应用电化学电化学基础理论和电池讲解

Nernst equation
mical kinetics
1905 塔菲尔 Tafel (Germanny ）
Tafel equation
1920s-70s Butler, Vomer, Frumkin, Bockris, Bard ….
Modern electroche
1970s-
Electrochemistry at molecular and atomic level
Electric phenomena /
processes
Electrochemical reactions
Chemical phenomena /
processes
Charge formation & transfer
Electrochemical Science & Technologies
formation & transformation
• 研究化学能与电能之间相互转换的原理与技术（The laws and the technologies concerning the conversion between chemical energy and electrical energy）
• 研究化学现象与电现象的相关性（Interrelation between chemical phenomena (chemical reactions, chemical changes, etc.) and electric phenomena (charge, current, potential, electric field, etc.)）
mistry
现代电化学
涉及的学科领域：
Chemistry, Physics, Mathematics Spectroscopes (spectroscopic electrochemistry) Biological science （bio-electrochemistry） Environmental science（environmental electrochemistry）
Electrochemistry
Electrochemical treatments of wastes
Electrochemical sensors
health
Electrochemical therapy
电化学研究对象 What does Electrochemistry deal with ?
of matters
Electric power
Energy conversion
Chemical power
电化学作为基础科学的研究范围
Solid-liquid interface
Interfacial charge transfer
Mass transport
Electrochemistry
Interfacial adsorption
electrochemical processes and reactions; 4. 电话学研究的策略与思想-The philosophy and strategies in
electrochemical studies
电化学发展史
History of more than two centuries
• 研究发生在电极与电解质界面的现象、过程和反应（The phenomena, processes and reactions occurring at interface between an electronic conductor (electrode) and an ionic conductor (electrolyte) ）
Thermodyna-
mics 1834 法拉第 Faraday (England ）
Faraday law
1870 Helmholtz (Germany ) theory for electric double layer
Electroche- 1889 能斯特 Nernst（ Germanny）
1791 伽伐尼Galvani （Italy） biological electric phenomena
1799 伏打Volta （ Italy ） Volta cell
Electrochemi- 1800 尼科尔森-卡莱尔 Nicholson - Carlisle（England）
calLeabharlann Baidu
water electrolysis
Quantum and computation mechanics（theoretic and computational electrochemistry）
Material science （material electrochemistry） Nanoscience and nanotechnology （Nano-electrochemistry） ......
Methods for
studying the
...
interface
电化学作为技术的研究范围
energy Batteries
Electrolysis & electrosynthesis
resources
Electrochemical protection of materials
environments
应用电化学 电化学基础理论和电池讲解
课程内容
1. 电化学基础理论 2. 电催化动力学 3. 锂离子电池 4. 电化学电容器 5. 燃料电池
第一章 电化学基础理论
1. 电化学发展简史-A historical view of electrochemical science 2. 电化学研究对象-What does electrochemistry deal with ? 3. 电化学过程和电化学反应的特点-The features of
两类导体
Electronic conductors（Metals、Semiconductors);
Ionic conductors (electrolyte solutions, solid electrolyte, ionic liquid, melted salts);