邻苯二甲酰亚胺转化成邻苯二甲酰胺 Reaction_04_01_2016_105133
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1. Single Step
92%
Overview
Steps/Stages Notes
1.1R:NH3, R:H2O, S:H2O
Reactants: 1, Reagents: 2, Solvents: 1, Steps:
1, Stages: 1, Most stages in any one step: 1
References
Ammonolysis of cyclic aromatic acid imides
By Arkhipova, I. A. et al
From Zhurnal Organicheskoi Khimii, 27(3),
621-8; 1991
CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.
2. Single Step
81%
Overview
Steps/Stages Notes
1.1R:NH3, S:H2O, 24 h, rt
literature preparation, Reactants: 1, Reagents:
1, Solvents: 1, Steps: 1, Stages: 1, Most
stages in any one step: 1
References
ONSH: Optimization of Oxidative
Alkylamination Reactions through Study of
the Reaction Mechanism
By Verbeeck, Stefan et al
From Journal of Organic Chemistry, 75(15),
5126-5133; 2010
Experimental Procedure
1H NMR (DMSO-d6): δ7.69 (s, 2H), 7.43-7.49 (m, 4H), 7.31 (s, 2H). 13C NMR (DMSO-d6) δ: 170.7,
136.7, 129.7, 128.1. HRMS (ESI) for C8H9N2O2+ [M + H]+ , calcd 165.0659, found 165.0645. CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.
3. Single Step
81%
Overview
Steps/Stages Notes
1.1R:NH3, S:H2O, 24 h, rt
literature preparation, Reactants: 1, Reagents:
1, Solvents: 1, Steps: 1, Stages: 1, Most
stages in any one step: 1
References
ONSH: Optimization of Oxidative
Alkylamination Reactions through Study of
the Reaction Mechanism
By Verbeeck, Stefan et al
From Journal of Organic Chemistry, 75(15),
5126-5133; 2010
CASREACT ®: Copyright © 2016 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.
4. Single Step
Overview
Steps/Stages Notes