On Schrodinger Flows to the Hyperbolic 2-space

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硅氮及亚硫酸

硅氮及亚硫酸

Synthesis of a sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst and applications in the hydrolysis of celluloseAnanda S.Amarasekara ⁎,Onome S.OwerehDepartment of Chemistry,Prairie View A&M University,Prairie View,TX 77446,USAa b s t r a c ta r t i c l e i n f o Article history:Received 27February 2010Received in revised form 17May 2010Accepted 19May 2010Available online 26May 2010Keywords:Ionic liquid Acid catalyst Modi fied silica Cellulose HydrolysisA sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst was prepared in 68%overall yield from 3-chloropropyl silica by a simple two step method involving nucleophilic substitution of chlorine with imidazole,then condensation with 1,3-propanesultone and acidi fication using HCl.This silica supported acid catalyst was shown to be effective in the hydrolysis of cellulose (DP ∼450)dissolved in 1-n -butyl-3-methylimidazolium chloride at 70°C,producing glucose and total reducing sugars in 26and 67%yields respectively.Published by Elsevier B.V.1.IntroductionFunctionalized ionic liquids are a signi ficant evolution in the ionic liquid arena and these materials have been developed for various special applications like catalysts,fossil fuel desulfurization reagents,lubricants and as monomers for the synthesis of ionic polymers [1–4].The sulfonic acid group functionalized acidic ionic liquids are an important sub-group in the ionic liquid based catalysts class,and have been used in numerous types of reactions including,esteri fication [5,6],alkylation [7],nitration of aromatic compounds [8],Beckmann rearrangement [9],and alkene polymerizations [10].These acidic ionic liquids can be used in neat or in a solvent in the catalysis applications and requires the separation of the catalyst during the isolation of the product.Immobilization of the functionalized ionic liquids have the bene fits of combining the ionic liquid characteristics with the common advantages of immobilizations,such as ease of recycling and improved selectivity in applications involving catalytic activity.There are several reports on the preparation of ionic liquid covalently grafted silicas as chiral catalysts [11],esteri fication catalysts [12,13],and functionalized hydroxyapatite-encapsulated-Fe 2O 3magnetic nanoparticles [14].Yokoyama et al.has recently reported [15]the immobilization of a sulfonic acid functiona-lized ionic liquid catalyst and application of this catalyst for the esteri fication and nitration of aromatic compounds.In this study,vinyl substituted imidazolium ionic liquid has been grafted on to 3-mercaptopropyltrimethoxysilane modi fied silica gel by free radical polymerization using azodiisobutyronitrile (AIBN)as the initiator.Among various interesting properties of ionic liquids,their ability to dissolve cellulose and lignocellulosic biomass has attracted the attention of a number of researchers in recent times [16,17].In this regard imidazolium ion based 1-n -butyl-3-methylimidazolium chlo-ride (BMIMCl)and 1-allyl-3-methylimidazolium chloride (AMIMCl)are well known for their cellulose dissolution capabilities.However,hydrolysis and degradation of cellulose in the ionic liquid medium is a relatively less explored application for these systems.Zhao et al.has recently reported [18,19]the homogeneous phase hydrolysis of cellulose using concentrated sulfuric acid as the catalyst in 1-n -butyl-3-methylimidazolium chloride medium without any pre-treatment.Furthermore,solid acid catalysts like HY-Zeolite are also known to be effective in the hydrolysis of cellulose in BMIMCl medium [20].Recently,we have shown [21]that cellulose dissolved in Brönsted acidic ionic liquids 1-(1-propylsulfonic)-3-methylimidazo-lium chloride and 1-(1-butylsulfonic)-3-methylimidazolium chloride can be hydrolyzed at 70°C under atmospheric pressure by the addition of 2.0equivalents of water per glucose unit to give glucose along with other reducing sugars.In these experiments,the hydrolysis of Sigmacell cellulose (DP ∼450)in 1-(1-propylsulfonic)-3-methyli-midazolium chloride produced the highest total reducing sugar (62%)and glucose (14%)yields,and was attained with 1h of preheating at 70°C and 30min heating at 70°C,after adding water.Our interest in the use of ionic liquid medium for the acid catalyzed hydrolysis of cellulose into glucose and fermentable sugars for the production of cellulosic-ethanol has led us to study the immobilizationCatalysis Communications 11(2010)1072–1075⁎Corresponding author.Tel.:+19362613107;fax:+19362613117.E-mail address:asamarasekara@ (A.S.Amarasekara).1566-7367/$–see front matter.Published by Elsevier B.V.doi:10.1016/j.catcom.2010.05.012Contents lists available at ScienceDirectCatalysis Communicationsj o u r n a l h o m e p a g e :w ww.e l s ev i e r.c o m /l o c a t e /c a tc o mof sulfonic acid functionalized ionic liquids on silica surface.In this communication we report an ef ficient and simple two step preparation of imidazolium based acidic ionic liquid modi fied silica using 3-chloropropyl silica as shown in Fig.1,and application of this catalyst for the hydrolysis of cellulose in BMIMCl medium.2.Experimental2.1.Materials and instrumentationFluka 60738silica gel 60,220–440mesh (particle size 0.035–0.070mm)was used for the preparation of 3-chloropropyl silica (1).(3-Chloropropyl)triethoxysilane,imidazole,1,3-propanesultone,1-n -butyl-3-methylimidazolium chloride (BMIMCl),and Sigmacell®cel-lulose (DP ∼450)were purchased from Aldrich Chemical Co.FT-IR spectra were recorded on a JASCO-470PLUS IR spectrometer using KBr pellets.Thermogravimetric analysis was carried out in air using TA instruments TGA 2050system.Elemental analysis was performed at QTI laboratories,New Jersey.Total reducing sugars (TRS)and glucose concentrations in aqueous solutions were determined using a Carey 50UV –Vis spectrophotometer and 1cm quartz cells.2.2.Synthesis of 3-chloropropyl silica (1)3-Chloropropyl silica (1)was prepared by using a modi fication of the method used by Adam et al.[22].A mixture silica (10.0g)and (3-chloropropyl)triethoxysilane (10.0mL,9.42g,42.5mmol)in 15mL of toluene was prepared and magnetically stirred for 15min at room temperature,and then re fluxed for 24h.The reaction mixture was cooled,and the product was filtered and repeatedly washed with toluene (3×10mL)and dried under reduced pressure at 100°C for 8h to produce 3-chloropropyl silica 1(10.9g).IR 465,699,802,1096,1638,2963,3453cm −1TGA:stable up to 270°C,5.5%weight loss with the decomposition of all organic structure at 660°C.Chloropropyl group loading was calculated as 0.71mmol/g by using thermogravimetric analysis data.2.3.Synthesis of 3-(1-imidazole)propyl silica (2)To a solution of imidazole (0.774g,11.38mmol)in 25mL of dry benzene,50%sodium hydride in mineral oil (0.546g,11.38mmol)was added and stirred under a nitrogen atmosphere at room temperature for 30min to give sodium imidazole.Then 3-chloropropyl silica (1)(5.00g,3.55mmol of Cl)was added and the mixture was re fluxed under a nitrogen atmosphere for 24h.The resulting product was filtered and washed with ethanol (3×20mL)and dried under vacuum at 100°C for 24h to give 4.93g of 3-(1-imidazole)propyl silica (2).IR 475,797,1093,1513,1638,2962,3453cm −1TGA:stable up to 224°C,7.5%weight loss with the decomposition of all organic structure at 550°C.3-(1-Imidazole)propyl group loading was calculated as 0.69mmol/g by using thermogravimetric analysis data.2.4.Synthesis of sulfonic acid functionalized acidic ionic liquid modi fied silica (3)3-(1-Imidazole)propyl silica (2)(3.78g, 2.61mmol of imidazole group)was suspended in 5mL of dry toluene and 1,3-propanesultone (0.320g,2.62mmol)was added.The resulting mixture was stirred at 100°C in an oil bath for 6h,and then cooled to room temperature,filtered and washed with dry toluene (3×10mL)to give imidazolium salt grafted silica.The intermediate was then treated with 36%w/w concentrated hydrochloric acid (0.266g,2.62mmol)and allowed to stand at room temperature for 24h.The resulting product was washed with ether (3×20mL),dried under vacuum at 100°C for 24h to give 3.96g of sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3)IR 463,803,1102,1565,1640,2932,3447cm −1Found:C,6.82;H,1.49;N,1.70%.Calc.for SiO 2·0.0486(C 9H 16N 2-SO 2Cl)·0.1H 2O:C,7.01;H,1.32;N,1.82%.TGA:stable up to 220°C,17.8%weight loss with the decomposi-tion of all organic structure at 660°C.Sulfonic acid group loading was calculated as 0.67mmol/g by using thermogravimetric analysis data.Determination of acidic sites:Titration of acidic ionic liquid modi fied silica catalyst (3)with 5.05×10−2M aq.NaOH,using phenolphthalein as the indicator gave SO 3H group loading as 0.677mmol/g.2.5.Synthesis of sulfonated silica (4)Sulfonated silica (4)was prepared by reacting silica with neat chlorosulfonic acid at room temperature,as shown in Fig.2,following the literature procedure [23].The acidic site loading in this sulfonated silica (4)was determined as 2.52mmol/g by titration with 5.05×10−2M aq.NaOH,using phenolphthalein as the indicator.2.6.General experimental procedure for hydrolysis of cellulose using 3,4,or H 2SO 4as catalystCellulose (0.030g,0.185mmol of glucose unit of cellulose)was dissolved in 0.300g of 1-n -butyl-3-methylimidazolium chloride (BMIMCl)ionic liquid by heating at 80°C for 4h.Then catalyst (5–10mol%),and deionized water (6.7μL,2.0equivalents/glucose unit of cellulose)were added and the sample was warmed in a thermostated water bath for a pre-determined time for the hydrolysis of cellulose.Then the reaction was quenched by adding 10.0mL of deionized water and transferred to a centrifuge tube and centrifuged at 3500rpm for 6min to precipitate and recover the acidic ionic liquid modi fied silica catalyst.The clear supernatant was collected and the acidic ionic liquid modi fied silica catalyst was repeatedly washed (dispersion in 3mL of deionized water followed by centrifugation,three cycles)for recycling experiments.The supernatant and the washings were combined and the total reducing sugar (TRS)and glucose produced during the hydrolysis of cellulose were measured using the procedures described in the Sections 2.6and 2.7.The average TRS and glucose yields produced in duplicate experiments are shown in Table 1as entries 1–8.Fig.1.Synthesis of sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3).1073A.S.Amarasekara,O.S.Owereh /Catalysis Communications 11(2010)1072–10752.7.Total reducing sugar (TRS)assay for cellulose hydrolyzate 2.50mL of the clear solution from the centrifuge tube was transferred to a vial and 0.50mL of DNS reagent [24]was added.The resulting solution was heated at 90°C for 5.0min to develop the red-orange color.Then the absorbance was measured at 550nm using 1cm quartz cells and Carey 50UV –Vis spectrophotometer.TRS Concentration in the solution was calculated by employing a standard curve prepared using glucose.2.8.Glucose assay for cellulose hydrolyzate1.0mL of the clear solution from the centrifuge tube was transferred to a vial,and2.0mL of glucose assay reagent [25](Sigma-Aldrich Glu 20kit)was added.The resulting solution was heated at 37°C for 30min,and reaction was quenched by adding 2.0mL of 12N H 2SO 4to give a pink solution.Then the absorbance was measured at 540nm using 1cm quartz cells and Carey 50UV –Vis spectrophotometer.Glucose concentration in the solution was calculated by employing a standard curve prepared using glucose.2.9.Reuse of the sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3)The washed acidic ionic liquid modi fied silica catalyst (3)was collected and dried in an oven at 105°C for 24h.This recycled catalyst was used for the hydrolysis of cellulose using procedure 2.5and the hydrolyzate was analyzed using procedures 2.6and 2.7.The results of reusing the same catalyst sample in five cycles are shown in Table 2.3.Results and discussion3.1.Synthesis of sulfonic acid functionalized acidic ionic liquid modi fied silica (3)Sulfonic acid functionalized acidic ionic liquid modi fied silica (3)was synthesized in two steps,and 68%overall yield as shown in Fig.1.3-Chloropropylsilica (1)was first prepared by reaction of (3-chlor-opropyl)triethoxysilane with silica and then nucleophilic substitution of the chlorine with imidazole group gave 3-(1-imidazole)propyl silica (2).Condensation of 3-(1-imidazole)propyl silica (2)with 1,3-propanesul-tone produced the imidazole salt,which was treated with one equivalent of hydrochloric acid to give the sulfonic acid functionalized acidic ionic liquid modi fied silica (3).This is a simple two step linear synthesis of acidic ionic liquid grafted silica when compared with the earlier approach for the preparation of a similar catalyst [15].3.2.Structural characterization of sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3)3.2.1.Elemental analysis and TG –DTGAcidic ionic liquid modi fied silica (3)was characterized using elemental analysis,thermogravimetric –derivative thermogravimetric (TG –DTG)analysis,and FT-IR spectroscopy.The thermogravimetric analysis (TG)curve showed (Fig.3)an initial weight loss of 2.4%up to 110°C due to surface silanol groups and the adsorbed water in plete loss of all the covalently attached organic structure is seen in the 220–660°C temperature range leaving SiO 2,and the organic fraction corresponds to 17.8%weight of the acidic ionic liquid modi fied silica.This decomposition of the organic structure occurs in two steps and the two peaks in the DTG curve at 390and 532°C,are related to 13.0and 4.8%weight losses.The immobilized acid catalyst is apparently stable up to about 220°C.By using the thermogravimetric data,the empirical formula of the catalyst can be calculated as SiO 2·0.0486(C 9H 16N 2SO 3Cl)·0.1H 2O.Structural characterization for the catalyst 3was supported by elemental analysis data shown in Section 2.4.These CHN analysis results are within ±0.19%of the CHN percentages calculated using thermogravimetric analysis based formula:SiO 2·0.0486(C 9H 16N 2SO 3Cl)·0.1H 2O.3.2.2.FT-IRThe FT-IR spectrum of the functionalized acidic ionic liquid modi fied silica (3)is shown in Fig.4.The peak at 1565cm −1canbeFig.2.Synthesis of sulfonated silica (4).Table 1Average percent yields of TRS and glucose produced in duplicate experiments of hydrolysis of untreated cellulose using sulfonic acid functionalized acidic ionic liquid modi fied silica (3),H 2SO 4,sulfonated silica (4),and 1-(1-propylsulfonic)-3-methyli-midazolium chloride (PSMIMCl).EntryCatalyst (mol%)Temperature (°C)Time (h)Yield (%)Ref.TRS Glucose 13(5)a 70 2.02610This work 23(5)a 70 4.02810This work 33(10)a 70 4.05215This work 43(10)a 70 6.06726This work 53(10)a 7010.05519This work 63(10)a90 6.02912This work 7H 2SO 4(10)a 70 6.0386This work 84(10)a70 6.02411This work 9PSMIMCl b 700.56214[21]10PSMIMCl b 70 1.0427[21]11PSMIMCl b704.0294[21]a0.030g of cellulose (DP ∼450)dissolved in 0.300g of 1-n -butyl-3-methylimidazolium chloride (BMIMCl),and 6.7μL of H 2O were added before the hydrolysis.b0.030g of cellulose (DP ∼450)dissolved in 0.300g of 1-(1-propylsulfonic)-3-methyli-midazolium chloride (PSMIMCl),and 6.7μL of H 2O were added before the hydrolysis.Table 2Average percent yields of TRS and glucose produced in duplicate experiments reutilizing catalyst (3)for the hydrolysis of untreated cellulose (DP ∼450).RunYield (%)TRS Glucose 16726265263642446025560220.030g of cellulose (DP ∼450)dissolved in 0.300g of 1-n -butyl-3-methylimidazolium chloride (BMIMCl),and 10mol%catalyst were used in all experiments.Reaction time:6h.Temperature:70°C and 6.7μL of H 2O was added before thehydrolysis.Fig.3.TG –DTG of sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3).1074 A.S.Amarasekara,O.S.Owereh /Catalysis Communications 11(2010)1072–1075assigned to the imidazolium ring,and Yokoyama has reported [15]a similar absorption at 1563cm −1for an imidazolium system attached to a silica surface through alkyl sul fide tether in their preparation of ionic liquid modi fied silica.The Si –O absorption of silica can be observed as a strong peak at 1102cm −1,whereas the weak absorption at 2932cm −1can be assigned to the C –H bonds in 3.Furthermore,the broad absorption in the region of 3447cm −1is due to the Si –OH groups on the surface of the silica.parison of the catalytic activity of acidic ionic liquid modi fied silica catalyst 3with other catalystsHydrolysis of cellulose using acidic ionic liquid modi fied silica catalyst produced glucose and other reducing sugars.The TRS and glucose yields produced in these hydrolysis experiments are shown in Table 1.Initial experiments using 5mol%of the catalyst 3(entries 1and 2)gave relatively low TRS and glucose yields,therefore the catalyst loading was increased to 10mol%in the subsequent set of experiments.The highest TRS and glucose yields of 67and 27%respectively were obtained in the experiment using 10mol%of catalyst 3,at 70°C after a 6h reaction time (entry 4).Heating the sample at 70°C for a longer time (entry 5)or at a higher temperature (entry 6)failed to give better yields of TRS and glucose,indicating the importance of reaction time and temperature in the hydrolysis reaction.Furthermore,longer heating times (entry 5)and higher temperatures (entry 6)produced excessive charring of the sample,giving black residues,and thus lowering the TRS and glucose yields.The experiment using 10mol%H 2SO 4catalyst (entry 7)produced 38%TRS yield and low 6%glucose yield.Sulfonated silica (4)produced only 24%TRS and 11%glucose (entry 8),showing the importance of the imidazolium chloride tether.The higher catalytic activity of acidic ionic liquid modi fied silica catalyst (3)may be due to hydrogen bonding interactions of chloride ion with the hydrogens of cellulose OH groups.Entries 9–11shows the results from our previous work on hydrolysis of cellulose using 1-(1-propylsulfonic)-3-methylimidazo-lium chloride (PSMIMCl)as the solvent as well as the catalyst.Even though,good TRS values are obtained in shorter times (entry 9;62%TRS in 0.5h)using PSMIMCl medium,glucose yields are comparatively lower in these experiments.Furthermore,longer reaction times like 4h (entry 11)resulted in much lower TRS and glucose values.3.4.Reuse of the catalyst (3)The reusability of the catalyst (3)was tested by using the same catalyst sample in five catalytic cycles using 10mol%of catalyst in the hydrolysis of cellulose at 70°C for 6h,and the results of these experiments are shown in Table 2.This catalyst recycling experiment shows that sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3)can be reused for the hydrolysis of cellulose in BMIMCl medium with a small loss of catalytic activity.4.ConclusionIn summary,we have demonstrated that sulfonic acid functiona-lized acidic ionic liquid modi fied silica (3)can be prepared in 68%overall yield from 3-chloropropyl silica (1),in a simple two step method by using nucleophilic substitution reaction of chlorine with imidazole anion and then condensation of the alkylimidazole silica with 1,3-propane sultone followed by acidi fication with HCl.The immobilized acidic ionic liquid catalyst (3)is shown to be effective in the hydrolysis of cellulose dissolved in 1-n -butyl-3-methylimidazo-lium chloride at 70°C and at atmospheric pressure.Additionally,the catalyst can be recovered through a simple separation protocol and can be reused with a small loss in the activity.AcknowledgmentsAuthors would like to thank Center for Environmentally Bene ficial Catalysis (CEBC)—University of Kansas,American Chemical Society-PRF grant UR1-49436and NSF grant CBET-0929970for financial support.References[1]J.H.Davis,Chem.Lett.33(2004)1072–1077.[2]Z.F.Fei,T.J.Geldbach,D.B.Zhao,P.J.Dyson,Chem.Eur.J.12(2006)2122–2130.[3]X.Li,D.Zhao,Z.Fei,L.Wang,Sci.China Ser.B 49(2006)385–401.[4]H.Olivier-Bourbigou,L.Magna,D.Morvan,Appl.Catal.,A 373(2010)1–56.[5] D.Jiang,Y.Y.Wang,L.Y.Dai,React.Kinet.Catal.Lett.93(2008)257–263.[6]Y.Zhao,J.Long,F.Deng,X.Liu,Z.Li,C.Xia,J.Peng,mun.10(2009)732–736.[7]K.Qiao,C.Yokoyama,Chem.Lett.33(2004)472–473.[8]K.Qiao,C.Yokoyama,Chem.Lett.33(2004)808–809.[9]K.Qiao,Y.Deng,C.Yokoyama,H.Sato,M.Yamashina,Chem.Lett.33(2004)1350–1351.[10]Y.Gu,F.Shi,Y.Deng,mun.4(2003)597–601.[11] B.Gadenne,P.Hesemann,V.Polshettiwar,J.J.E.Moreau,Eur.J.Inorg.Chem.(2006)3697–3702.[12]W.Hui,J.Zhang,G.Guan,Shiyou Huagong 38(2009)134–138.[13]J.Zhang,W.Hui,G.Guan,Huaxue Fanying Gongcheng Yu Gongyi 24(2008)503–508.[14]Y.Zhang,Y.Zhao,C.Xia,J.Mol.Catal.A:Chem.306(2009)107–112.[15]K.Qiao,H.Hagiwara,C.Yokoyama,J.Mol.Catal.A:Chem.246(2006)65–69.[16] A.Pinkert,K.N.Marsh,S.Pang,M.P.Staiger,Chem.Rev.109(2009)6712–6728.[17]L.Feng,Z.L.Chen,J.Mol.Liq.142(2008)1–5.[18] C.Li,Z.K.Zhao,Adv.Synth.Catal.349(2007)1847–1850.[19] C.Li,Q.Wang,Z.K.Zhao,Green Chem.2(2008)177–182.[20]Z.Zhang,Z.K.Zhao,Carbohydr.Res.344(2009)2069–2072.[21] A.S.Amarasekara,O.S.Owereh,Ind.Eng.Chem.Res.48(2009)10152–10155.[22] F.Adam,H.Osman,K.M.Hello,J.Colloid Interface Sci.331(2009)143–147.[23]H.R.Shaterian,M.Ghashang,M.Feyzi,Appl.Catal.,A 345(2008)128–133.[24] C.Breuil,J.N.Saddler,Enzyme Microb.Technol.7(1985)327–332.[25]H.U.Bergmeyer,E.Bernt,in:H.U.Bergmeyer (Ed.),Methods of Enzymatic Analysis,Academic Press,New York,1974,pp.1205–1212.Fig.4.FT-IR spectrum of sulfonic acid functionalized acidic ionic liquid modi fied silica catalyst (3).1075A.S.Amarasekara,O.S.Owereh /Catalysis Communications 11(2010)1072–1075。

海底两万里中物理学的句子

海底两万里中物理学的句子

海底两万里中物理学的句子英文回答:Physics plays a significant role in Jules Verne's novel "Twenty Thousand Leagues Under the Sea." As the story follows the adventures of Professor Aronnax, Ned Land, and Conseil aboard the Nautilus, many instances highlight the application of physics principles.One example is the concept of buoyancy. The Nautilus, being a submarine, must maintain neutral buoyancy to navigate underwater. This is achieved by adjusting the amount of water in the ballast tanks. By controlling the density of the Nautilus, Captain Nemo ensures that the upward force exerted by the water equals the downward force of the submarine, allowing it to float at a desired depth. This demonstrates Archimedes' principle, which states that an object immersed in a fluid experiences an upward buoyant force equal to the weight of the fluid it displaces.Another physics concept explored in the novel is pressure. As the Nautilus dives deeper into the ocean, the pressure increases significantly. The characters experience this firsthand when they descend to great depths and feel the pressure on their bodies. This aligns with Pascal's principle, which states that pressure is transmitted uniformly in all directions in a fluid. The immense pressure at great depths is a result of the weight of the water above pressing down on the submarine.Furthermore, the novel touches upon the principles of electricity and magnetism. The Nautilus is powered by electricity, and Verne describes the use of electric motors to propel the submarine through the water. The concept of electromagnetism is also evident in the use of magnetic fields to navigate and detect underwater objects. These applications of physics showcase the integration of scientific knowledge into the fictional world of the Nautilus.中文回答:物理学在朱尔·凡尔纳的小说《海底两万里》中起着重要的作用。

Thermal Science and Engineering

Thermal Science and Engineering

Thermal Science and Engineering Thermal science and engineering is a captivating field that delves into the intricate world of heat transfer and its applications. It explores the fundamental principles governing the movement of thermal energy and seeks to harness this knowledge for the betterment of society. From the design of efficient power plants to the development of innovative cooling systems, thermal science plays a pivotal role in shaping our modern world. At the heart of thermal science lies the concept of heat transfer, the process by which thermal energy migrates from regions of higher temperature to those of lower temperature. This transfer can occur through three primary mechanisms: conduction, convection, and radiation. Conduction involves the transfer of heat through a material medium, such as a metal rod, while convection relies on the movement of fluids, like air or water, to carry heat away. Radiation, on the other hand, transmits heat in the form of electromagnetic waves, requiring no physical medium for propagation. The study of thermal science encompasses a wide range of disciplines, including thermodynamics, fluid mechanics, and heat transfer. Thermodynamics provides a framework for understanding the relationship between heat, work, temperature, and energy. Fluid mechanics deals with the behavior of fluids at rest and in motion, crucial for analyzing heat transfer in systems involving fluids. Heat transfer, as mentioned earlier, focuses on the mechanisms and rates of heat transfer between different objects or systems. Thermal engineering leverages the principles of thermal science to design, analyze, and optimize systems involving heat transfer. It encompasses a vast array of applications, including power generation, refrigeration, air conditioning, and materials processing. Power plants, for instance, rely on the principles of thermodynamics and heat transfer to convert thermal energy into electricity. Refrigeration and air conditioning systemsexploit the properties of refrigerants to transfer heat from one location to another, providing us with comfortable living and working environments. The advancements in thermal science and engineering have had a profound impact on our daily lives. They have enabled the development of more efficient and environmentally friendly power plants, reducing our reliance on fossil fuels. Innovations in refrigeration and air conditioning have improved food preservation,enhanced comfort levels, and facilitated the growth of various industries. Moreover, advances in materials processing, driven by thermal science, have led to the creation of new materials with exceptional properties, paving the way for technological breakthroughs. In conclusion, thermal science and engineering is an indispensable field that underpins numerous technological advancements andsocietal benefits. Its principles govern the movement of thermal energy, enabling us to harness this energy for various purposes. From power generation to refrigeration, from materials processing to environmental sustainability, thermal science plays a crucial role in shaping our world and improving our quality of life. As we continue to push the boundaries of knowledge and innovation, the field of thermal science and engineering holds immense promise for addressing future challenges and creating a more sustainable future.。

城市污水处理厂设计(氧化沟工艺)

城市污水处理厂设计(氧化沟工艺)

城市污水处理厂设计(氧化沟工艺)贾琳琳(复旦大学化学与环境科学学院环境工程专业071班)指导老师:岳思羽[摘要]本设计是某城市污水处理厂的初步设计和施工图设计,此污水处理厂主要处理城市生活污水,水质较为复杂。

根据设计要求,该污水处理厂进水中N、P含量均偏高,在去除BOD5和SS的同时,还需要进行脱氮除磷处理,故采用采用以Carrousel氧化沟为主体的污水处理工艺流程,以及以重力式浓缩池为主体的污泥工艺流程。

该工艺具有工艺流程短、处理效果好、出水水质稳定、剩余污泥少、运行管理方便、基建与运行费用低等特点。

因此,更具有广泛的适应性,完全适合本设计的实际要求。

[关键词]城市污水处理厂Carrousel氧化沟重力式污泥浓缩池The Primary Design of an Urban Sewage Treatment PlantJia Linlin(Grade06, Class1, Environmental Engineering,School of Chemical and Environmental Sciences, Shaanxi University of Technology,Hanzhong 723001,Shaanxi)Tutor:Yue SiyuAbstract: It is a primary design and construction drawing for the sewage treatment plant development zone。

The municipal sewage is mainly treated in this plant。

Its water quality is more complicated。

According to the demands for the design, the contents of nitrogen and phosphorus are high in the water quality of this project 。

专业英语课文翻译

专业英语课文翻译

School of chemical engineering and pharmaceuticaltest tubes 试管test tube holder试管夹test tube brush 试管刷test tube rack试管架beaker烧杯stirring搅拌棒thermometer温度计boiling flask长颈烧瓶Florence flask平底烧瓶flask,round bottom,two-neck boiling flask,three-neck conical flask锥形瓶wide-mouth bottle广口瓶graduated cylinder量筒gas measuring tube气体检测管volumetric flask容量瓶transfer pipette移液管Geiser burette(stopcock)酸式滴定管funnel漏斗Mohr burette(with pinchcock)碱式滴定管watch glass表面皿evaporating dish蒸发皿ground joint磨口连接Petri dish有盖培养皿desiccators干燥皿long-stem funnel长颈漏斗filter funnel过滤漏斗Büchner funnel瓷漏斗separatory funnel分液漏斗Hirsh funnel赫尔什漏斗filter flask 吸滤瓶Thiele melting point tube蒂勒熔点管plastic squeez e bottle塑料洗瓶 medicine dropper药用滴管rubber pipette bulb 吸球microspatula微型压舌板pipet吸量管mortar and pestle研体及研钵filter paper滤纸Bunsen burner煤气灯burette stand滴定管架support ring支撑环ring stand环架distilling head蒸馏头side-arm distillation flask侧臂蒸馏烧瓶air condenser空气冷凝器centrifuge tube离心管fractionating column精(分)馏管Graham condenser蛇形冷凝器crucible坩埚crucible tongs坩埚钳beaker tong烧杯钳economy extension clamp经济扩展夹extension clamp牵引夹utility clamp铁试管夹hose clamp软管夹 burette clamp pinchcock;pinch clamp弹簧夹 screw clamp 螺丝钳ring clamp 环形夹goggles护目镜stopcock活塞wire gauze铁丝网analytical balance分析天平分析化学absolute error绝对误差accuracy准确度assay化验analyte(被)分析物calibration校准constituent成分coefficient of variation变异系数confidence level置信水平detection limit检出限determination测定estimation 估算equivalent point等当点gross error总误差impurity杂质indicator指示剂interference干扰internal standard内标level of significance显着性水平 limit of quantitation定量限masking掩蔽matrix基体precision精确度primary standard原始标准物purity纯度qualitative analysis定性分析 quantitative analysis定量分析random error偶然误差reagent试剂relative error相对误差robustness耐用性sample样品relative standard deviation相对标准偏差 selectivity选择性sensitivity灵敏度specificity专属性titration滴定significant figure有效数字solubility product溶度积standard addition标准加入法standard deviation标准偏差standardization标定法stoichiometric point化学计量点systematic error系统误差有机化学acid anhydride 酸酐acyl halide 酰卤alcohol 醇aldehyde 醛aliphatic 脂肪族的alkene 烯烃alkyne炔allyl烯丙基amide氨基化合物amino acid 氨基酸aromatic compound 芳香烃化合物amine胺butyl 丁基aromatic ring芳环,苯环 branched-chain支链chain链carbonyl羰基carboxyl羧基chelate螯合chiral center手性中心conformers构象copolymer共聚物derivative 衍生物dextrorotatary右旋性的diazotization重氮化作用dichloromethane二氯甲烷ester酯ethyl乙基fatty acid脂肪酸functional group 官能团general formula 通式glycerol 甘油,丙三醇heptyl 庚基heterocyclie 杂环的hexyl 己基homolog 同系物hydrocarbon 烃,碳氢化合物hydrophilic 亲水的hydrophobic 疏水的hydroxide 烃基ketone 酮levorotatory左旋性的methyl 甲基molecular formula分子式monomer单体octyl辛基open chain开链optical activity旋光性(度)organic 有机的organic chemistry 有机化学organic compounds有机化合物pentyl戊基phenol苯酚phenyl苯基polymer 聚合物,聚合体propyl丙基ring-shaped环状结构 zwitterion兼性离子saturated compound饱和化合物side chain侧链straight chain 直链tautomer互变(异构)体structural formula结构式triglyceride甘油三酸脂unsaturated compound不饱和化合物物理化学activation energy活化能adiabat绝热线amplitude振幅collision theory碰撞理论empirical temperature假定温度enthalpy焓enthalpy of combustion燃烧焓enthalpy of fusion熔化热enthalpy of hydration水合热enthalpy of reaction反应热enthalpy o f sublimation升华热enthalpy of vaporization汽化热entropy熵first law热力学第一定律first order reaction一级反应free energy自由能Hess’s law盖斯定律Gibbs free energy offormation吉布斯生成能heat capacity热容internal energy内能isobar等压线isochore等容线isotherm等温线kinetic energy动能latent heat潜能Planck’s constant普朗克常数potential energy势能quantum量子quantum mechanics量子力学rate law速率定律specific heat比热spontaneous自发的standard enthalpy change标准焓变standard entropy of reaction标准反应熵standard molar entropy标准摩尔熵standard pressure标压state function状态函数thermal energy热能thermochemical equation热化学方程式thermodynamic equilibrium热力学平衡uncertainty principle测不准定理zero order reaction零级反应 zero point energy零点能课文词汇实验安全及记录:eye wash眼药水first-aid kit急救箱gas line输气管safety shower紧急冲淋房water faucet水龙头flow chart流程图loose leaf活页单元操作分类:heat transfer传热Liquid-liquid extraction液液萃取liquid-solid leaching过滤vapor pressure蒸气压membrane separation薄膜分离空气污染:carbon dioxide 二氧化碳carbon monoxide一氧化碳particulate matter颗粒物质photochemical smog光化烟雾primary pollutants一次污染物secondary pollutants二次污染物 stratospheric ozone depletion平流层臭氧消耗sulfur dioxide二氧化硫volcanic eruption火山爆发食品化学:amino acid氨基酸,胺amino group氨基empirical formula实验式,经验式fatty acid脂肪酸peptide bonds肽键polyphenol oxidase 多酚氧化酶salivary amylase唾液淀粉酶 steroid hormone甾类激素table sugar蔗糖triacylglycerol三酰甘油,甘油三酯食品添加剂:acesulfame-K乙酰磺胺酸钾,一种甜味剂adrenal gland肾上腺ionizing radiation致电离辐射food additives食品添加剂monosodium glutamate味精,谷氨酸一钠(味精的化学成分)natural flavors天然食用香料,天然食用调料nutrasweet天冬甜素potassium bromide 溴化钾propyl gallate没食子酸丙酯sodium chloride氯化钠sodium nitraten硝酸钠sodium nitrite亚硝酸钠trans fats反式脂肪genetic food转基因食品food poisoning 食物中毒hazard analysis and critical control points (HACCP)危害分析关键控制点技术maternal and child health care妇幼保健护理national patriotic health campaign committee(NPHCC) 全国爱国卫生运动委员会rural health农村卫生管理the state food and drug administration (SFDA)国家食品药品监督管理局光谱:Astronomical Spectroscopy天文光谱学Laser Spectroscopy激光光谱学 Mass Spectrometry质谱Atomic Absorption Spectroscopy原子吸收光谱Attenuated T otal Reflectance Spectroscopy衰减全反射光谱Electron Paramagnetic Spectroscopy电子顺磁谱Electron Spectroscopy电子光谱Infrared Spectroscopy红外光谱Fourier Transform Spectrosopy傅里叶变换光谱Gamma-ray Spectroscopy伽玛射线光谱Multiplex or Frequency-Modulated Spectroscopy复用或频率调制光谱X-ray SpectroscopyX射线光谱色谱:Gas Chromatography气相色谱High Performance Liquid Chromatography高效液相色谱Thin-Layer Chromatography薄层色谱magnesium silicate gel硅酸镁凝胶retention time保留时间mobile phase流动相stationary phase固定相反应类型:agitated tank搅拌槽catalytic reactor催化反应器batch stirred tank reactor间歇搅拌反应釜continuous stirred tank 连续搅拌釜exothermic reactions放热反应pilot plant试验工厂fluidized bed Reactor流动床反应釜multiphase chemical reactions 多相化学反应packed bed reactor填充床反应器redox reaction氧化还原反应reductant-oxidant氧化还原剂acid base reaction酸碱反应additionreaction加成反应chemical equation化学方程式valence electron价电子combination reaction化合反应hybrid orbital 杂化轨道decomposition reaction分解反应substitution reaction取代(置换)反应Lesson5 Classification of Unit Operations单元操作Fluid flow流体流动它涉及的原理是确定任一流体从一个点到另一个点的流动和输送。

Catalysisand-Catalyst

Catalysisand-Catalyst
Reaction path for conversion of A + B into AB
5
Activation Energy
Activation Energy : The energy required to overcome the reaction barrier. Usually given a symbol Ea or ∆G≠
The last step cannot occur in a Langmuir-Hinshelwood mechanism
17
Eley-Rideal mechanism
Example
The reaction
A2 + 2B = 2AB
may have the following Eley-Rideal mechanism
The Activation Energy (Ea) determines how fast a reaction occurs, the higher Activation barrier, the slower the reaction rate. The lower the Activation barrier, the faster the reaction
(2) Supported Catalyst requires a high surface area support to disperse the primary catalyst the support may also act as a co-catalyst (bi-functional) or secondary catalyst for the reaction (promoter)
AB* = AB + *

关于惠更斯原理的英文作文

关于惠更斯原理的英文作文

关于惠更斯原理的英文作文The Wave Nature of Light and Huygens' PrincipleLight is a fundamental aspect of our universe, and understanding its behavior has been a central focus of scientific inquiry for centuries. One of the key principles that helps explain the wave-like properties of light is Huygens' Principle, named after the Dutch physicist and astronomer Christiaan Huygens.Huygens' Principle states that every point on a wavefront can be considered as a new source of secondary wavelets that spread out in all directions with the same speed as the original wave. The combined effect of these secondary wavelets determines the shape of the wavefront at a later time. This principle helps explain a variety of optical phenomena, including reflection, refraction, and diffraction.To understand Huygens' Principle in more detail, let's consider the case of a plane wave traveling through a medium. Imagine a flat wavefront, such as the surface of a still pond when a stone is dropped in. According to Huygens' Principle, each point on thiswavefront can be considered as a new source of secondary wavelets that spread out in all directions. As time passes, the combined effect of these secondary wavelets creates a new wavefront that maintains the same shape as the original, but has moved forward in the direction of propagation.This principle can also be applied to the case of reflection and refraction. When a wave encounters a boundary between two different media, such as the surface of a mirror or the interface between air and water, Huygens' Principle can be used to predict the behavior of the reflected and refracted waves. The secondary wavelets generated at the boundary interfere with each other, resulting in the familiar patterns of reflection and refraction that we observe in everyday life.One of the key implications of Huygens' Principle is that light can be considered as a wave phenomenon, rather than a stream of particles. This wave-like behavior of light was a significant departure from the prevailing particle-based theories of light that had dominated scientific thought for centuries. Huygens' Principle provided a powerful framework for understanding the propagation of light and the various optical phenomena that we observe.The wave nature of light has important practical applications in a wide range of fields, from telecommunications to medical imaging.For example, the principles of wave optics are fundamental to the design and operation of fiber-optic communication systems, which rely on the propagation of light through waveguides. Similarly, the wave-like properties of light are exploited in technologies such as lasers, which generate highly coherent and directional beams of light.In the field of medical imaging, the wave-like behavior of light is utilized in techniques such as ultrasound imaging and optical coherence tomography (OCT). In ultrasound imaging, high-frequency sound waves are used to create detailed images of the body's internal structures, while in OCT, the interference of low-coherence light is used to generate high-resolution images of biological tissues.Huygens' Principle has also had a profound impact on our understanding of the nature of light and its relationship to other forms of electromagnetic radiation. The wave-like behavior of light, as described by Huygens' Principle, is a fundamental aspect of the broader electromagnetic spectrum, which includes radio waves, microwaves, infrared radiation, visible light, ultraviolet radiation, X-rays, and gamma rays.The wave nature of light has also been crucial in the development of quantum mechanics, which has revolutionized our understanding of the behavior of matter and energy at the atomic and subatomic scales. In quantum mechanics, light is often described as a particle-wave duality, with both particle-like and wave-like properties. This dual nature of light has led to a rich and complex understanding of the fundamental nature of the universe.In conclusion, Huygens' Principle is a powerful and influential concept in the study of optics and the wave-like behavior of light. By considering each point on a wavefront as a new source of secondary wavelets, Huygens' Principle provides a framework for understanding a wide range of optical phenomena, from reflection and refraction to diffraction and interference. The wave-like nature of light, as described by Huygens' Principle, has had far-reaching implications for our understanding of the physical world and has led to numerous technological advancements in fields as diverse as telecommunications, medical imaging, and quantum mechanics.。

托福阅读语法点中的后置定语5大类型介绍

托福阅读语法点中的后置定语5大类型介绍

托福阅读语法点中的后置定语5大类型介绍店铺为大家带来“托福阅读语法点中的后置定语5大类型介绍”,希望对大家托福备考有所帮助。

更多精彩尽请关注店铺!托福阅读语法点中的后置定语5大类型介绍什么是托福阅读中的后置定语?托福阅读中后置定语,顾名思义分为后置和定语两个部分。

后置也就是此种短语出现的位置是在名词之后,定语就是起到修饰限定作用的短语,注意是短语而不是句子,本质上相当于形容词。

所以后置定语就是放在名词的后面起到限定修饰作用的短语。

托福阅读后置定语第一类形容词做后置定语。

如:fossil available.即为可用的化石。

托福阅读后置定语第二类介词短语做后置定语。

如lava on the surface,中on the surface介词短语修饰lava,表示为表面上的熔岩。

托福阅读后置定语第三类现在分词短语做后置定语。

如the blood vessels carrying cooled blood.中的carrying cooled blood就是现在分词短语用来修饰限定the blood vessels,理解为运载着凉的血液的血管。

托福阅读后置定语第四类过去分词短语做后置定语,the gradual drying of the soil caused by its diminished ability中的caused by its diminished ability就是过去分词短语做后置定语修饰the gradual drying of the soil,理解为减少的能力导致的土壤的干燥。

托福阅读后置定语第五类不定式短语做后置定语。

the ability to absorb water中to absorb water限定修饰 the ability,理解为吸收水的能力。

托福阅读TPO31第1篇:Speciation in Geographically Isolated Populations【1】Evolutionary biologists believe that speciation, theformation of a new species, often begins when some kind of physical barrier arises and divides a population of a single species into separate subpopulations. Physical separation between subpopulations promotes the formation of new species because once the members of one subpopulation can no longer mate with members of another subpopulation, they cannot exchange variant genes that arise in one of the subpopulations. In the absences of gene flow between the subpopulations, genetic differences between the groups begin to accumulate. Eventually the subpopulations become so genetically distinct that they cannot interbreed even if the physical barriers between them were removed. At this point the subpopulations have evolved into distinct species. This route to speciation is known as allopatry (“alio-” means “different”,and “patria” means “homeland”).【2】Allopatric speciation may be the main speciation route. This should not be surprising, since allopatry is pretty common. In general, the subpopulations of most species are separated from each other by some measurable distance. So even under normal situations the gene flow among the subpopulations is more of an intermittent trickle than a steady stream. In addition, barriers can rapidly arise and shut off the trickle. For example, in the 1800s a monstrous earthquake changed the course of the Mississippi River, a large river flowing in the central part of the United States of America. The change separated populations of insects now living along opposite shore, completely cutting off gene flow between them.【3】Geographic isolation also can proceed slowly, over great spans of time. We find evidence of such extended events in the fossil record, which affords glimpses into the breakup offormerly continuous environments. For example, during past ice ages, glaciers advanced down through North America and Europe and gradually cut off parts of populations from one another. When the glacier retreated, the separated populations of plants and animals came into contact again. Some groups that had descended from the same parent population were no longer reproductively compatible—they had evolved into separate species. In other groups, however, genetic divergences had not proceeded so far, and the descendants could still interbreed—for them, reproductive isolation was not completed, and so speciation had not occurred.【4】Allopatric speciation can also be brought by the imperceptibly slow but colossal movements of the tectonic plates that make up Earth’s surface. About 5 million years ago such geologic movements created the land bridge between North America and South America that we call the Isthmus of Panama. The formation of the isthmus had important consequences for global patterns of ocean water flow. While previously the gap between the continents had allowed a free flow of water, now the isthmus presented a barrier that divided the Atlantic Ocean from the Pacific Ocean. This division set the stage for allopatric speciation among populations of fishes and other marine species.【5】In the 1980s, John Graves studied two populations of closely related fishes, one population from the Atlantic side of isthmus, the other from the Pacific side. He compared four enzymes found in the muscles of each population. Graves found that all four Pacific enzymes function better at lower temperatures than the four Atlantic versions of the same enzymes. This is significant because Pacific seawater is typically 2 to 3 degrees cooler than seawater on the Atlantic side of isthmus.Analysis by gel electrophoresis revealed slight differences in amino acid sequence of the enzymes of two of the four pairs. This is significant because the amino acid sequence of an enzyme is determined by genes.【6】Graves drew two conclusions from these observations. First, at least some of the observed differences between the enzymes of the Atlantic and Pacific fish populations were not random but were the result of evolutionary adaption. Second, it appears that closely related populations of fishes on both sides of the isthmus are starting to genetically diverge from each other. Because Graves’s study of geographically isolated populations of isthmus fishes offers a glimpse of the beginning of a process of gradual accumulation of mutations that are neutral or adaptive, divergences here might be evidence of allopatric speciation in process.托福阅读TPO31试题第1篇:Speciation in Geographically Isolated Populations1.The word "promotes" in the passage is closest in meaning toA.describes.B.encourages.C.delays.D.requires.2.According to paragraph 1, allopatric speciation involves which of the following?A.The division of a population into subspecies.B.The reuniting of separated populations after they have become distinct species.C.The movement of a population to a new homeland.D.The absence of gene flow between subpopulations.3.Why does the author provide the information that "the subpopulations of most species are separated from each other by some measurable distance"?A.To indicate how scientists are able to determine whether subpopulations of a species are allopatric.B.To define what it means for a group of animals or plants to be a subpopulation.C.To suggest that allopatric speciation is not the only route to subpopulation.D.To help explain why allopatric speciation is a common way for new species to come about.4.The word "accumulate" in the passage is closest in meaning toA.Become more significant.B.Occur randomly.C.Gradually increase in number.D.Cause changes.5.In paragraph 2,why does the author mention that some insect populations were separated from each other by a change in the course of Mississippi River caused by an earthquake?A.To make the point that some kind of physical barrier separates the subpopulations of most species.B.To support the claim that the condition of allopatry can sometimes arise in a short time.C.To provide an example of a situation in which gene flow among the subpopulations of a species happens at a slow rate.D.To explain why insects living along opposite shores of the Mississippi River are very different from each other.6.According to paragraph 3,separation of subpopulations by glaciers resulted in speciation in those groups of plants andanimals thatA.were reproductively isolated even after the glaciers disappeared.B.had adjusted to the old conditions caused by the glaciers.C.were able to survive being separated from their parent population.D.had experienced some genetic divergences from their parent population.7.The word "colossal" in the passage is closet in meaning toA.consistent.B.gradual.C.enormous.D.effective.8.According to paragraph 4, which of the following is true of the geologic movements that brought about the Isthmus of Panama?A.The movements brought populations of certain fishes and marine organisms into contact with one another for the first time.B.The movements transferred populations of fishes and other marine animals between the Pacific and Atlantic Oceans.C.The movements created conditions that allowed water to flow more freely between the Pacific and Atlantic Oceans.D.The movements created conditions for the formation of new species of fishes and other marine animals.9.The word "sequence" in the passage is closet in meaning toA.quality.B.order.C.function.D.number.10.According to paragraph 5, by comparing the enzymesfrom two related groups of fishes on opposite sides of the isthmus, Graves found evidence thatA.there were slight genetic divergences between the two groups.B.the Atlantic group of fishes were descended from the Pacific group of fishes.C.the temperature of water on either side of the isthmus had changed.D.genetic changes in the Atlantic group of fishes were more rapid and frequent than in the Pacific group of fishes.11.It can be inferred from paragraph 5 and 6 that the reason Graves concluded that some of the differences between the Pacific and Atlantic enzymes were not random was thatA.each of the Pacific enzymes works better in cooler waters.B.the Enzymes of the Atlantic fish populations had not changed since the formation of the Isthmus of Panama.C.gel electrophoresis showed that the changes benefited both the Atlantic and the Pacific fish populations.D.the differences between the enzymes disappeared when the two fish populations were experimentally switched to other side of the isthmus.12.Which of the sentence below best expresses the essential information in the highlighted sentence in the passage? Incorrect choices change the meaning in important ways or leave out essential information.A.Graves's study provides evidence that isthmus fishes are in the process of becoming geographically isolated.B.Graves's study of mutating isthmus fishes yields results that differ from results of other studies involving allopatric speciation.C.Graves's study of isolated populations of isthmus fishesprovides some evidence that allopatric speciation might be beginningD.Grave's study indicates that when isolated, populations of isthmus fished register neutral or adaptive mutations.13. Look at the four squares [■] that indicate where the following sentence can be added to the passage.Where would the sentence best fit? The formation of the isthmus had important consequences for global patterns of ocean water flow.Allopatric speciation can also be brought by the imperceptibly slow but colossal movements of the tectonic plates that make up Earth's surface. ■【A】 About 5 million years ago such geologic movements created the land bridge between North America and South America that we call the Isthmus of Panama. The formation of the isthmus had important consequences for global patterns of ocean water flow. ■【B】While previously the gap between the continents had allowed a free flow of water, now the isthmus presented a barrier that divided the Atlantic Ocean from the Pacific Ocean. ■【C】This division set the stage for allopatric speciation among populations of fishes and other marine species. ■【D】14. Directions: An introductory sentence for a brief summary of the passage is provided below. Complete the summary by selecting the THREE answer choices that express the most important ideas in the passage. Some sentences do not belong in the summary because they express ideas that are not presented in the passages or are minor ideas in the passage. This question is worth 2 points.Allopatric speciation takes place when physically separated populations of a single species gradually diverge genetically to the point of becoming unable to interbreedA.Allopatric speciation is common because the gene flow between subpopulations is generally limited and the barriers that completely separate subpopulations can arise in a variety of ways.B.During past ice ages, some, but not all, subpopulations separated by glaciers evolved into distinct species.C.Speciation does not need to take place through allopatry because subpopulations will form distinct species whenever there are adaptive advantages or notD.Physical barriers from glaciers and the movement of tectonic plates form so slowly that the subpopulations on either side of the barriers usually do not form distinct species.E.Graves's study of fish populations separated by the Isthmus of Panama may well provide a picture of the beginning stages of speciation.F.Graves's study of physically separated fish populations show that there must be large differences between the environments of the isolated populations if allopatric speciation is to take place.托福阅读TPO31答案第1篇:Speciation in Geographically Isolated Populations1.promote本身是促进的意思。

氢键相互作用的英文

氢键相互作用的英文

氢键相互作用的英文Hydrogen Bonding Interactions.Introduction.Hydrogen bonding interactions are a crucial aspect of molecular chemistry, playing a pivotal role in determining the properties and behaviors of many substances. These interactions, though relatively weak compared to covalent or ionic bonds, can have profound effects on the stability, solubility, melting and boiling points, as well as the shape and structure of molecules and crystals. Understanding hydrogen bonding is essential for comprehending the chemistry of water, alcohols, acids, bases, and numerous other compounds.Definition and Characteristics of Hydrogen Bonding.Hydrogen bonding is a type of intermolecular attractive force that occurs between a hydrogen atom covalently bondedto a strongly electronegative atom (such as fluorine, oxygen, or nitrogen) and another strongly electronegative atom. The hydrogen atom in this arrangement is partially positively charged due to the high electronegativity of the bonded atom, while the other strongly electronegative atom is partially negatively charged. This partial positive and negative charge creates an electrostatic attraction between the two atoms, resulting in a hydrogen bond.The strength of hydrogen bonds varies depending on several factors, including the electronegativity of the atoms involved, the bond angle, and the presence of other nearby atoms or groups. Generally speaking.。

光速不变原理的英文

光速不变原理的英文

光速不变原理的英文The Principle of the Constancy of the Speed of Light.The principle of the constancy of the speed of light, also known as the special theory of relativity, is a fundamental concept in physics that revolutionized our understanding of space and time. This theory, proposed by Albert Einstein in 1905, states that the speed of light ina vacuum is constant and independent of the motion of the observer or the source of light.Before delving into the intricacies of this principle,it's crucial to understand what light is and how it behaves. Light is a form of electromagnetic radiation that travels through space as waves. These waves oscillateperpendicularly to their direction of propagation, andtheir speed is determined by the properties of the medium through which they travel. In a vacuum, light travels at a constant speed, denoted by the symbol 'c', approximately equal to 299,792,458 meters per second.The significance of the principle of the constancy of the speed of light lies in its implications for physics and cosmology. According to this principle, the speed of lightis the same for all observers, regardless of their relative motion. This means that if two observers are movingrelative to each other, they will measure the speed oflight to be the same, even though their measurements of distance and time will differ.This principle challenges the classical concepts of absolute space and time, introducing the idea of relativity. In the classical view, space and time were considered absolute and unchanging, with all observers agreeing on the measurements of distance and time. However, Einstein's theory suggests that space and time are relative and can be affected by the motion of observers.One of the consequences of the principle of the constancy of the speed of light is time dilation. This phenomenon occurs when time appears to slow down for an observer moving relative to another observer. For example,if an astronaut travels in a spacecraft at a high speed, the time they experience will be slower than the time experienced by someone on Earth. This is because the astronaut's frame of reference is moving relative to the Earth, and the principle of the constancy of the speed of light dictates that the speed of light remains constant regardless of the observer's motion.Another consequence is length contraction. This refers to the phenomenon where an object moving relative to an observer appears to be shorter than it actually is. This is because the moving object's length in the direction of motion is reduced due to the relative motion between the object and the observer.The principle of the constancy of the speed of light has far-reaching implications in physics and cosmology. It underpins many theories and experiments, including the famous Michelson-Morley experiment, which aimed to detect the existence of an ether, a hypothetical medium through which light travels. The negative results of this experiment led to the development of special relativity andthe abandonment of the ether theory.The principle of the constancy of the speed of light also forms the foundation of Einstein's general theory of relativity, which extends the ideas of special relativity to include gravity. General relativity suggests thatgravity is a manifestation of the curvature of spacetime caused by the presence of matter and energy.In conclusion, the principle of the constancy of the speed of light is a fundamental concept in physics that has revolutionized our understanding of space and time. It challenges the classical view of absolute space and time, introducing the idea of relativity and revolutionizing our understanding of the universe. The implications of this principle are vast and far-reaching, touching upon areas such as time dilation, length contraction, and the curvature of spacetime.。

专业英语带译文

专业英语带译文

数字拉丁或希腊前缀烷烃烷基烯烃醇醛中文译名从左至右alkane alkyl alkene alcohol aldehyde 烷烃、烷基、烯烃、醇、醛one mono- methane methyl —methanol methyl aldehyde 甲烷、甲基、甲醇、甲醛two di-bi- ethane ethyl ethene,ethyleneethanol ethyl aldehyde,ethanal 乙烷、乙基、乙烯、乙醇、乙醛three tri- propane propyl propene propanol propylaldehyde 丙four tetra-Quadri-butane butyl butene butanol butyladehyde 丁five pent(a)- pentane pentyl pentene pentanol pentanal 戊six hex(a)- hexane hexyl hexene hexanol hexanal 己seven hept(a)- heptane heptyl heptene heptanol heptanal,heptylaldehyde庚eight oct(a)- octane octyl octene octanol octyl aldehyde 辛nine non(a)- nonane nonyl nonene nonanol nonyl aldehyde 壬ten dec(a)- decane decyl decene decanol decylaldehyde,decanal癸它们能与其它有机化合物自由地混合并能溶于多种有机溶剂中。

They will mix freely with other organic compounds and are often soluble in organic solvents.氧的两对电子可以与两个不直接相连的碳共用而形成单键。

四川大学化工考研884复试面试英语题库翻译原文

四川大学化工考研884复试面试英语题库翻译原文
8. The function of distillation is to separate, by vaporization, a liquid mixture of miscible, and volatile substances into individual components or, in some cases, into groups of components. The separation of a mixture of alcohol and water into its component of liquid nitrogen, oxygen and argon, and of crude petroleum into gasoline, kerosene, fuel oil, and lubrication stock are examples of distillation.
4. A group of operations for separating the components of mixtures is based on the transfer of material from one homogeneous phase to another. Unlike purely mechanical separations, these methods utilize differences in vapor pressure or solubility, not density or particle size .The driving force for transfer is a concentration difference to or a concentration gradient ,much as a temperature difference or a temperature gradient provides the driving force heat transfer.

过程装备与控制工程专业外语(原文+翻译)

过程装备与控制工程专业外语(原文+翻译)

Unit 21Pumps1. IntroductionPump, device used to raise, transfer, or compress liquids and gases. Four' general classes of pumps for liquids are described below t In all of them , steps are taken to prevent cavitation (the formation of a vacuull1), which would reduce the flow and damage the structure of the pump, - pumps used for gases and vapors are usually known as compressors . The study of fluids in motion is called fluid dynamics.1.介绍泵是提出,转移或压缩液体和气体的设备。

下面介绍四种类型的泵。

在所有的这些中,我们一步步采取措施防止气蚀,气蚀将减少流量并且破坏泵的结构。

用来处理气体和蒸汽的泵称为压缩机,研究流体的运动的科学成为流体动力学。

Water Pump, device lor moving water from one location to another, using tubes or other machinery. Water pumps operate under pressures ranging from a fraction of a pound to more than 10,000 pounds per square inch. Everyday examples of water pumps range from small electric pumps that circulate and aerate water in aquariums and fountains to sump pumps that remove 'Water from beneath the foundations of homes.水泵是用管子或其他机械把水从一个地方传到另一个地方。

《物理化学》的中英文翻译

《物理化学》的中英文翻译

《物理化学》的中英文翻译第一篇:《物理化学》的中英文翻译复习《物理化学》过程中,顺便整理了专业名词的翻译,大家凑合着,依我看,简单的会考汉译英,复杂的会考英译汉。

不管怎么样,中文英文背过最好。

如果有错误,赶紧的,说。

1多相系统 heterogeneous system2自由度degree of freedom3相律 phase rule4独立组分数 number of independent component5凝聚系统 condensed system6三相点 triple point7超临界流体 supercritical fluid8超临界流体萃取supercritical fluid extraction9超临界流体色谱supercritical fluid chromatography10泡点 bubbling point11露点dew point12杠杆规则 level rule13连结线 tie line14部分蒸馏(分馏)fractional distillation15缔合分子 associated molecule16最低恒沸点 minimum azeotropic point17最低恒沸混合物low-boiling azeotrope18无水乙醇(绝对乙醇)absolute ethyl alcohol19最高恒沸点maximum azeotropic point20会溶点 consolute point21共轭层 conjugate layer22烟碱 nicotine23蒸汽蒸馏 steam distillation24步冷曲线 cooling curve25热分析法 thermal analysis26低共熔点 eutectic point27低共熔混合物eutectic mixture28异成分熔点 incongruent melting point29转熔温度 peritectic tempreture30固溶体 solid solution31退火 annealing32淬火 quenching33区域熔炼 zone melting34分凝系数 fractional coagulation coefficient35褶点 plait point36等温会溶点 isothermal consolute point37双节点溶解度曲线 binodal solubility cueve38一(二)级相变first(second)order phase transition39超流体 super fluid40顺磁体 paramagnetic substance41铁磁体 ferromagnetic substance第二篇:中英文翻译蓄电池 battery 充电 converter 转换器 charger开关电器Switch electric 按钮开关Button to switch 电源电器Power electric 插头插座 Plug sockets第三篇:中英文翻译Fundamentals This chapter describes the fundamentals of today’s wireless communications.First a detailed description of the radio channel and its modeling are presented, followed by the introduction of the principle of OFDM multi-carrier transmission.In addition, a general overview of the spread spectrum technique, especially DS-CDMA, is given and examples of potential applications for OFDM and DS-CDMA areanalyzed.This introduction is essential for a better understanding of the idea behind the combination of OFDM with the spread spectrum technique, which is briefly introduced in the last part of this chapter.1.1 Radio Channel Characteristics Understanding the characteristics of the communications medium is crucial for the appropriate selection of transmission system architecture, dimensioning of its components, and optimizing system parameters, especially since mobile radio channels are considered to be the most difficult channels, since they suffer from many imperfections like multipath fading, interference, Doppler shift, and shadowing.The choice of system components is totally different if, for instance, multipath propagation with long echoes dominates the radio propagation.Therefore, an accurate channel model describing the behavior of radio wave propagation in different environments such as mobile/fixed and indoor/outdoor is needed.This may allow one, through simulations, to estimate and validate the performance of a given transmission scheme in its several design phases.1.1.1 Understanding Radio Channels In mobile radio channels(see Figure 1-1), the transmitted signal suffers from different effects, which are characterized as follows: Multipath propagation occurs as a consequence of reflections, scattering, and diffraction of the transmitted electromagnetic wave at natural and man-made objects.Thus, at the receiver antenna, a multitude of waves arrives from many different directions with different delays, attenuations, and phases.The superposition of these waves results in amplitude and phase variations of the composite received signal.Doppler spread is caused by moving objects in the mobile radio channel.Changes in the phases and amplitudes of the arriving waves occur which lead to time-variant multipathpropagation.Even small movements on the order of the wavelength may result in a totally different wave superposition.The varying signal strength due to time-variant multipath propagation is referred to as fast fading.Shadowing is caused by obstruction of the transmitted waves by, e.g., hills, buildings, walls, and trees, which results in more or less strong attenuation of the signal pared to fast fading, longer distances have to be covered to significantly change the shadowing constellation.The varying signal strength due to shadowing is called slow fading and can be described by a log-normal distribution [36].Path loss indicates how the mean signal power decays with distance between transmitter and receiver.In free space, the mean signal power decreases with the square of the distance between base station(BS)and terminal station(TS).In a mobile radio channel, where often no line of sight(LOS)path exists, signal power decreases with a power higher than two and is typically in the order of three to five.Variations of the received power due to shadowing and path loss can be efficiently counteracted by power control.In the following, the mobile radio channel is described with respect to its fast fading characteristic.1.1.2 Channel Modeling The mobile radio channel can be characterized by the time-variant channel impulse response h(τ , t)or by the time-variant channel transfer function H(f, t), which is the Fourier transform of h(τ, t).The channel impulse response represents the response of the channel at time t due to an impulse applied at time t −τ.The mobile radio channel is assumed to be a wide-sense stationary random process, i.e., the channel has a fading statistic that remains constant over short periods of time or small spatial distances.In environments with multipath propagation, the channel impulseresponse is composed of a large number of scattered impulses received over Np different paths,Whereand ap, fD,p, ϕp, and τp are the amplitude, the Doppler frequency, the phase, and the propagation delay, respectively, associated with path p, p = 0,..., Np −1.The assigned channel transfer function isThe delays are measured relative to the first detectable path at the receiver.The Doppler Frequencydepends on the velocity v of the terminal station, the speed of light c, the carrier frequency fc, and the angle of incidence αp of a wave assigned to path p.A channel impulse response with corresponding channel transfer function is illustrated in Figure 1-2.The delay power density spectrum ρ(τ)that characterizes the frequency selectivity of the mobile radio channel gives the average power of the channel output as a function of the delay τ.The mean delay τ , the root mean square(RMS)de lay spread τRMS and the maximum delay τmax are characteristic parameters of the delay power density spectrum.The mean delay isWhereFigure 1-2 Time-variant channel impulse response and channel transfer function with frequency-selective fading is the power of path p.The RMS delay spread is defined as Similarly, the Doppler power density spectrum S(fD)can be defined that characterizes the time variance of the mobile radio channel and gives the average power of the channel output as a function of the Doppler frequency fD.The frequency dispersive properties of multipath channels are most commonly quantified by the maximum occurring Doppler frequency fDmax and the Doppler spread fDspread.The Doppler spread is the bandwidth of theDoppler power density spectrum and can take on values up to two times |fDmax|, i.e.,1.1.3Channel Fade Statistics The statistics of the fading process characterize the channel and are of importance for channel model parameter specifications.A simple and often used approach is obtained from the assumption that there is a large number of scatterers in the channel that contribute to the signal at the receiver side.The application of the central limit theorem leads to a complex-valued Gaussian process for the channel impulse response.In the absence of line of sight(LOS)or a dominant component, the process is zero-mean.The magnitude of the corresponding channel transfer functionis a random variable, for brevity denoted by a, with a Rayleigh distribution given byWhereis the average power.The phase is uniformly distributed in the interval [0, 2π].In the case that the multipath channel contains a LOS or dominant component in addition to the randomly moving scatterers, the channel impulse response can no longer be modeled as zero-mean.Under the assumption of a complex-valued Gaussian process for the channel impulse response, the magnitude a of the channel transfer function has a Rice distribution given byThe Rice factor KRice is determined by the ratio of the power of the dominant path to thepower of the scattered paths.I0 is the zero-order modified Bessel function of first kind.The phase is uniformly distributed in the interval [0, 2π].1.1.4Inter-Symbol(ISI)and Inter-Channel Interference(ICI)The delay spread can cause inter-symbol interference(ISI)when adjacent data symbols overlap and interfere with each other due to differentdelays on different propagation paths.The number of interfering symbols in a single-carrier modulated system is given by For high data rate applications with very short symbol duration Td < τmax, the effect of ISI and, with that, the receiver complexity can increase significantly.The effect of ISI can be counteracted by different measures such as time or frequency domain equalization.In spread spectrum systems, rake receivers with several arms are used to reduce the effect of ISI by exploiting the multipath diversity such that individual arms are adapted to different propagation paths.If the duration of the transmitted symbol is significantly larger than the maximum delay Td τmax, the channel produces a negligible amount of ISI.This effect is exploited with multi-carrier transmission where the duration per transmitted symbol increases with the number of sub-carriers Nc and, hence, the amount of ISI decreases.The number of interfering symbols in a multi-carrier modulated system is given byResidual ISI can be eliminated by the use of a guard interval(see Section 1.2).The maximum Doppler spread in mobile radio applications using single-carrier modulation is typically much less than the distance between adjacent channels, such that the effect of interference on adjacent channels due to Doppler spread is not a problem for single-carrier modulated systems.For multi-carrier modulated systems, the sub-channel spacing Fs can become quite small, such that Doppler effects can cause significant ICI.As long as all sub-carriers are affected by a common Doppler shift fD, this Doppler shift can be compensated for in the receiver and ICI can be avoided.However, if Doppler spread in the order of several percent of the sub-carrier spacing occurs, ICI may degrade the system performance significantly.T oavoid performance degradations due to ICI or more complex receivers with ICI equalization, the sub-carrier spacing Fs should be chosen assuch that the effects due to Doppler spread can be neglected(see Chapter 4).This approach corresponds with the philosophy of OFDM described in Section 1.2 and is followed in current OFDM-based wireless standards.Nevertheless, if a multi-carrier system design is chosen such that the Doppler spread is in the order of the sub-carrier spacing or higher, a rake receiver in the frequency domain can be used [22].With the frequency domain rake receiver each branch of the rake resolves a different Doppler frequency.1.1.5Examples of Discrete Multipath Channel Models Various discrete multipath channel models for indoor and outdoor cellular systems with different cell sizes have been specified.These channel models define the statistics of the 5 discrete propagation paths.An overview of widely used discrete multipath channel models is given in the following.COST 207 [8]: The COST 207 channel models specify four outdoor macro cell propagation scenarios by continuous, exponentially decreasing delay power density spectra.Implementations of these power density spectra by discrete taps are given by using up to 12 taps.Examples for settings with 6 taps are listed in Table 1-1.In this table for several propagation environments the corresponding path delay and power profiles are given.Hilly terrain causes the longest echoes.The classical Doppler spectrum with uniformly distributed angles of arrival of the paths can be used for all taps for simplicity.Optionally, different Doppler spectra are defined for the individual taps in [8].The COST 207 channel models are based on channel measurements with a bandwidth of 8–10 MHz in the 900-MHz band used for 2Gsystems such as GSM.COST 231 [9] and COST 259 [10]: These COST actions which are the continuation of COST 207 extend the channel characterization to DCS 1800, DECT, HIPERLAN and UMTS channels, taking into account macro, micro, and pico cell scenarios.Channel models with spatial resolution have been defined in COST 259.The spatial component is introduced by the definition of several clusters with local scatterers, which are located in a circle around the base station.Three types of channel models are defined.The macro cell type has cell sizes from 500 m up to 5000 m and a carrier frequency of 900 MHz or 1.8 GHz.The micro cell type is defined for cell sizes of about 300 m and a carrier frequency of 1.2 GHz or 5 GHz.The pico cell type represents an indoor channel model with cell sizes smaller than 100 m in industrial buildings and in the order of 10 m in an office.The carrier frequency is 2.5 GHz or 24 GHz.COST 273: The COST 273 action additionally takes multi-antenna channel models into account, which are not covered by the previous COST actions.CODIT [7]: These channel models define typical outdoor and indoor propagation scenarios for macro, micro, and pico cells.The fading characteristics of the various propagation environments are specified by the parameters of the Nakagami-m distribution.Every environment is defined in terms of a number of scatterers which can take on values up to 20.Some channel models consider also the angular distribution of the scatterers.They have been developed for the investigation of 3G system proposals.Macro cell channel type models have been developed for carrier frequencies around 900 MHz with 7 MHz bandwidth.The micro and pico cell channel type models have been developed for carrier frequencies between 1.8 GHz and 2 GHz.The bandwidths of the measurements are in the range of 10–100 MHz for macro cells and around 100 MHz for pico cells.JTC [28]: The JTC channel models define indoor and outdoor scenarios by specifying 3 to 10 discrete taps per scenario.The channel models are designed to be applicable for wideband digital mobile radio systems anticipated as candidates for the PCS(Personal Communications Systems)common air interface at carrier frequencies of about 2 GHz.UMTS/UTRA [18][44]: Test propagation scenarios have been defined for UMTS and UTRA system proposals which are developed for frequencies around 2 GHz.The modeling of the multipath propagation corresponds to that used by the COST 207 channel models.HIPERLAN/2 [33]: Five typical indoor propagation scenarios for wireless LANs in the 5 GHz frequency band have been defined.Each scenario is described by 18discrete taps of the delay power density spectrum.The time variance of the channel(Doppler spread)is modeled by a classical Jake’s spectrum with a maximum terminal speed of 3 m/h.Further channel models exist which are, for instance, given in [16].1.1.6Multi-Carrier Channel Modeling Multi-carrier systems can either be simulated in the time domain or, more computationally efficient, in the frequency domain.Preconditions for the frequency domain implementation are the absence of ISI and ICI, the frequency nonselective fading per sub-carrier, and the time-invariance during one OFDM symbol.A proper system design approximately fulfills these preconditions.The discrete channel transfer function adapted to multi-carrier signals results inwhere the continuous channel transfer function H(f, t)is sampled in time at OFDM symbol rate s and in frequency at sub-carrier spacing Fs.The durations is the total OFDM symbol duration including the guardinterval.Finally, a symbol transmitted onsub-channel n of the OFDM symbol i is multiplied by the resulting fading amplitude an,i and rotated by a random phase ϕn,i.The advantage of the frequency domain channel model is that the IFFT and FFT operation for OFDM and inverse OFDM can be avoided and the fading operation results in one complex-valued multiplication per sub-carrier.The discrete multipath channel models introduced in Section 1.1.5 can directly be applied to(1.16).A further simplification of the channel modeling for multi-carrier systems is given by using the so-called uncorrelated fading channel models.1.1.6.1Uncorrelated Fading Channel Models for Multi-Carrier Systems These channel models are based on the assumption that the fading on adjacent data symbols after inverse OFDM and de-interleaving can be considered as uncorrelated [29].This assumption holds when, e.g., a frequency and time interleaver with sufficient interleaving depth is applied.The fading amplitude an,i is chosen from a distribution p(a)according to the considered cell type and the random phase ϕn,I is uniformly distributed in the interval [0,2π].The resulting complex-valued channel fading coefficient is thus generated independently for each sub-carrier and OFDM symbol.For a propagation scenario in a macro cell without LOS, the fading amplitude an,i is generated by a Rayleigh distribution and the channel model is referred to as an uncorrelated Rayleigh fading channel.For smaller cells where often a dominant propagation component occurs, the fading amplitude is chosen from a Rice distribution.The advantages of the uncorrelated fading channel models for multi-carrier systems are their simple implementation in the frequency domain and the simple reproducibility of the simulation results.1.1.7Diversity The coherence bandwidth of amobile radio channel is the bandwidth over which the signal propagation characteristics are correlated and it can be approximated byThe channel is frequency-selective if the signal bandwidth B is larger than the coherence bandwidth.On the other hand, if B is smaller than , the channel is frequency nonselective or flat.The coherence bandwidth of the channel is of importance for evaluating the performance of spreading and frequency interleaving techniques that try to exploit the inherent frequency diversity Df of the mobile radio channel.In the case of multi-carrier transmission, frequency diversity is exploited if the separation of sub-carriers transmitting the same information exceeds the coherence bandwidth.The maximum achievable frequency diversity Df is given by the ratio between the signal bandwidth B and the coherence bandwidth,The coherence time of the channel is the duration over which the channel characteristics can be considered as time-invariant and can be approximated byIf the duration of the transmitted symbol is larger than the coherence time, the channel is time-selective.On the other hand, if the symbol duration is smaller than , the channel is time nonselective during one symbol duration.The coherence time of the channel is of importance for evaluating the performance of coding and interleaving techniques that try to exploit the inherent time diversity DO of the mobile radio channel.Time diversity can be exploited if the separation between time slots carrying the same information exceeds the coherence time.A number of Ns successive time slots create a time frame of duration Tfr.The maximum time diversity Dt achievable in one time frame is given by the ratio between the duration of a timeframe and the coherence time, A system exploiting frequency and time diversity can achieve the overall diversityThe system design should allow one to optimally exploit the available diversity DO.For instance, in systems with multi-carrier transmission the same information should be transmitted on different sub-carriers and in different time slots, achieving uncorrelated faded replicas of the information in both dimensions.Uncoded multi-carrier systems with flat fading per sub-channel and time-invariance during one symbol cannot exploit diversity and have a poor performance in time and frequency selective fading channels.Additional methods have to be applied to exploit diversity.One approach is the use of data spreading where each data symbol is spread by a spreading code of length L.This, in combination with interleaving, can achieve performance results which are given forby the closed-form solution for the BER for diversity reception in Rayleigh fading channels according to [40] Whererepresents the combinatory function,and σ2 is the variance of the noise.As soon as the interleaving is not perfect or the diversity offered by the channel is smaller than the spreading code length L, or MCCDMA with multiple access interference is applied,(1.22)is a lower bound.For L = 1, the performance of an OFDM system without forward error correction(FEC)is obtained, 9which cannot exploit any diversity.The BER according to(1.22)of an OFDM(OFDMA, MC-TDMA)system and a multi-carrier spread spectrum(MC-SS)system with different spreading code lengths L is shown in Figure 1-3.No other diversity techniques are applied.QPSK modulation is used for symbol mapping.The mobile radio channel is modeled as uncorrelatedRayleigh fading channel(see Section 1.1.6).As these curves show, for large values of L, the performance of MC-SS systems approaches that of an AWGN channel.Another form of achieving diversity in OFDM systems is channel coding by FEC, where the information of each data bit is spread over several code bits.Additional to the diversity gain in fading channels, a coding gain can be obtained due to the selection of appropriate coding and decoding algorithms.中文翻译 1基本原理这章描述今日的基本面的无线通信。

费恩曼物理学讲义第二卷 英文版

费恩曼物理学讲义第二卷 英文版

费恩曼物理学讲义第二卷英文版全文共10篇示例,供读者参考篇1Hey guys! Today I'm gonna talk about the second volume of "The Feynman Lectures on Physics" written by the super cool physicist Richard Feynman. This book is all about physics and it's gonna blow your mind!In this volume, Feynman talks about all kinds of cool stuff like electromagnetism, thermodynamics, and wave behavior. He explains things in a way that even I can understand, which is awesome! He starts off by talking about electric charges and how they interact with each other. It's like magic how they can attract or repel each other just because of their charges.Then he moves on to talk about magnets and how they work. Did you know that every magnet has a north and south pole? And when you put two magnets together, they either attract or repel each other depending on their poles. It's like they have invisible forces that make them move!Next, Feynman dives into thermodynamics which is all about heat and energy. He explains how heat moves from hot things tocold things and how we can use that to do work. It's like a big puzzle that he helps us put together.And finally, he talks about waves and how they behave. Waves are like ripples in water or sound moving through the air. He explains how they can interfere with each other and create cool patterns.Overall, this book is super interesting and fun to read. Feynman has a way of making complicated things simple and easy to understand. So if you're into physics or just want to learn more about how the world works, definitely check out "The Feynman Lectures on Physics"!篇2Title: Fun with Physics - Exploring Feynman Lectures on Physics Volume 2Hey everyone! Today I want to tell you all about this super cool book called "Feynman Lectures on Physics Volume 2". It's all about physics, which is basically the study of how things work in the world around us. This book is written by a super smart guy named Richard Feynman, who was a famous physicist.In this book, Feynman talks about lots of interesting stuff like electricity, magnetism, light, and even quantum mechanics. It may sound a bit complicated, but he explains everything in a really fun and easy-to-understand way. He tells stories, draws pictures, and uses simple language to help us understand even the most complex ideas.One of the coolest things Feynman talks about is electromagnetic waves. These are invisible waves of energy that travel through space and carry things like light and radio signals. Can you believe that the light we see every day is actually made up of these waves?Another fun thing he talks about is quantum mechanics, which is all about how tiny particles like atoms and electrons behave. It's like a whole new world where things can be in two places at once or disappear and reappear out of nowhere. It's so mind-blowing!So, if you're interested in learning more about how the world works and love a good challenge, I highly recommend checking out "Feynman Lectures on Physics Volume 2". It's a great way to have fun with physics and expand your knowledge about the universe. Who knows, maybe one day you'll be a famous physicist just like Richard Feynman!篇3Hey everyone, today I'm gonna tell you all about the second volume of Feynman's lectures on physics. It's super cool stuff, so let's dive right in!In this volume, Feynman talks about electromagnetism, optics, and the principles of conservation. He explains how electricity and magnetism are connected, and how light travels in waves. He also talks about how energy and momentum are always conserved in any physical process.One of the coolest things Feynman talks about is electromagnetic waves. These are waves that can travel through space without needing a medium, like air or water. He explains how these waves can be used for things like radio communication and x-ray imaging.Feynman also covers the laws of reflection and refraction, which explain how light bounces off surfaces and bends when it passes through different materials. He even talks about how rainbows are formed!Another important topic Feynman covers is the concept of symmetry in physics. He explains how certain physical laws remain the same even when you change the direction of time orthe position of objects. This idea of symmetry is a fundamental principle in modern physics.Overall, the second volume of Feynman's lectures on physics is full of fascinating ideas and concepts. It's a great read for anyone interested in learning more about the world around us. So, go check it out and expand your knowledge of the universe!篇4Hello everyone! Today I'm going to talk about the second volume of Feynman's Physics Lectures. It's super cool and interesting, just like the first volume! Professor Feynman explains all about electricity, magnetism, and light in this book.First, let's talk about electricity. Do you know what electricity is? It's like magic that makes things go zzzzt and light up! Professor Feynman teaches us all about electric charges, how they attract and repel each other, and how they flow through wires. He also tells us about circuits and how to use them to make cool things like lights and motors work.Next, let's talk about magnetism. Magnets are super fun to play with, right? Professor Feynman tells us all about how magnets work, how they attract and repel each other, and how they can make things move without touching them. He also talksabout the Earth's magnetic field and how it helps us find our way with a compass.Finally, let's talk about light. Light is what lets us see everything around us. Professor Feynman explains all about how light travels, how it can be bent and reflected, and how we see colors. He also talks about how light interacts with matter and how it can create amazing things like rainbows.So there you have it, the second volume of Feynman's Physics Lectures is full of amazing stuff about electricity, magnetism, and light. It's a great way to learn about the world around us and get excited about physics. I can't wait to read the next volume and learn even more cool stuff!篇5Hey guys! Today, I want to talk to you about the second volume of Richard Feynman's lectures on physics. It's super cool and has so much interesting stuff in it!In this book, Feynman talks about all kinds of things like electromagnetism, optics, thermodynamics, and more. He explains things in a really fun and easy-to-understand way that makes you want to learn more and more.One of the things I found really cool in this book is when Feynman talks about light and how it travels in waves. He explains it using really cool diagrams and examples that make it super easy to understand.Another thing I liked is when he talks about magnets and how they work. I always wondered why magnets stick together or push each other away, and Feynman explains it in a really fun and simple way that makes it easy to understand.Overall, I think this book is awesome and I would recommend it to anyone who wants to learn more about physics in a fun and easy way. It's definitely one of my favorite books and I can't wait to read the next volume!So, if you're looking for a fun and easy way to learn about physics, definitely check out Feynman's lectures. They're super cool and you'll learn a lot of awesome stuff!篇6Hi guys! Today I want to talk about the second volume of Richard Feynman's "Feynman Lectures on Physics". It's super cool and interesting, so let's dive in!In this book, Feynman covers a lot of topics like electromagnetism, optics, thermodynamics, and more. He explains things in a really fun and easy-to-understand way, so even if you're not a science genius, you can still learn a lot.One of the things Feynman talks about is electromagnetic fields. He explains how magnets and electric charges interact with each other, and how they create these invisible fields that surround them. It's like magic, but it's actually science!Feynman also talks about light and optics. He explains how light travels in waves, and how it can be bent and reflected by different materials. He even talks about things like lenses and mirrors, and how they can change the way light behaves.Another cool thing Feynman covers is thermodynamics. He talks about things like heat and energy, and how they move and change in different systems. It's really fascinating to learn about how things heat up and cool down, and how energy is transferred from one place to another.Overall, "Feynman Lectures on Physics" is a super fun and informative book that will teach you a lot about the world around you. So if you're curious about how things work, definitely check it out! Trust me, you won't be disappointed.篇7I'm really excited to tell you all about the second volume of "The Feynman Lectures on Physics"! It's packed full of amazing stuff that will make you love science even more.In this volume, you'll learn all about the amazing world of electromagnetism. That's a big word that means electricity and magnetism combined. Did you know that they're related to each other? It's crazy how the forces of electricity and magnetism work together to create all sorts of cool things in our world.You'll also get to dive into the world of optics, which is all about light and how it travels. Have you ever wondered why rainbows are so colorful, or how a lens helps you see things clearly? Well, you'll find out all about that in this volume.And if you're a fan of waves, you're in luck because this volume also covers the physics of waves. From sound waves to ocean waves, you'll learn all about how waves move and interact with each other. It's like taking a trip to the beach without even leaving your classroom!But don't worry, even though there's a lot of complicated stuff in this volume, Richard Feynman explains it all in a waythat's easy to understand. He's like a super smart scientist who also happens to be a really great teacher.So grab a copy of this book and get ready to be amazed by the wonders of physics! Who knows, you might even discover your inner scientist along the way.篇8Hey guys, have you ever heard of the famous physicist Richard Feynman? He's super cool and has a lot of amazing things to teach us about physics! Today, I'm going to tell you all about his second volume of lectures on physics.In the second volume of Feynman's lectures, he talks about all kinds of interesting stuff like electromagnetic fields, waves, and optics. He explains how light works and how it travels in waves. He also talks about how magnets work and how they create electromagnetic fields.Feynman even goes into detail about something called quantum mechanics, which is all about how tiny particles like electrons and photons behave. It's super interesting and kind of mind-blowing!One of the coolest things Feynman talks about in his lectures is how everything in the universe is connected through the laws of physics. He explains how electricity and magnetism are actually two sides of the same coin, and how they work together to create the world we live in.So, if you're interested in learning more about the amazing world of physics, definitely check out Feynman's second volume of lectures. It's full of cool experiments, mind-bending concepts, and tons of fun facts. Who knows, you might just discover your inner physicist!篇9Hey guys! Today I'm gonna talk about this super cool book called "The Feynman Lectures on Physics Volume 2". It's all about physics and stuff but don't worry, I'm gonna make it super fun to read!So, in this book, the famous physicist Richard Feynman talks about lots of different things like electricity, magnetism, and even light. He explains them in a really easy way so even kids like us can understand.One of the coolest things he talks about is electricity. He explains how electricity flows through wires and how it powersthings like lightbulbs and TVs. He even talks about how magnets work and how they can attract or repel each other.Feynman also talks about light and how it travels in waves. He explains how light can be reflected or refracted and how it creates colors. He even talks about how we see things and how our eyes work.There's so much cool stuff in this book that it's hard to cover it all. But trust me, if you're interested in science and physics, you'll love reading "The Feynman Lectures on Physics Volume 2".So there you have it, a little sneak peek into this awesome book. I hope you guys check it out and learn something new about the world around us. See you next time!篇10Title: Let's Learn Physics with Mr. Feynman!Hi everyone! Today we are going to talk about physics with the famous physicist Mr. Feynman. He is super smart and knows a lot about how things work in the world. So let's get started and learn some cool stuff together!First, let's talk about forces. Forces are things that can make objects move or stop moving. There are different types of forceslike gravity, friction, and magnetism. Gravity is what keeps us on the ground and pulls things downwards. Friction is what happens when objects rub against each other and slow down. Magnetism is when objects are attracted or repelled by magnets.Next, let's talk about energy. Energy is what makes things happen. There are different forms of energy like light, heat, and sound. Energy can change from one form to another, like when a light bulb turns electrical energy into light energy. Isn't that cool?Now, let's talk about motion. Motion is when objects change their position. Objects can move in different ways like straight, curved, or in a circle. And did you know that objects in motion stay in motion unless a force stops them? That's called inertia.Lastly, let's talk about electricity and magnetism. Electricity is what powers our devices like phones and computers. It flows through wires and circuits to make things work. Magnetism is what makes magnets stick together or push each other away. It's like magic, but it's actually science!So there you have it, a brief introduction to physics with Mr. Feynman. I hope you learned something new today and are excited to explore the world of science further. Remember, the world is full of wonders waiting to be discovered. Happy learning!。

约翰逊松·金属加工杰森-焊接砂烟盐号5粉末说明书

约翰逊松·金属加工杰森-焊接砂烟盐号5粉末说明书

Johnson Matthey Metal Joining Brazing Flux Johnson MattheyMetal Joining York Way, Royston, Hertfordshire, SG8 5HJ, UKTelephone:+44(0)1763253200Fax:+44(0)1763253168email:*****************: Tenacity™ No. 5 Flux PowderTenacity™ No.5 Flux Powder is a brazing flux suitable for use with silver brazing filler metals. It is active at 600˚C and is effective with alloys that melt below 850˚C.Tenacity™ No.5 shows good overheat resistance when compared to other silver brazing fluxes. This characteristic is useful when brazing stainless steel components for example, where because of its poor thermal conductivity there is a risk of overheating causing the flux to become exhausted and ineffective.Tenacity™ No.5 also shows an extended life at brazing temperature (time / temperature stability). This feature is important when brazing large assemblies in steel or copper for example, or wherever prolonged heating is necessary.Conforms to:EN 1045: FH10Working range: 600-900˚C Directions for UseTenacity™ No. 5 flux powder should be mixed with water and a few drops of liquid detergent to form a thick paste. Paste should then be brushed onto the joint surfaces before assembly. Further flux should then be applied externally either side of the joint mouth.It is good practice to mechanically clean and degrease the joint surface before applying flux. Heat slowly and evenly to thebrazing temperature, without local overheating. Use the flux as a temperature guide - it will become clear or opaque as brazing temperature is approached. If blackening of the flux occurs this is often a sign of insufficient flux, overheating or flux exhaustion. Flux Residue RemovalThe flux residues of this product are virtually insoluble in water. Immersion in a warm (>40˚C) 10% sodium hydroxide solution for 30 minutes followed by brushing in a stream of water is recommended. The residues are hard and will also respond well to mechanical removal methods such as grit blasting.Product Availability0.25kg plastic pots0.5kg plastic pots5kg plastic potsTenacity TM is a Johnson Matthey trademark.Johnson Matthey Plc cannot anticipate all conditions under which this information and our products or the products of other manufacturers in combination with our products will be used.This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is given in good faith, being based on the latest information available to Johnson Matthey Plc and is, to the best of Johnson Matthey Plc's knowledge and belief, accurate and reliable at the time of preparation. However, no representation,warranty or guarantee is made as to the accuracy or completeness of the information and Johnson Matthey Plc assumes no responsibility therefore and disclaims any liability for any loss, damage or injuryhowsoever arising (including in respect of any claim brought by any third party) incurred using this information. The product is supplied on the condition that the user accepts responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not be assumed. The text and images on this document are Copyright and property of Johnson Matthey.This datasheet may only be reproduced as information, for use with or for resale of Johnson Matthey products. The JM logo©, Johnson Matthey name© and product names referred to in this document aretrademarks of Johnson Matthey. Easy-flo® and Silver-flo® are registered to JM in the EU. Sil-fos™ is registered to JM in the UK and certain other countries but is marketed as Mattiphos™ in Germany and the USA.。

托福阅读真题及答案 PASSAGE 2

托福阅读真题及答案 PASSAGE 2

托福阅读真题及答案 PASSAGE 2选择出guo学习的人数越来越多,参加无疑是进入国外大学的一块敲门砖。

以下是网的关于托福阅读真题及答案:PASSAGE 2,供大家练习备考。

The geology of the Earth's surface is dominated by the particular properties of water. Present on Earth in solid, liquid, and gaseous states, water is exceptionally reactive. It dissolves, transports, and precipitates many chemical pounds and is constantly modifying the face of the Earth.Evaporated from the oceans, water vapor forms clouds, some of which are transported by wind over the continents. Condensation from the clouds provides the essential agentof continental erosion: rain. Precipitated onto the ground, the water trickles down to form brooks, streams, and rivers, constituting what are called the hydrographic work. This immense polarized work channels the water toward a single receptacle: an ocean. Gravity dominates this entire step in the cycle because water tends to minimize its potential energy by running from high altitudes toward the reference point, that is, sea level.The rate at which a molecule of water passes though the cycle is not random but is a measure of the relative sizeof the various reservoirs. If we define residence time asthe average time for a water molecule to pass through oneof the three reservoirs — atmosphere, continent, and ocean— we see that the times are very different. A water molecule stays, on average, eleven days in the atmosphere, one hundred years on a continent and forty thousand yearsin the ocean. This last figure shows the importance of the ocean as the principal reservoir of the hydrosphere but also the rapidity of water transport on the continents.A vast chemical separation process takes places during the flow of water over the continents. Soluble ions such as calcium, sodium, potassium, and some magnesium are dissolved and transported. Insoluble ions such as aluminum, iron, and silicon stay where they are and form the thin, fertile skin of soil on which vegetation can grow. Sometimes soils are destroyed and transported mechanically during flooding. The erosion of the continents thus results from two closely linked and interdependent processes, chemical erosion and mechanical erosion. Their respective interactions and efficiency depend on different factors.1. The word "modifying" in line 4 is closest in meaning to(A) changing(B) traveling(C) describing(D) destroying2. The word "which" in line 5 refers to(A) clouds(B) oceans(C) continents(D) pounds3. Aording to the passage , clouds are primarily formed by water(A) precipitating onto the ground(B) changing from a solid to a liquid state(C) evaporating from the oceans(D) being carried by wind4. The passage suggests that the purpose of the "hydrographic work" (line 8) is to(A) determine the size of molecules of water(B) prevent soil erosion caused by flooding(C) move water from the Earth's surface to the oceans(D) regulate the rate of water flow from streams and rivers5. What determines the rate at which a molecule of water moves through the cycle, as discussed in the third paragraph?(A) The potential energy contained in water(B) The effects of atmospheric pressure on chemical pounds(C) The amounts of rainfall that fall on the continents(D) The relative size of the water storage areas6. The word "rapidity" in line 19 is closest in meaning to(A) significance(B) method(C) swiftness(D) reliability7. The word "they" in line 24 refers to(A) insoluble ions(B) soluble ions(C) soils(D) continents8. All of the following are example of soluble ions EXCEPT(A) magnesium(B) iron(C) potassium(D) calcium9. The word "efficiency" in line 27 is closest in meaning to(A) relationship(B) growth(C) influence(D) effectiveness。

小学下册B卷英语第1单元全练全测(含答案)

小学下册B卷英语第1单元全练全测(含答案)

小学下册英语第1单元全练全测(含答案)英语试题一、综合题(本题有100小题,每小题1分,共100分.每小题不选、错误,均不给分)1.The park is ___ (beautiful/ugly).2.My dog loves to chase ______ (飞盘).3.What instrument has keys and is played by pressing?A. GuitarB. PianoC. ViolinD. Drums答案:B4.What is the name of the fairy tale character who leaves a glass slipper?A. Snow WhiteB. CinderellaC. Sleeping BeautyD. Little Red Riding Hood5. A __________ is a large area of natural beauty.6.My _____ (父亲) is my hero.7.My favorite teacher is _______ (名字). 她教我们 _______ (科目).8.What do we call the westernmost continent?A. AsiaB. AfricaC. North AmericaD. South America9.The _______ (The Great Migration) profoundly changed American demographics.10.My sister, ______ (我妹妹), loves to dance ballet.11.The __________ (历史的纪录片) provide visual representations.12.I have a favorite __________ (玩具类型) that is __________ (形容词).13.The manatee grazes on ________________ (水草).14.______ are found on the periodic table.15.What do you call the process of changing liquid to gas?A. MeltingB. FreezingC. EvaporationD. Condensation答案:C16.The ______ is known for her storytelling abilities.17. A chemical reaction releases energy in the form of ______.18._____ (vines) can cover fences and walls.19.What do you call the upper part of a tree?A. TrunkB. BranchC. CanopyD. Roots答案:C20.She has a ________ (passion) for helping others.21.They are ___ ice cream. (eating)22.Wildflowers grow without ______ (照顾).23.The children are _____ in the sandbox. (playing)24.What do we call a person who creates films?A. DirectorB. ProducerC. ActorD. Writer答案:A25.The atomic mass of an element is the average mass of its __________.26.The _______ (The New Deal) implemented programs to aid recovery during the Great Depression.27.The chemical symbol for nickel is ______.28.The invention of the telephone transformed ________ (沟通).29.What do we call a person who leads a group of people?A. LeaderB. FollowerC. GuideD. Member答案:A30.What is the opposite of 'happy'?A. SadB. JoyfulC. ExcitedD. Cheerful答案:A31.The __________ (历史的展望未来) influences policies.32.The ________ is a small animal.33.My sister loves to sing ____.34.I help my mom in the ________ after dinner.35.The weather is _______ (晴天) today.36.The dog is ______ (playing) with a stick.37.What do you call the main character in a story?A. AntagonistB. ProtagonistC. HeroD. Villain答案:B38.The __________ is a region known for its natural parks.39. A ______ is a positively charged particle in the nucleus of an atom.40.What is the capital of the British Virgin Islands?A. Road TownB. Virgin GordaC. AnegadaD. Jost Van Dyke答案:A41.I _____ (love) chocolate.42.What do we call a person who studies the causes and effects of diseases?A. EpidemiologistB. PathologistC. BiologistD. Pharmacologist答案:A43. A ______ is a bird that cannot fly but can run very fast.44.We will visit our ______ (grandparents) next week.45.What do you call a house made of ice?A. IglooB. TentC. CabinD. Mansion答案:A Igloo46.My friend is a _____ (艺术家) showcasing her portfolio.47.What is the name of the famous American author known for his short stories?A. Edgar Allan PoeB. Mark TwainC. Nathaniel HawthorneD. Ernest Hemingway48.What is the process of water turning into vapor?A. CondensationB. EvaporationC. PrecipitationD. Sublimation答案:B49.The _____ (basil) plant is great in pasta dishes.50.Which instrument has keys and is played with fingers?A. GuitarB. ViolinC. PianoD. Drum51. A physical change does not produce a new ______.52.What do you call a young gorilla?A. BabyB. CubC. KidD. Kit53.My friend is a talented __________ (画家).54.She likes to _____ (draw/write).55.My best friend is _______ (她的名字). 她总是很 _______ (形容词).56.What is the main ingredient in lemonade?A. WaterB. SugarC. LemonD. All of the above答案:D57.One of my favorite memories is when I __________. It was a special day because __________. I will always cherish that moment.58.The pH scale measures how _______ or basic a solution is.59. A ______ (种子库) preserves genetic diversity in plants.60.My ________ (玩具名称) helps me with my social skills.61.The ________ (温室效应) impacts climate.62. A substance that decreases the pH of a solution is called an _____.63.What is the term for the effect of gravity on time?A. Time DilationB. Gravitational TimeC. Temporal DistortionD. Space-Time Continuum64.My uncle loves __________ (音乐).65.My favorite animal is a ______ (金鱼) that swims beautifully.66.What do we call the process of converting a liquid into a solid?A. FreezingB. MeltingC. EvaporationD. Condensation67.The state of matter that has no fixed shape is __________.68.I found a _______ (小鸡) in the barn.69.The _______ is often used in landscaping designs.70.Which planet is known for its rings?A. EarthB. MarsC. JupiterD. Saturn71.The ______ is a type of plant that can survive in the desert.72.The ________ (兔子) hops around quickly and loves to eat carrots.73.The first human to orbit the Earth was ________ (尤里·加加林).74.My dad enjoys fishing at the ____ (lake).75. A _______ is an atom with an unequal number of protons and electrons.76.I can pretend to be a chef with my toy ________ (玩具名称).77.Light takes time to travel across the vastness of _______.78.I like to play ___ (cards).79.The _______ (小狼) howls at the moon during the night.80.The __________ can reveal the history of tectonic movements.81. A ____ is known for its ability to find food in the dark.82.Which planet has rings around it?A. EarthB. JupiterC. SaturnD. Venus答案:C83.Sedimentary rocks are formed from __________ materials.84.Gardening can be a rewarding ______ that connects people with nature. (园艺是一项有益的活动,可以将人们与自然联系起来。

Molecular lines in absorption recent results

Molecular lines in absorption recent results

a rXiv:as tr o-ph/9711184v117Nov1997Molecular lines in absorption:recent results Fran¸c oise Combes Observatoire de Paris,DEMIRM,61Av.de l’Observatoire F-75014Paris,France Tommy Wiklind Onsala Space Observatory,S-43992,Onsala,Sweden Abstract.Some recent results are presented about high redshift molec-ular absorption lines,namely about chemical abundances of elements,and in particular of water and molecular oxygen.Excitation temperatures of several molecules are found lower than the cosmic background temper-ature at the corresponding redshift z =0.88582in PKS1830-211,and interpretations are proposed.The radio flux monitoring of the two grav-itational images of PKS1830-211is presented over almost two years,but precise calibration is still preventing the determination of the time-delay without ambiguity.The high spectral resolution of radio observations allows to put constraints on the variation of the fine-structure constant over a large fraction of the Hubble time.1.Molecules unobservable from the ground at z =0Because of the atmospheric absorption in the H 2O and O 2lines,it is impossible to have a correct estimation of the abundances of theses two molecules in the local interstellar medium.The redshift allows us to get rid of the atmospheric absorption,and the highest column density line-of-sights are privileged targets to try to detect these fundamental molecules (bes &Wiklind 1996).1.1.WaterWe have chosen the absorbing cloud in front of B0218+357,where already opti-cally thick lines of CO,13CO and C 18O have been detected (Combes &Wiklind 1995).The optical depth of the CO(2-1)line was derived to be 1500.The red-shift is z =0.68466,and the fundamental ortho transition of water at 557GHz is redshifted to 331GHz into an atmospheric window.An attempt to observe water in emission at z =2.28has resulted in a tentative detection (Encrenaz et al.1993).According to models,the H 2O/H 2abundance ratio is expected between 10−7and 10−5(Leung et al.1984,Langer &Graedel 1989).Observations of isotopic lines,such as H 182O and HDO,or even H 3O +,have confirmed these ex-pectations.From the ground,water maser(/thermal?)emission at 183GHz hasbeen obtained by Cernicharo et al.(1994).However,it was thought until re-Figure 1.Spectrum of ortho–water in its fundamental line at557GHz,redshifted at331GHz,in absorption towards B0218+357.The line has the same width as the previously detected HCO+(2–1)andCO(2–1)lines.The velocity resolution is9.1,2.8and2.2km/s fromtop to bottom.All spectra have been obtained with the IRAM-30mtelescope,and normalised to the continuum level completely absorbed(33%of the total).cently that these abundances concerned only the neighbourhood of star-forming regions,such as the Orion hot core,where water ice is evaporated from grains. However,Cernicharo et al.(1997)detected with ISO water in absorption at 179µin front of SgrB2,and this revealed that cold water was ubiquitous.Our detection with the IRAM-30m of ortho-water in its fundamental line at 557GHz confirms this result.The line is highly optically thick,and has about the same width as the other optically thick lines detected in absorption in this cloud(seefigure1).If the excitation temperature was high(as in the Orion hot core),we would have expected to detect also the excited line at183GHz (redshifted at109GHz).An upper limit on this line gives us an upper limit on T ex of10-15K,and an estimation of the optical depth of the557GHz line of∼40000(Combes&Wiklind1997).This leads to an H2O/H2abundance ratio of 10−5,in the upper range of expected values.1.2.Molecular oxygenAs an element,oxygen is about twice as abundant as carbon(O/H∼8.5·10−4), meaning that at most half of the oxygen atoms can be used to make CO.The other half can be found in the form of atomic oxygen(OI),or molecules:O2, OH and H2O.Since OH and H2O are much less abundant than CO,in dense molecular clouds,we expect O2to be about as abundant as CO.Until recently, the upper limits on the O2/CO ratio was0.1,from observations of the isotopic line O18O and the direct O2in emission in remote starbursts.The upper limits obtained through absorption lines are more reliable,since they involve only one individual molecular cloud,where O2is not photo-dissociated(O2is expected to be much less ubiquitous than CO).We had already reported upper limits of O2/CO<1.3·10−2through IRAM-30m search of the424GHz and368GHz lines(Combes&Wiklind1995).We have improved these limits by observing the118.7GHz line at the Kitt Peak 12m(redshifted at70.5GHz),and the56.2GHz line at Green-Bank43m and Nobeyama45m(redshifted at33.4GHz).The new limit is O2/CO<2·10−3at 1σ(Combes et al.1997).There could be several explanations to this low oxygen abundance:•either the C/O abundance ratio in the gas phase is higher than1.Then all the oxygen atoms are used up in the CO molecules,the O2/CO ratio decreases exponentially with(C/O−1).This means that the oxygen is frozen into grains(mainly under the form of water ice or silicates).•the steady-state chemistry is never reached,and because of turbulence, only time-dependent models should apply(time-scales of less than1.3·105 yr).The oxygen is therefore under the OI form,even in dense molecular clouds.•due to chemical bi-stability,there exists two possible phases of the interstel-lar medium,the LIP and HIP(low and high ionization phases respectively,e.g.Le Bourlot et al.1993,1995).In the HIP,the O2/CO abundance canbe much lower than in the LIP.It remains to be explained why the HIP should be predominant in the ISM.Also in this model,the abundances of other elements,such as HCN or HCO+is not reproduced within orders of magnitude.2.Chemical abundancesOne of the aim of this work is to pinpoint evolution with redshift of the molecu-lar abundances,which could be different from the local ones because of different element abundances,different physical environment(temperature,densities,ra-diationfield).Many molecules have been detected at high redshift in absorption, HCO+,HCN,HNC,CO,CS,CCH,CN,H2O,N2H+,H2CO,C3H2,HC3N and isotopes;it is possible to try now a statistical comparison of abundance ratios between these detections and their analogues in the Milky Way.It is important to inter-compare absorption studies(and not emission),since there are spe-cial biases associated to each technique(absorption traces preferentially diffuseFigure 2.Column density of HCN plotted versus column densitites of HCO +,HNC and CS.The open circles represent Galactic diffuse clouds (Lucas &Liszt 1994,1996),filled circles represent data from Cen A (Wiklind &Combes 1997a)and open triangles represent ab-sorption data towards SgrB2(Greaves &Nyman 1996).The filled star represents our absorption data for PKS1413+135,open stars from B31504+377at z=0.673(Wiklind &Combes 1996b)and the filled triangle PKS1830–210at z=0.886(Wiklind &Combes 1996a).The full–drawn line in N (HCN )vs.N (HNC )is a linear fit to the data,showing how the HCN/HNC ratio increases with decreasing HCN column density.gas).Lucas &Liszt (1994,1996)have made a survey of molecular absorptions in front of extragalactic radio sources;they find surprising abundances,for in-stance HCO +one or two orders of magnitude larger than expected,that could be explained by turbulence-induced chemistry (Hogerheijde et al.1995,Falgar-one et al.1995).Curiously,they find only diffuse clouds in their survey,but this might be due to a bias towards high latitudes and unobscured line-of-sights.Absorptions towards the Galactic Center (Greaves &Nyman 1996)or in CenA (Wiklind &Combes 1997a)correct this bias,in view of a comparison with high redshift absorptions (which have sometimes high column densities).A sample of the results can be seen in figure 2,where abundances of HCO +,HCN,HNC and CS are intercompared.The main striking point is that the high-redshift abundances are perfectly compatible with the local ones.In partic-ular,the well known HCN/HNC variations with physical conditions is retrieved (Irvine et al.1987).In fact,there are more variations from cloud to cloud in the Milky Way than variations due to evolution.Changes in the abundances at large distances are within the dispersion of local variations,preventing any effects of evolution to be seen.3.Time-delay in PKS1830-211In the previous talk,Tommy has shown how the IRAM interferometer data have confirmed that only one of the two gravitational images is absorbed by molecular clouds at the main velocity (V=0or z =0.88582,Wiklind &Combes 1997c).Figure3.Results of the weekly monitoring of the quasar PKS1830-211in the HCO+(2-1)line at z=0.88582.The full and dashed linesrepresent observations done at the IRAM-30m and SEST-15m tele-scopes respectively.From bottom to top the curves are the measure ofthe continuum level successively of image B,A and total.An intrinsiclevel increase appears from1996to1997,in the two images.The SW image is entirely covered at V=0,which is also compatible with the BIMA data(Frye et al.1997),while the NE image is absorbed by clouds at V∼-150km/s(may be only partially).Since the absorption at V=0is optically thick,its depth is a good indicator of the continuum level of the SW image,while the total continuum detected with a single dish(without resolving the twoimages)is a measure of the sum of the NE+SW continuum levels.By a single observation,it is therefore possible to derive separately the continuum of both images.Through a monitoring of the source in its HCO+(2-1)absorption,we can derive the light curves of the NE and SW images,and try to determine the time-delay.We have carried out a weekly monitoring since the beginning of1996with the IRAM-30m and SEST-15m telescopes,the results are plotted infigure3. The SEST data have been normalised to be compared with the IRAM ones, both are pretty compatible.However,it is difficult to derive precisely the time-delay,since the intrinsic variations of the quasar have not been of high amplitude 1996-7,and the atmospheric calibrations introduce unwanted noise in the light curves.The expected time-delay is of the order of a few weeks.Another caveat, in view of determining the Hubble constant,is that a second lens at z=.19 could add some amplification or shearing effect(Lovell et al.1996).4.Cosmic background temperatureWhen the absorption occurs in relatively diffuse gas,where the density is notenough to excite the rotational ladder of the molecules,the excitation tempera-ture is close to the cosmic background temperature T bg,and could be a way to check its variation with redshift.This is the case of the gas absorbed in frontof PKS1830-211,where T ex∼T bg for most of the molecules.The measurement of T ex requires the detection of two nearby transitions.When the lower ones is optically thick,only an upper limit can be derived for T ex.Ideally,the twotransitions should be optically thin,but then the higher one is very weak,and long integration times are required.The results obtained with the SEST-15m and IRAM-30m are plotted in figure4.Surprisingly,the bulk of measurements points towards an excitation temperature lower than the background temperature at z=0.88582,i.e.T bg= 5.20K.This could be due to a non-LTE excitation.In fact,the excitation tem-perature is not the same for each couple of levels considered.If the effect of collisional excitations could be neglected,the levels would be in radiative equi-librium with the black body at T bg(the time-scale for this,of the order of A−1, is less than a few years years for all molecules).But collisions tend to excite the lower levels at a higher temperature(since T kin>T bg).The competition between the two processes is traced by the C/A ratio(collisions versus spon-taneous rates),which is non-negligible only for thefirst level,at low density. This will populate the J=1level a little bit higher with respect to the J=0 than expected from radiative equilibrium at T bg.The consequence is that the T ex(1-0)will be higher than T bg but T ex(2-1)will be lower than T bg.Since the T ex measured infigure4do not involve the fundamental levels(the corre-sponding transitions,in the cm domain,would be optically thick),this could be the explanation.A detailed non-LTE model should be built to confirm this hypothesis.5.Variation offine-structure constantThe high spectral resolution of heterodyne techniques,the narrowness of ab-sorption lines and their high redshift make these measurements favorable to try to refine the constraints on the variation of coupling constants with cos-mic time,variations that are predicted by for instance the Kaluza-Klein and superstring theories.By comparing the HI21cm line(Carilli et al.1992,1993) with rotational molecular lines,one can constrain the variations ofα2g p,αbe-ing thefine-structure constant,and g p the proton gyromagnetic ratio.Also,by intercomparison of rotational lines from different molecules,one can test the in-variance of the nucleon mass m p,since the frequencies are affected by centrifugal stretching.Recent works on these lines have considerably improved the previous lim-its(e.g.Potekhin&Varshalovich1994).By comparing various optical/UV lines(of H2,HI,CI,SiIV)in absorption in front of quasars,Cowie&Songaila (1995)constrained the variation ofα2g p m e/m p to4·10−15/yr.Varshalovich et al.(1996)from radio lines come to a limit of variation ofα2g p of8·10−15/yr. Drinkwater et al.(1997)by a more careful analysis of the same data conclude toFigure 4.Measure of the excitation temperatures for severalmolecules shown in abcissa,from two of their rotational transitions.When the lower transition is optically thick,only an upper limit isderived.The horizontal dash line is the cosmic background temper-ature expected from the big-bang at the redshift of the absorber forPKS1830-211,i.e.z=0.88582.5·10−16/yr.We have also derived a limit from PKS1413+135and PKS1830-211 data of∆z/(1+z)<10−5,which yield a corresponding limit of2·10−16/yr (Wiklind&Combes1997b).However,geophysical constraints are in fact supe-rior to all astrophysical ones.Damour et al.(1997)have recently come up with a limit of5·10−17/yr onαfrom the naturalfission reactors which operated about 2·109yr ago at Oklo(Gabon).These results were obtained through analysis of the neutron capture cross section of Samarium,in the Oklo uranium mine.Notice that we have reached an intrinsic maximum of precision with the astrophysical technique,since the limitation comes from the hypothesis that the various lines compared come from the same material,at exactly the same Doppler velocity along the line-of-sight.This hypothesis is obviously wrong when comparing HI and molecular lines;it is also wrong while intercomparing molecules,or even within lines of the same molecule,since opacity depends on excitation conditions which vary along the line of sight for each transition. ReferencesCarilli,C.L.,Perlman E.S.,Stocke J.T.1992,ApJ400,L13Carilli,C.L.,Rupen,M.P.,Yanny,B.1993,ApJ412,L59Cernicharo,J.,Gonz´a lez–Alfonso,E.,Alcolea,J.,Bachiller,R.,&John,D.1994, ApJ432,L59Cernicharo,J.,et al.1997,A&A323,L25Combes,F.,Wiklind T.1995,A&A303,L61Combes F.,Wiklind T.,1996,in Cold Gas at High Redshift,eds.M.N.Bremer, P.van der Werf,H.J.A.R¨o ttgering,C.L.Carilli,Kluwer Academic Pub., p.215Combes,F.,Wiklind T.1997,ApJ486,L59Combes F.,Wiklind T.,Nakai N.:1997,A&A327,L17Cowie L.L.,Songaila A.:1995,ApJ453,596Damour T.,Dyson F.:1997,Nucl.Phys.B.in press(hep-ph/9606486) Drinkwater M.J.,Webb J.K.,Barrow J.D.,Flambaun V.V.:1997,in”Structure and Evolution of the IGM from QSO Absorption Line Systems”IAP, paris,ed.P.Petitjean&S.Charlot,p.Encrenaz P.J.,Combes F.,Casoli,F.,Gerin,M.,Pagani,L.,Horellou,C.,& Gac,C.1993,A&A273,L19Falgarone E.,Pineau des Forˆe ts G.,RoueffE.:1995,A&A300,870Frye B.,Welch W.J.,Broadhurst T.:1997,ApJ478,L25Greaves J.S.,Nyman L.–˚A.,1996,A&A305,950Hogerheijde M.R.,de Geus E.J.,Spaans M.,van Langevelde H.J.,van DishoeckE.F.,1995,ApJ441,L93Irvine W.M.,Goldsmith P.F.,Hjalmarson A.:1987,in”Interstellar Processes”, eds. D.J.Hollenbach&H.A.Thronson,Reidel Publishers,ASSL,Pro-ceedings,p.561Langer,W.D.,&Graedel,T.E.1989,ApJS69,241Le Bourlot J.,Pineau des Forˆe ts G.,RoueffE.,1995,A&A297,251Le Bourlot J.,Pineau des Forˆe ts G.,RoueffE.,1993,ApJ416,L87Leung,C.M.,Herbst,E.,&Huebner,W.F.1984,ApJS56,231Lovell,J.E.J.,Reynolds,J.E.,Jauncey D.L.,et al.1996,ApJ472,L5Lucas R.,Liszt H.S.:1994,A&A282,L5Lucas R.,Liszt H.S.:1996,A&A307,237Potekhin A.Y.,Varshalovich D.A.:1994,A&AS104,89Varshalovich D.A.,Panchuk V.E.,Ivanchik A.V.:1996,Astron.Lett.22,6 Wiklind,T.,Combes,F.1996a,Nature,379,139Wiklind,T.,Combes,F.1996b,A&A315,86Wiklind,T.,Combes,F.1997a,A&A324,51Wiklind,T.,Combes,F.1997b,A&A in pressWiklind,T.,Combes,F.1997c,ApJ in press。

Alcohol

Alcohol

No, sorry there isn't one. The general advice is to drink plenty of water, possibly even a sports drink to rebalance those electrolytes and go back to bed.
Dehydration

Alcohol is a diuretic, which makes you wee more. In fact, you lose far more water in your urine than you are taking in the drink itself. Dehydration causes the brain to shrink away from the skull slightly. This triggers pain sensors on the outside surface of your brain.
When You’re Plastered
There are plenty of words to describe it: bladdered, slaughtered, mullered, legless or as drunk as a skunk. Call it what you will, if you keep drinking beyond the early warning signs you're heading for trouble - trouble focussing, trouble speaking, trouble keeping upright.For that classic sitcom moment, the thing to do at the end of the evening is fall off the barstool. Falling over is a common mistake when drunk because alcohol affects the cerebellum, the part of the brain that controls fine movements. If finding the end of your nose with your index finger is difficult, you know your cerebellum has been affected.
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where ∆M denotes the Laplacian operator on (M, g ) with the given metric g = (gαβ ), (g αβ ) is the inverse matrix of (gαβ ) and Γi jk are the Charistoffel symbols of the target manifold (N, h). We are interested in the case that target manifolds are K¨ ahler manifolds. It is a straightforward verification that Schr¨ odinger flow of maps from an Euclidean n 2 3 n-space R to the 2-sphere S ֒→ R is the eq.(1) (for example see [5], [15]) and the Schr¨ odinger flow of maps from an Euclidean n-space Rn to the hyperbolic 2-space H 2 ֒→ R2+1 is nothing else than Eq.(2) ([9]) for general n. The main object in the study of Schr¨ odinger flows is , of course, the solvability of the corresponding Cauchy or initial-boundary value problem and its solutions’ behaviors. However, comparing to those of heat flows or wave maps [31], this study is still at the beginning stage. In the case dimM = 1, the global existence of the Cauchy problem of the Schr¨ odinger flow of maps from R1 to S 2 was known in soliton theory. In 1999, Terng and Uhlenbeck showed the global of the Cauchy problem of the Schr¨ odinger flow of maps from 1 R to a complex compact Grassmannian in [34]. Chang, Shatah and Uhlenbeck proved in [5] the global existence and uniqueness of smooth solution to the Cauchy problem of Schr¨ odinger flow of maps from R1 to a compact Riemainn surface. It is conjectured (see, for example, [14]) that the Cauchy problem of Schr¨ odinger flows exists globally and uniquely whenever dimM = 1 and the target manifold N is a compact K¨ ahler manifolactive type: qt + qxx + 2|q |2q = 0. However, the nonlinear Schr¨ odinger equation of attractive and repulsive types have some different dynamical properties (e.g., the nonlinear Schr¨ odinger equation of attractive type has bright soliton solutions but no dark soliton solutions and, meanwhile, the nonlinear Schr¨ odinger equation of repulsive type has dark soliton solutions but no bright soliton solutions (see [24], [17])). The above results indicate that the Heisenberg model and the Minkowski Heisenberg model also have some different dynamical behaviors. It is very interesting to display different dynamical behaviors between the generalized Heisenberg models (1) and the generalized Minkowski Heisenberg models (2). The generalized Heisenberg model (1) and Minkowski Heisenberg model (2) are special cases of the so-called Schr¨ odinger flows ([18], [15], [34], [9]) or Schr¨ odinger maps ([5], [22], [28]) in geometry. Schr¨ odinger flow of maps from a Riemannian manifold (M, g ) to a symplectic manifold (N, ω ) is defined to be the (infinite dimensional) Hamiltonian system of the Hamiltonian function being the energy function E (u) = M |∇u|2dvg on the mapping space C k (M, N ) for some k > 0. More explicitly, the Schr¨ odinger flow of map u : M → N is expressed as the following evolution system: u t = J (u )τ (u ), where J is an almost complex structure on N which is compatible with the symplectic form ω of N (in other words, h(·, ·) = ω (·, J ·) is a Riemannian metric on N ) and τ (u) is the tension field of the map u, in local coordinates, τ l (u) = ∆M ul + Γl jk ∂uj ∂uk αβ g , ∂xα ∂xβ l = 1, · · · , dimN,
On Schr¨ odinger Flows to the Hyperbolic 2-Space
arXiv:math/0312028v2 [math.DG] 26 May 2004
Qing Ding
Abstract More recently, the local well-posedness of the Cauchy problem of the Schr¨ odinger 2 2 flow of maps from R to H , the hyperbolic 2-space, was proved in [28]. In this paper, we display a blow-up result of solutions to such a Schr¨ odinger flow. This shows a widely believed assertion that solutions to Schr¨ odinger flows may blow up in finite time in general when the dimensions of starting manifolds are greater than 2 ([14]).
I. Introduction
The Heisenberg model for a continuous ferromagnetic spin system with classical spin vector u = (u1 , u2 , u3 ) ∈ S 2 ֒→ R3 (see, for example, [27], [29] or [5]), i.e., ut = u×∆Rn u, x ∈ R n , n = 1, 2 , 3 , (1)
has been generalized to each Hermitian symmetric spaces (see for example [19], [34]). The followings are dual versions of Eq.(1) (see [28] and [22]), ˙ ∆Rn s, st = s× x ∈ R n , n = 1, 2 , 3 , (2)
2 2 where s = (s1 , s2 , s3 ) ∈ H 2 = {(s1 , s2 , s3 )||s|2 = s2 → R2+1 is a 1 + s2 − s3 = −1, s3 < 0} ֒ ˙ denotes the pseudospin vector in a unit sphere of the Minkowski 3-space R2+1 , and × 2+1 cross product in R (see [9]). When n = 1, Eq.(2) is called the Minkowski Heisenberg model in [9] and [10]. So, like the name, generalized Heisenberg models, for Eq.(1) with n ≥ 2, we will call Eq.(2) the generalized Minkowski Heisenberg models when n ≥ 2. We 2 2 would like to point out that there are two components of the surface s2 1 + s2 − s3 = −1 in R2+1 , i.e., s3 > 0 and s3 < 0. In this paper, without loss of generality, we shall fix H 2 with the component of s3 < 0, unless otherwise stated. When n = 1, Eq.(2) is integrable and it was proved in [9] that Eq.(2) with n = 1 is gauge equivalent to the nonlinear Schr¨ odinger equation of repulsive type: qt + qxx − 2|q |2q = 0 which is an important equation in quantum dynamics and nonlinear optics (see [17]). This is the dual result of the well-known statement in [38], which says that the Heisenberg model (i.e., (1) with n = 1) is gauge equivalent to the nonlinear Schr¨ odinger
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