第1章 气体
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第1章气体
一、单选题
1、某气体AB,在高温下建立下列平衡∶AB(g)==A(g)+B(g).若把1.00mol此气体在T=300K,P=101 kPa下放在某密闭容器中,加热到600K时,有25.0%解离。此时体系的内部压力(kPa)为( )
A. 253 B. 101 C.50.5 D.126
2、一敞口烧瓶在7℃时盛满某种气体,欲使1/3 的气体逸出烧瓶,需加热到()
A.100℃B.693 ℃C.420 ℃D.147 ℃
3、实际气体和理想气体更接近的条件是( )
A.高温高压 B. 低温高压 C. 高温低压 D. 低温低压
4、A,B两种气体在容器中混合,容器体积为V,在温度T下测得压力为P,V A ,V B 分别为两气体的分体积,P A ,P B 为两气体的分压,下列算式中不正确的一个是( )
A. PV A = n A RT
B. P A V A =n A RT
C. P A V= n A RV
D. P A (V A+V B )= n A RT
5、某容器中加入相同物质的量的NO和Cl2,在一定温度下发生反应:
NOCl(g)。平衡时,各物种分压的结论肯定错误的
NO(g)+1/2Cl
是()
A. P(NO)=P(Cl2)
B. P(NO)=P(NOCl)
C. P(NO)
D. P(NO)>P(NOCl)
6、The height of a column of liquid supported by atmospheric pressure is inversely
proportional to the density of the liquid. Mercury has a density of 13.6 g/mL. How high a column of water (density = 1.00 g/mL) would be supported by an atmospheric pressure of 0.876 atm? ( )
A. 9.05×103 mm
B. 1.03×104 mm
C. 49.0 mm
D. 11.9 mm
7、If you purchase a balloon filled with helium and take it outside on a cold day, you will notice that it shrinks and becomes less buoyant. What gas law explains this observation? ( )
A. Boyle's
B. Charles's
C. Avogadro's
D. Graham's
8、A sample of gas occupies 10.0 L at 50°C. Assuming that pressure is constant, what volume will the gas occupy at 100°C? ( )
A. 10.0 L
B. 20.0 L
C. 11.5 L
D. 5.0 L
9、What is the Charles's law constant (in L/K) for 200 mg of carbon dioxide at 600 mm pressure? ( )
A. 4.73 10–4 L/K
B. 5.64 10–3 L/K
C. 42.0 L/K
D. 2.11 103 L/K
10、At a given temperature and pressure, which gas occupies the smallest volume per unit mass? ( )
A O2 B. Ar C. CO2 D. Xe
11、At what temperature (in °C) will 25.0 g of carbon dioxide (at 1.00 atm) occupy.
( )
A. 188°C B 461°C C. –263°C D. –270°C
12、What is the molar mass of a gas that has a density of 3.11 g/L at 100°C and 1.50 atm pressure? ( )
A. 0.152 g/mol
B. 95.2 g/mol
C. 17.0 g/mol
D. 63.5 g/mol
13、What volume of N2 gas would be produced by the decomposition of 35.0 g NaN3 solid? (Assume that the gas is produced at 1.00 atm pressure and 150°C.) ( )
A 28.0 L B. 9.95 L C. 18.7 L D. 56.1 L
14、At what temperature would CO2 gas have the same average molecular speed as O2 gas has at 400 K? ( )
A. 250 K
B. 550 K
C. 400 K
D. 600K
15、How much faster does nitrogen escape from the balloon than oxygen? ( )
A. 1.07 times faster
B. 1.14 times faster
C. 0.875 times as fast
D. 0.935 times as fast
二、判断题(判断下列各项叙述是否正确,对,打“√”;错,打“×”。)
1、与理想气体相比,真实气体的相互作用力偏小。(×)
2、总压100Kpa的某气含A与B两种气体,A的摩尔分数为0.20,则B的分压