derived from gum rosins
11
How performance resins work
1E+9 Oil Resins
Control Control + resin Control + TDAE oil
13
Tire tread application results
Performance resin used as oil replacement
Application data for Eastman’s performance resins in three tire tread formulations
Resins have been used in tires for decades primarily for benefits during mixing (viscosity), tire building (tack) and curing (crosslinking) “Resin” is a very generic term applied to polymeric materials with: • Relatively small molecular weight, Mn range: ~ 500 – 1500 g/mol • High Tg in comparison to molecular weight
5
6
Eastman tire additives
Setting the standard for innovation
7
Defining the unmet needs
Tire development challenge
Approach
Introduction to Eastman Impera™ performance resin portfolio and discussion on desired tire performance, tread reformulation options and the impact of Impera™ on viscoelastic properties
1,000.000
Natural rubber
Glass transition temperature (˚K)
Polystyrene
400 350 300 250 200 150 100 50
Molecular weight (g/mol)
100.000
SBR
SIS - block copolymer
Wear or Noise
Rolling resistance
Eastman Impera™ performance resins are selected to enhance wet grip while maintaining rolling resistance
Standard performance triangle WG optimized without performance resins WG optimized with performance resins
Desired Outcome
Both teams identify potential synergies and some Impera™ performance resins are sampled to be evaluated in Company Name PCR tread compounds
3% Electronics
15% Tobacco 3% Other
11% Industrial Chemicals & Processing
2% Agriculture
3% Energy, Fuels & Water
7% Durable Goods
7% Health & Wellness
*Does not include revenue from Taminco or Commonwealth Laminating and Coating
Eastman is the world’s leading manufacturer of pure monomer and hydrogenated hydrocarbon resins. The Impera portfolio includes our best resins for improving wet grip while maintaining or improving rolling resistance.
Polypropylene PVC
10.000 1.000
Processing oils
100 -100
Tg, ˚C
0 100 200
101
102
103
104
105
Molecular weight (g/mol)
10
What are performance resins?
Materials that modify the viscoelastic profile of polymers, resulting in compounds with modified properties (e.g. glass transition behavior, dynamic modulus) without negatively impacting mechanical properties They are produced from petrochemical or natural feedstock
Wet grip
Regulations and tire labeling drives reformulation to optimize performance Many leverage technology in polymers, additives, and fillers Additives are vital to fine-tune tread performance at relatively low loading levels
12
Eastman Impera™ performance resins
Product portfolio
Suggested Application
Product
Impera™ E1501 Impera™ E1502 Impera™ P1503 Impera™ P1504 Impera™ P1505
Global locations and headquarters
3
Diversified product lines & technologies
2014 sales revenue by market
16% Building & Construction
4
15% Coຫໍສະໝຸດ Baidusumables 18% Transportation
Your name and title/function during meeting Other…
Names and titles/functions during meeting Others…
Objective
Understand Company Name PCR tread performance requirements and introduce Eastman’s performance resins to determine if further evaluation can enable improved tire performance.
Hydrocarbon resin (HCR)
• Aliphatic, aromatic, mixed aliphatic-aromatic • Styrene and/or AMS pure monomer resin (PMR)
Coumarone-Indene
• Derived from coal coke
3
G'
1E+8
2
G' (Pa)
tan
1E+7
WG better RR better
1E+6
tan
Both oil and resin soften the rubbery modulus
1
1E+5 -40 -20 0 20 40 60
0
Temperature (° C)
Adding HCR results in significant shift of Tg to higher temperature and significantly wet grip without much loss in rolling resistance
High-performance auto tint
► Saflex® ► Interlayer glass laminate
► Impera™ performance ► resins
Additives for tires
► Solus® ► Performance additives
► Santoflex® ► Antidegradants for tires ► Eastman plasticizers
Impera™ performance resins can enable tread compounders to have a balanced performance – significantly improving WG without sacrificing RR and wear
9
Resins usage in tires
Flexible underbody coatings
► Crystex® ► Vulcanizing agent for tires ► Eastman adhesion promoters
TPO bumper primers/coatings
► Eastman cellulose esters ► Performance additives
Customer name, location
1
2
Proposed discussion guide
Eastman Impera™ performance resins – meeting location meeting date and time
Eastman participants
Target/customer participants
Description
Hydrogenated Hydrogenated Aromatic Aromatic Aromatic
Softening point
100°C 100°C 100°C 85°C 140°C
WG/RR balance for UHP, HP, AS, Summer tires
Handling & traction in racing tires
• High silica sSBR/BR (70/30) PCR tread • Carbon black sSBR/BR (70/30) PCR tread • Carbon black NR/sSBR (70/30) light truck tread
8
Significance of wet grip
Standard EU tire label
Comparison of braking distances on wet roads
72m
Well-balanced tire
82m
Tire designed with focus on low rolling resistance
5
Transportation is a strategic focus
Innovative products in attractive market segments
► Eastman Solvents
Automotive OEM coatings
► ►
OEM After Market
► LLumar® V-KOOL®
Natural rosins and Polyterpene resin
• Derived from gum rosins
11
How performance resins work
1E+9 Oil Resins
Control Control + resin Control + TDAE oil
13
Tire tread application results
Performance resin used as oil replacement
Application data for Eastman’s performance resins in three tire tread formulations
Resins have been used in tires for decades primarily for benefits during mixing (viscosity), tire building (tack) and curing (crosslinking) “Resin” is a very generic term applied to polymeric materials with: • Relatively small molecular weight, Mn range: ~ 500 – 1500 g/mol • High Tg in comparison to molecular weight