美国药典中色谱柱编号及填料明细

美国药典规定色谱柱类型

L1：十八烷基键合多孔硅胶或无机氧化物微粒固定相，简称ODS柱L2：30～50mm表面多孔薄壳型键合十八烷基固定相，简称C18柱L3：多孔硅胶微粒，即一般的硅胶柱L4：30～50mm表面多孔薄壳型硅胶柱L5：30～50mm表面多孔薄壳型氧化铝柱L6：30～50mm实心微球表面包覆磺化碳氟聚合物，强阳离子交换柱L7：全多孔硅胶微粒键合C8官能团固定相，简称C8柱L8：全多孔硅胶微粒键合非交联NH2固定相，简称NH2柱L9：强酸性阳离子交换基团键合全多孔不规则形硅胶固定相，即SCX柱L10：多孔硅胶微球键合氰基固定相（CN），简称CN柱L11：键合苯基多孔硅胶微球固定相，简称苯基柱L12：无孔微球键合季胺功能团的强阴离子交换柱L13：三乙基硅烷化学键合全多孔硅胶微球固定相（C1），简称C1柱L14：10mm硅胶化学键合强碱性季铵盐阴离子交换固定相，简称SAX柱L15：已基硅烷化学键合全多孔硅胶微球固定相，简称C6柱L16：二甲基硅烷化学键合全多孔硅胶微粒固定相C2柱L17：氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换柱L18：3～10mm全多孔硅胶化学键合胺基（NH2）和氰基（CN）柱L19：钙型磺化交联苯乙烯－二乙烯基苯共聚物，强阳离子交换柱L20：二羟基丙烷基化学键合多孔硅胶微球固定相（Diol），简称二醇基柱L21：刚性苯乙烯－二乙烯基苯共聚物微球填料柱L22：带有磺酸基团的多孔苯乙烯阳离子交换柱L23：带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换柱L24：表面含有大量羟基的半刚性聚乙烯醇亲水凝胶柱L25：聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。

能分离分子量100～5000MW 范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相L26：丁基硅烷化学键合全多孔硅胶微球固定相，即C4柱L27：30～50mm的全多孔硅胶微粒L28：多功能载体，100Å的高纯硅胶加以氨基键合以及C8反相键合的官能团L29:氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5mm，孔径80ÅL30:全多孔硅胶键合乙基硅烷固定相L31:季胺基改性孔径2000Å的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂L32: L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料L33:能够分离分子量4000～40000MW范围蛋白质分子的球形硅胶固定相, pH稳定性好L34：铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9mm球形L35：锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150ÅL36:5mm胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰L37：适合分离分子量2000～40000MW的聚甲基丙烯酸酯凝胶L38：水溶性甲基丙烯酸酯基质SEC色谱柱L39：亲水全多孔聚羟基甲基丙烯酸酯色谱柱L40：Tris 3,5－二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微球L41：球形硅胶表面固定α1酸糖蛋白固定相L42: C8和C18硅烷化学键合多孔硅胶固定相L43:硅胶微球键合五氟代苯基固定相L44:多功能固定相,60 Å高纯硅胶基质键合磺酸阳离子交换功能团和C8反相功能团L45: β-环糊精键合多孔硅胶微球L46:季胺基改性苯乙烯-二乙烯基苯聚合物微球L1 Octadecyl silane chemically bonded to porous silica or ceramic.L1 十八烷基键合硅烷化学键合于多孔硅胶或陶瓷微粒，3-10u。

美国药典usp L1～L60对应色谱柱类型及型号

下面分别是USPL1～L60的对应。

L1—Octadecyl silane chemically bonded to porous silica or ceramic micro-particles,3to 10µm in diameter.L2—Octadecyl silane chemically bonded to silica gel of a controlled surface porosity that has been bonded to a solid spherical core,30to 50µm in diameter.L3—Porous silica particles,5to 10µm in diameter.L4—Silica gel of controlled surface porosity bonded to a solid spherical core,30to 50µm in diameter.L5—Alumina of controlled surface porosity bonded to a solid spherical core,30to 50µm in diameter.L6—Strong cation-exchange packing–sulfonated fluorocarbon polymer coated on a solid spherical core,30to 50µm in diameter.L7—Octylsilane chemically bonded to totally porous silica particles,3to 10µm in diameter.L8—An essentially monomolecular layer of aminopropylsilane chemically bonded to totally porous silica gel support,10µm in diameter.L9—10-µm irregular or spherical,totally porous silica gel having a chemically bonded,strongly acidic cation-exchange coating.L10—Nitrile groups chemically bonded to porous silica particles,3to 10µm in diameter.L11—Phenyl groups chemically bonded to porous silica particles,5to 10µm in diameter.L12—Astrong anion-exchange packing made by chemically bonding a quaternary amine to a solid silica spherical core,30to 50µm in diameter.L13—Trimethylsilane chemically bonded to porous silica particles,3to 10µm in diameter.L14—Silica gel 10µm in diameter having a chemically bonded,strongly basic quaternary ammonium anion-exchange coating.L15—Hexylsilane chemically bonded to totally porous silica particles,3to 10µm in diameter.L16—Dimethylsilane chemically bonded to porous silica particles,5to 10µm in diameter.L17—Strong cation-exchange resin consisting of sulfonated cross-linkedstyrene-divinylbenzene copolymer in the hydrogen form,7to 11µm in diameter.L18—Amino and cyano groups chemically bonded to porous silica particles,3to 10µm in diameter.L19—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the calcium form,about 9µm in diameter.L20—Dihydroxypropane groups chemically bonded to porous silica particles,5to 10µm in diameter.L21—Arigid,spherical styrene-divinylbenzene copolymer,5to 10µm in diameter.L22—Acation-exchange resin made of porous polystyrene gel with sulfonic acid groups,about 10µm in size.L23—An anion-exchange resin made of porous polymethacrylate or polyacrylate gel with quaternary ammonium groups,about 10µm in size.L24—Asemi-rigid hydrophilic gel consisting of vinyl polymers with numerous hydroxyl groups on the matrix surface,32to 63µm in diameter.5L25—Packing having the capacity to separate compounds with a molecular weight range from 100–5000(as determined by polyethylene oxide),applied to neutral,anionic,and cationic water-soluble polymers.Apolymethacrylate resin base,cross-linked with polyhydroxylated ether (surface contained some residual carboxyl functional groups)was found suitable.L26—Butyl silane chemically bonded to totally porous silica particles,5to 10µm in diameter.L27—Porous silica particles,30to 50µm in diameter.L28—Amultifunctional support,which consists of a high purity,100Å,spherical silica substrate that has been bonded with anionic exchanger,amine functionality in addition to a conventional reversed phase C8functionality.L29—Gamma alumina,reverse-phase,low carbon percentage by weight,alumina-based polybutadiene spherical particles,5µm in diameter with a pore volume of 80Å.L30—Ethyl silane chemically bonded to totally porous silica particles,3to 10µm in diameter.L31—Astrong anion-exchange resin-quaternary amine bonded on latex particles attached to acore of 8.5-µm macroporous particles having a pore size of 2000Åand consisting of ethylvinylbenzene cross-linked with 55%divinylbenzene.L32—Achiral ligand-exchange packing–L-proline copper complex covalently bonded to irregularly shaped silica particles,5to 10µm in diameter.L33—Packing having the capacity to separate dextrans by molecular size over a range of 4,000to 500,000Da.It is spherical,silica-based,and processed to provide pHstability.6L34—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the lead form,about 9µm in diameter.L35—Azirconium-stabilized spherical silica packing with a hydrophilic (diol-type)molecular monolayer bonded phase having a pore size of 150Å.L36—A3,5-dinitrobenzoyl derivative of L-phenylglycine covalently bonded to 5-µm aminopropyl silica.L37—Packing having the capacity to separate proteins by molecular size over a range of 2,000to 40,000Da.It is a polymethacrylate gel.L38—Amethacrylate-based size-exclusion packing for water-soluble samples.L39—Ahydrophilic polyhydroxymethacrylate gel of totally porous spherical resin.L40—Cellulose tris-3,5-dimethylphenylcarbamate coated porous silica particles,5to 20µm in diameter.L41—Immobilized a1-acid glycoprotein on spherical silica particles,5µm in diameter.L42—Octylsilane and octadecylsilane groups chemically bonded to porous silica particles,5µm in diameter.L43—Pentafluorophenyl groups chemically bonded to silica particles by a propyl spacer,5to 10µm in diameter.L44—Amultifunctional support,which consists of a high purity,60Å,spherical silica substrate that has been bonded with a cationic exchanger,sulfonic acid functionality in addition to a conventional reversed phase C8functionality.L45—Beta cyclodextrin bonded to porous silica particles,5to 10µm in diameter.L46—Polystyrene/divinylbenzene substrate agglomerated with quaternary amine functionalized latex beads,10µm in diameter.L47—High-capacity anion-exchange microporous substrate,fully functionalized with trimethlyamine groups,8µm in diameter.7L48—Sulfonated,cross-linked polystyrene with an outer layer of submicron,porous,anion-exchange microbeads,15µm in diameter.L49—Areversed-phase packing made by coating a thin layer of polybutadiene onto spherical porous zirconia particles,3to 10µm in diameter.8L50—Multifunction resin with reversed-phase retention and strong anion-exchange functionalities.The resin consists of ethylvinylbenzene,55%cross-linked with divinylbenzene copolymer,3to 15µm in diameter,and a surface area not less than 350m2per g.Substrate is coated with quaternary ammonium functionalized latex particles consisting of styrene cross-linked with divinylbenzene.9L51—Amylose tris-3,5-dimethylphenylcarbamate-coated,porous,spherical,silica particles,5to 10µm in diameter.10L52—Astrong cation exchange resin made of porous silica with sulfopropyl groups,5to 10µm in diameter.11L53—Weak cation-exchange resin consisting of ethylvinylbenzene,55%cross-linked with divinylbenzene copolymer,3to 15µm diameter.Substrate is surface grafted with carboxylic acid and/or phosphoric acid functionalized monomers.Capacity not less than 500µEq/column.12 L54—Asize exclusion medium made of covalent bonding of dextran to highly cross-linked porous agarose beads,about 13µm in diameter.13L55—Astrong cation-exchange resin made of porous silica coated with polybutadiene–maleic acid copolymer,about 5µm in diameter.14L56—Isopropyl silane chemically bonded to totally porous silica particles,3to 10µm in diameter.15L57—Achiral-recognition protein,ovomucoid,chemically bonded to silica particles,about 5µmin diameter,with a pore size of 120Å.L58—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the sodium form,about 7to 11µm in diameter.16L59—Packing having the capacity to separate proteins by molecular weight over the range of 10to 500kDa.It is spherical (10µm),silica-based,and processed to provide hydrophilic characteristics and pHstability.17USP28L60—Spherical,porous silica gel,3or 5µm in diameter,the surface of which has been covalently modified with palmitamidopropyl groups and endcapped with acetamidopropyl groups to a ligand density of about 6µmoles per m2.18USP28。

USP柱子填料说明

USP色谱柱中文解说实验中常常用到USP作为检验依据，其中有一些关于色谱柱的要求现将其中个色谱柱要求罗列如有不恰当的请大家指正L1和L8是美国药典(USP)规定的色谱柱编号，其实就是C18柱和NH2柱。

下面是对应的色谱柱类型。

L1：十八烷基键合多孔硅胶或无机氧化物微粒固定相，简称C18或ODSL2：30～50um表面多孔薄壳型键合C18(ODS)固定相L3：多孔硅胶微粒即一般的硅胶柱L4：30～50um表面多孔薄壳型硅胶L5：30～50um表面多孔薄壳型氧化铝L6：30～50um实心微球表面包覆磺化碳氟聚合物－强阳离子交换固定相L7：全多孔硅胶微粒键合C8官能团固定相简称C8柱L8：全多孔硅胶微粒键合非交联NH2固定相简称NH2柱L9：强酸性阳离子交换基团键合全多孔不规则形硅胶固定相L10：多孔硅胶微球键合氰基固定相（CN）简称CN柱L11：键合苯基多孔硅胶微球固定相简称苯基柱L12：无孔微球键合季胺功能团的强阴离子填料L13：三乙基硅烷化学键合全多孔硅胶微球固定相（C1）简称C1柱L14:10um硅胶化学键合强碱性季铵盐阴离子交换固定相简称SAX柱L15：已基硅烷化学键合全多孔硅胶微球固定相简称C6柱L16：二甲基硅烷化学键合全多孔硅胶微粒固定相L17：氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换树脂L18: 3～10um全多孔硅胶化学键合胺基（NH2）和氰基（CN）L19：钙型磺化交联苯乙烯－二乙烯基苯共聚物，强阳离子交换树脂L20：二羟基丙烷基化学键合多孔硅胶微球固定相（Diol）简称二醇基柱L21：刚性苯乙烯－二乙烯基苯共聚物微球L22：带有磺酸基团的多孔苯乙烯阳离子交换树脂L23：带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换树脂L24：表面含有大量羟基的半刚性聚乙烯醇亲水凝胶L25：聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。

能分离分子量100～5000MW范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相L26：丁基硅烷化学键合全多孔硅胶微球固定相L27：30～50um的全多孔硅胶微粒L28：多功能载体，100?的高纯硅胶加以氨基键合以及C8反相键合的官能团L29: 氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5um，孔径80?L30: 全多孔硅胶键合乙基硅烷固定相L31: 季胺基改性孔径2000?的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂L32: L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料L33: 能够分离分子量4000～40000MW范围蛋白质分子的球形硅胶固定相,pH稳定性好L34：铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9um球形L35：锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150?L36: 5um胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰L37：适合分离分子量2000～40,000Mw的聚甲基丙烯酸酯凝胶L38：水溶性甲基丙烯酸酯基质SEC色谱柱L39：亲水全多孔聚羟基甲基丙烯酸酯色谱柱L40：Tris 3,5－二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微球L41：球形硅胶表面固定α1酸糖蛋白固定相L42: C8和C18硅烷化学键合多孔硅胶固定相L43: 硅胶微球键合五氟代苯基固定相L44: 多功能固定相,60 ?高纯硅胶基质键合磺酸阳离子交换功能团和C8反相功能团L45: β-环糊精键合多孔硅胶微球L46: 季胺基改性苯乙烯-二乙烯基苯聚合物微球电解质注射液检查项：成分----钠盐、钾盐、钙盐、镁盐，氯离子，还有醋酸盐和乳酸盐（或者醋酸盐和柠檬酸）检查方法：1.钠、钾、钙、镁—原子吸收分光光度法（其中钙和镁应注意浓度以适用于原子吸收）2.氯离子----用0.1mol/L的硝酸银滴定3.醋酸盐---- L17柱（氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换树脂）210nm4.乳酸盐---- L1柱C18或ODS 210nm 4.6mm*10cm分析日常工作注意事项1.实验操作，定量实验时应避免一些太不精确的操作现象，如自身1%对照，吸取0.1ml至10ml、定量限与检测限时应有体现稀释过程的相应图谱等。

符合美国药典的各种分析色谱柱Dr.maisch

氨基和氰基化学键合于多孔微粒硅，粒径3-10u。
Reprosil PAC
USP-L19
由磺化的苯乙烯-二乙烯基苯交连共聚物组成的钙型阳离子交换树脂，粒径7-11u
Reprogel Ca++
USP-L20
二甲氧基丙烷基化学键合于多孔硅胶微粒，粒径5-10u。
Reprosil 100 Diol
Reprosil-Pur Diol
Reprosil100 C8
Reprosil-Pur C8
Reprosil Gold C8
Reprosil -Pur Basic C8 (HD)
Reprosil80 C8
Reprospher C8 (DE)
Equisil BDS C8
USP-L8
全多孔硅胶微粒键合非交联NH2固定相
Reprosil 100 NH2
Reprosil-Pur C18-AQ
Reprosil-Pur ODS-3
Reprosil Gold C18
Reprosil Saphir C18
Reprosil 80 ODS-2
Reprosil-Pur Basic C18 (HD)
Reprospher C18 (DE)
Equisil ODS
Equisil BDS C18
USP-L34
铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9mm球形
Reprogel PΒιβλιοθήκη , 9 μmUSP-L36
5mm胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰
Reprosil Chiral-PhenylGlycin
USP-L37
适合分离分子量2000～40000MW的聚甲基丙烯酸酯凝胶

美国药典USP气相色谱柱对照表

美国药典USP气相色谱柱对照表美国药典USP气相色谱柱对照表L62 C30硅胶键合于完全多孔球状硅胶，粒径3~15μm。

G48 Highly polar, partially cross-linked cyanopolysiloxane.Rt-2560G46 14% 氰丙基苯基- 86% 甲基聚硅氧烷CB-1701MXT?-1701Rtx?-1701VF-1701ms OV-1701CBX-1701DB-1701DB-1701P G43 6% 氰丙基苯基- 94% 二甲基聚硅氧烷MXT?-624DB-624MXT?-Volatiles CBX-1301 MXT?-1301OV-1301CB-624Rtx?-1301 VF-624ms/VF-1301ms Rtx?-624CB-1301CBX-624 G42 35% 苯基- 65% 二甲基乙烯聚硅氧烷DB-35Rtx?-35MXT?-35CBX-35HP-35DB-35MSG38 固定相G1 加减尾剂MXT-1Rtx?-1MS Rtx?-1G36 1% 乙烯基- 5% 苯基甲基聚硅氧烷Rtx?-5MS Rtx?-5CBX-5MXT?-5G35 聚乙二醇和硝基对苯二甲酸二乙二醇酯DB-FFAP HP-FFAP CB-FFAPG32 20% Phenylmethyl-80% dimethylpolysiloxane.MXT?-20G27 5% 苯基- 95% 甲基聚硅氧烷CB-5XTI?-5Rtx?-5SIL MS VF-5msRtx?-5PONA HP-5MS HP-5DB-5MSSE-52DB-5SE-54G25 聚乙二醇TPA（Carbowax 20M 对苯二酸）FFAP CBX-FFAPG19 25% 苯基- 25% 氰丙基甲基聚硅氧烷OV-225Rtx?-225VF-23ms CBX-225G17 75% 苯基- 25% 甲基聚硅氧烷MXT?-65G16 聚乙二醇（平均分子量15,000）DB-WAX CBX-Wax CB-WAX Stabilwax?PEG-20M Stabilwax?-DB Stabilwax?-DA MXT?-WAXG15 聚乙二醇（平均分子量3000－3700）Rtx?-WaxG14 聚乙二醇（平均分子量950－1050）VF-WAXmsG8 90％3氰基丙基－10％苯基甲基聚硅氧烷HP-88Rtx?-2330G7 50%-3-氰丙基聚硅氧烷-50%苯甲基硅氧烷DB-225CB-225G6 三氟丙基甲基聚硅氧烷MXT?-200Rtx?-200G5 3-氰丙基聚氧硅烷DB-23G3 50%苯基-50%甲基聚硅氧烷(50% Phenyl-50% methylpolysiloxane)DB-17HT Rtx?-50Rtx?-17VF-17msMXT?-50DB-17MS CBX-17HP-50+DB-17CB-17VF-Xms OV-17G2 二甲基聚硅烷胶（Dimethylpolysiloxane Gum)CB-1MXT?-1HT Sim Dist HP-1DB-1MSCB-101VF-1ms DB-1MXT?-1 Sim DistHP-PONAG1 二甲基聚硅氧烷油（Dimethylpolysiloxane oil)SE-30CBX-1CB-101CB-PONARtx?-1PONA OV-101OV-1CB-TVOC0 其他分类(气相填充柱色谱柱)L1 十八烷基硅烷化学键合到多孔硅胶或陶瓷微粒，粒径为1.5 到10 μmL10 腈基化学键合到多孔硅胶颗粒，粒径为3 到10 μmL11 苯基化学键合到多孔硅胶颗粒，粒径为1.5 到10 μmL14 具有化学键合的、强碱性季铵阴离子交换涂层的硅胶，粒径为10 μmL18 氨基和氰基化学键合到多孔硅胶颗粒，粒径为5 到10 μmL2 十八烷基硅烷化学键合到表面孔隙度可控制的多孔硅胶（已键合到固体球形核），粒径为3到50 μm L20 二羟基丙烷基化学键合到多孔硅胶颗粒，粒径为3 到10 μmL3 多孔硅胶颗粒，粒径为5 到10 μmL56 丙基硅烷化学键合到全多孔硅胶颗粒，粒径为3 到10 μmL7 辛基硅烷化学键合到全多孔微硅胶颗粒，粒径为1.5 到10 μm L8 氨丙基硅烷以单分子层形式化学键合到多孔硅胶载体上，粒径为10 μmS10 丙烯晴和二乙烯基苯高交联共聚物S1A 硅藻土S2 苯乙烯－二乙烯基苯共聚物：比表面小于50m2/g，平均孔径0.3-0.4umS3 苯乙烯－二乙烯基苯共聚物：比表面为50－6000m2/g，平均孔径0.0075umS4 苯乙烯－二乙烯基苯共聚物（含-O和-N）：比表面为400－600m2/g，平均孔径0.0076umS6 苯乙烯－二乙烯基苯共聚物：比表面为250－350m2/g，平均孔径0.0091umS7 石墨化碳比表面12 m2/gS8 4-乙烯吡啶和苯乙烯二乙烯基苯共聚物G0 其他分类CB-AL2O3/S LZP-950CBX-Phenol PLOT GDX-102农残C农残A农残B CB-PLOT QLZP-920LZP-930LZP-940CB-Metal APLOT GDX-202PLOT GDX-501CB-PLOT U MXT?-500 Sim Dist VF-35ms Rtx?-VMS Rtx?-2887Rtx?-20Rtx?-VGC CB-PLOT Silica FAMEWAX CB-202PLOT GDX-502CBX PLOT-5A MXT?-BAC1CB-AL2O3/MRt-βDEXsa Rtx?-502.2PLOT TDX-01B PLOT TDX-03 PLOT GDX-403PLOT GDX-401MXT?-BAC2HP-PLOT QCB-204Rt-βDEXsp PLOT GDX-203CBX-Dexsil 300 HP-PLOT 氧化铝/S Rtx?-VRX PLOT GDX-103Rt-SPLOTPLOT GDX-201C-2000MXT?-2887PLOT TDX-02B PONA MXT?-502.2PLOT GDX-105苯甲酚专用柱CB-PLOT 5A Rtx?-CLPesticides2Rtx?-440PLOT GDX-303苯系物专用柱DB-608Rtx?-CLPesticides CB-Dexsil 300Rt-βDEXcst Rtx?-PCB MXT?-65TG Rt-βDEXseCB-201Rtx?-XLB Rt-βDEXsm Rt-QPLOTPLOT GDX-104CB-BasicWax PLOT GDX-101CB-PLOT SPLOT GDX-301VF-200ms。

USP药典L1～L60对应色谱柱

下面分别是USPL1～L60的对映。

L1—Octadecyl silane chemically bonded to porous silica or ceramic micro-particles,3to 10µm in diameter.L2—Octadecyl silane chemically bonded to silica gel of a controlled surface porosity that has been bonded to a solid spherical core,30to 50µm in diameter.L3—Porous silica particles,5to 10µm in diameter.L4—Silica gel of controlled surface porosity bonded to a solid spherical core,30to 50µm in diameter.L5—Alumina of controlled surface porosity bonded to a solid spherical core,30to 50µm in diameter.L6—Strong cation-exchange packing–sulfonated fluorocarbon polymer coated on a solid spherical core,30to 50µm in diameter.L7—Octylsilane chemically bonded to totally porous silica particles,3to 10µm in diameter.L8—An essentially monomolecular layer of aminopropylsilane chemically bonded to totally porous silica gel support,10µm in diameter.L9—10-µm irregular or spherical,totally porous silica gel having a chemically bonded,strongly acidic cation-exchange coating.L10—Nitrile groups chemically bonded to porous silica particles,3to 10µm in diameter.L11—Phenyl groups chemically bonded to porous silica particles,5to 10µm in diameter.L12—Astrong anion-exchange packing made by chemically bonding a quaternary amine to a solid silica spherical core,30to 50µm in diameter.L13—Trimethylsilane chemically bonded to porous silica particles,3to 10µm in diameter.L14—Silica gel 10µm in diameter having a chemically bonded,strongly basic quaternary ammonium anion-exchange coating.L15—Hexylsilane chemically bonded to totally porous silica particles,3to 10µm in diameter.L16—Dimethylsilane chemically bonded to porous silica particles,5to 10µm in diameter.L17—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the hydrogen form,7to 11µm in diameter.L18—Amino and cyano groups chemically bonded to porous silica particles,3to 10µm in diameter.L19—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the calcium form,about 9µm in diameter.L20—Dihydroxypropane groups chemically bonded to porous silica particles,5to 10µm in diameter.L21—Arigid,spherical styrene-divinylbenzene copolymer,5to 10µm in diameter.L22—Acation-exchange resin made of porous polystyrene gel with sulfonic acid groups,about 10µm in size.L23—An anion-exchange resin made of porous polymethacrylate or polyacrylate gel with quaternary ammonium groups,about 10µm in size.L24—Asemi-rigid hydrophilic gel consisting of vinyl polymers with numerous hydroxyl groups on the matrix surface,32to 63µm in diameter.5L25—Packing having the capacity to separate compounds with a molecular weight range from 100–5000(as determined by polyethylene oxide),applied to neutral,anionic,and cationic water-soluble polymers.Apolymethacrylate resin base,cross-linked with polyhydroxylated ether (surface contained some residual carboxyl functional groups)was found suitable.L26—Butyl silane chemically bonded to totally porous silica particles,5to 10µm in diameter.L27—Porous silica particles,30to 50µm in diameter.L28—Amultifunctional support,which consists of a high purity,100Å,spherical silica substrate that has been bonded with anionic exchanger,amine functionality in addition to a conventional reversed phase C8functionality.L29—Gamma alumina,reverse-phase,low carbon percentage by weight,alumina-based polybutadiene spherical particles,5µm in diameter with a pore volume of 80Å.L30—Ethyl silane chemically bonded to totally porous silica particles,3to 10µm in diameter.L31—Astrong anion-exchange resin-quaternary amine bonded on latex particles attached toa core of 8.5-µm macroporous particles having a pore size of 2000Åand consisting of ethylvinylbenzene cross-linked with 55%divinylbenzene.L32—Achiral ligand-exchange packing–L-proline copper complex covalently bonded to irregularly shaped silica particles,5to 10µm in diameter.L33—Packing having the capacity to separate dextrans by molecular size over a range of 4,000to 500,000Da.It is spherical,silica-based,and processed to provide pHstability.6L34—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the lead form,about 9µm in diameter.L35—Azirconium-stabilized spherical silica packing with a hydrophilic (diol-type)molecular monolayer bonded phase having a pore size of 150Å.L36—A3,5-dinitrobenzoyl derivative of L-phenylglycine covalently bonded to 5-µm aminopropyl silica.L37—Packing having the capacity to separate proteins by molecular size over a range of 2,000to 40,000Da.It is a polymethacrylate gel.L38—Amethacrylate-based size-exclusion packing for water-soluble samples.L39—Ahydrophilic polyhydroxymethacrylate gel of totally porous spherical resin.L40—Cellulose tris-3,5-dimethylphenylcarbamate coated porous silica particles,5to 20µm in diameter.L41—Immobilized a1-acid glycoprotein on spherical silica particles,5µm in diameter.L42—Octylsilane and octadecylsilane groups chemically bonded to porous silica particles,5µm in diameter.L43—Pentafluorophenyl groups chemically bonded to silica particles by a propyl spacer,5to 10µm in diameter.L44—Amultifunctional support,which consists of a high purity,60Å,spherical silica substrate that has been bonded with a cationic exchanger,sulfonic acid functionality in addition to a conventional reversed phase C8functionality.L45—Beta cyclodextrin bonded to porous silica particles,5to 10µm in diameter.L46—Polystyrene/divinylbenzene substrate agglomerated with quaternary amine functionalized latex beads,10µm in diameter.L47—High-capacity anion-exchange microporous substrate,fully functionalized with trimethlyamine groups,8µm in diameter.7L48—Sulfonated,cross-linked polystyrene with an outer layer of submicron,porous,anion-exchange microbeads,15µm in diameter.L49—Areversed-phase packing made by coating a thin layer of polybutadiene onto spherical porous zirconia particles,3to 10µm in diameter.8L50—Multifunction resin with reversed-phase retention and strong anion-exchange functionalities.The resin consists of ethylvinylbenzene,55%cross-linked with divinylbenzene copolymer,3to 15µm in diameter,and a surface area not less than 350m2per g.Substrate is coated with quaternary ammonium functionalized latex particles consisting of styrene cross-linked with divinylbenzene.9L51—Amylose tris-3,5-dimethylphenylcarbamate-coated,porous,spherical,silica particles,5to 10µm in diameter.10L52—Astrong cation exchange resin made of porous silica with sulfopropyl groups,5to 10µm in diameter.11L53—Weak cation-exchange resin consisting of ethylvinylbenzene,55%cross-linked with divinylbenzene copolymer,3to 15µm diameter.Substrate is surface grafted with carboxylic acid and/or phosphoric acid functionalized monomers.Capacity not less than 500µEq/column.12L54—Asize exclusion medium made of covalent bonding of dextran to highly cross-linked porous agarose beads,about 13µm in diameter.13L55—Astrong cation-exchange resin made of porous silica coated with polybutadiene–maleic acid copolymer,about 5µm in diameter.14L56—Isopropyl silane chemically bonded to totally porous silica particles,3to 10µm in diameter.15L57—Achiral-recognition protein,ovomucoid,chemically bonded to silica particles,about 5µm in diameter,with a pore size of 120Å.L58—Strong cation-exchange resin consisting of sulfonated cross-linked styrene-divinylbenzene copolymer in the sodium form,about 7to 11µm in diameter.16L59—Packing having the capacity to separate proteins by molecular weight over the range of 10to 500kDa.It is spherical (10µm),silica-based,and processed to provide hydrophilic characteristics and pHstability.17USP28L60—Spherical,porous silica gel,3or 5µm in diameter,the surface of which has been covalently modified with palmitamidopropyl groups and endcapped with acetamidopropyl groups to a ligand density of about 6µmoles per m2.18USP28。

美国药典中的色谱柱编号

L1 Octadecyl silane chemically bonded to porous silica or ceramic.L1 十八烷基键合硅烷化学键合于多孔硅胶或陶瓷微粒，3-10u。

L2 Octadecyl silane chemically bonded to silica gel of a controlled surface porosity that has been bonded to a solid spherical core, 30 to 50 μm in diameter.L2 十八烷基键合硅烷化学键合于表面空隙率一定的键合在紧密球核上的硅胶，粒径30-50u。

L3 Porous silica particles, 5 to 10 μm in diameter.L3 多孔硅胶颗粒，粒径5-10u。

L4 Silica gel of controlled surface porosity bonded to a solid spherical core,30 to 50 μm in diameter.L4 表面空隙率一定的硅胶键合于紧密球核上，粒径30-50u。

L5 Alumina of controlled surface porosity bonded to a solid spherical core,30 to 50 μm in diameter.L5 表面空隙率一定的氧化铝键合于紧密球核上，粒径30-50u。

L6 Strong cation-exchange packing: sulfonated fluorocarbon polymer coated on a solid spherical core, 30 to 50 μm in diameter.L6 强阳离子交换填料：磺化氟代烃聚合物涂渍于紧密球核上，粒径30-50u。

L7 Octyl silane chemically bonded to totally porous silica particles, 1.5 to 10 μm in diameter.L7 辛基硅烷化学键合于完全多孔硅胶担体，粒径10u。

美国药典USP气相色谱柱对照表

美国药典USP气相色谱柱对照表L62 C30硅胶键合于完全多孔球状硅胶，粒径3~15μm。

G48 Highly polar, partially cross-linked cyanopolysiloxane.Rt-2560G46 14% 氰丙基苯基- 86% 甲基聚硅氧烷CB-1701MXT®-1701Rtx®-1701VF-1701ms OV-1701CBX-1701DB-1701DB-1701P G43 6% 氰丙基苯基- 94% 二甲基聚硅氧烷MXT®-624DB-624MXT®-Volatiles CBX-1301 MXT®-1301OV-1301CB-624Rtx®-1301 VF-624ms/VF-1301ms Rtx®-624CB-1301CBX-624 G42 35% 苯基- 65% 二甲基乙烯聚硅氧烷DB-35Rtx®-35MXT®-35CBX-35HP-35DB-35MSG38 固定相G1 加减尾剂MXT-1Rtx®-1MS Rtx®-1G36 1% 乙烯基- 5% 苯基甲基聚硅氧烷Rtx®-5MS Rtx®-5CBX-5MXT®-5G35 聚乙二醇和硝基对苯二甲酸二乙二醇酯DB-FFAP HP-FFAP CB-FFAPG32 20% Phenylmethyl-80% dimethylpolysiloxane.MXT®-20G27 5% 苯基- 95% 甲基聚硅氧烷CB-5XTI®-5Rtx®-5SIL MS VF-5msRtx®-5PONA HP-5MS HP-5DB-5MSSE-52DB-5SE-54G25 聚乙二醇TPA（Carbowax 20M 对苯二酸）FFAP CBX-FFAPG19 25% 苯基- 25% 氰丙基甲基聚硅氧烷OV-225Rtx®-225VF-23ms CBX-225G17 75% 苯基- 25% 甲基聚硅氧烷MXT®-65G16 聚乙二醇（平均分子量15,000）DB-WAX CBX-Wax CB-WAX Stabilwax®PEG-20M Stabilwax®-DB Stabilwax®-DA MXT®-WAXG15 聚乙二醇（平均分子量3000－3700）Rtx®-WaxG14 聚乙二醇（平均分子量950－1050）VF-WAXmsG8 90％3氰基丙基－10％苯基甲基聚硅氧烷HP-88Rtx®-2330G7 50%-3-氰丙基聚硅氧烷-50%苯甲基硅氧烷DB-225CB-225G6 三氟丙基甲基聚硅氧烷MXT®-200Rtx®-200G5 3-氰丙基聚氧硅烷DB-23G3 50%苯基-50%甲基聚硅氧烷(50% Phenyl-50% methylpolysiloxane)DB-17HT Rtx®-50Rtx®-17VF-17msMXT®-50DB-17MS CBX-17HP-50+DB-17CB-17VF-Xms OV-17G2 二甲基聚硅烷胶（Dimethylpolysiloxane Gum)CB-1MXT®-1HT Sim Dist HP-1DB-1MSCB-101VF-1ms DB-1MXT®-1 Sim DistHP-PONAG1 二甲基聚硅氧烷油（Dimethylpolysiloxane oil)SE-30CBX-1CB-101CB-PONARtx®-1PONA OV-101OV-1CB-TVOC0 其他分类(气相填充柱色谱柱)L1 十八烷基硅烷化学键合到多孔硅胶或陶瓷微粒，粒径为1.5 到10 μmL10 腈基化学键合到多孔硅胶颗粒，粒径为3 到10 μmL11 苯基化学键合到多孔硅胶颗粒，粒径为1.5 到10 μmL14 具有化学键合的、强碱性季铵阴离子交换涂层的硅胶，粒径为10 μmL18 氨基和氰基化学键合到多孔硅胶颗粒，粒径为5 到10 μmL2 十八烷基硅烷化学键合到表面孔隙度可控制的多孔硅胶（已键合到固体球形核），粒径为3到50 μm L20 二羟基丙烷基化学键合到多孔硅胶颗粒，粒径为3 到10 μmL3 多孔硅胶颗粒，粒径为5 到10 μmL56 丙基硅烷化学键合到全多孔硅胶颗粒，粒径为3 到10 μmL7 辛基硅烷化学键合到全多孔微硅胶颗粒，粒径为1.5 到10 μmL8 氨丙基硅烷以单分子层形式化学键合到多孔硅胶载体上，粒径为10 μmS10 丙烯晴和二乙烯基苯高交联共聚物S1A 硅藻土S2 苯乙烯－二乙烯基苯共聚物：比表面小于50m2/g，平均孔径0.3-0.4umS3 苯乙烯－二乙烯基苯共聚物：比表面为50－6000m2/g，平均孔径0.0075umS4 苯乙烯－二乙烯基苯共聚物（含-O和-N）：比表面为400－600m2/g，平均孔径0.0076umS6 苯乙烯－二乙烯基苯共聚物：比表面为250－350m2/g，平均孔径0.0091umS7 石墨化碳比表面12 m2/gS8 4-乙烯吡啶和苯乙烯二乙烯基苯共聚物G0 其他分类CB-AL2O3/S LZP-950CBX-Phenol PLOT GDX-102农残C农残A农残B CB-PLOT QLZP-920LZP-930LZP-940CB-Metal APLOT GDX-202PLOT GDX-501CB-PLOT U MXT®-500 Sim Dist VF-35ms Rtx®-VMS Rtx®-2887Rtx®-20Rtx®-VGC CB-PLOT Silica FAMEWAX CB-202PLOT GDX-502CBX PLOT-5A MXT®-BAC1CB-AL2O3/MRt-βDEXsa Rtx®-502.2PLOT TDX-01B PLOT TDX-03 PLOT GDX-403PLOT GDX-401MXT®-BAC2HP-PLOT QCB-204Rt-βDEXsp PLOT GDX-203CBX-Dexsil 300 HP-PLOT 氧化铝/S Rtx®-VRX PLOT GDX-103Rt-SPLOTPLOT GDX-201C-2000MXT®-2887PLOT TDX-02B PONA MXT®-502.2PLOT GDX-105苯甲酚专用柱CB-PLOT 5A Rtx®-CLPesticides2Rtx®-440PLOT GDX-303苯系物专用柱DB-608Rtx®-CLPesticides CB-Dexsil 300Rt-βDEXcst Rtx®-PCB MXT®-65TG Rt-βDEXseCB-201Rtx®-XLB Rt-βDEXsm Rt-QPLOTPLOT GDX-104CB-BasicWax PLOT GDX-101CB-PLOT SPLOT GDX-301VF-200ms。

【免费下载】美国药典色谱柱型号对照

美国药典色谱柱型号对照下面是USP规定的编号所对应的色谱柱类型。

L1：十八烷基键合多孔硅胶或无机氧化物微粒固定相，简称ODS柱L2：30～50mm表面多孔薄壳型键合十八烷基固定相，简称C18柱L3：多孔硅胶微粒，即一般的硅胶柱L4：30～50mm表面多孔薄壳型硅胶柱L5：30～50mm表面多孔薄壳型氧化铝柱L6：30～50mm实心微球表面包覆磺化碳氟聚合物，强阳离子交换柱L7：全多孔硅胶微粒键合C8官能团固定相，简称C8柱L8：全多孔硅胶微粒键合非交联NH2固定相，简称NH2柱L9：强酸性阳离子交换基团键合全多孔不规则形硅胶固定相，即SCX柱L10：多孔硅胶微球键合氰基固定相（CN），简称CN柱L11：键合苯基多孔硅胶微球固定相，简称苯基柱L12：无孔微球键合季胺功能团的强阴离子交换柱L13：三乙基硅烷化学键合全多孔硅胶微球固定相（C1），简称C1柱L14：10mm硅胶化学键合强碱性季铵盐阴离子交换固定相，简称SAX柱L15：已基硅烷化学键合全多孔硅胶微球固定相，简称C6柱L16：二甲基硅烷化学键合全多孔硅胶微粒固定相C2柱L17：氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换柱L18：3～10mm全多孔硅胶化学键合胺基（NH2）和氰基（CN）柱L19：钙型磺化交联苯乙烯－二乙烯基苯共聚物，强阳离子交换柱L20：二羟基丙烷基化学键合多孔硅胶微球固定相（Diol），简称二醇基柱L21：刚性苯乙烯－二乙烯基苯共聚物微球填料柱L22：带有磺酸基团的多孔苯乙烯阳离子交换柱L23：带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换柱L24：表面含有大量羟基的半刚性聚乙烯醇亲水凝胶柱L25：聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。

能分离分子量100～5000MW 范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相L26：丁基硅烷化学键合全多孔硅胶微球固定相，即C4柱L27：30～50mm的全多孔硅胶微粒L28：多功能载体，100Å的高纯硅胶加以氨基键合以及C8反相键合的官能团L29:氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5mm，孔径80ÅL30:全多孔硅胶键合乙基硅烷固定相L31:季胺基改性孔径2000Å的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂L32: L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料L33:能够分离分子量4000～40000MW范围蛋白质分子的球形硅胶固定相, pH稳定性好L34：铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9mm球形L35：锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150ÅL36:5mm胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰L37：适合分离分子量2000～40000MW的聚甲基丙烯酸酯凝胶L38：水溶性甲基丙烯酸酯基质SEC色谱柱L39：亲水全多孔聚羟基甲基丙烯酸酯色谱柱L40：Tris 3,5－二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微球L41：球形硅胶表面固定α1酸糖蛋白固定相L42: C8和C18硅烷化学键合多孔硅胶固定相L43:硅胶微球键合五氟代苯基固定相L44:多功能固定相,60 Å高纯硅胶基质键合磺酸阳离子交换功能团和C8反相功能团L45: β-环糊精键合多孔硅胶微球L46:季胺基改性苯乙烯-二乙烯基苯聚合物微球L1 Octadecyl silane chemically bonded to porous silica or ceramic.L1 十八烷基键合硅烷化学键合于多孔硅胶或陶瓷微粒，3-10u。

美国药典色谱柱型号比较

美国药典色谱柱型号对照下面是USP规定的编号所对应的色谱柱类型。

L1：十八烷基键合多孔硅胶或无机氧化物微粒固定相，简称ODS柱L2：30～50mm表面多孔薄壳型键合十八烷基固定相，简称C18柱L3：多孔硅胶微粒，即一般的硅胶柱L4：30～50mm表面多孔薄壳型硅胶柱L5：30～50mm表面多孔薄壳型氧化铝柱L6：30～50mm实心微球表面包覆磺化碳氟聚合物，强阳离子交换柱L7：全多孔硅胶微粒键合C8官能团固定相，简称C8柱L8：全多孔硅胶微粒键合非交联NH2固定相，简称NH2柱L9：强酸性阳离子交换基团键合全多孔不规则形硅胶固定相，即SCX柱L10：多孔硅胶微球键合氰基固定相（CN），简称CN柱L11：键合苯基多孔硅胶微球固定相，简称苯基柱L12：无孔微球键合季胺功能团的强阴离子交换柱L13：三乙基硅烷化学键合全多孔硅胶微球固定相（C1），简称C1柱L14：10mm硅胶化学键合强碱性季铵盐阴离子交换固定相，简称SAX柱L15：已基硅烷化学键合全多孔硅胶微球固定相，简称C6柱L16：二甲基硅烷化学键合全多孔硅胶微粒固定相C2柱L17：氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换柱L18：3～10mm全多孔硅胶化学键合胺基（NH2）和氰基（CN）柱L19：钙型磺化交联苯乙烯－二乙烯基苯共聚物，强阳离子交换柱L20：二羟基丙烷基化学键合多孔硅胶微球固定相（Diol），简称二醇基柱L21：刚性苯乙烯－二乙烯基苯共聚物微球填料柱L22：带有磺酸基团的多孔苯乙烯阳离子交换柱L23：带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换柱L24：表面含有大量羟基的半刚性聚乙烯醇亲水凝胶柱L25：聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。

能分离分子量100～5000MW 范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相L26：丁基硅烷化学键合全多孔硅胶微球固定相，即C4柱L27：30～50mm的全多孔硅胶微粒L28：多功能载体，100Å的高纯硅胶加以氨基键合以及C8反相键合的官能团L29:氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5mm，孔径80ÅL30:全多孔硅胶键合乙基硅烷固定相L31:季胺基改性孔径2000Å的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂L32: L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料L33:能够分离分子量4000～40000MW范围蛋白质分子的球形硅胶固定相, pH稳定性好L34：铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9mm球形L35：锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150ÅL36:5mm胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰L37：适合分离分子量2000～40000MW的聚甲基丙烯酸酯凝胶L38：水溶性甲基丙烯酸酯基质SEC色谱柱L39：亲水全多孔聚羟基甲基丙烯酸酯色谱柱L40：Tris 3,5－二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微球L41：球形硅胶表面固定α1酸糖蛋白固定相L42: C8和C18硅烷化学键合多孔硅胶固定相L43:硅胶微球键合五氟代苯基固定相L44:多功能固定相,60 Å高纯硅胶基质键合磺酸阳离子交换功能团和C8反相功能团L45: β-环糊精键合多孔硅胶微球L46:季胺基改性苯乙烯-二乙烯基苯聚合物微球L1 Octadecyl silane chemically bonded to porous silica or ceramic.L1 十八烷基键合硅烷化学键合于多孔硅胶或陶瓷微粒，3-10u。

usp美国药典液相方法色谱柱汇总

usp美国药典液相方法色谱柱汇总USP美国药典液相方法色谱柱类型汇总USP即美国药典，为高效液相色谱柱填料规定了一些指标，并根据类型进行了序列编排，即USP L1---USP L60系列。

USP 填料描述L1 C18烷基化学键合于多孔硅胶或陶瓷微粒，3-10u L2 C18烷基化学键合于多孔硅胶，30-50u L3 多孔硅胶微粒，5-10uL4 硅胶微粒，30-50uL5 氧化铝微粒，30-50uL6 强阳离子交换填料:磺化氟碳聚合物涂于固体球形核粒上，30-50u L7 C8烷基化学键合于3-10u完全多孔硅胶微粒 L8 单分子层丙氨基化学键合于10u硅胶载体， L9 强酸性阳离子交换基团键合于10u无定形多孔硅胶， L10 氰基化学键合于5-10u多孔硅胶颗粒， L11 苯基化学键合于5-10u多孔硅胶颗粒， L12 季铵基化学键合于30-50u固体硅胶小球上，强阴离子交换填料 L13 三甲基硅烷化学键合于5-10u多孔硅胶颗粒， L14 带强碱性季铵基的阴离子交换涂料化学键合于10u硅胶微粒， L15 六烷基化学键合于全多孔硅胶颗粒，3-10u L16 二甲基化学键合于全多孔硅胶颗粒，5-10u L17 强阳离子交换树脂:氢型、磺化交联的苯乙烯二乙烯基苯共聚物，7-11u L18 氨基和氰基官能团键合于5-10u的多孔硅胶颗粒上 L19 强阳离子交换树脂:钙型、磺化交联的苯乙烯二乙烯基苯共聚物，9u L20 二羟基丙烷基团化学键合于多孔硅胶颗粒，5-10u L21 刚性的苯乙烯二乙烯基苯共聚物小球，5-10u L22 阳离子交换树脂:带磺酸基团的多孔苯乙烯聚合物小球，外径约10u阴离子交换树脂:带季铵基团的聚甲基丙烯酸甲酯或聚丙烯酸甲酯多孔胶体，约10u外L23 径L24 基体表面带大量羟基团的聚乙烯构成的半刚性亲水凝胶，32-63u外径该填料应能分离分子量从100-5000道尔顿的化合物，用于分离中性，阳离子型及阴离子L25 型的水溶性聚合物。

美国药典(USP)中规定的色谱柱类型

美国药典（USP）中规定的色谱柱类型Chromatographic ReagentsThe following list of packings (L), phases (G), and supports (S) is intended to be a convenient reference for the chromatographer. [note—Particle sizes given in this listing are those generally provided. Where other, usually finer, sizes are required, the individual monograph specifies the desired particle size. Within any category of packings or phases listed below, there may be a wide range of columns available. Where it is necessary to define more specifically the chromatographic conditions, the individual monograph so indicates.]Change to read:PackingsL1—Octadecyl silane chemically bonded to porous silica or ceramic micro-particles, 1.5 to 10 µm in diameter, or a monolithic silica rod.L2—Octadecyl silane chemically bonded to silica gel of a controlled surface porosity that has been bonded to a solid spherical core, 30 to 50 µm in diameter.L3—Porous silica particles, 3 USP31 to 10 µm in diameter, or a monolithic silica rod. USP31L4—Silica gel of controlled surface porosity bonded to a solid spherical core, 30 to 50µm in diameter.L5—Alumina of controlled surface porosity bonded to a solid spherical core, 30 to 50 µm in diameter.L6—Strong cation-exchange packing–sulfonated fluorocarbon polymer coated on a solid spherical core, 30 to 50 µm in diameter.L7—Octylsilane chemically bonded to totally porous silica particles, 1.5 to 10 µm in diameter, or a monolithic silica rod. USP31L8—An essentially monomolecular layer of aminopropylsilane chemically bonded to totally porous silica gel support, 3 to 10 µm in diameter.L9—Irregular or spherical, totally porous silica gel having a chemically bonded, strongly acidic cation-exchange coating, 3 to 10 µm in diameter.L10—Nitrile groups chemically bonded to porous silica particles, 3 to 10 µm in diameter.L11—Phenyl groups chemically bonded to porous silica particles, 1.5 to 10 µm in diameter.L12—A strong anion-exchange packing made by chemically bonding a quaternary amine to a solid silica spherical core, 30 to 50 µm in diameter.L13—Trimethylsilane chemically bonded to porous silica particles, 3 to 10 µm in diameter.L14—Silica gel having a chemically bonded, strongly basic quaternary ammoniumanion-exchange coating, 5 to 10 µm in diameter.L15—Hexylsilane chemically bonded to totally porous silica particles, 3 to 10 µm in diameter.L16—Dimethylsilane chemically bonded to porous silica particles, 5 to 10 µm in diameter.L17—Strong cation-exchange resin consisting of sulfonated cross-linkedstyrene-divinylbenzene copolymer in the hydrogen form, 7 to 11 µm in diameter.L18—Amino and cyano groups chemically bonded to porous silica particles, 3 to 10 µm in diameter.L19—Strong cation-exchange resin consisting of sulfonated cross-linkedstyrene-divinylbenzene copolymer in the calcium form, about 9 µm in diameter.L20—Dihydroxypropane groups chemically bonded to porous silica particles, 5 to 10 µm in diameter.L21—A rigid, spherical styrene-divinylbenzene copolymer, 5 to 10 µm in diameter.L22—A cation-exchange resin made of porous polystyrene gel with sulfonic acid groups, about 10 µm in size.L23—An anion-exchange resin made of porous polymethacrylate or polyacrylate gel with quaternary ammonium groups, about 10 µm in size.L24—A semi-rigid hydrophilic gel consisting of vinyl polymers with numerous hydroxyl groups on the matrix surface, 32 to 63 µm in diameter.[note—Available as YMC-Pack PVA-SIL manufactured by YMC Co., Ltd. and distributed by Waters Corp. ().]L25—Packing having the capacity to separate compounds with a molecular weight range from 100–5000 (as determined by polyethylene oxide), applied to neutral, anionic, and cationicwater-soluble polymers. A polymethacrylate resin base, cross-linked with polyhydroxylated ether (surface contained some residual carboxyl functional groups) was found suitable.L26—Butyl silane chemically bonded to totally porous silica particles, 3 to 10 µm in diameter.L27—Porous silica particles, 30 to 50 µm in diameter.L28—A multifunctional support, which consists of a high purity, 100 , spherical silica substrate that has been bonded with anionic exchanger, amine functionality in addition to a conventional reversed phase C8 functionality.L29—Gamma alumina, reverse-phase, low carbon percentage by weight, alumina-based polybutadiene spherical particles, 5 µm in diameter with a pore volume of 80 .L30—Ethyl silane chemically bonded to totally porous silica particles, 3 to 10 µm in diameter.L31—A hydroxide-selective, strong anion-exchange resin-quaternary amine bonded on latex particles attached to a core of 8.5-µm macroporous particles having a pore size of 2000 and consisting of ethylvinylbenzene cross-linked with 55% divinylbenzene.L32—A chiral ligand-exchange packing–l-proline copper complex covalently bonded to irregularly shaped silica particles, 5 to 10 µm in diameter.L33—Packing having the capacity to separate dextrans by molecular size over a range of4,000 to 500,000 Da. It is spherical, silica-based, and processed to provide pH stability.[note—Available as TSKgel G4000 SWXL from Tosoh Biosep ().]L34—Strong cation-exchange resin consisting of sulfonated cross-linkedstyrene-divinylbenzene copolymer in the lead form, about 9 µm in diameter.L35—A zirconium-stabilized spherical silica packing with a hydrophilic (diol-type) molecular monolayer bonded phase having a pore size of 150 .L36—A 3,5-dinitrobenzoyl derivative of l-phenylglycine covalently bonded to 5-µm aminopropyl silica.L37—Packing having the capacity to separate proteins by molecular size over a range of2,000 to 40,000 Da. It is a polymethacrylate gel.L38—A methacrylate-based size-exclusion packing for water-soluble samples.L39—A hydrophilic polyhydroxymethacrylate gel of totally porous spherical resin.L40—Cellulose tris-3,5-dimethylphenylcarbamate coated porous silica particles, 5 to 20µm in diameter.L41—Immobilized 1-acid glycoprotein on spherical silica particles, 5 µm in diameter.L42—Octylsilane and octadecylsilane groups chemically bonded to porous silica particles, 5 µm in diameter.L43—Pentafluorophenyl groups chemically bonded to silica particles by a propyl spacer, 5 to 10 µm in diameter.L44—A multifunctional support, which consists of a high purity, 60 , spherical silica substrate that has been bonded with a cationic exchanger, sulfonic acid functionality in addition to a conventional reversed phase C8 functionality.L45—Beta cyclodextrin bonded to porous silica particles, 5 to 10 µm in diameter.L46—Polystyrene/divinylbenzene substrate agglomerated with quaternary amine functionalized latex beads, about 10 µm in diameter.L47—High-capacity anion-exchange microporous substrate, fully functionalized with trimethlyamine groups, 8 µm in diameter.[note—Available as CarboPac MA1 and distributed by Dionex Corp. ().]L48—Sulfonated, cross-linked polystyrene with an outer layer of submicron, porous,anion-exchange microbeads, 15 µm in diameter.L49—A reversed-phase packing made by coating a thin layer of polybutadiene onto spherical porous zirconia particles, 3 to 10 µm in diameter.[note—Available as Zirchrom PBD, manufactured by ZirChrom Separations, Inc., distributed by Alltech, .]L50—Multifunction resin with reversed-phase retention and strong anion-exchange functionalities. The resin consists of ethylvinylbenzene, 55% cross-linked with divinylbenzene copolymer, 3 to 15 µm in diameter, and a surface area not less than 350 m2 per g. Substrate is coated with quaternary ammonium functionalized latex particles consisting of styrene cross-linked with divinylbenzene.[note—Available as OmniPac PAX-500 and distributed by Dionex Corp. ().]L51—Amylose tris-3,5-dimethylphenylcarbamate-coated, porous, spherical, silica particles, 5 to 10 µm in diameter.[note—Available as Chiralpak AD from Chiral Technologies, Inc., ().]L52—A strong cation-exchange resin made of porous silica with sulfopropyl groups, 5 to 10µm in diameter.[note—Available as TSK IC SW Cation from Tosoh Biosep ().]L53—Weak cation-exchange resin consisting of ethylvinylbenzene, 55% cross-linked with divinylbenzene copolymer, 3 to 15 µm diameter. Substrate is surface grafted with carboxylic acid and/or phosphoric acid functionalized monomers. Capacity not less than 500 µEq/column.[note—Available as IonPac CS14 distributed by Dionex Corp. ().]L54—A size exclusion medium made of covalent bonding of dextran to highly cross-linked porous agarose beads, about 13 µm in diameter.[note—Available as Superdex Peptide HR 10/30 from Amersham Pharmacia Biotech ().]L55—A strong cation-exchange resin made of porous silica coated with polybutadiene–maleic acid copolymer, about 5 µm in diameter.[note—Available as IC-Pak C M/D from Waters Corp. ().]L56—Propyl silane chemically bonded to totally porous silica particles, 3 to 10 µm in diameter.[note—Available as Zorbax SB-C3 from Agilent Technologies (/chem).]L57—A chiral-recognition protein, ovomucoid, chemically bonded to silica particles, about 5µm in diameter, with a pore size of 120 .[note—Available as Ultron ES-OVM from Agilent Technologies (/chem).]L58—Strong cation-exchange resin consisting of sulfonated cross-linkedstyrene-divinylbenzene copolymer in the sodium form, about 6 to 30 µm 1S (USP31) in diameter.[note—Available as Aminex HPX-87N from Bio-Rad Laboratories, (2000/01 catalog,#125-0143) .]L59—Packing having the capacity to separate proteins by molecular weight over the range of 10 to 500 kDa. It is spherical (10 µm), silica-based, and processed to provide hydrophilic characteristics and pH stability.[note—Available as TSKgel G3000SW Column (analytical column) and TSKgel Guard (guard column) from Tosoh Biosep (part numbers 05789 and 05371, respectively)().]L60—Spherical, porous silica gel, 10 µm or less in diameter, the surface of which has been covalently modified with alkyl amide groups and endcapped.[note—Available as Supelcosil ABZ from Supelco (/supelco).]L61—A hydroxide selective strong anion-exchange resin consisting of a highly cross-linked core of 13 µm microporous particles having a pore size less than 10 units and consisting of ethylvinylbenzene cross-linked with 55% divinylbenzene with a latex coating composed of 85 nm diameter microbeads bonded with alkanol quaternary ammonium ions (6%).[note—Available as Ion Pac AS-11 and AG-11 from Dionex ().]L62—C30 silane bonded phase on a fully porous spherical silica, 3 to 15 µm in diameter.L63— Glycopeptide teicoplanin linked through multiple covalent bonds to a 100- units spherical silica.[Note—Available as Chirobiotic T from Astec ().] 1S (USP31)美国药典(USP)规定的色谱柱编号见下面，是对应的色谱柱类型。

美国USP色谱柱编号对照表

美国USP色谱柱编号对照表L1：十八烷基键合多孔硅胶或无机氧化物微粒固定相，简称C18或ODSL2：30～50um表面多孔薄壳型键合C18(ODS)固定相L3：多孔硅胶微粒即一般的硅胶柱L4：30～50um表面多孔薄壳型硅胶L5：30～50um表面多孔薄壳型氧化铝L6：30～50um实心微球表面包覆磺化碳氟聚合物－强阳离子交换固定相L7：全多孔硅胶微粒键合C8官能团固定相简称C8柱L8：全多孔硅胶微粒键合非交联NH2固定相简称NH2柱L9：强酸性阳离子交换基团键合全多孔不规则形硅胶固定相L10：多孔硅胶微球键合氰基固定相（CN）简称CN柱L11：键合苯基多孔硅胶微球固定相简称苯基柱L12：无孔微球键合季胺功能团的强阴离子填料L13：三乙基硅烷化学键合全多孔硅胶微球固定相（C1）简称C1柱L14:10um硅胶化学键合强碱性季铵盐阴离子交换固定相简称SAX柱L15：已基硅烷化学键合全多孔硅胶微球固定相简称C6柱L16：二甲基硅烷化学键合全多孔硅胶微粒固定相L17：氢型磺化交联苯乙烯-二乙烯基苯共聚物,强阳离子交换树脂L18: 3～10um全多孔硅胶化学键合胺基（NH2）和氰基（CN）L19：钙型磺化交联苯乙烯－二乙烯基苯共聚物，强阳离子交换树脂L20：二羟基丙烷基化学键合多孔硅胶微球固定相（Diol）简称二醇基柱L21：刚性苯乙烯－二乙烯基苯共聚物微球L22：带有磺酸基团的多孔苯乙烯阳离子交换树脂L23：带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换树脂L24：表面含有大量羟基的半刚性聚乙烯醇亲水凝胶L25：聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。

能分离分子量100～5000MW范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相L26：丁基硅烷化学键合全多孔硅胶微球固定相L27：30～50um的全多孔硅胶微粒L28：多功能载体，100?的高纯硅胶加以氨基键合以及C8反相键合的官能团L29: 氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5um，孔径80?L30: 全多孔硅胶键合乙基硅烷固定相L31: 季胺基改性孔径2000?的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂L32: L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料L33: 能够分离分子量4000～40000MW范围蛋白质分子的球形硅胶固定相,pH稳定性好L34：铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9um球形L35：锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150?L36: 5um胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰L37：适合分离分子量2000～40,000Mw的聚甲基丙烯酸酯凝胶L38：水溶性甲基丙烯酸酯基质SEC色谱柱L39：亲水全多孔聚羟基甲基丙烯酸酯色谱柱L40：Tris 3,5－二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微球L41：球形硅胶表面固定α1酸糖蛋白固定相L42: C8和C18硅烷化学键合多孔硅胶固定相L43: 硅胶微球键合五氟代苯基固定相L44: 多功能固定相,60 ?高纯硅胶基质键合磺酸阳离子交换功能团和C8反相功能团L45: β-环糊精键合多孔硅胶微球L46: 季胺基改性苯乙烯-二乙烯基苯聚合物微球。

USP色谱柱编号对应表

L19
钙型磺化交联苯乙烯－二乙烯基苯共聚物，强阳离子交换柱
L20
二羟基丙烷基化学键合多孔硅胶微ห้องสมุดไป่ตู้固定相（Diol）
二醇基柱
L21
刚性苯乙烯－二乙烯基苯共聚物微球填料柱
L22
带有磺酸基团的多孔苯乙烯阳离子交换柱
L23
带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换柱
L24
表面含有大量羟基的半刚性聚乙烯醇亲水凝胶柱
L29
氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5μm，孔径80Å
L30
全多孔硅胶键合乙基硅烷固定相
L31
季胺基改性孔径2000Å的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂
L32
L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位体的交换手性色谱填料
L33
能够分离分子量4000～40000范围蛋白质分子的球形硅胶固定相, pH稳定性好
美国药典(USP)规定的色谱柱编号对应表
USP编号
填料/说明
简称
L1
十八烷基键合多孔硅胶或无机氧化物微粒固定相
ODS柱
L2
30～50μm表面多孔薄壳型键合十八烷基固定相
C18柱
L3
多孔硅胶微粒，即一般的硅胶柱
L4
30～50μm表面多孔薄壳型硅胶柱
L5
30～50μm表面多孔薄壳型氧化铝柱
L6
30～50μm实心微球表面包覆磺化碳氟聚合物，强阳离子交换柱
L34
铅型磺化交联苯乙烯－二乙烯基苯共聚物强阳离子交换树脂，9mm球形
L35
锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150Å
L36
5mm胺丙基硅胶键合L-苯基氨基乙酸－3,5二硝基苯甲酰

美国药典USP气相色谱柱对照表

G25 聚乙二醇 TPA（Carbowax 20M 对苯二酸）
FFAP CBX-FFAP
G19 25% 苯基- 25% 氰丙基甲基聚硅氧烷
OV-225 Rtx®-225 VF-23ms CBX-225
G17 75% 苯基- 25% 甲基聚硅氧烷
MXT®-65
G16 聚乙二醇（平均分子量 15,000）
பைடு நூலகம்
L56 丙基硅烷化学键合到全多孔硅胶颗粒，粒径为 3 到 10 μ m L7 辛基硅烷化学键合到全多孔微硅胶颗粒，粒径为 1.5 到 10 μ m L8 氨丙基硅烷以单分子层形式化学键合到多孔硅胶载体上，粒径为 10 μ m S10 丙烯晴和二乙烯基苯高交联共聚物 S1A 硅藻土 S2 苯乙烯－二乙烯基苯共聚物：比表面小于 50m2/g，平均孔径 0.3-0.4um S3 苯乙烯－二乙烯基苯共聚物：比表面为 50－6000m2/g，平均孔径 0.0075um S4 苯乙烯－二乙烯基苯共聚物（含-O 和-N）：比表面为 400－600m2/g，平均孔径 0.0076um S6 苯乙烯－二乙烯基苯共聚物：比表面为 250－350m2/g，平均孔径 0.0091um S7 石墨化碳比表面 12 m2/g S8 4-乙烯吡啶和苯乙烯二乙烯基苯共聚物 G0 其他分类
G1 二甲基聚硅氧烷油（Dimethylpolysiloxane oil)
SE-30 Rtx®-1PONA CBX-1 OV-101 CB-101 OV-1 CB-PONA CB-TVOC
0 其他分类(气相填充柱色谱柱) L1 十八烷基硅烷化学键合到多孔硅胶或陶瓷微粒，粒径为 1.5 到 10 μ m L10 腈基化学键合到多孔硅胶颗粒，粒径为 3 到 10 μ m L11 苯基化学键合到多孔硅胶颗粒，粒径为 1.5 到 10 μ m L14 具有化学键合的、强碱性季铵阴离子交换涂层的硅胶，粒径为 10 μ m L18 氨基和氰基化学键合到多孔硅胶颗粒，粒径为 5 到 10 μ m L2 十八烷基硅烷化学键合到表面孔隙度可控制的多孔硅胶（已键合到固体球形核），粒径为 3 到 50 μ m L20 二羟基丙烷基化学键合到多孔硅胶颗粒，粒径为 3 到 10 μ m L3 多孔硅胶颗粒，粒径为 5 到 10 μ m

USP 42中色谱柱编号对应表

L7
全多孔硅胶微粒键合C8官能团固定相
C8柱
L8
全多孔硅胶微粒键合非交联NH2固定相3 to 10 μm
NH2柱
L9
强酸性阳离子交换基团键合全多孔不规则形硅胶固定相
SCX柱
L10
多孔硅胶微球键合氰基固定相（CN）
CN柱
L11
键合苯基多孔硅胶微球固定相
苯基柱
L12
无孔微球键合季胺功能团的强阴离子交换柱
L25
聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。能分离分子量100～5000范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相
L26
丁基硅烷化学键合全多孔硅胶微球固定相
2.1×100mm,5μm
L27
30～50μm的全多孔硅胶微粒
L28
多功能载体，100Å的高纯硅胶加以氨基键合以及C8反相键合的官能团
美国药典(USP42)规定的色谱柱编号对应表
USP编号
填料/说明
简称
L1
十八烷基键合多孔硅胶或无机氧化物微粒固定相
ODS柱
L2
30～50μm表面多孔薄壳型键合十八烷基固定相
C18柱
L3
多孔硅胶微粒，即一般的硅胶柱
L4
30～50μm表面多孔薄壳型硅胶柱
L5
30～50μm表面多孔薄壳型氧化铝柱
L6
30～50μm实心微球表面包覆磺化碳氟聚合物，强阳离子交换柱
L29
氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5μm，孔径80Å
L30
全多孔硅胶键合乙基硅烷固定相
L31
季胺基改性孔径2000Å的交联苯乙烯和二乙烯基苯(55%)强阴离子交换树脂

USP色谱柱编号对应表

团
L45
性环糊精键合多孔硅胶微球
L46
季胺基改性苯乙烯-二乙烯基苯聚合物微球
L25
聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功能团）树脂。能分离分子量100〜5000范围的水溶性中性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的固定相
L26
丁基硅烷化学键合全多孔硅胶微球固定相
2.1x100mm,5
gm
L27
30〜50gm的全多孔硅胶微粒
L28
多功能载体，100?的高纯硅胶加以氨基键合以及C8反相键合的官能团
L19
钙型磺化交联苯乙烯-二乙烯基苯共聚物，强阳离子交换柱
L20
二羟基丙烷基化学键合多孔硅胶微球固定相（Diol）
二醇基柱
L21
刚性苯乙烯-二乙烯基苯共聚物微球填料柱
L22
带有磺酸基团的多孔苯乙烯阳离子交换柱
L23
带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离子交换柱
L24
表面含有大量羟基的半刚性聚乙烯醇亲水凝胶柱
美国药典（USP）规定的色谱柱编号对应表
USP编号
填料/说明
简称
L1
十八烷基键合多孔硅胶或无机氧化物微粒固定相
ODS柱
L2
30〜50表面多孔薄壳型键合十八烷基固定相
C18柱
L3
多孔硅胶微粒，即一般的硅胶柱
L4
30〜50^m表面多孔薄壳型硅胶柱
L5
30〜50^m表面多孔薄壳型氧化铝柱
L6
30~50gm实心微球表面包覆磺化碳氟聚合物，强阳离子交换柱
L34
铅型磺化交联苯乙烯-二乙烯基苯共聚物强阳离子交换树脂，9mm球形
L35
锆稳定的硅胶微球键合二醇基亲水分子单层固定相，孔径150?

USPGC色谱柱规格对照（固定相）

苯甲基二四基聚硅氧烷（10%苯取代）
35% phenyl-65% dimet hylpolysiloxane G42
(percentages refer to molar substitution).
35%苯基 -6 5%乙烯基硅烷（百分比参见分子取代度）
6% cyanopropylphenyl-94% G43 dimethylpolysiloxane (percentages refer to
compound of polyethylene glycol with a G16
物粘合物的高分子合物。[注- -- -商名聚乙二
diepoxide linker.
醇合物 20M，或 Carbowax 20M,色谱试剂
[note—A vailable commercially as
商处购得]
G3
50% Phenyl-50% methylpolysiloxane.
50%苯基 -5 0%甲基聚硅氧烷
G4
Diethylene glycol succinate poly ester.
聚丁二酸乙二醇酯
G5
3-Cy anopropylpolysiloxane.
3-氰丙基聚氧硅烷
G6
Trifl uo rop ro pylmethylpolysiloxa ne.
25% 2-Cyanoethyl-75% G26
methylpolysiloxane.
25％ 2-氰基乙基－7 5％甲基聚硅氧烷
G27
5% Phenyl-95% methylpolysiloxane.
5%苯基- 95%甲基聚硅氧烷

美国药典中色谱柱编号及填料明细

30～50μm 的全多孔硅胶微粒
多功能载体，100Å 的高纯硅胶加以氨基键合以及 C8 反
相键合的官能团
氧化铝,反相键合,含碳量低,氧化铝基聚丁二稀小球,5μ
m，孔径 80Å
全多孔硅胶键合乙基硅烷固定相
季胺基改性孔径 2000Å 的交联苯乙烯和二乙烯基苯
(55%)强阴离子交换树脂
L32
L-脯氨酸铜配合物共价键合于不规则形硅胶微粒的配位
酰
L37
适合分离分子量 2000～40000 的聚甲基丙烯酸酯凝胶
L38
水溶性甲基丙烯酸酯基质 SEC 色谱柱
L39
亲水全多孔聚羟基甲基丙烯酸酯色谱柱
L40
Tris 3,5－二甲基苯基氨基甲酸酯纤维素涂覆多孔硅胶微
球
L41
球形硅胶表面固定α1 酸糖蛋白固定相
L42
C8 和 C18 硅烷化学键合多孔硅胶固定相
带有季胺基团的聚甲基丙烯酸甲酯或聚丙烯酸酯多孔离
子交换柱
表面含有大量羟基的半刚性聚乙烯醇亲水凝胶柱
聚甲基丙烯酸酯树脂交联羟基醚（表面含有残余羧基功
能团）树脂。能分离分子量 100～5000 范围的水溶性中
性、阳离子型及阴离子型聚合物（用聚氧乙烯测定）的
固定相
丁基硅烷化学键合全多孔硅胶微球固定相
C4 柱
L25 Packing having the capacity to separate compounds with a MW range from 100
to 5000 daltons (as determined by polyethylene oxide), applied to neutral, anionic,
C2 柱

Benson液相色谱柱介绍

美国Benson液相色谱柱1、BP-100 H +碳水化合物色谱柱●USP L17；BP-100, H+, 6%交联度的磺化苯乙烯-二乙烯基苯树脂，H型●稀酸做流动相●应用于UV检测器、RI检测器和电导率检测器●分离碳水化合物、有机酸、醇类●应用：酒类、乳品加工业、生物反应, 医疗科技BP-100，H+碳水化合物色谱柱，除了交联程度和磺化作用不同外，与离子交换柱（850, BP-OA,有机酸）类似。

交联和磺化的优化不仅能够分离样品中的碳水化合物，而且能够分离有机酸和醇。

常温下仅用稀酸作为流动相。

从分析葡萄酒和果汁中的有机酸及碳水化合物过程中可得出发酵过程和产品质量的信息。

有机酸峰洗脱次数受pH值和温度的影响，质子化的物质能更好地被保留，稀释溶剂改性剂如乙腈能引起反压增加，从而减少大部分物质的洗脱时间，尤其是那些具有高树脂反应性能的组分如2、BP-100 碳水化合物 Pb++色谱柱▪USP L34； BP-100, Pb++, 6%交联度的磺化苯乙烯-二乙烯基苯树脂▪分离单糖和二糖的分辨率和选择性高；分离度高；▪蒸馏水做流动相▪应用：奶制品, 谷类, 肉制品, 植物纤维BP-100 碳水化合物 Pb++色谱柱，填充10μm的磺化苯乙烯二乙烯基苯树脂，Pb型，复杂的糖类常常被用来给食品和饮料加入独特的口味。

纤维素产品里戊糖和已醣能够被很好的分离，尤其是葡萄糖，木糖，半乳糖，纤维二糖，树胶醛糖和甘露糖，这款色谱柱能分离在钙型色谱柱尚未完全分离的木糖，半乳糖和甘露糖。

此外，还能更好的分离一些样品中大量同时存在的蔗糖和乳糖。

3、BP-100 碳水化合物 Ca++色谱柱▪USP L19； BP-100, Ca++ , 6%交联度的磺化苯乙烯-二乙烯基苯树脂，Ca型▪分离单糖和糖醇；分离度高；▪蒸馏水做流动相▪应用：烤制品、蔬菜、果汁、软饮料、啤酒酿造、奶制品BP-100 碳水化合物Ca++柱子只用水为流动相，可用于分离焙烤食品中的糖和糖醇，如山梨醇，甘露醇和木糖醇，这些往往被用作果汁，软饮料，啤酒和乳制品的甜味剂。