量子力学 氢原子

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光谱

氢原子的库仑势和能级

氢原子的定态波函数可表为径

向部分和角度部分的乘积。

主量子数

轨道量子数

磁量子数

简并度

基态(1,0,0)

电子径向分布的概率密度()()22

nl nl w r R r r =

A. an electron in a 4p state is always farther from the center of the atom than is an electron in a 2p state.

B. an electron in a 2p state can be found at the atom’s center.

C. a 3p state has 3 units of orbital angular momentum.

D. none of the above is true.

This illustration shows radial probability distribution functions for three hydrogen-atom wave functions, plotted versus r/a (r = distance from the center of the atom and a = 0.0529 nm). It follows that

A. an electron in a 4p state is always farther from the center of the atom than is an electron in a 2p state.

B. an electron in a 2p state can be found at the atom’s center.

C. a 3p state has 3 units of orbital angular momentum.

D. none of the above is true.

This illustration shows radial probability distribution functions for three hydrogen-atom wave functions, plotted versus r/a (r = distance from the center of the atom and a = 0.0529 nm). It follows that

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